MXPA05005899A - Derivados plaguicidas de 5-(acilamino) pirazoles. - Google Patents
Derivados plaguicidas de 5-(acilamino) pirazoles.Info
- Publication number
- MXPA05005899A MXPA05005899A MXPA05005899A MXPA05005899A MXPA05005899A MX PA05005899 A MXPA05005899 A MX PA05005899A MX PA05005899 A MXPA05005899 A MX PA05005899A MX PA05005899 A MXPA05005899 A MX PA05005899A MX PA05005899 A MXPA05005899 A MX PA05005899A
- Authority
- MX
- Mexico
- Prior art keywords
- alkyl
- compound
- haloalkyl
- group
- formula
- Prior art date
Links
- 230000000361 pesticidal effect Effects 0.000 title claims description 8
- 125000004442 acylamino group Chemical group 0.000 title description 2
- 150000003217 pyrazoles Chemical class 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 112
- 238000000034 method Methods 0.000 claims abstract description 44
- 150000003839 salts Chemical class 0.000 claims abstract description 40
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 36
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims description 164
- 125000000217 alkyl group Chemical group 0.000 claims description 89
- 125000001188 haloalkyl group Chemical group 0.000 claims description 44
- 229910052736 halogen Inorganic materials 0.000 claims description 42
- 150000002367 halogens Chemical class 0.000 claims description 42
- 125000003545 alkoxy group Chemical group 0.000 claims description 22
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 22
- 239000000575 pesticide Substances 0.000 claims description 19
- 229910052717 sulfur Inorganic materials 0.000 claims description 17
- 229910052760 oxygen Inorganic materials 0.000 claims description 16
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 125000002947 alkylene group Chemical group 0.000 claims description 13
- 125000004438 haloalkoxy group Chemical group 0.000 claims description 12
- 125000005842 heteroatom Chemical group 0.000 claims description 12
- 229910052721 tungsten Inorganic materials 0.000 claims description 12
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 11
- 125000000623 heterocyclic group Chemical group 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 229920006395 saturated elastomer Polymers 0.000 claims description 10
- 125000006526 (C1-C2) alkyl group Chemical group 0.000 claims description 9
- 101100258328 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) crc-2 gene Proteins 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 8
- 125000003342 alkenyl group Chemical group 0.000 claims description 7
- 125000006272 (C3-C7) cycloalkyl group Chemical group 0.000 claims description 6
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 6
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 6
- 239000003085 diluting agent Substances 0.000 claims description 6
- 125000004076 pyridyl group Chemical group 0.000 claims description 6
- 125000006536 (C1-C2)alkoxy group Chemical group 0.000 claims description 5
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims description 5
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims description 5
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 5
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 5
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims description 5
- 230000010933 acylation Effects 0.000 claims description 5
- 238000005917 acylation reaction Methods 0.000 claims description 5
- 125000006413 ring segment Chemical group 0.000 claims description 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 4
- 125000001118 alkylidene group Chemical group 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 230000007717 exclusion Effects 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- 125000006590 (C2-C6) alkenylene group Chemical group 0.000 claims description 3
- 125000006643 (C2-C6) haloalkenyl group Chemical group 0.000 claims description 3
- 125000000392 cycloalkenyl group Chemical group 0.000 claims description 3
