DE2448716B2 - HAND WASH PASTE - Google Patents

HAND WASH PASTE

Info

Publication number
DE2448716B2
DE2448716B2 DE19742448716 DE2448716A DE2448716B2 DE 2448716 B2 DE2448716 B2 DE 2448716B2 DE 19742448716 DE19742448716 DE 19742448716 DE 2448716 A DE2448716 A DE 2448716A DE 2448716 B2 DE2448716 B2 DE 2448716B2
Authority
DE
Germany
Prior art keywords
mixture
hand washing
paste
reducing
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19742448716
Other languages
German (de)
Other versions
DE2448716A1 (en
DE2448716C3 (en
Inventor
Heinz Dipl.-Chem. 5600 Wuppertal Wallrath
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boehringer Ingelheim Pharma GmbH and Co KG
Original Assignee
Dr Karl Thomae GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dr Karl Thomae GmbH filed Critical Dr Karl Thomae GmbH
Priority claimed from DE19742448716 external-priority patent/DE2448716C3/en
Priority to DE19742448716 priority Critical patent/DE2448716C3/en
Priority to IT51360/75A priority patent/IT1047535B/en
Priority to AT736275A priority patent/AT342173B/en
Priority to DK451775A priority patent/DK152377C/en
Priority to CH1313675A priority patent/CH616702A5/en
Priority to IE2219/75A priority patent/IE43304B1/en
Priority to NO753437A priority patent/NO142531C/en
Priority to BE160864A priority patent/BE834410A/en
Priority to NLAANVRAGE7511930,A priority patent/NL180851B/en
Priority to FR7531131A priority patent/FR2287506A1/en
Priority to GB41671/75A priority patent/GB1501942A/en
Priority to LU73570A priority patent/LU73570A1/xx
Priority to FI752827A priority patent/FI58512C/en
Priority to SE7511412A priority patent/SE417980B/en
Priority to ES441719A priority patent/ES441719A1/en
Publication of DE2448716A1 publication Critical patent/DE2448716A1/en
Publication of DE2448716B2 publication Critical patent/DE2448716B2/en
Publication of DE2448716C3 publication Critical patent/DE2448716C3/en
Application granted granted Critical
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0042—Reducing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Veterinary Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Devices For Medical Bathing And Washing (AREA)

Description

Die vorliegende Erfindung betrifft eine neue Handwaschpaste, die vorzugsweise zum Entfernen von Farbverschmutzungen geeignet ist, sowie ein Verfahren zu ihrer Herstellung.The present invention relates to a new hand washing paste, which is preferably used for removing Paint soiling is suitable, as well as a method for their production.

In der deutschen Patentschrift 10 31460 wird erstmals eine Handwaschpaste beschrieben, bei welcher das Netzmittel erst im Augenblick der Anwendung gebildet wird. Bei dieser wird die der waschaktiven Substanz zugrunde liegende Säure in einfacher Weise auf Grund »hrer öllöslichkeit in eine ölphase eingearbeitet Zum Beispiel läßt sich die auf Grund einer Kondensation von Fettsäure mit Sarkosin erhaltene Säure in ein natürliches Pflanzenöl wie Rizinusöl einarbeiten, wobei zur Konsistenzverbesserung noch Metallseifen zugefügt werden können. In diese Grundlage läßt sich nun ein Gemisch aus Soda, Natriumdithionit und Bimssteinpulver einarbeiten. Diese anorganischen Grundstoffe werden von der ölphase derart umgeben, daß eine Reaktion mit der Säure unter Salzbüdung nicht möglich ist Selbst geringe Wasseranteile werden in einer derartigen Weise emulgiert, daß auch sie keinen vorzeitigen Abiäüf der Reaktion bewirken. Beim Aufbringen dieser Paste auf die Hände und Zugabe von Wasser setzt dann erst Jer Neutralisationsvorgang unter Bildung des wirksamen Netzmittels wie auch der Entwicklung von Schwefeldioxid ein.In the German patent 10 31460 is for the first time a hand washing paste described in which the wetting agent is only used at the moment of use is formed. In this case, the acid on which the washing-active substance is based is removed in a simple manner incorporated into an oil phase due to its oil solubility For example, that obtained due to condensation of fatty acid with sarcosine Incorporate acid into a natural vegetable oil such as castor oil, while still improving the consistency Metal soaps can be added. A mixture of soda and sodium dithionite can now be added to this base and work in pumice stone powder. These inorganic raw materials are surrounded by the oil phase in such a way that that a reaction with the acid under salt formation is not possible. Even small amounts of water are in emulsified in such a way that they too do not cause the reaction to stop prematurely. At the Applying this paste to the hands and adding water then starts the neutralization process with the formation of the effective wetting agent as well as the evolution of sulfur dioxide.

