MXPA04003467A - Procedimiento para la alcoxilacion de compuestos organicos en presencia de materiales estructurales novedosos. - Google Patents
Procedimiento para la alcoxilacion de compuestos organicos en presencia de materiales estructurales novedosos.Info
- Publication number
- MXPA04003467A MXPA04003467A MXPA04003467A MXPA04003467A MXPA04003467A MX PA04003467 A MXPA04003467 A MX PA04003467A MX PA04003467 A MXPA04003467 A MX PA04003467A MX PA04003467 A MXPA04003467 A MX PA04003467A MX PA04003467 A MXPA04003467 A MX PA04003467A
- Authority
- MX
- Mexico
- Prior art keywords
- alkoxylation
- organic compounds
- framework materials
- novel framework
- metal ion
- Prior art date
Links
- 150000002894 organic compounds Chemical class 0.000 title abstract 4
- 239000000463 material Substances 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910021645 metal ion Inorganic materials 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 229920005830 Polyurethane Foam Polymers 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000013384 organic framework Substances 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000011496 polyurethane foam Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyethers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/039,733 US20030078311A1 (en) | 2001-10-19 | 2001-10-19 | Process for the alkoxylation of organic compounds in the presence of novel framework materials |
| PCT/EP2002/011700 WO2003035717A1 (en) | 2001-10-19 | 2002-10-18 | Process for the alkoxylation of organic compounds in the presence of novel framework materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA04003467A true MXPA04003467A (es) | 2004-07-30 |
Family
ID=21907076
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA04003467A MXPA04003467A (es) | 2001-10-19 | 2002-10-18 | Procedimiento para la alcoxilacion de compuestos organicos en presencia de materiales estructurales novedosos. |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US20030078311A1 (enExample) |
| EP (1) | EP1440106B1 (enExample) |
| JP (1) | JP4173101B2 (enExample) |
| KR (1) | KR100940290B1 (enExample) |
| CN (1) | CN100424115C (enExample) |
| AT (1) | ATE535560T1 (enExample) |
| CA (1) | CA2464352A1 (enExample) |
| ES (1) | ES2376050T3 (enExample) |
| MX (1) | MXPA04003467A (enExample) |
| PL (1) | PL370429A1 (enExample) |
| RU (1) | RU2308465C2 (enExample) |
| TW (1) | TWI300072B (enExample) |
| WO (1) | WO2003035717A1 (enExample) |
Families Citing this family (77)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2269761T3 (es) * | 2001-04-30 | 2007-04-01 | The Regents Of The University Of Michigan | Estructuras organometalicas isorreticulares, procedimiento para su formacion, y diseño sistematico del calibre de poros y funcionalidad de los mismos, con aplicacion para el almacenamiento de gases. |
| US6893564B2 (en) * | 2002-05-30 | 2005-05-17 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
| US7008607B2 (en) * | 2002-10-25 | 2006-03-07 | Basf Aktiengesellschaft | Process for preparing hydrogen peroxide from the elements |
| KR101278432B1 (ko) * | 2003-05-09 | 2013-07-04 | 더 리젠츠 오브 더 유니버시티 오브 미시간 | 결정들에서 우수한 수준의 표면적과 다공성의 성취를 위한 방법의 이행 |
| US7309380B2 (en) * | 2003-06-30 | 2007-12-18 | Basf Aktiengesellschaft | Gas storage system |
| US20050004404A1 (en) * | 2003-07-03 | 2005-01-06 | Basf Akiengesellschaft | Process for the alkoxylation of monools in the presence of metallo-organic framework materials |
