NL2000053C2 - Systemen, methoden en katalysatoren voor het produceren van een ruwe-oliehoudend product. - Google Patents
Systemen, methoden en katalysatoren voor het produceren van een ruwe-oliehoudend product. Download PDFInfo
- Publication number
- NL2000053C2 NL2000053C2 NL2000053A NL2000053A NL2000053C2 NL 2000053 C2 NL2000053 C2 NL 2000053C2 NL 2000053 A NL2000053 A NL 2000053A NL 2000053 A NL2000053 A NL 2000053A NL 2000053 C2 NL2000053 C2 NL 2000053C2
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- NL
- Netherlands
- Prior art keywords
- grams
- crude
- catalyst
- column
- metal
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims description 433
- 239000012043 crude product Substances 0.000 title claims description 130
- 238000000034 method Methods 0.000 title claims description 106
- 229910052751 metal Inorganic materials 0.000 claims description 397
- 239000002184 metal Substances 0.000 claims description 397
- 239000011148 porous material Substances 0.000 claims description 257
- 150000002739 metals Chemical class 0.000 claims description 145
- 239000000047 product Substances 0.000 claims description 134
- 239000010779 crude oil Substances 0.000 claims description 112
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 109
- 239000000203 mixture Substances 0.000 claims description 90
- 230000000737 periodic effect Effects 0.000 claims description 62
- 229910052757 nitrogen Inorganic materials 0.000 claims description 55
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 50
- 150000001875 compounds Chemical class 0.000 claims description 49
- 239000002994 raw material Substances 0.000 claims description 43
- 229910052739 hydrogen Inorganic materials 0.000 claims description 42
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 38
- 239000001257 hydrogen Substances 0.000 claims description 38
- 238000012545 processing Methods 0.000 claims description 32
- 238000009826 distribution Methods 0.000 claims description 31
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- 150000003839 salts Chemical class 0.000 description 54
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- 150000002430 hydrocarbons Chemical class 0.000 description 31
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 30
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- 150000007513 acids Chemical class 0.000 description 7
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
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- 229910052804 chromium Inorganic materials 0.000 description 5
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
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- 238000002441 X-ray diffraction Methods 0.000 description 4
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- 229910052785 arsenic Inorganic materials 0.000 description 4
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 4
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
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- 238000004458 analytical method Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
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- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 3
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- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
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- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000012685 metal catalyst precursor Substances 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- CZDSWLXAULJYPZ-UHFFFAOYSA-J molybdenum(4+);dicarbonate Chemical compound [Mo+4].[O-]C([O-])=O.[O-]C([O-])=O CZDSWLXAULJYPZ-UHFFFAOYSA-J 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 125000005608 naphthenic acid group Chemical group 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000001935 peptisation Methods 0.000 description 1
