DE2448716A1 - HAND WASH PASTE - Google Patents

HAND WASH PASTE

Info

Publication number
DE2448716A1
DE2448716A1 DE19742448716 DE2448716A DE2448716A1 DE 2448716 A1 DE2448716 A1 DE 2448716A1 DE 19742448716 DE19742448716 DE 19742448716 DE 2448716 A DE2448716 A DE 2448716A DE 2448716 A1 DE2448716 A1 DE 2448716A1
Authority
DE
Germany
Prior art keywords
mixture
hand washing
paste
sodium perborate
silicone oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19742448716
Other languages
German (de)
Other versions
DE2448716B2 (en
DE2448716C3 (en
Inventor
Heinz Dipl Chem Wallrath
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boehringer Ingelheim Pharma GmbH and Co KG
Original Assignee
Dr Karl Thomae GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dr Karl Thomae GmbH filed Critical Dr Karl Thomae GmbH
Priority claimed from DE19742448716 external-priority patent/DE2448716C3/en
Priority to DE19742448716 priority Critical patent/DE2448716C3/en
Priority to IT51360/75A priority patent/IT1047535B/en
Priority to AT736275A priority patent/AT342173B/en
Priority to DK451775A priority patent/DK152377C/en
Priority to CH1313675A priority patent/CH616702A5/en
Priority to SE7511412A priority patent/SE417980B/en
Priority to FR7531131A priority patent/FR2287506A1/en
Priority to IE2219/75A priority patent/IE43304B1/en
Priority to FI752827A priority patent/FI58512C/en
Priority to NLAANVRAGE7511930,A priority patent/NL180851B/en
Priority to GB41671/75A priority patent/GB1501942A/en
Priority to BE160864A priority patent/BE834410A/en
Priority to NO753437A priority patent/NO142531C/en
Priority to LU73570A priority patent/LU73570A1/xx
Priority to ES441719A priority patent/ES441719A1/en
Publication of DE2448716A1 publication Critical patent/DE2448716A1/en
Publication of DE2448716B2 publication Critical patent/DE2448716B2/en
Publication of DE2448716C3 publication Critical patent/DE2448716C3/en
Application granted granted Critical
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0042—Reducing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Devices For Medical Bathing And Washing (AREA)

Description

Case 5Case 5

Dr.Bu./pf/Kp.Dr.Bu./pf/Kp.

DR. KARL THOMAE GMBH, BIBERACH AN DER RISSDR. KARL THOMAE GMBH, BIBERACH AN DER RISS

Handwas chp as t eHand wash chp as t e

Die vorliegende Erfindung betrifft eine neue Handwaschpaste, die vorzugsweise zum Entfernen von ParbVerschmutzungen geeignet ist, sowie ein Verfahren zu ihrer Herstellung.The present invention relates to a new hand washing paste, which is preferably suitable for removing parquet soiling, as well as a process for its production.

In der deutschen Patentschrift 1.031.460 wird erstmals eine Handwaschpaste beschrieben, bei welcher das Netzmittel erst im Augenblick der Anwendung gebildet wird. Bei dieser wird die der waschaktiven Substanz zugrunde liegende Säure in einfacher Weise auf Grund ihrer öllöslichkeit in eine ölphase eingearbeitet. Zum Beispiel läßt sich die auf Grund einer Kondensation von Fettsäure mit Sarkosin erhaltene Säure in ein natürliches Pflanzenöl wie Rizinusöl einarbeiten, wobei zur Konsistenzverbesserung noch Metallseifen zugefügt werden können. In diese Grundlage läßt sich nun ein Gemisch aus Spda, Natriumdithionit und Bimssteinpulver einarbeiten. Diese anorganischen Grundstoffe werden von der ölphase derart umgeben, daß eine Reaktion mit der Säure unter Salzbildung nicht möglich ist. Selbst geringe Wasseranteile werden in einer derartigen Weise emulgiert, daß auch sie keinen vorzeitigen Ablauf der Reaktion bewirken. Beim Aufbringen dieser Paste auf die Hände undIn the German patent specification 1.031.460, a hand washing paste is used for the first time described in which the wetting agent is only formed at the moment of application. In this case, that of the active washing The acid on which the substance is based is incorporated into an oil phase in a simple manner due to its oil solubility. For example the acid obtained as a result of condensation of fatty acid with sarcosine can be converted into a natural vegetable oil such as castor oil work in, whereby metal soaps can be added to improve the consistency. A mixture can now be incorporated into this basis Work in from Spda, sodium dithionite and pumice stone powder. These inorganic basic substances are surrounded by the oil phase in such a way that a reaction with the acid with salt formation does not occur is possible. Even small amounts of water are emulsified in such a way that they too do not expire prematurely Cause reaction. When applying this paste on the hands and

609817/1252609817/1252

Zugabe von Wasser setzt dann erst der NeutralisationsVorgang unter Bildung des wirksamen Netzmittels wie auch der Entwicklung von Schwefeldioxid ein.The addition of water then only starts the neutralization process Formation of the effective wetting agent as well as the development of sulfur dioxide.

