MXPA04004513A - Celda de electrolisis con electrodo de difusion de gas. - Google Patents
Celda de electrolisis con electrodo de difusion de gas.Info
- Publication number
- MXPA04004513A MXPA04004513A MXPA04004513A MXPA04004513A MXPA04004513A MX PA04004513 A MXPA04004513 A MX PA04004513A MX PA04004513 A MXPA04004513 A MX PA04004513A MX PA04004513 A MXPA04004513 A MX PA04004513A MX PA04004513 A MXPA04004513 A MX PA04004513A
- Authority
- MX
- Mexico
- Prior art keywords
- gas
- electrode
- fed
- planar element
- electrolysis cell
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/28—Per-compounds
- C25B1/30—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/04—Diaphragms; Spacing elements characterised by the material
- C25B13/08—Diaphragms; Spacing elements characterised by the material based on organic materials
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0232—Metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0239—Organic resins; Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0241—Composites
- H01M8/0245—Composites in the form of layered or coated products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0223—Composites
- H01M8/0228—Composites in the form of layered or coated products
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Inert Electrodes (AREA)
- Electrolytic Production Of Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Esta descrita una celda electrolitica de membrana que comprende un compartimiento anodico y un compartimiento catodico, en donde al menos uno de los dos compartimientos contiene un electrodo alimentado con gas y un elemento plano poroso esta interpuesto entre la membrana y el electrodo alimentado con gas. Un flujo de electrolito quimicamente agresivo atraviesa el elemento plano poroso descendiendo bajo el efecto de la fuerza de gravedad. El elemento plano consiste en un elemento plastico que sobrelleva las condiciones operativas agresivas: el uso de materias plasticas perfluoradas tales como ECTFE, PTEFE, FEP, PFA es preferido, aunque sean fuertemente hidrofobicas. Cuando el electrodo alimentado con gas es un catodo y el gas contiene oxigeno, el gas atraviesa el compartimiento catodico hacia lo alto para minimizar el riesgo de acumulacion de hidrogeno. La celda provista del catodo de oxigeno es particularmente ventajosa para la electrolisis de cloruro sodico.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT2001MI002379A ITMI20012379A1 (it) | 2001-11-12 | 2001-11-12 | Cella di elettrolisi con elettrodi a diffusione di gas |
PCT/EP2002/012661 WO2003042430A2 (en) | 2001-11-12 | 2002-11-12 | Electrochemical cell with gas diffusion electrodes |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA04004513A true MXPA04004513A (es) | 2004-09-10 |
Family
ID=11448592
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA04004513A MXPA04004513A (es) | 2001-11-12 | 2002-11-12 | Celda de electrolisis con electrodo de difusion de gas. |
Country Status (18)
Country | Link |
---|---|
US (1) | US7670472B2 (es) |
EP (1) | EP1446515B1 (es) |
JP (1) | JP4209777B2 (es) |
KR (1) | KR100939448B1 (es) |
CN (1) | CN1303255C (es) |
AT (1) | ATE509143T1 (es) |
AU (1) | AU2002351989B2 (es) |
BR (1) | BR0214015B1 (es) |
CA (1) | CA2466498C (es) |
ES (1) | ES2365604T3 (es) |
HU (1) | HU227835B1 (es) |
IT (1) | ITMI20012379A1 (es) |
MA (1) | MA26231A1 (es) |
MX (1) | MXPA04004513A (es) |
PL (1) | PL209191B1 (es) |
RU (1) | RU2303085C2 (es) |
WO (1) | WO2003042430A2 (es) |
ZA (1) | ZA200403438B (es) |
Families Citing this family (58)
Publication number | Priority date | Publication date | Assignee | Title |
