MXPA04008020A - Composiciones de revestimiento de dos componentes que contienen poliol de tipo copoliester altamente ramificado. - Google Patents
Composiciones de revestimiento de dos componentes que contienen poliol de tipo copoliester altamente ramificado.Info
- Publication number
- MXPA04008020A MXPA04008020A MXPA04008020A MXPA04008020A MXPA04008020A MX PA04008020 A MXPA04008020 A MX PA04008020A MX PA04008020 A MXPA04008020 A MX PA04008020A MX PA04008020 A MXPA04008020 A MX PA04008020A MX PA04008020 A MXPA04008020 A MX PA04008020A
- Authority
- MX
- Mexico
- Prior art keywords
- highly branched
- coating composition
- composition according
- group
- hydroxyl
- Prior art date
Links
- 239000008199 coating composition Substances 0.000 title claims abstract description 103
- 229920005862 polyol Polymers 0.000 title claims abstract description 84
- 150000003077 polyols Chemical class 0.000 title claims abstract description 83
- 229920001634 Copolyester Polymers 0.000 title claims abstract description 47
- 239000000203 mixture Substances 0.000 claims abstract description 86
- 238000000576 coating method Methods 0.000 claims abstract description 59
- 238000004132 cross linking Methods 0.000 claims abstract description 46
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 38
- 239000011230 binding agent Substances 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 37
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 37
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 37
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 28
- 230000008569 process Effects 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims description 98
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 68
- 239000004970 Chain extender Substances 0.000 claims description 52
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 42
- 239000011248 coating agent Substances 0.000 claims description 42
- 229920000642 polymer Polymers 0.000 claims description 40
- 239000003795 chemical substances by application Substances 0.000 claims description 35
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical group O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 25
- 238000006116 polymerization reaction Methods 0.000 claims description 23
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- 238000004260 weight control Methods 0.000 claims description 22
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 21
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 21
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical group OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 20
- 230000000379 polymerizing effect Effects 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 14
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 14
- 229920000728 polyester Polymers 0.000 claims description 14
- 239000000758 substrate Substances 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 13
- 229920000058 polyacrylate Polymers 0.000 claims description 13
- 150000001412 amines Chemical class 0.000 claims description 10
- 150000002596 lactones Chemical class 0.000 claims description 10
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 7
- 150000002009 diols Chemical class 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 5
- 150000002118 epoxides Chemical class 0.000 claims description 4
- 125000003700 epoxy group Chemical group 0.000 claims description 4
- 230000035876 healing Effects 0.000 claims description 4
- 150000003512 tertiary amines Chemical class 0.000 claims description 3
- 150000003606 tin compounds Chemical class 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- 229920000608 Polyaspartic Polymers 0.000 claims description 2
- 150000004705 aldimines Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 235000011007 phosphoric acid Nutrition 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 2
- 239000004606 Fillers/Extenders Substances 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 claims 1
- 150000003460 sulfonic acids Chemical class 0.000 claims 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 41
- 239000007787 solid Substances 0.000 description 33
- 238000006243 chemical reaction Methods 0.000 description 30
- 239000000243 solution Substances 0.000 description 30
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 25
