NO125033B - - Google Patents
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- Publication number
- NO125033B NO125033B NO6918A NO1869A NO125033B NO 125033 B NO125033 B NO 125033B NO 6918 A NO6918 A NO 6918A NO 1869 A NO1869 A NO 1869A NO 125033 B NO125033 B NO 125033B
- Authority
- NO
- Norway
- Prior art keywords
- capsule
- polyvinyl alcohol
- capsules
- borate ester
- alkylene glycol
- Prior art date
Links
- 239000002775 capsule Substances 0.000 claims description 84
- -1 alkylene glycol cyclic borate ester Chemical class 0.000 claims description 41
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 38
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 28
- 239000000243 solution Substances 0.000 claims description 27
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 25
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 14
- 239000000376 reactant Substances 0.000 claims description 13
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 8
- 239000004327 boric acid Substances 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- UUUGYDOQQLOJQA-UHFFFAOYSA-L vanadyl sulfate Chemical compound [V+2]=O.[O-]S([O-])(=O)=O UUUGYDOQQLOJQA-UHFFFAOYSA-L 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 229940041260 vanadyl sulfate Drugs 0.000 claims description 6
- 229910000352 vanadyl sulfate Inorganic materials 0.000 claims description 6
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 239000011162 core material Substances 0.000 description 15
- 238000002360 preparation method Methods 0.000 description 14
- 238000006460 hydrolysis reaction Methods 0.000 description 12
- 230000007062 hydrolysis Effects 0.000 description 11
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 9
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 description 7
- 235000011152 sodium sulphate Nutrition 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- JRMXMZUJZODGOW-UHFFFAOYSA-N boronooxyboronic acid 2-methylpentane-2,4-diol Chemical compound B(O)(O)OB(O)O.CC(C)(CC(C)O)O.CC(C)(CC(C)O)O JRMXMZUJZODGOW-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000005538 encapsulation Methods 0.000 description 5
- 238000005191 phase separation Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- 230000001939 inductive effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 244000215068 Acacia senegal Species 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920000084 Gum arabic Polymers 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000205 acacia gum Substances 0.000 description 3
- 235000010489 acacia gum Nutrition 0.000 description 3
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007771 core particle Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- IPAJDLMMTVZVPP-UHFFFAOYSA-N Crystal violet lactone Chemical compound C1=CC(N(C)C)=CC=C1C1(C=2C=CC(=CC=2)N(C)C)C2=CC=C(N(C)C)C=C2C(=O)O1 IPAJDLMMTVZVPP-UHFFFAOYSA-N 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000002744 anti-aggregatory effect Effects 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- VBWXUNLGIPZSPM-UHFFFAOYSA-N boronooxyboronic acid dioctyl benzene-1,2-dicarboxylate Chemical compound B(O)(O)OB(O)O.C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC VBWXUNLGIPZSPM-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 239000011365 complex material Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- AVIYEYCFMVPYST-UHFFFAOYSA-N hexane-1,3-diol Chemical compound CCCC(O)CCO AVIYEYCFMVPYST-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000003385 ring cleavage reaction Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- AGFASGGUHBOODX-UHFFFAOYSA-L vanadyl sulfate dihydrate Chemical compound O.O.[V+2]=O.[O-]S([O-])(=O)=O AGFASGGUHBOODX-UHFFFAOYSA-L 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
- Y10T428/2987—Addition polymer from unsaturated monomers only
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US70113068A | 1968-01-29 | 1968-01-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
NO125033B true NO125033B (zh) | 1972-07-10 |
Family
ID=24816193
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO6918A NO125033B (zh) | 1968-01-29 | 1969-01-03 |
Country Status (11)
Country | Link |
---|---|
US (1) | US3565818A (zh) |
BE (1) | BE726582A (zh) |
BR (1) | BR6905913D0 (zh) |
CH (1) | CH494062A (zh) |
DK (1) | DK125372B (zh) |
FR (1) | FR1602062A (zh) |
GB (1) | GB1198956A (zh) |
IT (1) | IT1037008B (zh) |
NL (1) | NL6901370A (zh) |
NO (1) | NO125033B (zh) |