Es wurde nun überraschenderweise gefunden, daß die bleichende und somit die reinigende Wirkung bei einer Waschpaste ähnlicher Zusammensetzung, wie in der Deutschen Patentschrift 10 31460 beschrieben, die beispielsweise Butytglykol, Fettsäurealkyzoiamid, nichtionogener Emulgator, Hexylenglykol, Pine-Öl, Lanolin, Triäthanolamin, Talkum, pyrogene Kieselsäure, Bimsmehl und ein wasserfreies Reduktionsmittel wie -Natriumdithionit enthält, dadurch wesentlich gesteigert wird, daS ihr gleichzeitig als Oxidationsmittel granuliertes, mit Silikonö! überzogenes Natriumperborat beigemischt wirdIt has now surprisingly been found that the bleaching and thus the cleaning effect in a Washing paste of similar composition, as described in German Patent 10 31460, the for example butyte glycol, fatty acid alkyzoiamide, nonionic Emulsifier, hexylene glycol, pine oil, lanolin, triethanolamine, talc, fumed silica, pumice powder and contains an anhydrous reducing agent such as sodium dithionite, which is significantly increased that your granulated, with silicone oil! Coated sodium perborate mixed in will

Das Natriumperborat-Granulat hat vorzugsweise eine Teilchengröße, die der des verwendeten Bimssteins entspricht und in der Größenordnung von 30 bis 60 μ liegt (DIN-Normgröße ca. G V2). Es ist erforderlich,The sodium perborate granules preferably have a particle size that of the pumice stone used corresponds and is in the order of 30 to 60 μ (DIN standard size approx. G V2). It is necessary,

»dieses Natriumperborat-Granulat zuerst mit Silikonöl zu vermischen, wobei die Gewichtsverhältnisse Natri-»These sodium perborate granules first with silicone oil to mix, the weight ratios of sodium

S iimperborat zu Silikonöl zwischen 2 zu 1 und 4 zu 1 schwanken können. Diese Mischung wird dann mit der zweiten Mischung, bestehend aus einem wasserfreien Netzmitte!, einem Reduktionsmittel und den übrigen, oben angegebenen Bestandteilen, innig vermengt Als Reduktionsmittel eignen sich beispielsweise Brenzkatechin, Natriumsulfit- oder bisulfit, insbesondere aber NatriumdithionitS iimperborate to silicone oil between 2 to 1 and 4 to 1 can fluctuate. This mixture is then mixed with the second mixture consisting of an anhydrous Netzmitte !, a reducing agent and the other components specified above, intimately mixed as Reducing agents are, for example, pyrocatechol, sodium sulfite or bisulfite, but in particular Sodium Dithionite

In dieser so hergestellten Paste kann das Reduktionsmitte! nicht mit dem Oxdationsmittel Natriumperborat reagieren, diese Paste ist unbeschränkt lagerfähig, sie verliert auch nach langer Lagerzeit nicht ihre reduzierenden und oxidierenden Eigenschaften. Wird diese Paste zum Waschen benutzt, so tritt zuerst die reduzierende und, hiervon zeitiicL verzögert, dieIn this paste produced in this way, the reducing agent! not with the oxidizing agent sodium perborate react, this paste can be stored indefinitely, it does not lose its reducing properties even after a long period of storage and oxidizing properties. If this paste is used for washing, the first step is the reducing and, of this, time delayed, the

μ oxidierende Wirkung in den Vordergrund.μ oxidizing effect in the foreground.