- 150000002987 phenanthrenes Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000012163 sequencing technique Methods 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 229910052713 technetium Inorganic materials 0.000 description 1
- GKLVYJBZJHMRIY-UHFFFAOYSA-N technetium atom Chemical compound [Tc] GKLVYJBZJHMRIY-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/10—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing platinum group metals or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/883—Molybdenum and nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US67013605P | 2005-04-11 | 2005-04-11 | |
US67013605 | 2005-04-11 |
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NL2000053C2 true NL2000053C2 (nl) | 2007-07-27 |
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NL2000053A NL2000053C2 (nl) | 2005-04-11 | 2006-04-11 | Systemen, methoden en katalysatoren voor het produceren van een ruwe-oliehoudend product. |
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Country | Link |
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US (1) | US20060231457A1 (fr) |
EP (1) | EP1869144A1 (fr) |
JP (1) | JP2008536001A (fr) |
CN (1) | CN101166809A (fr) |
BR (1) | BRPI0610669A2 (fr) |
CA (1) | CA2604009A1 (fr) |
NL (1) | NL2000053C2 (fr) |
NO (1) | NO20075769L (fr) |
RU (1) | RU2007141711A (fr) |
WO (1) | WO2006110595A1 (fr) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7534342B2 (en) | 2003-12-19 | 2009-05-19 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
US20100098602A1 (en) | 2003-12-19 | 2010-04-22 | Opinder Kishan Bhan | Systems, methods, and catalysts for producing a crude product |
US7745369B2 (en) | 2003-12-19 | 2010-06-29 | Shell Oil Company | Method and catalyst for producing a crude product with minimal hydrogen uptake |
BRPI0610670B1 (pt) * | 2005-04-11 | 2016-01-19 | Shell Int Research | método para produzir um produto bruto, catalisador para produzir um produto bruto, e, método para fabricar um catalisador |
CA2604006A1 (fr) | 2005-04-11 | 2006-10-19 | Shell International Research Maatschappij B.V. | Procede et catalyseur pour produire un produit brut a teneur reduite en azote |
US20080083650A1 (en) | 2006-10-06 | 2008-04-10 | Bhan Opinder K | Methods for producing a crude product |
DE08825898T1 (de) | 2007-05-03 | 2010-10-21 | Auterra, Inc. | Produkt mit monomeren und polymeren von titanylen und herstellungsverfahren dafür |
US8894843B2 (en) | 2008-03-26 | 2014-11-25 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
US9206359B2 (en) | 2008-03-26 | 2015-12-08 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
US9061273B2 (en) | 2008-03-26 | 2015-06-23 | Auterra, Inc. | Sulfoxidation catalysts and methods and systems of using same |
US8764973B2 (en) | 2008-03-26 | 2014-07-01 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
US8298404B2 (en) | 2010-09-22 | 2012-10-30 | Auterra, Inc. | Reaction system and products therefrom |
US9828557B2 (en) | 2010-09-22 | 2017-11-28 | Auterra, Inc. | Reaction system, methods and products therefrom |
BR112014015372B1 (pt) | 2011-12-22 | 2020-01-14 | Advanced Refining Technologies Llc | Composição de suporte de catalisador de alumina, método para preparar um suporte de catalisador e composição de catalisador para hidroconversão e método parahidroprocessamento de um destilado médio ou uma matéria-prima de hidrocarboneto pesado |
US10450516B2 (en) | 2016-03-08 | 2019-10-22 | Auterra, Inc. | Catalytic caustic desulfonylation |
Family Cites Families (103)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2921023A (en) * | 1957-05-14 | 1960-01-12 | Pure Oil Co | Removal of naphthenic acids by hydrogenation with a molybdenum oxidesilica alumina catalyst |