SE (1) | SE338301B (zh) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4349530A (en) * | 1980-12-11 | 1982-09-14 | The Ohio State University | Implants, microbeads, microcapsules, preparation thereof and method of administering a biologically-active substance to an animal |
US4884873A (en) * | 1981-09-16 | 1989-12-05 | Manchester R & D Partnership | Encapsulated liquid crystal material, apparatus and method having interconnected capsules |
US5089904A (en) * | 1981-09-16 | 1992-02-18 | Fergason James L | Encapsulated liquid crystal material, apparatus and method |
US5082351A (en) * | 1981-09-16 | 1992-01-21 | Manchester R & D Partnership | Encapsulated liquid crystal material, apparatus and method |
US4707080A (en) * | 1981-09-16 | 1987-11-17 | Manchester R & D Partnership | Encapsulated liquid crystal material, apparatus and method |
US4435047A (en) * | 1981-09-16 | 1984-03-06 | Manchester R & D Partnership | Encapsulated liquid crystal and method |
US4884877A (en) * | 1984-05-22 | 1989-12-05 | Manchester R & D Partnership | Liquid crystal temperature sensor and materials utilizing microencapsulated liquid crystal |
US5130828A (en) * | 1984-05-22 | 1992-07-14 | Manchester R&D Partnership | Liquid crystal temperature sensor and materials |
US5168380A (en) * | 1985-03-01 | 1992-12-01 | Manchester R & D Partnership An Ohio Limited Partnership | Multiple containment mediums of operationally nematic liquid crystal responsive to a prescribed input |
US5208686A (en) * | 1985-03-01 | 1993-05-04 | Manchester R&D Partnership | Liquid crystal color display and method |
US5345322A (en) * | 1985-03-01 | 1994-09-06 | Manchester R&D Limited Partnership | Complementary color liquid crystal display |
US5142389A (en) * | 1985-03-01 | 1992-08-25 | Manchester R & D Limited Partnership | Liquid crystal color display and method |
US4657582A (en) * | 1985-05-30 | 1987-04-14 | Pennwalt Corporation | Polyhydroxy polymer delivery systems |
US5461027A (en) * | 1989-01-24 | 1995-10-24 | Griffin Corporation | Microencapsulated pendimethalin and method of making and using same |
JP2914452B2 (ja) * | 1989-09-28 | 1999-06-28 | 三菱製紙株式会社 | マイクロカプセル及びその製造方法 |
US5599767A (en) * | 1994-05-27 | 1997-02-04 | Micro Flo Company | Salt sensitive binder system |
US5849412A (en) * | 1995-02-17 | 1998-12-15 | Medlogic Global Corporation | Encapsulated materials |
US5932285A (en) * | 1995-02-17 | 1999-08-03 | Medlogic Global Corporation | Encapsulated materials |
DE19827425B4 (de) * | 1998-06-19 | 2004-04-01 | Wacker-Chemie Gmbh | Vernetzbare Polymerpulver-Zusammensetzungen und deren Verwendung |
US6562460B1 (en) | 2001-11-20 | 2003-05-13 | Encap Technologies, Llc | Microencapsulated particles and process for manufacturing same |
US6833191B2 (en) * | 2001-11-20 | 2004-12-21 | Encap Technologies, Llc | Microencapsulated particles and process for manufacturing same |
US6899958B2 (en) | 2002-06-21 | 2005-05-31 | Encap Technologies, Llc. | Moisture barrier resins |
GB0704335D0 (en) * | 2007-03-07 | 2007-04-11 | Fujifilm Imaging Colorants Ltd | Process for preparing an encapsulated particulate solid |
KR102634590B1 (ko) | 2015-12-22 | 2024-02-06 | 롬 앤드 하아스 컴패니 | 수성 매질 내에 분포된 액적 |
KR102693615B1 (ko) | 2015-12-22 | 2024-08-08 | 롬 앤드 하아스 컴패니 | 수성 매질 중에 분포된 액적 |
KR102682029B1 (ko) | 2015-12-22 | 2024-07-04 | 롬 앤드 하아스 컴패니 | 수성 매질 중에 분포된 액적의 현탁 중합 방법 |
-
1968
- 1968-01-29 US US701130*A patent/US3565818A/en not_active Expired - Lifetime
- 1968-12-19 SE SE17465/68A patent/SE338301B/xx unknown
- 1968-12-21 IT IT25481/68A patent/IT1037008B/it active
- 1968-12-24 FR FR1602062D patent/FR1602062A/fr not_active Expired
-
1969
- 1969-01-03 NO NO6918A patent/NO125033B/no unknown
- 1969-01-07 GB GB847/69A patent/GB1198956A/en not_active Expired
- 1969-01-08 BE BE726582D patent/BE726582A/xx unknown
- 1969-01-13 CH CH71869A patent/CH494062A/fr not_active IP Right Cessation
- 1969-01-28 BR BR205913/69A patent/BR6905913D0/pt unknown
- 1969-01-28 DK DK45069AA patent/DK125372B/da unknown
- 1969-01-28 NL NL6901370A patent/NL6901370A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
SE338301B (zh) | 1971-09-06 |
BR6905913D0 (pt) | 1973-02-08 |
DK125372B (da) | 1973-02-12 |
BE726582A (zh) | 1969-06-16 |
FR1602062A (zh) | 1970-10-05 |
US3565818A (en) | 1971-02-23 |
GB1198956A (en) | 1970-07-15 |
NL6901370A (zh) | 1969-07-31 |
CH494062A (fr) | 1970-07-31 |
IT1037008B (it) | 1979-11-10 |
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