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TWI255865B (en) * | 2002-11-27 | 2006-06-01 | Asahi Kasei Chemicals Corp | Bipolar, zero-gap type electrolytic cell |
DE10333853A1 (de) * | 2003-07-24 | 2005-02-24 | Bayer Materialscience Ag | Elektrochemische Zelle |
DE10342148A1 (de) * | 2003-09-12 | 2005-04-07 | Bayer Materialscience Ag | Verfahren zur Elektrolyse einer wässrigen Lösung von Chlorwasserstoff oder Alkalichlorid |
DE102004018748A1 (de) | 2004-04-17 | 2005-11-10 | Bayer Materialscience Ag | Elektrochemische Zelle |
JP2006219694A (ja) | 2005-02-08 | 2006-08-24 | Permelec Electrode Ltd | ガス拡散電極 |
JP4834329B2 (ja) * | 2005-05-17 | 2011-12-14 | クロリンエンジニアズ株式会社 | イオン交換膜型電解槽 |
ITMI20060054A1 (it) * | 2006-01-16 | 2007-07-17 | Uhdenora Spa | Distributore di corrente elastico per celle a percolatore |
ITMI20060726A1 (it) | 2006-04-12 | 2007-10-13 | De Nora Elettrodi S P A | Elettrodo a diffusione gassosa per celle a percolazione di elettrolita |
WO2008080118A1 (en) | 2006-12-23 | 2008-07-03 | Miox Corporation | Internal flow control in electrolytic cells |
WO2010002861A1 (en) * | 2008-07-02 | 2010-01-07 | Miox Corporation | Internal flow control in electrolytic cells |
KR101263593B1 (ko) * | 2009-02-17 | 2013-05-10 | 맥알리스터 테크놀로지즈 엘엘씨 | 전기분해 중에 가스 포집을 위한 장치 및 방법 |
BRPI1008696A2 (pt) | 2009-02-17 | 2016-03-08 | Mcalister Technologies Llc | célula eletrolítica e método para usar a mesma. |
US9040012B2 (en) | 2009-02-17 | 2015-05-26 | Mcalister Technologies, Llc | System and method for renewable resource production, for example, hydrogen production by microbial electrolysis, fermentation, and/or photosynthesis |
WO2010096504A1 (en) * | 2009-02-17 | 2010-08-26 | Mcalister Technologies, Llc | Apparatus and method for controlling nucleation during electrolysis |
US9067810B2 (en) * | 2009-03-02 | 2015-06-30 | Chester J. Sohn | Electrolytic apparatus for treating ballast water and treatment system using same |
US9315908B2 (en) * | 2010-07-13 | 2016-04-19 | Chlorine Engineers Corp. | Electrolytic cell for producing chlorine—sodium hydroxide and method of producing chlorine—sodium hydroxide |
CN102456904B (zh) * | 2010-10-29 | 2014-04-09 | 大连融科储能技术发展有限公司 | 一种液流储能电池结构 |
DE102010054159A1 (de) * | 2010-12-10 | 2012-06-14 | Bayer Materialscience Aktiengesellschaft | Verfahren zum Einbau von Sauerstoffverzehrelektroden in elektrochemischen Zellen und elektrochemische Ze lle |
DE102010062803A1 (de) * | 2010-12-10 | 2012-06-14 | Bayer Materialscience Aktiengesellschaft | Verfahren zum Einbau von Sauerstoffverzehrelektroden in elektrochemische Zellen und elektrochemische Zellen |
DE102010054643A1 (de) | 2010-12-15 | 2012-06-21 | Bayer Material Science Ag | Elektrolyseur mit spiralförmigem Einlaufschlauch |
DE102011008163A1 (de) * | 2011-01-10 | 2012-07-12 | Bayer Material Science Ag | Beschichtung für metallische Zellelement-Werkstoffe einer Elektrolysezelle |
DE102011017264A1 (de) | 2011-04-15 | 2012-10-18 | Bayer Material Science Ag | Alternativer Einbau einer Gas-Diffussions-Elektrode in eine elektrochemische Zelle |
DE102011100768A1 (de) | 2011-05-06 | 2012-12-06 | Bayer Material Science Ag | Elektrochemische Zelle mit Rahmendichtung zur alternativen Abdichtung gegenRandläufigkeiten des Elektrolyten |
EP2525430A1 (de) * | 2011-05-19 | 2012-11-21 | Siemens Aktiengesellschaft | Befeuchtungszelle mit Stützgewebe aus Fluorkunststoff |
US8562810B2 (en) | 2011-07-26 | 2013-10-22 | Ecolab Usa Inc. | On site generation of alkalinity boost for ware washing applications |
TWI568888B (zh) * | 2011-09-15 | 2017-02-01 | 第諾拉工業公司 | 氣體擴散電極及其製法和電化電解池 |
ITMI20111938A1 (it) * | 2011-10-26 | 2013-04-27 | Industrie De Nora Spa | Comparto anodico per celle per estrazione elettrolitica di metalli |
