NL8102696A - Electrolytisch bad alsmede werkwijze voor het electro- lytisch verwijderen van afzettingen van substraten onder toepassing van dit bad. - Google Patents
Electrolytisch bad alsmede werkwijze voor het electro- lytisch verwijderen van afzettingen van substraten onder toepassing van dit bad. Download PDFInfo
- Publication number
- NL8102696A NL8102696A NL8102696A NL8102696A NL8102696A NL 8102696 A NL8102696 A NL 8102696A NL 8102696 A NL8102696 A NL 8102696A NL 8102696 A NL8102696 A NL 8102696A NL 8102696 A NL8102696 A NL 8102696A
- Authority
- NL
- Netherlands
- Prior art keywords
- bath
- compound
- amount
- present
- thiocyanate
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 33
- 239000000758 substrate Substances 0.000 title description 13
- -1 thiocyanate compound Chemical class 0.000 claims description 59
- 229910052751 metal Inorganic materials 0.000 claims description 49
- 239000002184 metal Substances 0.000 claims description 49
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 47
- 239000010953 base metal Substances 0.000 claims description 41
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 29
- 150000001875 compounds Chemical class 0.000 claims description 26
- 229910052759 nickel Inorganic materials 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 23
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims description 20
- 239000003112 inhibitor Substances 0.000 claims description 18
- 150000001412 amines Chemical class 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 15
- 229910000831 Steel Inorganic materials 0.000 claims description 11
- 150000003863 ammonium salts Chemical class 0.000 claims description 11
- 239000010959 steel Substances 0.000 claims description 11
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 10
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 10
- 239000001630 malic acid Substances 0.000 claims description 10
- 235000011090 malic acid Nutrition 0.000 claims description 10
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 claims description 9
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 claims description 7
- 150000002366 halogen compounds Chemical class 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 229910001959 inorganic nitrate Inorganic materials 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- ZVCDLGYNFYZZOK-UHFFFAOYSA-M sodium cyanate Chemical compound [Na]OC#N ZVCDLGYNFYZZOK-UHFFFAOYSA-M 0.000 claims description 6
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052794 bromium Inorganic materials 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims description 5
- 150000002828 nitro derivatives Chemical class 0.000 claims description 5
- OFNHPGDEEMZPFG-UHFFFAOYSA-N phosphanylidynenickel Chemical compound [P].[Ni] OFNHPGDEEMZPFG-UHFFFAOYSA-N 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 4
- WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 150000003891 oxalate salts Chemical class 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 239000011135 tin Substances 0.000 claims description 3
- 229910001369 Brass Inorganic materials 0.000 claims description 2
- 239000010951 brass Substances 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- KERTUBUCQCSNJU-UHFFFAOYSA-L nickel(2+);disulfamate Chemical compound [Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O KERTUBUCQCSNJU-UHFFFAOYSA-L 0.000 claims description 2
- 150000003567 thiocyanates Chemical class 0.000 claims 2
- ZCKAMNXUHHNZLN-UHFFFAOYSA-N Chlorphentermine Chemical compound CC(C)(N)CC1=CC=C(Cl)C=C1 ZCKAMNXUHHNZLN-UHFFFAOYSA-N 0.000 claims 1
- 229910000599 Cr alloy Inorganic materials 0.000 claims 1
- 229910001128 Sn alloy Inorganic materials 0.000 claims 1
- QYTOONVFPBUIJG-UHFFFAOYSA-N azane;cyanic acid Chemical compound [NH4+].[O-]C#N QYTOONVFPBUIJG-UHFFFAOYSA-N 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 claims 1
- 229950007046 chlorphentermine Drugs 0.000 claims 1
- 238000006731 degradation reaction Methods 0.000 claims 1
- 150000003141 primary amines Chemical class 0.000 claims 1
- 150000003335 secondary amines Chemical class 0.000 claims 1
- 230000001256 tonic effect Effects 0.000 claims 1
- 238000000576 coating method Methods 0.000 description 28
- 239000011248 coating agent Substances 0.000 description 20
- 239000012190 activator Substances 0.000 description 18
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 11
- 238000005530 etching Methods 0.000 description 10
- 238000003756 stirring Methods 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 229940099690 malic acid Drugs 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000011282 treatment Methods 0.000 description 8
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 150000004820 halides Chemical class 0.000 description 7
- 229910052736 halogen Inorganic materials 0.000 description 7
- 150000002367 halogens Chemical class 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 239000006172 buffering agent Substances 0.000 description 6
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 5
- 229940116298 l- malic acid Drugs 0.000 description 5
- 229910017604 nitric acid Inorganic materials 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- QGJDXUIYIUGQGO-UHFFFAOYSA-N 1-[2-[(2-methylpropan-2-yl)oxycarbonylamino]propanoyl]pyrrolidine-2-carboxylic acid Chemical compound CC(C)(C)OC(=O)NC(C)C(=O)N1CCCC1C(O)=O QGJDXUIYIUGQGO-UHFFFAOYSA-N 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 150000002823 nitrates Chemical class 0.000 description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- 229910000640 Fe alloy Inorganic materials 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- FATUQANACHZLRT-KMRXSBRUSA-L calcium glucoheptonate Chemical compound [Ca+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O FATUQANACHZLRT-KMRXSBRUSA-L 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 239000010802 sludge Substances 0.000 description 3
- 229910000851 Alloy steel Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Chemical compound Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- DOLZKNFSRCEOFV-UHFFFAOYSA-L nickel(2+);oxalate Chemical compound [Ni+2].[O-]C(=O)C([O-])=O DOLZKNFSRCEOFV-UHFFFAOYSA-L 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- ZNHBMOUCJIUSNM-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;ethane-1,2-diamine Chemical compound NCCN.OCCN(CCO)CCO ZNHBMOUCJIUSNM-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- SLAMLWHELXOEJZ-UHFFFAOYSA-N 2-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1[N+]([O-])=O SLAMLWHELXOEJZ-UHFFFAOYSA-N 0.000 description 1
- 229910000619 316 stainless steel Inorganic materials 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- 101100190227 Drosophila melanogaster PGRP-SA gene Proteins 0.000 description 1
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 240000006927 Foeniculum vulgare Species 0.000 description 1
- 235000004204 Foeniculum vulgare Nutrition 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229910000760 Hardened steel Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920001944 Plastisol Polymers 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 101150041326 air-2 gene Proteins 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- DVARTQFDIMZBAA-UHFFFAOYSA-O ammonium nitrate Chemical class [NH4+].[O-][N+]([O-])=O DVARTQFDIMZBAA-UHFFFAOYSA-O 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 150000001913 cyanates Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 235000010350 erythorbic acid Nutrition 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 150000002497 iodine compounds Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229940026239 isoascorbic acid Drugs 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 208000020442 loss of weight Diseases 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000004999 plastisol Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- YEDBDKITOXSHCO-UHFFFAOYSA-M sodium;2-nitrobenzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1[N+]([O-])=O YEDBDKITOXSHCO-UHFFFAOYSA-M 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F5/00—Electrolytic stripping of metallic layers or coatings
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- ing And Chemical Polishing (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/166,215 US4264420A (en) | 1979-10-29 | 1980-07-07 | Electrolytic stripping bath and process |
| US16621580 | 1980-07-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL8102696A true NL8102696A (nl) | 1982-02-01 |
Family
ID=22602308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8102696A NL8102696A (nl) | 1980-07-07 | 1981-06-03 | Electrolytisch bad alsmede werkwijze voor het electro- lytisch verwijderen van afzettingen van substraten onder toepassing van dit bad. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4264420A (OSRAM) |
| JP (1) | JPS587720B2 (OSRAM) |
| AR (1) | AR227670A1 (OSRAM) |
| AU (1) | AU541039B2 (OSRAM) |
| BE (1) | BE888936R (OSRAM) |
| BR (1) | BR8103856A (OSRAM) |
| CA (1) | CA1171816A (OSRAM) |
| DE (1) | DE3125565A1 (OSRAM) |
| ES (1) | ES8300883A1 (OSRAM) |
| FR (1) | FR2486109A1 (OSRAM) |
| GB (1) | GB2079321B (OSRAM) |
| IT (1) | IT1142772B (OSRAM) |
| NL (1) | NL8102696A (OSRAM) |
| PT (1) | PT73255B (OSRAM) |
| SE (1) | SE453307B (OSRAM) |
| ZA (1) | ZA813704B (OSRAM) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4400248A (en) * | 1982-03-08 | 1983-08-23 | Occidental Chemical Corporation | Electrolytic stripping process |