- 125000000232 haloalkynyl group Chemical group 0.000 claims description 3
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims description 2
- 125000006644 (C2-C6) haloalkynyl group Chemical group 0.000 claims description 2
- 101100134929 Gallus gallus COR9 gene Proteins 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 230000029936 alkylation Effects 0.000 claims description 2
- 238000005804 alkylation reaction Methods 0.000 claims description 2
- 238000010534 nucleophilic substitution reaction Methods 0.000 claims description 2
- 239000000273 veterinary drug Substances 0.000 claims description 2
- 125000000304 alkynyl group Chemical group 0.000 claims 2
- 125000000262 haloalkenyl group Chemical group 0.000 claims 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims 2
- 125000006583 (C1-C3) haloalkyl group Chemical group 0.000 claims 1
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- 150000003254 radicals Chemical group 0.000 description 28
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- 239000000047 product Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
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- 229910052801 chlorine Inorganic materials 0.000 description 13
- 206010061217 Infestation Diseases 0.000 description 12
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 12
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- 125000001424 substituent group Chemical group 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
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- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 8
- QFMDFTQOJHFVNR-UHFFFAOYSA-N 1-[2,2-dichloro-1-(4-ethylphenyl)ethyl]-4-ethylbenzene Chemical compound C1=CC(CC)=CC=C1C(C(Cl)Cl)C1=CC=C(CC)C=C1 QFMDFTQOJHFVNR-UHFFFAOYSA-N 0.000 description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
- 240000007594 Oryza sativa Species 0.000 description 6
- 241001481696 Rhipicephalus sanguineus Species 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
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- 230000009261 transgenic effect Effects 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
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- 239000000853 adhesive Substances 0.000 description 5
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- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
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- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- JWXZLCFGVKMEEK-UHFFFAOYSA-N triarathene Chemical compound C1=CC(Cl)=CC=C1C1=CC(C=2C=CC=CC=2)=C(C=2C=CC=CC=2)S1 JWXZLCFGVKMEEK-UHFFFAOYSA-N 0.000 description 1
- 125000004306 triazinyl group Chemical group 0.000 description 1
- 125000001425 triazolyl group Chemical group 0.000 description 1
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940078499 tricalcium phosphate Drugs 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 235000019731 tricalcium phosphate Nutrition 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 241000701451 unidentified granulovirus Species 0.000 description 1
- 244000045561 useful plants Species 0.000 description 1
- LESVOLZBIFDZGS-UHFFFAOYSA-N vamidothion Chemical compound CNC(=O)C(C)SCCSP(=O)(OC)OC LESVOLZBIFDZGS-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000013598 vector Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000005943 zeta-Cypermethrin Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/14—Ectoparasiticides, e.g. scabicides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Tropical Medicine & Parasitology (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Pharmacology & Pharmacy (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02027062 | 2002-12-03 | ||
| PCT/EP2003/012619 WO2004049803A1 (en) | 2002-12-03 | 2003-11-12 | Pesticidal 5- (acylamino) pyrazole derivatives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA05005899A true MXPA05005899A (es) | 2005-08-29 |