| DE10355087A1 (de) * | 2003-11-24 | 2005-06-09 | Basf Ag | Verfahren zur elektrochemischen Herstellung eines kristallinen porösen metallorganischen Gerüstmaterials |
| WO2006028479A1 (en) * | 2003-12-05 | 2006-03-16 | The Regents Of The University Of Michigan | Metal-organic polyhedra |
| JP4659356B2 (ja) * | 2003-12-26 | 2011-03-30 | 株式会社イノアックコーポレーション | 再生ポリウレタンフォームの製造方法 |
| CA2584912A1 (en) | 2004-10-22 | 2006-05-04 | The Regents Of The University Of Michigan | Covalently linked organic frameworks and polyhedra |
| US7524444B2 (en) * | 2004-11-09 | 2009-04-28 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
| US7343747B2 (en) * | 2005-02-23 | 2008-03-18 | Basf Aktiengesellschaft | Metal-organic framework materials for gaseous hydrocarbon storage |
| ES2558536T3 (es) * | 2005-04-07 | 2016-02-05 | The Regents Of The University Of Michigan Technology Management Wolverine Tower Office | Adsorción elevada de gas en un marco metal-orgánico con sitios metálicos abiertos |
| US8628055B2 (en) * | 2005-07-27 | 2014-01-14 | The Board Of Trustees Of The University Of Illinois | Bi-direction rapid action electrostatically actuated microvalve |
| US7799120B2 (en) * | 2005-09-26 | 2010-09-21 | The Regents Of The University Of Michigan | Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature |
| US8123834B2 (en) * | 2005-10-06 | 2012-02-28 | The Board Of Trustees Of The University Of Illinois | High gain selective metal organic framework preconcentrators |
| DE102005054523A1 (de) | 2005-11-14 | 2007-05-16 | Basf Ag | Poröses metallorganisches Gerüstmaterial enthaltend ein weiteres Polymer |
| WO2007101241A2 (en) | 2006-02-28 | 2007-09-07 | The Regents Of The University Of Michigan | Preparation of functionalized zeolitic frameworks |
| US7880026B2 (en) * | 2006-04-14 | 2011-02-01 | The Board Of Trustees Of The University Of Illinois | MOF synthesis method |
| US20090092818A1 (en) | 2006-04-18 | 2009-04-09 | Basf Se | Organometallic aluminum fumarate backbone material |
| US7441574B2 (en) | 2006-08-17 | 2008-10-28 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| US9017584B2 (en) * | 2006-10-30 | 2015-04-28 | Alan M. Gilbert | Flame-retardant materials and systems |
| US9719019B1 (en) | 2006-10-30 | 2017-08-01 | Alan M. Gilbert | Flame-retardant materials and systems |
| US20080111114A1 (en) * | 2006-10-30 | 2008-05-15 | Gilbert Alan M | Flame-retardant materials and systems |
| RU2009120403A (ru) | 2006-10-30 | 2010-12-10 | Басф Се (De) | Нафталиндикарбоксилат алюминия в качестве пористого металлорганического материала со скелетной структурой |
| WO2008091976A1 (en) * | 2007-01-24 | 2008-07-31 | The Regents Of The University Of California | Crystalline 3d- and 2d-covalent organic frameworks |
| EP2155390B1 (de) | 2007-04-24 | 2012-10-17 | Basf Se | Metallorganische gerüstmaterialien mit hexagonal-trigonaler struktur basierend auf aluminium, eisen oder chrom, sowie einer dicarbonsäure |
| EP2155608A4 (en) * | 2007-05-11 | 2011-01-12 | Univ California | ADSORPTIVE GAS SEPARATION OF MULTICOMPOSE GASES |
| EP2167511A4 (en) * | 2007-07-17 | 2010-12-22 | Univ California | PREPARATION OF FUNCTIONALIZED ZEOLITE FRAME |
| US9132411B2 (en) | 2007-08-30 | 2015-09-15 | The Regents Of The University Of Michigan | Strategies, linkers and coordination polymers for high-performance sorbents |