US3025231A (en) * | 1959-06-03 | 1962-03-13 | Texaco Inc | Catalytic hydrogenation of heavy oils such as shale oil |
US3080435A (en) * | 1960-07-18 | 1963-03-05 | Shell Oil Co | Dehydrogenation process |
NL285285A (fr) * | 1961-11-10 | |||
US3553279A (en) * | 1968-03-29 | 1971-01-05 | Texas Instruments Inc | Method of producing ethylene |
US3558474A (en) * | 1968-09-30 | 1971-01-26 | Universal Oil Prod Co | Slurry process for hydrorefining petroleum crude oil |
US3576737A (en) * | 1969-03-25 | 1971-04-27 | Chevron Res | Vanadium removal from hydrocarbons |
US3663431A (en) * | 1969-10-15 | 1972-05-16 | Union Oil Co | Two-phase hydrocarbon conversion system |
BE758565A (nl) * | 1969-11-18 | 1971-05-06 | Shell Int Research | Werkwijze voor het katalytisch hydrogenerend omzetten van een residualekoolwaterstofolie |
US3716478A (en) * | 1970-02-10 | 1973-02-13 | Agency Ind Science Techn | Hydrogenation treatment of hydrocarbon oil |
US3712861A (en) * | 1970-10-19 | 1973-01-23 | Mobil Oil Corp | Upgrading a hydrocarbon utilizing a catalyst of metal sulfides dispersed in alumina |
US3730876A (en) * | 1970-12-18 | 1973-05-01 | A Sequeira | Production of naphthenic oils |
US3716479A (en) * | 1970-12-23 | 1973-02-13 | Mobil Oil Corp | Demetalation of hydrocarbon charge stocks |
US3812028A (en) * | 1971-05-18 | 1974-05-21 | Standard Oil Co | Hydrotreatment of fossil fuels |
US3786138A (en) * | 1971-08-16 | 1974-01-15 | Atlantic Richfield Co | Hydrogen generation |
JPS5139645B2 (fr) * | 1972-12-30 | 1976-10-29 | ||
US3876532A (en) * | 1973-02-27 | 1975-04-08 | Gulf Research Development Co | Method for reducing the total acid number of a middle distillate oil |
US3948759A (en) * | 1973-03-28 | 1976-04-06 | Exxon Research And Engineering Company | Visbreaking a heavy hydrocarbon feedstock in a regenerable molten medium in the presence of hydrogen |
US3960712A (en) * | 1973-04-30 | 1976-06-01 | Universal Oil Products Company | Hydrodesulfurization of asphaltene-containing black oil with a gamma-alumina composite catalyst of specified particle density |
US3931052A (en) * | 1973-08-29 | 1976-01-06 | Mobil Oil Corporation | Alumina-supported catalyst for residua demetalation and desulfurization |
US3891541A (en) * | 1973-08-29 | 1975-06-24 | Mobil Oil Corp | Process for demetalizing and desulfurizing residual oil with hydrogen and alumina-supported catalyst |
US3876523A (en) * | 1973-08-29 | 1975-04-08 | Mobil Oil Corp | Catalyst for residua demetalation and desulfurization |
US3887455A (en) * | 1974-03-25 | 1975-06-03 | Exxon Research Engineering Co | Ebullating bed process for hydrotreatment of heavy crudes and residua |
US3928176A (en) * | 1974-04-01 | 1975-12-23 | Exxon Research Engineering Co | Heavy crude conversion |
US3960708A (en) * | 1974-05-31 | 1976-06-01 | Standard Oil Company | Process for upgrading a hydrocarbon fraction |
US3960706A (en) * | 1974-05-31 | 1976-06-01 | Standard Oil Company | Process for upgrading a hydrocarbon fraction |
US4016067A (en) * | 1975-02-21 | 1977-04-05 | Mobil Oil Corporation | Process for demetalation and desulfurization of petroleum oils |
JPS51122105A (en) * | 1975-04-18 | 1976-10-26 | Toa Nenryo Kogyo Kk | Process for hydrofining of hydrocarbon oil |
US4196102A (en) * | 1975-12-09 | 1980-04-01 | Chiyoda Chemical Engineering & Construction Co., Ltd. | Catalysts for demetallization treatment of _hydrocarbons supported on sepiolite |
GB1561629A (en) * | 1975-12-10 | 1980-02-27 | Ici Ltd | Catalyst |
US4067799A (en) * | 1976-07-02 | 1978-01-10 | Exxon Research And Engineering Company | Hydroconversion process |
US4191635A (en) * | 1977-12-21 | 1980-03-04 | Standard Oil Company (Indiana) | Process for the cracking of heavy hydrocarbon streams |