Family
ID=32405692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA05005899A MXPA05005899A (es) | 2002-12-03 | 2003-11-12 | Derivados plaguicidas de 5-(acilamino) pirazoles. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US7514561B2 (enExample) |
| EP (1) | EP1569517B1 (enExample) |
| JP (1) | JP4759682B2 (enExample) |
| KR (1) | KR101288753B1 (enExample) |
| CN (2) | CN1719974A (enExample) |
| AR (1) | AR042255A1 (enExample) |
| AU (1) | AU2003288038B2 (enExample) |
| BR (1) | BRPI0316993B1 (enExample) |
| CA (1) | CA2508412C (enExample) |
| CO (1) | CO5690506A2 (enExample) |
| EA (1) | EA011505B1 (enExample) |
| ES (1) | ES2436746T3 (enExample) |
| MX (1) | MXPA05005899A (enExample) |
| NZ (1) | NZ540462A (enExample) |
| WO (1) | WO2004049803A1 (enExample) |
| ZA (1) | ZA200503743B (enExample) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006082952A1 (ja) * | 2005-02-01 | 2006-08-10 | Takeda Pharmaceutical Company Limited | アミド化合物 |
| US20080176826A1 (en) * | 2005-05-25 | 2008-07-24 | Michael Puhl | Pyridine Compounds For Combating Arthropod Pests and Nematodes |
| NZ612417A (en) | 2008-11-19 | 2015-02-27 | Merial Inc | Compositions comprising an aryl pyrazole and/or a formamidine, methods and uses thereof |
| UA108641C2 (uk) | 2010-04-02 | 2015-05-25 | Паразитицидна композиція, яка містить чотири активних агенти, та спосіб її застосування | |
| UA114611C2 (uk) * | 2011-10-26 | 2017-07-10 | Дау Аґросаєнсиз Елелсі | Пестицидні композиції і способи, що їх стосуються |
| BR112014011775A8 (pt) | 2011-11-17 | 2017-07-11 | Merial Ltd | Composições compreendendo um aril pirazol e um imidazol substituído, métodos e usos dos mesmos |
| CN105636441B (zh) | 2013-10-17 | 2018-06-15 | 美国陶氏益农公司 | 制备杀虫化合物的方法 |
| MX2016004940A (es) | 2013-10-17 | 2016-06-28 | Dow Agrosciences Llc | Proceso para la preparacion de compuestos plaguicidas. |
| JP6487426B2 (ja) | 2013-10-17 | 2019-03-20 | ダウ アグロサイエンシィズ エルエルシー | 有害生物防除化合物の調製法 |
| US9085564B2 (en) | 2013-10-17 | 2015-07-21 | Dow Agrosciences Llc | Processes for the preparation of pesticidal compounds |
| JP2016535010A (ja) * | 2013-10-17 | 2016-11-10 | ダウ アグロサイエンシィズ エルエルシー | 有害生物防除性化合物の製造方法 |
| KR20160072155A (ko) | 2013-10-17 | 2016-06-22 | 다우 아그로사이언시즈 엘엘씨 | 살충성 화합물의 제조 방법 |
| CN105636443A (zh) | 2013-10-17 | 2016-06-01 | 美国陶氏益农公司 | 制备杀虫化合物的方法 |
| GB201322334D0 (en) | 2013-12-17 | 2014-01-29 | Agency Science Tech & Res | Maleimide derivatives as modulators of WNT pathway |
| JP2017523163A (ja) | 2014-07-31 | 2017-08-17 | ダウ アグロサイエンシィズ エルエルシー | ３−（３−クロロ−１ｈ−ピラゾール−１−イル）ピリジンの製造方法 |
| US9249122B1 (en) | 2014-07-31 | 2016-02-02 | Dow Agrosciences Llc | Process for the preparation of 3-(3-chloro-1H-pyrazol-1-yl)pyridine |
| BR112017000418A2 (pt) | 2014-07-31 | 2017-11-07 | Dow Agrosciences Llc | processo para a preparação de 3-(3-cloro-1h-pirazol-1-il)piridina |
| US9024031B1 (en) | 2014-08-19 | 2015-05-05 | Dow Agrosciences Llc | Process for the preparation of 3-(3-chloro-1H-pyrazol-1-yl)pyridine |
| EP3191455A4 (en) | 2014-09-12 | 2018-01-24 | Dow AgroSciences LLC | Process for the preparation of 3-(3-chloro-1h-pyrazol-1-yl)pyridine |
| AU2015339096B2 (en) | 2014-10-31 | 2018-08-02 | Boehringer Ingelheim Animal Health USA Inc. | Parasiticidal composition comprising fipronil |
| WO2016163383A1 (ja) * | 2015-04-09 | 2016-10-13 | 住友化学株式会社 | オキサリルアミド化合物及びその有害節足動物防除用途 |
| WO2016163379A1 (ja) * | 2015-04-09 | 2016-10-13 | 住友化学株式会社 | オキサリルアミド化合物及びその有害節足動物防除用途 |
| CN105732505B (zh) * | 2016-01-28 | 2018-10-12 | 中南民族大学 | 丙烯酰胺化芳基吡唑型化合物及其溶剂热一锅合成法与应用 |
| CN105712933B (zh) * | 2016-01-28 | 2019-01-11 | 中南民族大学 | 甲酰化芳基吡唑衍生物及其醚热合成方法和应用 |
| CN106417329B (zh) * | 2016-09-27 | 2019-08-27 | 辽宁省蚕业科学研究所 | 一类柞蚕饰腹寄蝇病防治化合物及使用方法 |
| WO2018125815A1 (en) | 2016-12-29 | 2018-07-05 | Dow Agrosciences Llc | Processes for the preparation of pesticidal compounds |
| WO2018125817A1 (en) | 2016-12-29 | 2018-07-05 | Dow Agrosciences Llc | Processes for the preparation of pesticidal compounds |