| US4404074A (en) * | 1982-05-27 | 1983-09-13 | Occidental Chemical Corporation | Electrolytic stripping bath and process |
| JPS59194939U (ja) * | 1983-06-13 | 1984-12-25 | 富士通株式会社 | カラ−プリンタ装置 |
| JPS60153442A (ja) * | 1984-01-20 | 1985-08-12 | Mazda Motor Corp | エンジンの燃料供給装置 |
| JPS60153443A (ja) * | 1984-01-20 | 1985-08-12 | Mazda Motor Corp | エンジンの燃料供給装置 |
| JPH01174314U (OSRAM) * | 1988-05-30 | 1989-12-12 | ||
| FR2747400B1 (fr) * | 1996-04-12 | 1998-05-22 | Usinor Sacilor | Procede de conditionnement de la surface externe en cuivre ou alliage de cuivre d'un element d'une lingotiere de coulee continue des metaux, du type comportant une etape de nickelage et une etape de denickelage |
| US6042713A (en) * | 1997-04-01 | 2000-03-28 | Keatch; Richard | Method for removing metal contaminants |
| JP4264338B2 (ja) * | 2003-12-11 | 2009-05-13 | 新光電気工業株式会社 | 銅の電解剥離液及び電解剥離方法 |
| JP4268515B2 (ja) * | 2003-12-26 | 2009-05-27 | 新光電気工業株式会社 | 電解剥離方法 |
| JP4684841B2 (ja) * | 2005-10-14 | 2011-05-18 | 株式会社太洋工作所 | 表面処理装置及び表面処理方法 |
| DE102012109063A1 (de) | 2011-09-26 | 2013-03-28 | Ekpro Gmbh | Edelmetallextraktion aus Brennstoffzellen |
| US11649558B2 (en) * | 2015-03-13 | 2023-05-16 | Okuno Chemical Industries Co., Ltd. | Electrolytic stripping agent for jig |
| DE102015106432A1 (de) | 2015-04-27 | 2016-10-27 | Gramm Technik Gmbh | Verfahren und Vorrichtung zur Herstellung eines Werkstücks |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD81549A (OSRAM) * | ||||
| US3492210A (en) * | 1967-10-16 | 1970-01-27 | Hamilton Cosco Inc | Electrolytic stripping of nonferrous metals from a ferrous metal base |
| BE722317A (OSRAM) * | 1968-10-15 | 1969-03-14 | ||
| DE1908625B2 (de) * | 1969-02-21 | 1971-08-12 | Bergische Metallwarenfabrik Dillen berg & Co KG, 5601 Gruiten | Bad zu elektrolytischen abloesen von metallueberzuegen von grundkoerpern aus rostfreiem stahl |
| DE1926228C3 (de) * | 1969-05-22 | 1974-02-21 | Bergische Metallwarenfabrik Dillenberg & Co Kg, 5601 Gruiten | Bad zum elektrolytischen Ablösen von Metallüberzügen aus Nickel oder Chrom von Grundkörpern aus Buntmetall |
| US3793172A (en) * | 1972-09-01 | 1974-02-19 | Western Electric Co | Processes and baths for electro-stripping plated metal deposits from articles |
| DE2363352C3 (de) * | 1973-12-20 | 1980-12-11 | Hoechst Ag, 6000 Frankfurt | Bad zum elektrolytischen Ablösen von Metallen |
| JPS5120032A (ja) * | 1974-08-09 | 1976-02-17 | Okuno Chem Ind Co | Kinzokudenchakubutsuyodenkaihakurieki |
| FR2345503A1 (fr) * | 1976-03-22 | 1977-10-21 | Oxy Metal Industries Corp | Compositions et procede pour l'enlevement d'alliages de nickel deposes par voie electrolytique |
| US4233124A (en) * | 1979-10-29 | 1980-11-11 | Oxy Metal Industries Corporation | Electrolytic stripping bath and process |
-
1980
- 1980-07-07 US US06/166,215 patent/US4264420A/en not_active Expired - Lifetime
-
1981
- 1981-05-13 CA CA000377450A patent/CA1171816A/en not_active Expired
- 1981-05-13 SE SE8103008A patent/SE453307B/sv not_active IP Right Cessation
- 1981-05-20 AU AU70859/81A patent/AU541039B2/en not_active Ceased
- 1981-05-22 BE BE0/204885A patent/BE888936R/fr not_active IP Right Cessation
- 1981-05-22 AR AR285415A patent/AR227670A1/es active
- 1981-05-22 IT IT48514/81A patent/IT1142772B/it active
- 1981-06-02 FR FR8110904A patent/FR2486109A1/fr active Granted
- 1981-06-03 ZA ZA00813704A patent/ZA813704B/xx unknown
- 1981-06-03 NL NL8102696A patent/NL8102696A/nl not_active Application Discontinuation
- 1981-06-17 ES ES503193A patent/ES8300883A1/es not_active Expired
- 1981-06-17 BR BR8103856A patent/BR8103856A/pt not_active IP Right Cessation
- 1981-06-24 PT PT73255A patent/PT73255B/pt unknown
- 1981-06-25 JP JP56099053A patent/JPS587720B2/ja not_active Expired
- 1981-06-30 DE DE19813125565 patent/DE3125565A1/de not_active Ceased
- 1981-07-01 GB GB8120360A patent/GB2079321B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE8103008L (sv) | 1982-01-08 |
| FR2486109A1 (fr) | 1982-01-08 |
| AR227670A1 (es) | 1982-11-30 |
| GB2079321B (en) | 1983-09-21 |
| IT1142772B (it) | 1986-10-15 |
| AU541039B2 (en) | 1984-12-13 |
| PT73255B (en) | 1982-07-22 |
| BE888936R (fr) | 1981-11-23 |
| SE453307B (sv) | 1988-01-25 |
| US4264420A (en) | 1981-04-28 |
| CA1171816A (en) | 1984-07-31 |
| BR8103856A (pt) | 1982-03-09 |
| DE3125565A1 (de) | 1982-04-01 |
| GB2079321A (en) | 1982-01-20 |
| FR2486109B1 (OSRAM) | 1984-11-30 |
| ZA813704B (en) | 1982-09-29 |
| JPS5751299A (en) | 1982-03-26 |
| IT8148514A0 (it) | 1981-05-22 |
| PT73255A (en) | 1981-07-01 |
| JPS587720B2 (ja) | 1983-02-10 |
| ES503193A0 (es) | 1982-11-01 |
| ES8300883A1 (es) | 1982-11-01 |
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