JPS5579043A (en) * | 1978-12-13 | 1980-06-14 | Chiyoda Chem Eng & Constr Co Ltd | Hydrogenation catalyst for heavy hydrocarbon oil |
US4446244A (en) * | 1979-09-26 | 1984-05-01 | Chevron Research Company | Hydrocarbons hydroprocessing with imogolite catalyst |
US4357263A (en) * | 1979-10-22 | 1982-11-02 | Mobil Oil Corporation | Catalyst for the upgrading of aromatic liquids |
JPS595011B2 (ja) * | 1979-11-27 | 1984-02-02 | 千代田化工建設株式会社 | 重質炭化水素油の水素化処理用触媒ならびにその製法 |
FI803329L (fi) * | 1980-10-23 | 1982-04-24 | Farmos Oy | Vaextsubstratbaedd |
US4591426A (en) * | 1981-10-08 | 1986-05-27 | Intevep, S.A. | Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content |
US4376037A (en) * | 1981-10-16 | 1983-03-08 | Chevron Research Company | Hydroprocessing of heavy hydrocarbonaceous oils |
US4427535A (en) * | 1981-11-02 | 1984-01-24 | Hydrocarbon Research, Inc. | Selective operating conditions for high conversion of special petroleum feedstocks |
US4447314A (en) * | 1982-05-05 | 1984-05-08 | Mobil Oil Corporation | Demetalation, desulfurization, and decarbonization of petroleum oils by hydrotreatment in a dual bed system prior to cracking |
JPS58219293A (ja) * | 1982-06-15 | 1983-12-20 | Chiyoda Chem Eng & Constr Co Ltd | 重質油の水素化分解方法 |
FR2528721B1 (fr) * | 1982-06-17 | 1986-02-28 | Pro Catalyse Ste Fse Prod Cata | Catalyseur supporte presentant une resistance accrue aux poisons et son utilisation en particulier pour l'hydrotraitement de fractions petrolieres contenant des metaux |
US4437980A (en) * | 1982-07-30 | 1984-03-20 | Rockwell International Corporation | Molten salt hydrotreatment process |
US4886594A (en) * | 1982-12-06 | 1989-12-12 | Amoco Corporation | Hydrotreating catalyst and process |
US4450068A (en) * | 1982-12-20 | 1984-05-22 | Phillips Petroleum Company | Demetallization of hydrocarbon containing feed streams |
US4460707A (en) * | 1982-12-28 | 1984-07-17 | Union Oil Company Of California | Hydroprocessing catalyst and method for preparing it |
FR2538813A1 (fr) * | 1982-12-31 | 1984-07-06 | Inst Francais Du Petrole | Procede d'hydrotraitement convertissant en au moins deux etapes une fraction lourde d'hydrocarbures contenant des impuretes soufrees et des impuretes metalliques |
US4498979A (en) * | 1983-09-12 | 1985-02-12 | Exxon Research & Engineering Co. | Hydrodesulfurization process with conversion of heavy hydrocarbons utilizing a catalyst containing a group IIA metal component |
US4587012A (en) * | 1983-10-31 | 1986-05-06 | Chevron Research Company | Process for upgrading hydrocarbonaceous feedstocks |
US4588709A (en) * | 1983-12-19 | 1986-05-13 | Intevep, S.A. | Catalyst for removing sulfur and metal contaminants from heavy crudes and residues |
US4520128A (en) * | 1983-12-19 | 1985-05-28 | Intevep, S.A. | Catalyst having high metal retention capacity and good stability for use in the demetallization of heavy crudes and method of preparation of same |
US4572778A (en) * | 1984-01-19 | 1986-02-25 | Union Oil Company Of California | Hydroprocessing with a large pore catalyst |
US4564439A (en) * | 1984-06-29 | 1986-01-14 | Chevron Research Company | Two-stage, close-coupled thermal catalytic hydroconversion process |
US4659454A (en) * | 1984-12-21 | 1987-04-21 | Mobil Oil Corporation | Hydrocracking of heavy feeds plus light fractions with dispersed dual function catalyst |
US4665261A (en) * | 1985-06-21 | 1987-05-12 | Atlantic Richfield Company | Hydrocarbon conversion process using a molten salt |
US5108581A (en) * | 1985-09-09 | 1992-04-28 | Exxon Research And Engineering Company | Hydroconversion of heavy feeds by use of both supported and unsupported catalysts |
US4661265A (en) * | 1985-09-30 | 1987-04-28 | Amoco Corporation | Catalyst deoiling process |