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 24
- 239000002253 acid Substances 0.000 description 24
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 24
- 239000010410 layer Substances 0.000 description 21
- -1 molecule Chemical class 0.000 description 21
- 238000012360 testing method Methods 0.000 description 21
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 20
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 18
- 239000005058 Isophorone diisocyanate Substances 0.000 description 17
- 239000000470 constituent Substances 0.000 description 17
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 15
- 238000010411 cooking Methods 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 238000005259 measurement Methods 0.000 description 13
- 239000002585 base Substances 0.000 description 12
- 150000007974 melamines Chemical class 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- 239000012948 isocyanate Substances 0.000 description 11
- 230000008961 swelling Effects 0.000 description 11
- 239000008096 xylene Substances 0.000 description 11
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 238000005227 gel permeation chromatography Methods 0.000 description 8
- 150000002513 isocyanates Chemical class 0.000 description 8
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 7
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000012975 dibutyltin dilaurate Substances 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 7
- 238000000526 short-path distillation Methods 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 238000002845 discoloration Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 6
- 238000010992 reflux Methods 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 238000000113 differential scanning calorimetry Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 4
- WHBMMWSBFZVSSR-UHFFFAOYSA-N 3-hydroxybutyric acid Chemical compound CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 description 4
- REKYPYSUBKSCAT-UHFFFAOYSA-N 3-hydroxypentanoic acid Chemical compound CCC(O)CC(O)=O REKYPYSUBKSCAT-UHFFFAOYSA-N 0.000 description 4
- ALRHLSYJTWAHJZ-UHFFFAOYSA-N 3-hydroxypropionic acid Chemical compound OCCC(O)=O ALRHLSYJTWAHJZ-UHFFFAOYSA-N 0.000 description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical class OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 4
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- 235000009161 Espostoa lanata Nutrition 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003377 acid catalyst Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000005253 cladding Methods 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical class CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 2
- WPWHSFAFEBZWBB-UHFFFAOYSA-N 1-butyl radical Chemical compound [CH2]CCC WPWHSFAFEBZWBB-UHFFFAOYSA-N 0.000 description 2
- AAMHBRRZYSORSH-UHFFFAOYSA-N 2-octyloxirane Chemical compound CCCCCCCCC1CO1 AAMHBRRZYSORSH-UHFFFAOYSA-N 0.000 description 2
- WACQLQIAUWURGA-UHFFFAOYSA-N 3-hydroxy-2,2-bis(hydroxymethyl)propanoic acid Chemical compound OCC(CO)(CO)C(O)=O WACQLQIAUWURGA-UHFFFAOYSA-N 0.000 description 2
- RDFQSFOGKVZWKF-UHFFFAOYSA-N 3-hydroxy-2,2-dimethylpropanoic acid Chemical compound OCC(C)(C)C(O)=O RDFQSFOGKVZWKF-UHFFFAOYSA-N 0.000 description 2
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- BFKVXNPJXXJUGQ-UHFFFAOYSA-N [CH2]CCCC Chemical compound [CH2]CCCC BFKVXNPJXXJUGQ-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000002981 blocking agent Substances 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
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- 238000007796 conventional method Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 2
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- BHXIWUJLHYHGSJ-UHFFFAOYSA-N ethyl 3-ethoxypropanoate Chemical compound CCOCCC(=O)OCC BHXIWUJLHYHGSJ-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid group Chemical group C(CCCCC)(=O)O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 description 2
- 238000010191 image analysis Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229920002397 thermoplastic olefin Polymers 0.000 description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 2
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4063—Mixtures of compounds of group C08G18/62 with other macromolecular compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/40—High-molecular-weight compounds