Es war zu erwarten, daß beim Waschprozeß durch die lösende Wirkung des Wassers, verstärkt durch die Wirkung des Netzmittels, das Reduktionsmittel in erster Linie mit dem Oxidationsmittel reagiert, wobei sich dann beide Stoffe gegenseitig neutralisieren und damit für die reinigende bzw. bleichende Wirkung auf die Haut oder das Gewebe ausfallen. Es hat sich tatsächlich aber gezeigt, daß beim V/aschprc/eß zuerst das Reduktionsmittel auf den zu reinigenden Gegenstand einwirkt und erst später, etwa nach 2 bis 5 Minuten, auch das Oxidationsmittel voll wirksam wirdIt was to be expected that during the washing process by the dissolving effect of the water, reinforced by the Effect of the wetting agent, the reducing agent reacts primarily with the oxidizing agent, whereby then both substances neutralize each other and thus for the cleansing or bleaching effect on the skin or the fabric will fail. It actually did though shown that in the case of V / aschprc / eß the reducing agent first acts on the object to be cleaned and only later, after about 2 to 5 minutes, that too Oxidizing agent becomes fully effective

Dieser doppelte Reinigungseffekt der erfindungsgemäßen Waschpaste ist von großer Bedeutung, z. B. bei der Entfernung von Schmutzflecken, die gleichzeitig Farbstoffe enthalten, die nur reduktiv oder oxidativ gebleicht werden können.This double cleaning effect of the invention Washing paste is of great importance, e.g. B. in the removal of dirt stains at the same time Contain dyes that can only be bleached reductively or oxidatively.

Beispiel 1example 1

72,0 kg granuliertes Natrium-perborat werden in 25,0 kg Silikonöl eingerührt (Mischung I). 28,48 kg Butylglykol, 128,55 kg Fettsäurealkylolamid 31,0 kg nichtionogener Emulgator, 8,02 kg Pine-Öl, 40,41kg Hexylenglykol, 196,34 kg Talkum, 5,0 kg pyrogene72.0 kg of granulated sodium perborate are stirred into 25.0 kg of silicone oil (mixture I). 28.48 kg Butyl glycol, 128.55 kg fatty acid alkyl amide 31.0 kg nonionic emulsifier, 8.02 kg pine oil, 40.41 kg Hexylene glycol, 196.34 kg talc, 5.0 kg pyrogenic

^ Kieselsäure, !5,04 kg Lgsoiin, 274 kg Triäthasoiamin, 94,0 ivg Natriumdithionit und 158,07 kg Bimsmehl G Vz werden zusammen gegeben und intensiv miteinander vermischt (Misch- ig II).^ Silicic acid,! 5.04 kg Lgsoiin, 274 kg Triethasoiamin, 94.0 ivg sodium dithionite and 158.07 kg pumice flour G Vz are given together and mixed intensively with one another (mixed ig II).

Mischung I wira in Mischung H eingetragen und gutMixture I is entered in Mixture H and is good

vermengtmixed up

Beispiel 2Example 2

Es werden 6,1 kg Natrium-perborat mit 2$ kg Silikonöl kalt granuliert (Mischung I). 21,0 kg Rizinusöl,6.1 kg of sodium perborate are cold granulated with 2 kg of silicone oil (mixture I). 21.0 kg castor oil,

SS 84 kg Kondensationsprodukt Fettsäure-Sarkosin, 4,0 kg Aluir.iniumpalmitat und 2,OKg riexyiengiykoi werden miteinander vermischt (Mischung II). Gleichzeitig wird eine Mischung von 6,9 kg kalzinierter Soda, 15,0 kg Natrium-dithionit und 333 kg Bimssteinmehl hergestellt (Mischung IJI)LSS 84 kg condensation product fatty acid-sarcosine, 4.0 kg Aluir.inium palmitate and 2, OKg riexyiengiykoi be mixed together (mixture II). At the same time will a mixture of 6.9 kg of calcined soda, 15.0 kg of sodium dithionite and 333 kg of pumice powder was produced (Mixture IJI) L

Die Mischung III wird mit der Mischung II· kalt vermengt, danach wird Mischung I in die Mischung II + IH eingetragen.Mixture III is mixed cold with mixture II, then mixture I is mixed into the mixture II + IH registered.