US4746419A (en) * | 1985-12-20 | 1988-05-24 | Amoco Corporation | Process for the hydrodemetallation hydrodesulfuration and hydrocracking of a hydrocarbon feedstock |
US4729826A (en) * | 1986-02-28 | 1988-03-08 | Union Oil Company Of California | Temperature controlled catalytic demetallization of hydrocarbons |
US4738884A (en) * | 1986-03-03 | 1988-04-19 | Owens-Corning Fiberglas Corporation | Asphalt adhesives superimposed on asphalt-based roofing sheet |
DE3623430A1 (de) * | 1986-07-11 | 1988-01-28 | Veba Oel Entwicklungs Gmbh | Verfahren zur hydrierenden behandlung von mit chlorbiphenylen u. dgl. kontaminierten mineraloelen |
US4830736A (en) * | 1986-07-28 | 1989-05-16 | Chevron Research Company | Graded catalyst system for removal of calcium and sodium from a hydrocarbon feedstock |
US4917789A (en) * | 1987-02-03 | 1990-04-17 | Fina Technology, Inc. | Catalytic dewaxing process |
US5047142A (en) * | 1988-05-13 | 1991-09-10 | Texaco Inc. | Catalyst composition and method for hydroprocessing petroleum feedstocks |
JP2631712B2 (ja) * | 1988-08-18 | 1997-07-16 | コスモ石油株式会社 | 重質炭化水素油の水素化処理触媒組成物ならびにそれを用いる水素化処理方法 |
US4992157A (en) * | 1988-08-29 | 1991-02-12 | Uop | Process for improving the color and color stability of hydrocarbon fraction |
US5089463A (en) * | 1988-10-04 | 1992-02-18 | Chevron Research And Technology Company | Hydrodemetalation and hydrodesulfurization catalyst of specified macroporosity |
US4992163A (en) * | 1989-12-13 | 1991-02-12 | Exxon Research And Engineering Company | Cat cracking feed preparation |
EP0460300A1 (fr) * | 1990-06-20 | 1991-12-11 | Akzo Nobel N.V. | Procédé de préparation d'un catalyseur présulfuré, procédé de préparation d'un catalyseur sulfuré et utilisation d'un tel catalyseur |
US5089453A (en) * | 1990-06-25 | 1992-02-18 | Chevron Research And Technology Company | Hydroconversion catalyst and method for making the catalyst |
US5200060A (en) * | 1991-04-26 | 1993-04-06 | Amoco Corporation | Hydrotreating process using carbides and nitrides of group VIB metals |
US5171727A (en) * | 1991-08-26 | 1992-12-15 | Uop | Method of preparing a catalyst for the hydroconversion of asphaltene-containing hydrocarbonaceous charge stocks |
US5223472A (en) * | 1992-04-14 | 1993-06-29 | Union Oil Company Of California | Demetallation catalyst |
US5300212A (en) * | 1992-10-22 | 1994-04-05 | Exxon Research & Engineering Co. | Hydroconversion process with slurry hydrotreating |
FR2701270B1 (fr) * | 1993-02-08 | 1995-04-14 | Inst Francais Du Petrole | Procédé d'élimination du mercure dans les hydrocarbures par passage sur un catalyseur présulfuré. |
US5397456A (en) * | 1993-02-19 | 1995-03-14 | Texaco Inc. | Hydroconversion process employing catalyst with specified pore size distribution |
US5395536A (en) * | 1993-05-07 | 1995-03-07 | Baker Hughes, Inc. | Wastewater organic acid removal process |
US5514273A (en) * | 1993-10-01 | 1996-05-07 | Texaco Inc. | Hydroconversion process employing catalyst with specified pore size distribution |
US5620592A (en) * | 1994-07-29 | 1997-04-15 | Chevron U.S.A. Inc. | Low macropore resid conversion catalyst |
NO303837B1 (no) * | 1994-08-29 | 1998-09-07 | Norske Stats Oljeselskap | FremgangsmÕte for Õ fjerne hovedsakelig naftensyrer fra en hydrokarbonolje |
DE19600684A1 (de) * | 1995-02-17 | 1996-08-22 | Linde Ag | Verfahren zum Spalten von Kohlenwasserstoffen und Vorrichtung |
US5885441A (en) * | 1997-04-11 | 1999-03-23 | Intevep, S.A. | Steam conversion process and catalyst |
US5807469A (en) * | 1995-09-27 | 1998-09-15 | Intel Corporation | Flexible continuous cathode contact circuit for electrolytic plating of C4, tab microbumps, and ultra large scale interconnects |