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- C—CHEMISTRY; METALLURGY
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
- C08G18/4269—Lactones
- C08G18/4277—Caprolactone and/or substituted caprolactone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US35906602P | 2002-02-20 | 2002-02-20 | |
| PCT/US2003/004883 WO2003070844A1 (en) | 2002-02-20 | 2003-02-19 | Two component coating compositions containing highly branched copolyester polyol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA04008020A true MXPA04008020A (es) | 2004-11-26 |
Family
ID=27757768
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA04008020A MXPA04008020A (es) | 2002-02-20 | 2003-02-19 | Composiciones de revestimiento de dos componentes que contienen poliol de tipo copoliester altamente ramificado. |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6998154B2 (https=) |
| EP (1) | EP1476515A1 (https=) |
| JP (1) | JP2005517795A (https=) |
| KR (1) | KR20040096585A (https=) |
| AU (1) | AU2003216307A1 (https=) |
| BR (1) | BR0307823A (https=) |
| CA (1) | CA2476851A1 (https=) |
| MX (1) | MXPA04008020A (https=) |
| TW (1) | TW200303340A (https=) |
| WO (1) | WO2003070844A1 (https=) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200303340A (en) | 2002-02-20 | 2003-09-01 | Du Pont | Two component coating compositions containing highly branched copolyester polyol |
| ATE328973T1 (de) | 2002-02-20 | 2006-06-15 | Du Pont | Lacke mit hochverzweigtem copolyesterpolyol |
| JP4343672B2 (ja) * | 2003-04-07 | 2009-10-14 | キヤノン株式会社 | フルカラー画像形成用カラートナー |
| US7361715B2 (en) * | 2003-12-16 | 2008-04-22 | Ppg Industries Ohio, Inc. | Polymer additives for powder coatings |
| US20050238899A1 (en) * | 2004-04-27 | 2005-10-27 | Isao Nagata | High solids clearcoat compositions containing silane functional compounds |
| DE102004026904A1 (de) | 2004-06-01 | 2005-12-22 | Basf Ag | Hochfunktionelle, hoch- oder hyperverzweigte Polyester sowie deren Herstellung und Verwendung |
| WO2005121209A1 (ja) * | 2004-06-11 | 2005-12-22 | Kansai Paint Co., Ltd. | ポリエステル樹脂及び熱硬化性水性塗料組成物 |
| US20050277732A1 (en) * | 2004-06-14 | 2005-12-15 | Yu Poli C | Two-component coating composition |
| US20070003691A1 (en) * | 2005-05-05 | 2007-01-04 | Rodrigues Allan B J | Color clustering technique for matching refinish paints |
| WO2007016234A2 (en) * | 2005-07-29 | 2007-02-08 | E. I. Du Pont De Nemours And Company | Method for producing damage resistant multi-layer coatings on an automotive body or part thereof |
| US7666331B2 (en) * | 2005-08-31 | 2010-02-23 | Transitions Optical, Inc. | Photochromic article |
| US8754166B2 (en) * | 2005-09-12 | 2014-06-17 | Axalta Coating Systems Ip Co., Llc | Coatings system with common activator and common volumetric mix ratio |
| US7740911B2 (en) * | 2005-10-07 | 2010-06-22 | E. I. Du Pont De Nemours And Company | Method of forming a multi-layer coating on automobile bodies without a primer bake |
| JP4961727B2 (ja) * | 2005-11-25 | 2012-06-27 | Ｂａｓｆコーティングスジャパン株式会社 | 塗料組成物、塗装仕上げ方法及び塗装物品 |
| WO2007149299A1 (en) * | 2006-06-16 | 2007-12-27 | E. I. Du Pont De Nemours And Company | Color chips prepared by color clustering used for matching refinish paints |
| DE102006044035A1 (de) * | 2006-09-14 | 2008-03-27 | Basf Coatings Ag | Calciumhydrogenphosphathaltige Beschichtungszusammensetzung, Verfahren zu ihrer Herstellung, ihre Verwendung und mit ihr beschichtete Substrate |
| US7867617B2 (en) * | 2006-09-29 | 2011-01-11 | E.I. Du Pont De Nemours And Company | Low temperature curable melamine containing coating composition and the use thereof |
| US8568888B2 (en) * | 2007-03-15 | 2013-10-29 | Nanovere Technologies, Inc. | Dendritic polyurethane coating |
| US8206827B2 (en) * | 2007-03-15 | 2012-06-26 | Nanovere Technologies, Llc | Dendritic polyurethane coating |
| DE102007026722A1 (de) * | 2007-06-06 | 2008-12-11 | Basf Coatings Japan Ltd., Yokohama | Klarlackzusammensetzungen enthaltend hyperverzweigte, dendritische hydroxyfunktionelle Polyester |
| DE102007026724A1 (de) * | 2007-06-06 | 2008-12-11 | Basf Coatings Japan Ltd., Yokohama | Bindemittel mit hoher OH-Zahl und sie enthaltende Klarlackzusammensetzungen mit guten optischen Eigenschaften und guter Kratz- und Chemikalienbeständigkeit |