| US8222179B2 (en) * | 2007-08-30 | 2012-07-17 | The Regents Of The University Of Michigan | Porous coordination copolymers and methods for their production |
| US8383545B2 (en) * | 2007-08-30 | 2013-02-26 | The Regents Of The University Of Michigan | Strategies, linkers and coordination polymers for high-performance sorbents |
| US8691748B2 (en) * | 2007-09-25 | 2014-04-08 | The Regents Of The University Of California | Edible and biocompatible metal-organic frameworks |
| BRPI0817443A2 (pt) * | 2007-09-28 | 2015-06-16 | Inst Francais Du Petrole | Processo de produção de ésteres alcoólicos, a partir de triglicerídeos e de álcoois, por meio de catalisadores heterogêneos à base de sólido híbrido de matriz mista orgânica - inorgânica |
| FR2921660B1 (fr) | 2007-10-01 | 2015-09-25 | Centre Nat Rech Scient | Nanoparticules hybrides organiques inorganiques a base de carboxylates de fer. |
| FR2921661B1 (fr) * | 2007-10-01 | 2013-05-31 | Centre Nat Rech Scient | Solide hybride organique inorganique a surface modifiee. |
| US8034952B2 (en) * | 2007-11-15 | 2011-10-11 | University Of South Florida | Supramolecular assemblies and building blocks |
| US8123841B2 (en) * | 2008-01-16 | 2012-02-28 | The Board Of Trustees Of The University Of Illinois | Column design for micro gas chromatograph |
| US8142745B2 (en) * | 2008-02-21 | 2012-03-27 | Exxonmobil Research And Engineering Company | Separation of carbon dioxide from nitrogen utilizing zeolitic imidazolate framework materials |
| US8071063B2 (en) | 2008-02-21 | 2011-12-06 | Exxonmobile Research And Engineering Company | Separation of hydrogen from hydrocarbons utilizing zeolitic imidazolate framework materials |
| US8142746B2 (en) * | 2008-02-21 | 2012-03-27 | Exxonmobil Research And Engineering Company | Separation of carbon dioxide from methane utilizing zeolitic imidazolate framework materials |
| FR2929278A1 (fr) * | 2008-04-01 | 2009-10-02 | Centre Nat Rech Scient | Solide hybride cristallin poreux pour l'adsorption et la liberation de gaz a interet biologique. |
| US8269029B2 (en) * | 2008-04-08 | 2012-09-18 | The Board Of Trustees Of The University Of Illinois | Water repellent metal-organic frameworks, process for making and uses regarding same |
| WO2009149381A2 (en) * | 2008-06-05 | 2009-12-10 | The Regents Of University Of California | Chemical framework compositions and methods of use |
| WO2010080618A2 (en) | 2008-12-18 | 2010-07-15 | The Regents Of The University Of California | Porous reactive frameworks |
| EP2356072A1 (en) | 2008-12-29 | 2011-08-17 | The Regents of the University of California | A gas sensor incorporating a porous framework |
| US8674128B2 (en) | 2009-01-15 | 2014-03-18 | The Regents Of The University Of California | Conductive organometallic framework |
| US8709134B2 (en) | 2009-02-02 | 2014-04-29 | The Regents Of The University Of California | Reversible ethylene oxide capture in porous frameworks |
| FR2942229B1 (fr) | 2009-02-18 | 2011-02-25 | Univ Paris Curie | Materiau solide hybride inorganique-organique polycarboxylate a base de titane, son procede de preparation et utilisations |
| CN102482294B (zh) | 2009-06-19 | 2016-02-03 | 加利福尼亚大学董事会 | 复杂的混合配体开放骨架材料 |
| US8876953B2 (en) | 2009-06-19 | 2014-11-04 | The Regents Of The University Of California | Carbon dioxide capture and storage using open frameworks |
| EP2403815A1 (en) | 2009-07-27 | 2012-01-11 | The Regents of The University of California | Oxidative homo-coupling reactions of aryl boronic acids using a porous copper metal-organic framework as a highly efficient heterogeneous catalyst |
| US8841471B2 (en) | 2009-09-25 | 2014-09-23 | The Regents Of The University Of California | Open metal organic frameworks with exceptional surface area and high gas storage capacity |
| ES2547729T3 (es) | 2009-11-30 | 2015-10-08 | Basf Se | Materiales de estructura organometálicos a base de ácido 2,5-furandicarboxílico o ácido 2,5-tiofendicarboxílico |
| US8716359B2 (en) * | 2010-03-18 | 2014-05-06 | Vanderbilt Chemicals, Llc | Polyurethane foam scorch inhibitor |
| US8425662B2 (en) | 2010-04-02 | 2013-04-23 | Battelle Memorial Institute | Methods for associating or dissociating guest materials with a metal organic framework, systems for associating or dissociating guest materials within a series of metal organic frameworks, and gas separation assemblies |
| EP2585472A4 (en) * | 2010-07-20 | 2014-02-12 | Univ California | FUNCTIONALIZATION OF ORGANIC MOLECULES WITH METAL ORGANIC FRAMEWORK (MOFS) AS CATALYSTS |
| RU2013119647A (ru) | 2010-09-27 | 2014-11-10 | Те Риджентс Оф Те Юниверсити Оф Калифорния | Проводящие открытые каркасные структуры |
| AU2012207079A1 (en) | 2011-01-21 | 2013-07-04 | The Regents Of The University Of California | Preparation of metal-triazolate frameworks |
| CN103459404B (zh) | 2011-02-04 | 2016-08-31 | 加利福尼亚大学董事会 | 金属儿茶酚化物骨架的制备 |
| KR102011160B1 (ko) | 2011-10-13 | 2019-08-14 | 더 리젠츠 오브 더 유니버시티 오브 캘리포니아 | 예외적으로 큰 기공 간극을 갖는 금속 유기 골격체 |
| WO2013158484A1 (en) | 2012-04-18 | 2013-10-24 | King Abdullah University Of Science And Technology | Electrode separator |
| CN103333182A (zh) * | 2013-06-04 | 2013-10-02 | 中南大学 | 一种制备mof-5的方法 |
| US10035127B2 (en) | 2013-11-04 | 2018-07-31 | The Regents Of The University Of California | Metal-organic frameworks with a high density of highly charged exposed metal cation sites |
| WO2015127033A1 (en) | 2014-02-19 | 2015-08-27 | The Regents Of The University Of California | Acid, solvent, and thermal resistant metal-organic frameworks |
| CN107148422A (zh) | 2014-03-18 | 2017-09-08 | 加利福尼亚大学董事会 | 包含微孔金属有机骨架的有序超晶格的介观材料 |
| ES2823823T3 (es) | 2014-03-27 | 2021-05-10 | Basf Se | Películas porosas que comprenden materiales de estructura organometálica |
| US10087205B2 (en) | 2014-03-28 | 2018-10-02 | The Regents Of The University Of California | Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups |
| EP2985075A1 (en) | 2014-08-15 | 2016-02-17 | Basf Se | Shaped body made of a porous material |
| US10118877B2 (en) | 2014-12-03 | 2018-11-06 | The Regents Of The University Of California | Metal-organic frameworks for aromatic hydrocarbon separations |
| US10058855B2 (en) | 2015-05-14 | 2018-08-28 | The Regents Of The University Of California | Redox-active metal-organic frameworks for the catalytic oxidation of hydrocarbons |
| WO2017091779A1 (en) | 2015-11-27 | 2017-06-01 | The Regents Of The University Of California | Zeolitic imidazolate frameworks |
| EP3380228A1 (en) | 2015-11-27 | 2018-10-03 | The Regents of The University of California | Covalent organic frameworks with a woven structure |
| ES2765740T3 (es) | 2015-11-27 | 2020-06-10 | Basf Se | Síntesis ultrarápida de elevado rendimiento-espacio-tiempo de armazones orgánicos-metal |
| US11452967B2 (en) | 2017-07-17 | 2022-09-27 | Zymergen Inc. | Metal-organic framework materials |
| WO2021220166A1 (en) | 2020-04-28 | 2021-11-04 | King Abdullah University Of Science And Technology | Electrode separators |