US6210564B1 (en) * | 1996-06-04 | 2001-04-03 | Exxon Research And Engineering Company | Process for desulfurization of petroleum feeds utilizing sodium metal |
US5856609A (en) * | 1996-09-12 | 1999-01-05 | Phillips Petroleum Company | Aromatic hydrodealkylation process with sulfur oxide containing catalyst |
EP0848992B1 (fr) * | 1996-12-17 | 2002-03-27 | Institut Francais Du Petrole | Catalyseur contenant du bore et du silicium et son utilisation en hydrotraitement de charges hydrocarbonées |
US5744025A (en) * | 1997-02-28 | 1998-04-28 | Shell Oil Company | Process for hydrotreating metal-contaminated hydrocarbonaceous feedstock |
FR2764213B1 (fr) * | 1997-06-10 | 1999-07-16 | Inst Francais Du Petrole | Catalyseur d'hydrotraitement de charges hydrocarbonees dans un reacteur a lit fixe |
US5897769A (en) * | 1997-08-29 | 1999-04-27 | Exxon Research And Engineering Co. | Process for selectively removing lower molecular weight naphthenic acids from acidic crudes |
US5871636A (en) * | 1997-08-29 | 1999-02-16 | Exxon Research And Engineering Company | Catalytic reduction of acidity of crude oils in the absence of hydrogen |
US6218333B1 (en) * | 1999-02-15 | 2001-04-17 | Shell Oil Company | Preparation of a hydrotreating catalyst |
US6554994B1 (en) * | 1999-04-13 | 2003-04-29 | Chevron U.S.A. Inc. | Upflow reactor system with layered catalyst bed for hydrotreating heavy feedstocks |
US6509291B2 (en) * | 2000-04-11 | 2003-01-21 | Akzo Nobel N.V. | Process for sulfiding a catalyst containing an S-containing additive |
US6524469B1 (en) * | 2000-05-16 | 2003-02-25 | Trans Ionics Corporation | Heavy oil upgrading process |
US6203313B1 (en) * | 2000-06-09 | 2001-03-20 | Rebbecca L. Holmes | Candle having reconfigurable shape |
US20020056664A1 (en) * | 2000-09-07 | 2002-05-16 | Julie Chabot | Extension of catalyst cycle length in residuum desulfurization processes |
US6547957B1 (en) * | 2000-10-17 | 2003-04-15 | Texaco, Inc. | Process for upgrading a hydrocarbon oil |
RU2282784C2 (ru) * | 2001-04-20 | 2006-08-27 | Эксонмобил Апстрим Рисерч Компани | Способ и устройство для обогащения тяжелой нефти |
US20030042174A1 (en) * | 2001-06-18 | 2003-03-06 | Petronetiics Llc. | Method to treat emulsified hydrocarbon mixtures |
US6841062B2 (en) * | 2001-06-28 | 2005-01-11 | Chevron U.S.A. Inc. | Crude oil desulfurization |
US6887369B2 (en) * | 2001-09-17 | 2005-05-03 | Southwest Research Institute | Pretreatment processes for heavy oil and carbonaceous materials |
US20030070808A1 (en) * | 2001-10-15 | 2003-04-17 | Conoco Inc. | Use of syngas for the upgrading of heavy crude at the wellhead |
-
2006
- 2006-04-07 EP EP06740768A patent/EP1869144A1/fr not_active Withdrawn
- 2006-04-07 RU RU2007141711/04A patent/RU2007141711A/ru not_active Application Discontinuation
- 2006-04-07 CN CNA2006800146543A patent/CN101166809A/zh active Pending
- 2006-04-07 CA CA002604009A patent/CA2604009A1/fr not_active Abandoned
- 2006-04-07 BR BRPI0610669A patent/BRPI0610669A2/pt not_active IP Right Cessation
- 2006-04-07 WO PCT/US2006/013176 patent/WO2006110595A1/fr active Application Filing
- 2006-04-07 JP JP2008506548A patent/JP2008536001A/ja not_active Abandoned
- 2006-04-07 US US11/400,628 patent/US20060231457A1/en not_active Abandoned
- 2006-04-11 NL NL2000053A patent/NL2000053C2/nl not_active IP Right Cessation
-
2007
- 2007-11-09 NO NO20075769A patent/NO20075769L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
WO2006110595A1 (fr) | 2006-10-19 |
US20060231457A1 (en) | 2006-10-19 |
CN101166809A (zh) | 2008-04-23 |
CA2604009A1 (fr) | 2006-10-19 |
EP1869144A1 (fr) | 2007-12-26 |
BRPI0610669A2 (pt) | 2017-01-31 |
RU2007141711A (ru) | 2009-05-20 |
NL2000053A1 (nl) | 2006-10-12 |
JP2008536001A (ja) | 2008-09-04 |
NO20075769L (no) | 2007-11-09 |
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