Es wurde nun überraschenderweise gefunden, daß die bleichende und somit die reinigende Wirkung bei einer Waschpaste ähnlicher Zusammensetzung, wie in der Deutschen Patentschrift 1 031 460 beschrieben, die beispielsweise Butylgylkol, Lauridit, Emulan, Hexylenglykol, Pine-Öl, Lanolin, Triäthanolamin, Talkum, Aerosil, ßimsmehl und ein wasserfreies Reduktionsmittel wie Natriumdithionit enthält, dadurch wesentlich gesteigert wird, daß ihr gleichzeitig als Oxidationsmittel granuliertes, mit Silikonöl überzogenes Natriumperborat beigemischt wird.It has now been found, surprisingly, that the bleaching and thus the cleaning effect with a washing paste of a similar composition, as described in German patent specification 1 031 460, which, for example, butyl glycol, lauridite, emulan, Hexylene glycol, pine oil, lanolin, triethanolamine, talc, aerosil, ßim flour and an anhydrous reducing agent such as sodium dithionite, is significantly increased by the fact that you at the same time Granulated sodium perborate coated with silicone oil is added as the oxidizing agent.

Das Natriumperborat-Granulat hat vorzugsweise eine Teilchengröße, die der des verwendeten Bimssteins entspricht und in der Größenordnung von 30 bis 60 JU liegt (DIN-Normgröße ca. G 1/2). Es ist erforderlich, dieses Natriumperborat-Granulat zuerst mit Silikonöl zu vermischen, wobei die Gewichtsverhältnisse Natriumperborat zu Silikonöl zwischen 2 zu 1 und 4 zu 1 schwanken können. Diese Mischung wird dann mit der zweiten Mischung, bestehend aus einem wasserfreien Netzmittel, einem Reduktionsmittel und den übrigen, oben angegebenen Bestandteilen, innig vermengt. Al3 Reduktionsmittel eigenen sich beispielsweise Brenzkatechin, Natriumsulfitoder bisulfit, insbesondere aber Natriumdithionit. In dieser so hergestellten Paste kann das Reduktionsmittel nicht mit dem Oxidationsmittel Natriumperborat reagieren, diese Paste ist unbeschränkt lagerfähig, sie verliert auch nach langer Lagerzeit nicht ihre reduzierenden und oxidierenden Eigenschaften. Wird diese Paste zum Waschen benutzt, so tritt zuerst die reduzierende und, hiervon zeitlich verzögert, die oxidierende Wirkung in den Vordergrund. The sodium perborate granulate preferably has a particle size which corresponds to that of the pumice stone used and is of the order of 30 to 60 JU (DIN standard size approx. G 1/2). It is necessary to first mix these sodium perborate granules with silicone oil, whereby the weight ratios of sodium perborate to silicone oil can vary between 2: 1 and 4: 1. This mixture is then intimately mixed with the second mixture, consisting of an anhydrous wetting agent, a reducing agent and the other constituents indicated above. Al3 reducing agents are suitable, for example, pyrocatechol, sodium sulfite or bisulfite, but especially sodium dithionite. In this paste produced in this way, the reducing agent cannot react with the oxidizing agent sodium perborate, this paste can be stored indefinitely, it does not lose its reducing and oxidizing properties even after a long storage period. If this paste is used for washing, the reducing effect and, after a time delay, the oxidizing effect come to the fore.