| US7872078B2 (en) * | 2007-08-28 | 2011-01-18 | Ppg Industries Ohio, Inc. | Curable film-forming compositions demonstrating self-healing properties |
| US20100222505A1 (en) * | 2007-08-28 | 2010-09-02 | Ppg Industries Ohio, Inc. | Curable film-forming compositions demonstrating self-healing properties |
| MX2010013569A (es) * | 2008-06-18 | 2010-12-21 | Du Pont | Composicion de revestimiento a base de poliester y politrimetileno eter diol. |
| DE102008060454A1 (de) * | 2008-12-05 | 2010-06-10 | Basf Coatings Ag | Beschichtungsmittel und daraus hergestellte Beschichtungen mit hoher Kratzbeständigkeit und Witterungsstabilität sowie guten optischen Eigenschaften |
| CA2746797A1 (en) | 2008-12-30 | 2010-07-08 | E.I. Du Pont De Nemours And Company | Waterborne coating composition containing polytrimethylene ether diol |
| US20110135832A1 (en) * | 2009-12-04 | 2011-06-09 | Basf Coatings Ag | Method and composition for refinish coatings |
| US20110152457A1 (en) * | 2009-12-17 | 2011-06-23 | E. I. Du Pont De Nemours And Company | Polyester Compositions with Good Melt Rheological Properties |
| US20110152456A1 (en) * | 2009-12-17 | 2011-06-23 | E. I. Du Pont De Nemours And Company | Polyester Compositions with Good Melt Rheological Properties |
| US8410205B2 (en) * | 2010-08-31 | 2013-04-02 | E I Du Pont De Nemours And Company | Matting agent composition containing low molecular weight polytrimethylene ether glycol |
| JP2012087183A (ja) * | 2010-10-18 | 2012-05-10 | Dic Corp | 耐傷性に優れるコーティング樹脂組成物 |
| KR101292292B1 (ko) | 2011-02-18 | 2013-08-05 | 포항공과대학교 산학협력단 | 강판용 도료 조성물 및 이를 이용한 표면처리강판 |
| US20130034741A1 (en) * | 2011-08-04 | 2013-02-07 | Ppg Industries Ohio, Inc. | Branched polyester polymers comprising isophthalic acid and coatings comprising the same |
| DE112012005181B4 (de) | 2011-12-12 | 2019-07-04 | Coatings Foreign Ip Co. Llc | Wasserbasierende Beschichtungszusammensetzung, die Polytrimethylenetherpolyol aus Bioressourcen enthält, Mehrschichtlackierung und Verfahren zum Bilden einer Mehrschichtlackierung |
| US9714362B2 (en) * | 2012-02-21 | 2017-07-25 | Axalta Coating Systems IP Co. LLC | Low temperature curing coating composition and use thereof |
| CN102911349B (zh) * | 2012-10-11 | 2014-05-07 | 华南理工大学 | 一种己内酯改性超支化聚酯及其制备方法与应用 |
| US20150079294A1 (en) * | 2013-09-13 | 2015-03-19 | Bayer Materialscience Llc | Coating compositions and methods for their use |
| CN107109205A (zh) * | 2014-12-30 | 2017-08-29 | 佐治亚-太平洋化工品有限公司 | 含超支化聚氨酯涂层的涂覆支撑剂及其使用方法 |
| CN108368246B (zh) * | 2015-12-16 | 2020-06-09 | 巴斯夫涂料有限公司 | 羧基官能的聚醚基反应产物和包含所述反应产物的水性底涂料 |
| CN111448230B (zh) | 2017-12-22 | 2022-10-28 | 三菱化学株式会社 | 树脂组合物、涂料组合物、涂装物 |
| US20240002580A1 (en) * | 2020-12-03 | 2024-01-04 | Huntsman International Llc | Aromatic polyester polyol compound |
| CN114276525B (zh) * | 2021-12-30 | 2023-06-06 | 优卡化学(上海)有限公司 | 一种高支化聚酯产物、触变复合物及涂料 |
| CN116042074B (zh) * | 2023-01-16 | 2024-05-14 | Ppg涂料(天津)有限公司 | 双组份涂料组合物 |
| CN118852594A (zh) * | 2024-07-08 | 2024-10-29 | 佛山麦吉新材料科技有限公司 | 一种超支化聚酯多元醇及其合成方法及超支化水性聚氨酯 |
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|---|---|---|---|---|
| US3169945A (en) * | 1956-04-13 | 1965-02-16 | Union Carbide Corp | Lactone polyesters |
| US3585160A (en) * | 1969-04-21 | 1971-06-15 | Du Pont | Polymer having pendent amino acrylate goups and pendent oxazoline ester groups useful for forming coating compositions |
| US4098743A (en) * | 1976-05-26 | 1978-07-04 | Ppg Industries, Inc. | Polylactone-polyurethanes and aqueous dispersions thereof |
| US4242243A (en) * | 1979-07-18 | 1980-12-30 | E. I. Du Pont De Nemours And Company | High solids ambient temperature curing coatings of acrylic-fatty acid drying oil resins |
| US4719132A (en) * | 1984-09-21 | 1988-01-12 | Ppg Industries, Inc. | Process for the preparation of multi-layered coatings and coated articles derived therefrom |
| US4692481A (en) * | 1984-09-27 | 1987-09-08 | E. I. Du Pont De Nemours And Company | Process for matching color of paint to a colored surface |
| US4849480A (en) * | 1985-10-23 | 1989-07-18 | E. I. Du Pont De Nemours And Company | Crosslinked polymer microparticle |
| US4822685A (en) | 1987-12-10 | 1989-04-18 | Ppg Industries, Inc. | Method for preparing multi-layered coated articles and the coated articles prepared by the method |
| US5010140A (en) * | 1989-05-31 | 1991-04-23 | E. I. Du Pont De Nemours And Company | Process for preparing stabilized polymer dispersion |