| CN107629005A (zh) * | 2017-08-22 | 2018-01-26 | 王泊理 | 多取代苯基吡唑衍生物及其制备方法和用途 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3602728A1 (de) | 1985-05-17 | 1986-11-20 | Bayer Ag, 51373 Leverkusen | Schaedlingsbekaempfungsmittel auf basis von pyrazolderivaten |
| US5232940A (en) | 1985-12-20 | 1993-08-03 | Hatton Leslie R | Derivatives of N-phenylpyrazoles |
| GB8531485D0 (en) | 1985-12-20 | 1986-02-05 | May & Baker Ltd | Compositions of matter |
| GB8713768D0 (en) | 1987-06-12 | 1987-07-15 | May & Baker Ltd | Compositions of matter |
| GB9120641D0 (en) | 1991-09-27 | 1991-11-06 | Ici Plc | Heterocyclic compounds |
| US5556873A (en) * | 1993-02-24 | 1996-09-17 | Rhone-Poulenc Inc. | Pesticidal 1-aryl-5-(substituted alkyl (thio) amido)pyrazoles |
| GB9306184D0 (en) | 1993-03-25 | 1993-05-19 | Zeneca Ltd | Heteroaromatic compounds |
| DE4343832A1 (de) | 1993-12-22 | 1995-06-29 | Bayer Ag | Substituierte 1-Arylpyrazole |
| DE4414333A1 (de) | 1994-04-25 | 1995-10-26 | Bayer Ag | Substituierte Pyridylpyrazole |
| WO1997028126A1 (en) | 1996-01-30 | 1997-08-07 | Takeda Chemical Industries, Ltd. | Arylpyrazole insecticides |
| EP0811615A1 (en) * | 1996-06-03 | 1997-12-10 | Rhone-Poulenc Agrochimie | 1-Aryl-5-(substituted alkyl (thio) amido) pyrazoles and their use as pesticides |
| JP3735159B2 (ja) * | 1996-06-17 | 2006-01-18 | ローヌ−プーラン・アグロシミ | 新規な農薬 |
| GB9625045D0 (en) | 1996-11-30 | 1997-01-22 | Pfizer Ltd | Parasiticidal compounds |
| DE19650197A1 (de) | 1996-12-04 | 1998-06-10 | Bayer Ag | 3-Thiocarbamoylpyrazol-Derivate |
| AR021608A1 (es) | 1998-12-11 | 2002-07-31 | Merial Ltd | Represion de artropodos en animales |
-
2003
- 2003-11-12 JP JP2004556131A patent/JP4759682B2/ja not_active Expired - Fee Related
- 2003-11-12 CN CNA2003801048559A patent/CN1719974A/zh active Pending
- 2003-11-12 ES ES03779895.6T patent/ES2436746T3/es not_active Expired - Lifetime
- 2003-11-12 NZ NZ540462A patent/NZ540462A/en not_active IP Right Cessation
- 2003-11-12 EP EP03779895.6A patent/EP1569517B1/en not_active Expired - Lifetime
- 2003-11-12 WO PCT/EP2003/012619 patent/WO2004049803A1/en not_active Ceased
- 2003-11-12 US US10/537,547 patent/US7514561B2/en not_active Expired - Lifetime
- 2003-11-12 CN CNA2006101492437A patent/CN1944413A/zh active Pending
- 2003-11-12 MX MXPA05005899A patent/MXPA05005899A/es active IP Right Grant
- 2003-11-12 CA CA2508412A patent/CA2508412C/en not_active Expired - Fee Related
- 2003-11-12 AU AU2003288038A patent/AU2003288038B2/en not_active Ceased
- 2003-11-12 EA EA200500930A patent/EA011505B1/ru not_active IP Right Cessation
- 2003-11-12 KR KR1020057009951A patent/KR101288753B1/ko not_active Expired - Fee Related
- 2003-11-12 BR BRPI0316993A patent/BRPI0316993B1/pt not_active IP Right Cessation
- 2003-12-01 AR ARP030104421A patent/AR042255A1/es active IP Right Grant
-
2005
- 2005-05-10 ZA ZA200503743A patent/ZA200503743B/en unknown
- 2005-05-31 CO CO05052700A patent/CO5690506A2/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| US20060135778A1 (en) | 2006-06-22 |
| KR20050084103A (ko) | 2005-08-26 |
| CN1944413A (zh) | 2007-04-11 |
| JP4759682B2 (ja) | 2011-08-31 |
| JP2006509004A (ja) | 2006-03-16 |
| ES2436746T3 (es) | 2014-01-07 |
| BRPI0316993B1 (pt) | 2016-07-05 |
| EP1569517B1 (en) | 2013-10-02 |
| AR042255A1 (es) | 2005-06-15 |
| EP1569517A1 (en) | 2005-09-07 |
| BR0316993A (pt) | 2005-10-25 |
| WO2004049803A1 (en) | 2004-06-17 |
| EA011505B1 (ru) | 2009-04-28 |
| AU2003288038B2 (en) | 2009-04-23 |
| AU2003288038A1 (en) | 2004-06-23 |
| CA2508412A1 (en) | 2004-06-17 |
| EA200500930A1 (ru) | 2006-10-27 |
| US7514561B2 (en) | 2009-04-07 |
| CO5690506A2 (es) | 2006-10-31 |
| ZA200503743B (en) | 2006-11-29 |
| NZ540462A (en) | 2008-03-28 |
| KR101288753B1 (ko) | 2013-07-23 |
| CA2508412C (en) | 2011-07-26 |
| CN1719974A (zh) | 2006-01-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |