MXPA04007388A - Metodo para producir anhidrido ftalico. - Google Patents
Metodo para producir anhidrido ftalico.Info
- Publication number
- MXPA04007388A MXPA04007388A MXPA04007388A MXPA04007388A MXPA04007388A MX PA04007388 A MXPA04007388 A MX PA04007388A MX PA04007388 A MXPA04007388 A MX PA04007388A MX PA04007388 A MXPA04007388 A MX PA04007388A MX PA04007388 A MXPA04007388 A MX PA04007388A
- Authority
- MX
- Mexico
- Prior art keywords
- phthalic anhydride
- maximum temperature
- catalyst layer
- degree
- producing phthalic
- Prior art date
Links
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 title abstract 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
- C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Furan Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Proceso para preparar anhidrido ftalico mediante oxidacion de fase de gas de xileno, naftaleno o mezclas de los mismos en un reactor de coraza-y-tubo termostatado por medio de un medio de transferencia termica a traves de tres o mas catalizadores diferentes de lecho fijo dispuestos en zonas, en donde el proceso se lleva a cabo de manera que la temperatura maxima en la segunda zona de catalizador en la direccion de flujo es hasta 50 degree C inferior a la temperatura maxima en la primera zona de catalizador, y la temperatura maxima en la tercera zona desde la entrada de gas es de 30 a 100 degree C inferior a aquella en la primera zona de catalizador.El proceso de la presente invencion hace posible preparar anhidrido ftalico en rendimientos elevados bajo condiciones industrialmente relevantes.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10206989A DE10206989A1 (de) | 2002-02-19 | 2002-02-19 | Verfahren zur Herstellung von Phthalsäureanhydrid |
PCT/EP2003/001066 WO2003070680A1 (de) | 2002-02-19 | 2003-02-04 | Verfahren zur herstellung von phthalsäureanhydrid |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA04007388A true MXPA04007388A (es) | 2004-10-11 |
Family
ID=27618790
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA04007388A MXPA04007388A (es) | 2002-02-19 | 2003-02-04 | Metodo para producir anhidrido ftalico. |
Country Status (11)
Country | Link |
---|---|
US (1) | US7151184B2 (es) |
EP (1) | EP1478614B1 (es) |
JP (1) | JP4559736B2 (es) |
KR (1) | KR100934519B1 (es) |
CN (1) | CN1281568C (es) |
AT (1) | ATE354559T1 (es) |
AU (1) | AU2003208789A1 (es) |
DE (2) | DE10206989A1 (es) |
ES (1) | ES2280728T3 (es) |
MX (1) | MXPA04007388A (es) |
WO (1) | WO2003070680A1 (es) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10323817A1 (de) * | 2003-05-23 | 2004-12-09 | Basf Ag | Verfahren zur Herstellung von Phthalsäureanhydrid |
DE10323818A1 (de) | 2003-05-23 | 2004-12-09 | Basf Ag | Katalysatorsysteme zur Herstellung von Phthalsäureanhydrid |
US8097558B2 (en) * | 2004-05-29 | 2012-01-17 | Sud-Chemie Ag | Catalyst and method for producing phthalic anhydride |
DE102004026472A1 (de) * | 2004-05-29 | 2005-12-22 | Süd-Chemie AG | Mehrlagen-Katalysator zur Herstellung von Phthalsäureanhydrid |
CN100496740C (zh) * | 2004-05-29 | 2009-06-10 | 苏德-化学股份公司 | 用于制备邻苯二甲酸酐的多层催化剂 |
KR100850857B1 (ko) * | 2005-02-01 | 2008-08-06 | 주식회사 엘지화학 | 불포화 지방산의 제조방법 |
DE102005009473A1 (de) * | 2005-03-02 | 2006-09-07 | Süd-Chemie AG | Mehrlagen-Katalysator zur Herstellung von Phthalsäureanhydrid |
PL1853381T3 (pl) * | 2005-03-02 | 2012-08-31 | Clariant Int Ltd | Sposób produkcji wielowarstwowego katalizatora do produkcji bezwodnika kwasu ftalowego |
BRPI0520292A2 (pt) * | 2005-05-22 | 2009-04-28 | Sued Chemie Ag | catalisador de camadas méltiplas para produÇço de anidrido de Ácido ftÁlico |
DE102005031465A1 (de) * | 2005-07-04 | 2007-01-11 | Basf Ag | Verfahren zum Anfahren von Oxidationskatalysatoren |
US8106220B2 (en) | 2006-05-19 | 2012-01-31 | Basf Se | Preparation of phthalic anhydride by gas phase oxidation of O-xylene in a main reactor and postreactor |
KR101395989B1 (ko) | 2006-05-19 | 2014-05-16 | 바스프 에스이 | o-크실렌 기상 산화에 의한 프탈산 무수물의 제조 |
EP2024085A1 (de) * | 2006-05-19 | 2009-02-18 | Basf Se | Katalysatorsystem zur herstellung von carbonsäuren und/oder carbonsäureanhydriden |
US8901320B2 (en) | 2010-04-13 | 2014-12-02 | Basf Se | Process for controlling a gas phase oxidation reactor for preparation of phthalic anhydride |