| US5279862A (en) * | 1991-10-21 | 1994-01-18 | E. I. Du Pont De Nemours And Company | Process for refinishing clear coat/color coat finish |
| SE9200564L (sv) * | 1992-02-26 | 1993-03-15 | Perstorp Ab | Dendritisk makromolekyl av polyestertyp, foerfarande foer framstaellning daerav samt anvaendning daerav |
| SE503342C2 (sv) * | 1994-10-24 | 1996-05-28 | Perstorp Ab | Hyperförgrenad makromolekyl av polyestertyp samt förfarande för dess framställning |
| US6093777A (en) * | 1994-12-21 | 2000-07-25 | Perstorp Ab | Dendritic polyester macromolecule in thermosetting resin matrix |
| SE9504652D0 (sv) * | 1995-12-22 | 1995-12-22 | Perstorp Ab | Polyester compound |
| US5763528A (en) * | 1996-12-17 | 1998-06-09 | E. I. Du Pont De Nemours And Company | Coating compositions containing non-aqueous dispersed polymers having a high glass transition temperature |
| US6114489A (en) * | 1997-03-27 | 2000-09-05 | Herberts Gmbh | Reactive hyperbranched polymers for powder coatings |
| SE510128C2 (sv) * | 1997-06-26 | 1999-04-19 | Perstorp Ab | Förfarande för framställning av dendritisk polyol |
| US6458885B1 (en) * | 1998-05-29 | 2002-10-01 | Ppg Industries Ohio, Inc. | Fast drying clear coat composition |
| FR2783418B1 (fr) * | 1998-09-17 | 2000-11-10 | Oreal | Composition anti-rides comprenant une association de polymeres tenseurs d'origine synthetique et/ou naturelle et de polyesters dendritiques |
| US6114458A (en) * | 1998-09-23 | 2000-09-05 | International Business Machines Corporation | Highly branched radial block copolymers |
| US6221494B1 (en) * | 1998-11-03 | 2001-04-24 | E.I. Du Pont De Nemours And Company | Reactive oligomers for isocyanate coatings |
| US6130286A (en) * | 1998-12-18 | 2000-10-10 | Ppg Industries Ohio, Inc. | Fast drying clear coat composition with low volatile organic content |
| WO1999060046A1 (en) * | 1998-12-30 | 1999-11-25 | Eastman Chemical Company | Gel resistant, hydrolytically stable polyester resins with high hydroxyl functionality and carboxylic acid functionality for isocyanate cross-linkable, waterborne coatings |
| NZ514218A (en) | 1999-03-17 | 2003-05-30 | Ei Du Pont De Nemours And Company | High solids clear coating composition |
| BR0011204A (pt) | 1999-05-05 | 2002-02-19 | Du Pont | Composição de revestimento e método de produção de um revestimento sobre um substrato |
| US6569956B1 (en) | 1999-12-22 | 2003-05-27 | Basf Corporation | Hyperbranched polyol macromolecule, method of making same, and coating composition including same |
| US6562603B2 (en) * | 2000-08-04 | 2003-05-13 | E. I. Du Pont De Nemours And Company | 3-hydroxycarboxylic acid production and use in branched polymers |
| TW200303340A (en) * | 2002-02-20 | 2003-09-01 | Du Pont | Two component coating compositions containing highly branched copolyester polyol |
| ATE328973T1 (de) * | 2002-02-20 | 2006-06-15 | Du Pont | Lacke mit hochverzweigtem copolyesterpolyol |
-
2003
- 2003-01-24 TW TW92101598A patent/TW200303340A/zh unknown
- 2003-02-19 JP JP2003569747A patent/JP2005517795A/ja not_active Withdrawn
- 2003-02-19 MX MXPA04008020A patent/MXPA04008020A/es not_active Application Discontinuation
- 2003-02-19 AU AU2003216307A patent/AU2003216307A1/en not_active Abandoned
- 2003-02-19 KR KR10-2004-7012886A patent/KR20040096585A/ko not_active Withdrawn
- 2003-02-19 BR BR0307823A patent/BR0307823A/pt not_active IP Right Cessation
- 2003-02-19 US US10/370,338 patent/US6998154B2/en not_active Expired - Lifetime
- 2003-02-19 EP EP20030742817 patent/EP1476515A1/en not_active Withdrawn
- 2003-02-19 WO PCT/US2003/004883 patent/WO2003070844A1/en not_active Ceased
- 2003-02-19 CA CA 2476851 patent/CA2476851A1/en not_active Abandoned
-
2004
- 2004-10-13 US US10/964,502 patent/US7199194B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003216307A1 (en) | 2003-09-09 |
| US7199194B2 (en) | 2007-04-03 |
| CA2476851A1 (en) | 2003-08-28 |
| US20040043152A1 (en) | 2004-03-04 |
| BR0307823A (pt) | 2004-12-14 |
| JP2005517795A (ja) | 2005-06-16 |
| TW200303340A (en) | 2003-09-01 |
| KR20040096585A (ko) | 2004-11-16 |
| US20050054786A1 (en) | 2005-03-10 |
| US6998154B2 (en) | 2006-02-14 |
| EP1476515A1 (en) | 2004-11-17 |
| WO2003070844A1 (en) | 2003-08-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA | Abandonment or withdrawal |