DE102012204040A1 (de) * | 2012-03-15 | 2013-09-19 | Bayer Materialscience Aktiengesellschaft | Verfahren zur Elektrolyse von Alkalichloriden mit Sauerstoffverzehrelektroden |
CA3101570C (en) * | 2012-05-28 | 2023-06-20 | Hydrogenics Corporation | Electrolyser and energy system |
CA2876236A1 (en) | 2012-06-12 | 2013-12-19 | Monash University | Breathable electrode and method for use in water splitting |
CN102978656B (zh) * | 2012-08-16 | 2015-04-08 | 郭越玖 | 一种实现旋转离心重力水电解制氢方法的装置 |
ITMI20121736A1 (it) * | 2012-10-16 | 2014-04-17 | Industrie De Nora Spa | Cella di elettrolisi di soluzioni alcaline |
US8808512B2 (en) | 2013-01-22 | 2014-08-19 | GTA, Inc. | Electrolyzer apparatus and method of making it |
US9222178B2 (en) | 2013-01-22 | 2015-12-29 | GTA, Inc. | Electrolyzer |
US9127244B2 (en) | 2013-03-14 | 2015-09-08 | Mcalister Technologies, Llc | Digester assembly for providing renewable resources and associated systems, apparatuses, and methods |
ITMI20130563A1 (it) * | 2013-04-10 | 2014-10-11 | Uhdenora Spa | Metodo di adeguamento di celle elettrolitiche aventi distanze interelettrodiche finite |
DE102013011298A1 (de) * | 2013-07-08 | 2015-02-12 | Uhdenora S.P.A. | Vorrichtung und Verfahren zum Betrieb einer Elektrolyse mit einer Sauerstoff-Verzehr Kathode |
CN112127961B (zh) | 2013-07-19 | 2023-03-28 | Itm动力(研究)有限公司 | 减压系统 |
AU2014295913A1 (en) | 2013-07-31 | 2016-02-11 | Aquahydrex Pty Ltd | Method and electrochemical cell for managing electrochemical reactions |
JP6436464B2 (ja) * | 2013-12-04 | 2018-12-12 | コヴェストロ ドイチュラント アクチエンゲゼルシャフトCovestro Deutschland AG | 電力を融通自在に使用するための装置および方法 |
WO2015184388A1 (en) | 2014-05-29 | 2015-12-03 | Liquid Light, Inc. | Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode |
NL2014797B1 (en) * | 2015-05-12 | 2017-01-27 | Stichting Wetsus European Centre Of Excellence For Sustainable Water Tech | Bio-electrochemical system for recovery of components and/or generating electrical energy from a waste stream and method there for. |
WO2017043591A1 (ja) * | 2015-09-08 | 2017-03-16 | 旭硝子株式会社 | 塩化アルカリ電解用イオン交換膜の製造方法および塩化アルカリ電解装置の製造方法 |
CN105461023B (zh) * | 2015-11-06 | 2018-08-10 | 北京航空航天大学 | 一种采用氧还原阴极的电解槽装置 |
KR20180128962A (ko) | 2016-04-07 | 2018-12-04 | 코베스트로 도이칠란트 아게 | 클로르-알칼리 전기분해를 위한 이중기능성 전극 및 전기분해 장치 |
RU2623437C1 (ru) * | 2016-08-15 | 2017-06-26 | Общество с ограниченной ответственностью "Завод электрохимических преобразователей" (ООО "ЗЭП") | Электролизер для получения водорода и кислорода из воды |
MX2019005676A (es) * | 2016-11-15 | 2019-09-10 | Giner Life Sciences Inc | Dispositivo percutáneo de difusión de gases adecuado para su uso con un implante subcutáneo. |
CN108624907A (zh) * | 2018-04-26 | 2018-10-09 | 复旦大学 | 非金属基体高效催化电极及其制备方法 |
DE102018209520A1 (de) * | 2018-06-14 | 2019-12-19 | Thyssenkrupp Uhde Chlorine Engineers Gmbh | Elektrolysezelle |
CN109536989A (zh) * | 2018-08-26 | 2019-03-29 | 熵零技术逻辑工程院集团股份有限公司 | 一种电化学合成装置 |
EP3626861A1 (de) * | 2018-09-18 | 2020-03-25 | Covestro Deutschland AG | Elektrolysezelle, elektrolyseur und verfahren zur reduktion von co2 |
CN110943269B (zh) * | 2018-09-25 | 2021-03-16 | 武汉大学 | 一种高性能的气液两相介质温差电池 |
EP3670706B1 (de) * | 2018-12-18 | 2024-02-21 | Covestro Deutschland AG | Verfahren zur membran-elektrolyse von alkalichloridlösungen mit gasdiffusionselektrode |
US20220145479A1 (en) | 2019-02-01 | 2022-05-12 | Aquahydrex, Inc. | Electrochemical system with confined electrolyte |
RU2757206C1 (ru) * | 2021-01-25 | 2021-10-12 | Юрий Петрович Келлер | Электролизер с укреплённой мембраной |
CN113213596A (zh) * | 2021-05-27 | 2021-08-06 | 成都工业学院 | 一种含砷废水处理装置 |