WO2011128814A1 (en) | 2010-04-13 | 2011-10-20 | Basf Se | Process for controlling a gas phase oxidation reactor for preparation of phthalic anhydride |
CN105339337A (zh) * | 2013-06-26 | 2016-02-17 | 巴斯夫欧洲公司 | 制备邻苯二甲酸酐的方法 |
EP4182307A1 (de) * | 2020-07-14 | 2023-05-24 | Clariant International Ltd | Verfahren zur inbetriebnahme eines reaktors zur herstellung von phthalsäureanhydrid |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE216299C (es) | ||||
US3565829A (en) | 1967-10-04 | 1971-02-23 | Basf Ag | Supported catalysts containing vanadium pentoxide and titanium dioxide |
DE1769998B2 (de) | 1968-08-20 | 1977-01-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von phthalsaeureanhydrid |
DE2510994B2 (de) | 1975-03-13 | 1977-04-14 | Basf Ag, 6700 Ludwigshafen | Vanadium- und titanhaltiger traegerkatalysator |
DE2546268C3 (de) | 1975-10-16 | 1983-11-24 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Phthalsäureanhydrid aus o-Xylol oder Naphthalin |
DE2547624C2 (de) | 1975-10-24 | 1981-10-08 | Basf Ag, 6700 Ludwigshafen | Vanadinpentoxid, Titandioxid, Antimon und Rubidium enthaltende Trägerkatalysatoren |
AU529228B2 (en) | 1977-07-13 | 1983-06-02 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Catalytic vapour phase oxidation |
JPS603307B2 (ja) | 1978-11-29 | 1985-01-26 | 株式会社日本触媒 | 無水フタル酸の製造方法 |
DE2914683A1 (de) | 1979-04-11 | 1980-10-16 | Basf Ag | Vanadium- und titan- und/oder zirkonhaltiger traegerkatalysator |
CA1145902A (en) | 1979-11-20 | 1983-05-10 | Hydrochem Industrial Services, Inc. | Gelled pigs for cleaning and sanitizing pipelines |
JPS591378B2 (ja) | 1979-12-03 | 1984-01-11 | 株式会社日本触媒 | 無水フタル酸製造用触媒 |
CA1261860A (en) | 1984-05-21 | 1989-09-26 | Yoshiyuki Nakanishi | Method for the preparation of pyromellitic acid or its anhydride |
JPS63253080A (ja) | 1987-04-10 | 1988-10-20 | Nippon Steel Chem Co Ltd | 無水フタル酸の製造方法 |
DE4013051A1 (de) | 1990-04-24 | 1991-11-07 | Basf Ag | Verfahren zur herstellung von phthalsaeureanhydrid aus o-xylol |
SE9700655L (sv) | 1997-02-25 | 1998-05-11 | Neste Oy | Förfarande för framställning av ftalsyraanhydrid |
JP4025891B2 (ja) | 1997-02-27 | 2007-12-26 | ビーエーエスエフ アクチェンゲゼルシャフト | 芳香族炭化水素の接触気相酸化用シェル触媒の製造方法 |
DE19707943C2 (de) | 1997-02-27 | 1999-07-08 | Basf Ag | Verfahren zur Herstellung von Phthalsäureanhydrid und Katalysator hierfür |
CN1280979A (zh) * | 1999-06-24 | 2001-01-24 | 株式会社日本触媒 | 用于生产邻苯二甲酸酐的方法 |
JP4557378B2 (ja) * | 1999-06-24 | 2010-10-06 | 株式会社日本触媒 | 無水フタル酸の製造方法 |
DE10040827A1 (de) * | 2000-08-21 | 2002-03-07 | Basf Ag | Verfahren zur Herstellung von Phthalsäureanhydrid |
-
2002
- 2002-02-19 DE DE10206989A patent/DE10206989A1/de not_active Withdrawn
-
2003
- 2003-02-04 ES ES03706423T patent/ES2280728T3/es not_active Expired - Lifetime
- 2003-02-04 US US10/503,983 patent/US7151184B2/en not_active Expired - Fee Related
- 2003-02-04 DE DE50306580T patent/DE50306580D1/de not_active Expired - Lifetime
- 2003-02-04 AT AT03706423T patent/ATE354559T1/de active
- 2003-02-04 AU AU2003208789A patent/AU2003208789A1/en not_active Abandoned
- 2003-02-04 JP JP2003569590A patent/JP4559736B2/ja not_active Expired - Fee Related
- 2003-02-04 WO PCT/EP2003/001066 patent/WO2003070680A1/de active IP Right Grant
- 2003-02-04 MX MXPA04007388A patent/MXPA04007388A/es active IP Right Grant
- 2003-02-04 EP EP03706423A patent/EP1478614B1/de not_active Revoked
- 2003-02-04 KR KR1020047012803A patent/KR100934519B1/ko not_active IP Right Cessation
- 2003-02-04 CN CNB038041952A patent/CN1281568C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2005529075A (ja) | 2005-09-29 |
KR20040086396A (ko) | 2004-10-08 |
WO2003070680A1 (de) | 2003-08-28 |
CN1281568C (zh) | 2006-10-25 |
JP4559736B2 (ja) | 2010-10-13 |
DE50306580D1 (de) | 2007-04-05 |
US7151184B2 (en) | 2006-12-19 |
AU2003208789A1 (en) | 2003-09-09 |
ATE354559T1 (de) | 2007-03-15 |
KR100934519B1 (ko) | 2009-12-29 |
EP1478614B1 (de) | 2007-02-21 |
ES2280728T3 (es) | 2007-09-16 |
EP1478614A1 (de) | 2004-11-24 |
US20050148782A1 (en) | 2005-07-07 |
DE10206989A1 (de) | 2003-08-21 |
CN1635989A (zh) | 2005-07-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant or registration |