Claims (4)

Patentansprüche:Patent claims: 1. Handwaschpaste mit einem Gehalt an einem reduzierend und an einem oxidierend wirkenden Mittel, dadurch gekennzeichnet, daß sie ein wasserfreies Reduktionsmittel sowie ein mit Silikonöl überzogenes Natriumperborat-Granulat enthält1. Hand washing paste with a content of a reducing and an oxidizing agent Agent, characterized in that it contains an anhydrous reducing agent and one with Contains sodium perborate granules coated with silicone oil 2. Handwaschpaste nach Anspruch 1, dadurch gekennzeichnet, daß diese Natriumdithionit als Reduktionsmittel enthält2. Hand washing paste according to claim 1, characterized in that this sodium dithionite as Contains reducing agents 3. Handwaschpaste nach Anspruch 1 und 2, dadurch gekennzeichnet, daß das Gewichtsverhältnis Natriumperborat zu Silikonöl 2:1 bis 4 :1 zu beträgt3. hand washing paste according to claim 1 and 2, characterized in that the weight ratio Sodium perborate to silicone oil is 2: 1 to 4: 1 too 4. Handwaschpaste nach Anspruch 1, 2 und 3, dadurch gekennzeichnet, daß diese wasserfreie, hautschonende Netzmittel enthält4. hand washing paste according to claim 1, 2 and 3, characterized in that this anhydrous, Contains skin-friendly wetting agents
DE19742448716 1974-10-12 1974-10-12 Hand washing paste Expired DE2448716C3 (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
DE19742448716 DE2448716C3 (en) 1974-10-12 Hand washing paste
IT51360/75A IT1047535B (en) 1974-10-12 1975-09-16 PASTA TO WASH YOUR HANDS
AT736275A AT342173B (en) 1974-10-12 1975-09-26 HAND WASH PASTE
DK451775A DK152377C (en) 1974-10-12 1975-10-07 WATER-FREE HANDWASH WASTE
CH1313675A CH616702A5 (en) 1974-10-12 1975-10-09 Handwashing paste.
NLAANVRAGE7511930,A NL180851B (en) 1974-10-12 1975-10-10 METHOD FOR PREPARING A HAND WASHING PASTE
FI752827A FI58512C (en) 1974-10-12 1975-10-10 PASTA FOER HANDTVAETT
BE160864A BE834410A (en) 1974-10-12 1975-10-10 PASTE FOR HAND CLEANING
IE2219/75A IE43304B1 (en) 1974-10-12 1975-10-10 Cleansing composition
FR7531131A FR2287506A1 (en) 1974-10-12 1975-10-10 PASTE FOR HAND CLEANING
GB41671/75A GB1501942A (en) 1974-10-12 1975-10-10 Cleansing composition
LU73570A LU73570A1 (en) 1974-10-12 1975-10-10
NO753437A NO142531C (en) 1974-10-12 1975-10-10 WATER-FREE HANDWASH WASTE.
SE7511412A SE417980B (en) 1974-10-12 1975-10-10 HANDWASH PASTA WITH A CONTENT AND REDUCING EFFECTIVE EXCEPT FOR CURRENTLY WATER-FREE ADDITIVES AND LIQUIDS
ES441719A ES441719A1 (en) 1974-10-12 1975-10-11 Cleansing composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19742448716 DE2448716C3 (en) 1974-10-12 Hand washing paste

Publications (3)

Publication Number Publication Date
DE2448716A1 DE2448716A1 (en) 1976-04-22
DE2448716B2 true DE2448716B2 (en) 1977-01-13
DE2448716C3 DE2448716C3 (en) 1977-09-01

Family

ID=

Also Published As

Publication number Publication date
AT342173B (en) 1978-03-28
IE43304B1 (en) 1981-01-28
DK152377C (en) 1988-07-25
DK152377B (en) 1988-02-22
NL180851B (en) 1986-12-01
CH616702A5 (en) 1980-04-15
FI752827A (en) 1976-04-13
DK451775A (en) 1976-04-13
BE834410A (en) 1976-04-12
IE43304L (en) 1976-04-12
FI58512B (en) 1980-10-31
SE417980B (en) 1981-04-27
ATA736275A (en) 1977-07-15
NO753437L (en) 1976-04-13
GB1501942A (en) 1978-02-22
DE2448716A1 (en) 1976-04-22
FR2287506A1 (en) 1976-05-07
LU73570A1 (en) 1977-02-09
FI58512C (en) 1981-02-10
ES441719A1 (en) 1977-11-01
IT1047535B (en) 1980-10-20
NO142531C (en) 1980-09-03
NO142531B (en) 1980-05-27
NL7511930A (en) 1976-04-14
FR2287506B1 (en) 1979-01-05
SE7511412L (en) 1976-04-13

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
E77 Valid patent as to the heymanns-index 1977