| CN113828281B (zh) * | 2021-09-18 | 2023-07-14 | 集美大学 | 一种聚氨酯复合材料的制备方法、产品及应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3144418A (en) * | 1959-08-17 | 1964-08-11 | Union Carbide Corp | Polymerization of epoxides |
| DE4408772B4 (de) | 1993-03-16 | 2006-09-07 | Mitsubishi Chemical Corp. | Verfahren zur Herstellung eines Polyoxyalkylenglykols und neues Metallaluminosilikat |
| US5601437A (en) | 1994-10-17 | 1997-02-11 | Methode Electronics, Inc. | Clockspring with centering display device |
| US5648508A (en) | 1995-11-22 | 1997-07-15 | Nalco Chemical Company | Crystalline metal-organic microporous materials |
| US5767323A (en) * | 1995-12-22 | 1998-06-16 | Arco Chemical Technology, L.P. | Process for preparing polyoxyalkylene polyether polyols having low levels of transition metals through double metal cyanide complex polyoxyalkylation |
| DE19928156A1 (de) | 1999-06-19 | 2000-12-28 | Bayer Ag | Aus Polyetherpolyolen hergestellte Polyurethan-Weichschäume |
| EP1220727B1 (en) | 1999-07-21 | 2008-12-24 | Black & Decker Inc. | Power drivable chuck |
| DE19941242A1 (de) * | 1999-08-31 | 2001-03-08 | Basf Ag | Polyetheralkohole |
| DE19949092A1 (de) | 1999-10-12 | 2001-04-19 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
| DE10111230A1 (de) | 2001-03-08 | 2002-09-19 | Basf Ag | Metallorganische Gerüstmaterialien und Verfahren zu deren Herstellung |
| DE10143195A1 (de) | 2001-09-04 | 2003-03-20 | Basf Ag | Integriertes Verfahren zur Herstellung von Polyurethan-Schäumen |
-
2001
- 2001-10-19 US US10/039,733 patent/US20030078311A1/en not_active Abandoned
-
2002
- 2002-10-18 CN CNB028207831A patent/CN100424115C/zh not_active Expired - Fee Related
- 2002-10-18 EP EP02781271A patent/EP1440106B1/en not_active Expired - Lifetime
- 2002-10-18 CA CA002464352A patent/CA2464352A1/en not_active Abandoned
- 2002-10-18 KR KR1020047005723A patent/KR100940290B1/ko not_active Expired - Fee Related
- 2002-10-18 US US10/492,192 patent/US7279517B2/en not_active Expired - Fee Related
- 2002-10-18 JP JP2003538229A patent/JP4173101B2/ja not_active Expired - Fee Related
- 2002-10-18 ES ES02781271T patent/ES2376050T3/es not_active Expired - Lifetime
- 2002-10-18 PL PL02370429A patent/PL370429A1/xx not_active Application Discontinuation
- 2002-10-18 WO PCT/EP2002/011700 patent/WO2003035717A1/en not_active Ceased
- 2002-10-18 AT AT02781271T patent/ATE535560T1/de active
- 2002-10-18 MX MXPA04003467A patent/MXPA04003467A/es active IP Right Grant
- 2002-10-18 TW TW091124078A patent/TWI300072B/zh active
- 2002-10-18 RU RU2004115338/04A patent/RU2308465C2/ru not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JP4173101B2 (ja) | 2008-10-29 |
| CN1571803A (zh) | 2005-01-26 |
| TWI300072B (en) | 2008-08-21 |
| KR20040083413A (ko) | 2004-10-01 |
| ATE535560T1 (de) | 2011-12-15 |
| KR100940290B1 (ko) | 2010-02-05 |
| US20040249189A1 (en) | 2004-12-09 |
| CA2464352A1 (en) | 2003-05-01 |
| ES2376050T3 (es) | 2012-03-08 |
| WO2003035717A9 (en) | 2004-12-29 |
| CN100424115C (zh) | 2008-10-08 |
| EP1440106A1 (en) | 2004-07-28 |
| WO2003035717A1 (en) | 2003-05-01 |
| EP1440106B1 (en) | 2011-11-30 |
| PL370429A1 (en) | 2005-05-30 |
| RU2308465C2 (ru) | 2007-10-20 |
| US20030078311A1 (en) | 2003-04-24 |
| JP2005506421A (ja) | 2005-03-03 |
| US7279517B2 (en) | 2007-10-09 |
| RU2004115338A (ru) | 2005-10-27 |
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