CN114672827A (zh) * | 2022-03-04 | 2022-06-28 | 化学与精细化工广东省实验室 | 一种阴阳极同步直接生产过氧化氢的电解槽 |
CN116876000B (zh) * | 2023-09-01 | 2023-11-10 | 高密建滔化工有限公司 | 一种氯碱制备设备及其制备方法 |
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JPS61130347A (ja) * | 1984-11-30 | 1986-06-18 | Asahi Glass Co Ltd | 新規な電解用複層隔膜 |
US5599638A (en) * | 1993-10-12 | 1997-02-04 | California Institute Of Technology | Aqueous liquid feed organic fuel cell using solid polymer electrolyte membrane |
US5868912A (en) * | 1993-11-22 | 1999-02-09 | E. I. Du Pont De Nemours And Company | Electrochemical cell having an oxide growth resistant current distributor |
JPH08302492A (ja) * | 1995-04-28 | 1996-11-19 | Permelec Electrode Ltd | ガス拡散電極を使用する電解槽 |
IT1284072B1 (it) * | 1996-06-26 | 1998-05-08 | De Nora Spa | Cella elettrochimica a membrana provvista di elettrodi a diffusione gassosa contattati da portacorrente metallici lisci e porosi a |
JP3553775B2 (ja) * | 1997-10-16 | 2004-08-11 | ペルメレック電極株式会社 | ガス拡散電極を使用する電解槽 |
DE69929442T2 (de) * | 1998-08-25 | 2006-08-24 | Toagosei Co., Ltd. | Elektrolytische sodazelle mit gasdiffusionselektrode |
IT1317753B1 (it) * | 2000-02-02 | 2003-07-15 | Nora S P A Ora De Nora Impiant | Cella di elettrolisi con elettrodo a diffusione di gas. |
US6797136B2 (en) * | 2001-09-07 | 2004-09-28 | Akzo Nobel N.V. | Electrolytic cell |
-
2001
- 2001-11-12 IT IT2001MI002379A patent/ITMI20012379A1/it unknown
-
2002
- 2002-11-12 PL PL368714A patent/PL209191B1/pl unknown
- 2002-11-12 KR KR1020047007131A patent/KR100939448B1/ko not_active IP Right Cessation
- 2002-11-12 CN CNB028224477A patent/CN1303255C/zh not_active Expired - Lifetime
- 2002-11-12 AT AT02787662T patent/ATE509143T1/de active
- 2002-11-12 CA CA2466498A patent/CA2466498C/en not_active Expired - Fee Related
- 2002-11-12 WO PCT/EP2002/012661 patent/WO2003042430A2/en active IP Right Grant
- 2002-11-12 ES ES02787662T patent/ES2365604T3/es not_active Expired - Lifetime
- 2002-11-12 BR BRPI0214015-2A patent/BR0214015B1/pt not_active IP Right Cessation
- 2002-11-12 HU HU0402380A patent/HU227835B1/hu not_active IP Right Cessation
- 2002-11-12 JP JP2003544240A patent/JP4209777B2/ja not_active Expired - Fee Related
- 2002-11-12 RU RU2004117772/15A patent/RU2303085C2/ru active
- 2002-11-12 AU AU2002351989A patent/AU2002351989B2/en not_active Ceased
- 2002-11-12 US US10/494,476 patent/US7670472B2/en active Active
- 2002-11-12 EP EP02787662A patent/EP1446515B1/en not_active Expired - Lifetime
- 2002-11-12 MX MXPA04004513A patent/MXPA04004513A/es active IP Right Grant
-
2004
- 2004-05-04 MA MA27667A patent/MA26231A1/fr unknown
- 2004-05-06 ZA ZA2004/03438A patent/ZA200403438B/en unknown
Also Published As
Publication number | Publication date |
---|---|
AU2002351989B2 (en) | 2007-07-19 |
JP4209777B2 (ja) | 2009-01-14 |
KR20050044403A (ko) | 2005-05-12 |
WO2003042430A3 (en) | 2004-03-11 |
CN1585836A (zh) | 2005-02-23 |
KR100939448B1 (ko) | 2010-01-29 |
HUP0402380A2 (hu) | 2005-03-29 |
RU2303085C2 (ru) | 2007-07-20 |
ES2365604T3 (es) | 2011-10-07 |
CA2466498C (en) | 2011-07-12 |
PL209191B1 (pl) | 2011-08-31 |
ITMI20012379A1 (it) | 2003-05-12 |
WO2003042430A2 (en) | 2003-05-22 |
ZA200403438B (en) | 2005-07-27 |
EP1446515A2 (en) | 2004-08-18 |
ATE509143T1 (de) | 2011-05-15 |
MA26231A1 (fr) | 2004-07-01 |
BR0214015A (pt) | 2004-10-13 |
EP1446515B1 (en) | 2011-05-11 |
CA2466498A1 (en) | 2003-05-22 |
US20050000798A1 (en) | 2005-01-06 |
PL368714A1 (en) | 2005-04-04 |
RU2004117772A (ru) | 2005-04-10 |
HU227835B1 (en) | 2012-05-02 |
JP2005509744A (ja) | 2005-04-14 |
CN1303255C (zh) | 2007-03-07 |
US7670472B2 (en) | 2010-03-02 |
BR0214015B1 (pt) | 2012-09-18 |
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