Bs war zu erwarten, daß beim Waschprozeß durch die lösende Wirkung des Wassers, verstärkt durch die Wirkung des Netzmittels, das Reduktionsmittel in erster Linie mit dem Oxidationsmittel reagiert,It was to be expected that during the washing process due to the dissolving effect of the water, reinforced by the action of the wetting agent, the reducing agent reacts primarily with the oxidizing agent,

609817/1252609817/1252

wobei sich- dann beide Stoffe gegenseitig neutralisieren und damit für die reinigende bzw. bleichende Wirkung auf die Haut oder das Gewebe ausfallen. Es hat sich tatsächlich aber gezeigt, daß beim Waschprozeß zuerst das Reduktionsmittel auf den zu reinigenden Gegenstand einwirkt und erst später, etwa nach 2 bis 5 Minuten, auch das Oxidationsmittel voll wirksam wird.where- then both substances neutralize each other and thus for the cleansing or bleaching effect on the skin or the Tissues fail. However, it has actually been shown that the Washing process first apply the reducing agent to the one to be cleaned The object acts and only later, after about 2 to 5 minutes, does the oxidizing agent become fully effective.

Dieser doppelte Reinigungseffekt der erfindungsgeraäßen Waschpaste ist von großer Bedeutung, z.B. bei der Entfernung von Schmutzflekken, die gleichzeitig Farbstoffe enthalten, die nur reduktiv oder oxidativ gebleicht werden können.This double cleaning effect of the washing paste according to the invention is of great importance, e.g. when removing dirt stains, which also contain dyes that are only reductive or can be oxidatively bleached.

Beispiel 1example 1

72,0 kg granuliertes Natrium-perborat werden in 25,0 kg Silikonöl 2000 eingerührt (Mischung I). 28,48 kg Butylglykol, 128,55 kg Lauridit VD, 31,0 kg Emulan, 8,02 kg Pine-öl, 40,41 kg Hexylenglykol, 196,84 kg Talkum, 5,0 kg Aerosil, 15,04 kg Lanolin, 27,5 kg Triäthanolamin, 94,0 kg Natriumdithionit und 158,07 kg Bimsmehl G 1/2 werden zusammen gegeben und intensiv miteinander vermischt (Mischung II).
Mischung I wird in Mischung II eingetragen und gut vermengt.72.0 kg of granulated sodium perborate are stirred into 25.0 kg of silicone oil 2000 (mixture I). 28.48 kg butyl glycol, 128.55 kg Lauridit VD, 31.0 kg emulan, 8.02 kg pine oil, 40.41 kg hexylene glycol, 196.84 kg talc, 5.0 kg Aerosil, 15.04 kg lanolin , 27.5 kg of triethanolamine, 94.0 kg of sodium dithionite and 158.07 kg of pumice flour G 1/2 are added together and intensively mixed with one another (mixture II).
Mixture I is added to mixture II and mixed well.

Beispiel 2Example 2

Es werden 6,1 kg Natrium-perborat mit 2,9 kg Silikonöl 2000 kalt granuliert (Mischung I). 21,0 kg Riziniusöl, 8,5 kg Kondensationsprodukt Pettsäure-Sarkosin, 4,0 kg Aluminiumpalmitat und 2,0 kg Hexylenglykol werden miteinander vermischt (Mischung II). Gleichzeitig wird eine Mischung von 6,9 kg kalzinierter Soda, 15,0 kg Natrium-dithionit und 33,5 kg Bimssteinmehl hergestellt (Mischung III).6.1 kg of sodium perborate are granulated cold with 2.9 kg of silicone oil 2000 (mixture I). 21.0 kg castor oil, 8.5 kg condensation product Fatty acid sarcosine, 4.0 kg aluminum palmitate and 2.0 kg of hexylene glycol are mixed with one another (mixture II). At the same time a mixture of 6.9 kg of calcined soda, 15.0 kg of sodium dithionite and 33.5 kg of pumice stone flour were produced (Mixture III).

Die Mischung III wird mit der Mischung II kalt vermengt, danach wird Mischung I in die Mischung II + III eingetragen.Mixture III is blended cold with mixture II, then mixture I is added to mixture II + III.

60981 7/125260981 7/1252

Claims (4)

PatentansprücheClaims MLJ Handwaschpaste mit einem Gehalt an einem reduzierend und an einem oxidierend wirkenden Mittel, dadurch gekennzeichnet, daß sie ein wasserfreies Reduktionsmittel sowie ein mit Silikonöl überzogenes Natriumperborat-Granulat enthält.MLJ hand washing paste containing a reducing and an oxidizing agent, characterized in that it is an anhydrous reducing agent and a Contains sodium perborate granules coated with silicone oil. 2. Handwaschpaste nach Anspruch 1, dadurch gekennzeichnet, daß diese Natriumdithionit als Reduktionsmittel enthält.2. hand washing paste according to claim 1, characterized in that this contains sodium dithionite as a reducing agent. 3. Handwaschpaste nach Anspruch 1 und 2, dadurch gekennzeichnet, daß das Gewichtsverhältnis Natriumperborat zu Silikonöl 2 : 1 bis 4 : 1 zu beträgt.3. Hand washing paste according to claim 1 and 2, characterized in that the weight ratio of sodium perborate to silicone oil is 2: 1 to 4 : 1. 4. Handwaschpaste nach Anspruch 1, 2 und 3, dadurch gekennzeichnet, daß diese wasserfreie, hautschonende Netzmittel enthält.4. hand washing paste according to claim 1, 2 and 3, characterized in that that this contains water-free, skin-friendly wetting agents. 609817/1252609817/1252
DE19742448716 1974-10-12 1974-10-12 Hand washing paste Expired DE2448716C3 (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
DE19742448716 DE2448716C3 (en) 1974-10-12 Hand washing paste
IT51360/75A IT1047535B (en) 1974-10-12 1975-09-16 PASTA TO WASH YOUR HANDS
AT736275A AT342173B (en) 1974-10-12 1975-09-26 HAND WASH PASTE
DK451775A DK152377C (en) 1974-10-12 1975-10-07 WATER-FREE HANDWASH WASTE
CH1313675A CH616702A5 (en) 1974-10-12 1975-10-09 Handwashing paste.
FI752827A FI58512C (en) 1974-10-12 1975-10-10 PASTA FOER HANDTVAETT
NO753437A NO142531C (en) 1974-10-12 1975-10-10 WATER-FREE HANDWASH WASTE.
IE2219/75A IE43304B1 (en) 1974-10-12 1975-10-10 Cleansing composition
SE7511412A SE417980B (en) 1974-10-12 1975-10-10 HANDWASH PASTA WITH A CONTENT AND REDUCING EFFECTIVE EXCEPT FOR CURRENTLY WATER-FREE ADDITIVES AND LIQUIDS
NLAANVRAGE7511930,A NL180851B (en) 1974-10-12 1975-10-10 METHOD FOR PREPARING A HAND WASHING PASTE
GB41671/75A GB1501942A (en) 1974-10-12 1975-10-10 Cleansing composition
BE160864A BE834410A (en) 1974-10-12 1975-10-10 PASTE FOR HAND CLEANING
FR7531131A FR2287506A1 (en) 1974-10-12 1975-10-10 PASTE FOR HAND CLEANING
LU73570A LU73570A1 (en) 1974-10-12 1975-10-10
ES441719A ES441719A1 (en) 1974-10-12 1975-10-11 Cleansing composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19742448716 DE2448716C3 (en) 1974-10-12 Hand washing paste

Publications (3)

Publication Number Publication Date
DE2448716A1 true DE2448716A1 (en) 1976-04-22
DE2448716B2 DE2448716B2 (en) 1977-01-13
DE2448716C3 DE2448716C3 (en) 1977-09-01

Family

ID=

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992006166A1 (en) * 1990-09-29 1992-04-16 Henkel Kommanditgesellschaft Auf Aktien Bleaching-agent preparation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992006166A1 (en) * 1990-09-29 1992-04-16 Henkel Kommanditgesellschaft Auf Aktien Bleaching-agent preparation
US5328489A (en) * 1990-09-29 1994-07-12 Henkel Kommanditgesellschaft Auf Aktien Non-aqueous liquid bleach containing 40-70% perborate monohydrate in a nonionic surfactant

Also Published As

Publication number Publication date
FI752827A (en) 1976-04-13
FI58512C (en) 1981-02-10
IE43304B1 (en) 1981-01-28
LU73570A1 (en) 1977-02-09
NL7511930A (en) 1976-04-14
NO142531B (en) 1980-05-27
SE7511412L (en) 1976-04-13
ES441719A1 (en) 1977-11-01
GB1501942A (en) 1978-02-22
ATA736275A (en) 1977-07-15
FI58512B (en) 1980-10-31
FR2287506A1 (en) 1976-05-07
FR2287506B1 (en) 1979-01-05
DE2448716B2 (en) 1977-01-13
CH616702A5 (en) 1980-04-15
NO753437L (en) 1976-04-13
SE417980B (en) 1981-04-27
IT1047535B (en) 1980-10-20
NO142531C (en) 1980-09-03
IE43304L (en) 1976-04-12
DK451775A (en) 1976-04-13
DK152377C (en) 1988-07-25
DK152377B (en) 1988-02-22
BE834410A (en) 1976-04-12
AT342173B (en) 1978-03-28
NL180851B (en) 1986-12-01

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
E77 Valid patent as to the heymanns-index 1977