MXPA02002793A - Formulaciones de fotoiniciador. - Google Patents
Formulaciones de fotoiniciador.Info
- Publication number
- MXPA02002793A MXPA02002793A MXPA02002793A MXPA02002793A MXPA02002793A MX PA02002793 A MXPA02002793 A MX PA02002793A MX PA02002793 A MXPA02002793 A MX PA02002793A MX PA02002793 A MXPA02002793 A MX PA02002793A MX PA02002793 A MXPA02002793 A MX PA02002793A
- Authority
- MX
- Mexico
- Prior art keywords
- alkyl
- bis
- aqueous
- alkoxy
- phenyl
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 108
- 238000009472 formulation Methods 0.000 title description 36
- -1 biphenylyl Chemical group 0.000 claims abstract description 87
- 239000000725 suspension Substances 0.000 claims abstract description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000002270 dispersing agent Substances 0.000 claims abstract description 23
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 15
- 150000002367 halogens Chemical class 0.000 claims abstract description 15
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 14
- 239000001257 hydrogen Substances 0.000 claims abstract description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 11
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims abstract description 8
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 7
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims abstract description 3
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims description 49
- 125000000217 alkyl group Chemical group 0.000 claims description 31
- 239000000654 additive Substances 0.000 claims description 30
- 238000000227 grinding Methods 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 27
- 238000000576 coating method Methods 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 24
- 150000001412 amines Chemical class 0.000 claims description 23
- 125000003545 alkoxy group Chemical group 0.000 claims description 19
- 239000007900 aqueous suspension Substances 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 18
- GUCYFKSBFREPBC-UHFFFAOYSA-N [phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C(=O)C1=C(C)C=C(C)C=C1C GUCYFKSBFREPBC-UHFFFAOYSA-N 0.000 claims description 15
- 239000000976 ink Substances 0.000 claims description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 13
- 238000007639 printing Methods 0.000 claims description 13
- 239000000758 substrate Substances 0.000 claims description 13
- 239000000049 pigment Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000006096 absorbing agent Substances 0.000 claims description 10
- 239000003139 biocide Substances 0.000 claims description 10
- 229920000058 polyacrylate Polymers 0.000 claims description 9
- 229920006395 saturated elastomer Polymers 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000003860 storage Methods 0.000 claims description 7
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 claims description 6
- 238000003801 milling Methods 0.000 claims description 6
- 238000007645 offset printing Methods 0.000 claims description 6
- 239000011343 solid material Substances 0.000 claims description 6
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 5
- LFOXEOLGJPJZAA-UHFFFAOYSA-N [(2,6-dimethoxybenzoyl)-(2,4,4-trimethylpentyl)phosphoryl]-(2,6-dimethoxyphenyl)methanone Chemical compound COC1=CC=CC(OC)=C1C(=O)P(=O)(CC(C)CC(C)(C)C)C(=O)C1=C(OC)C=CC=C1OC LFOXEOLGJPJZAA-UHFFFAOYSA-N 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 238000007650 screen-printing Methods 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 4
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 3
- HGBBFIVJLKAPGV-UHFFFAOYSA-N [(2,4-dipentoxyphenyl)-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical compound CCCCCOC1=CC(OCCCCC)=CC=C1P(=O)(C(=O)C=1C(=CC(C)=CC=1C)C)C(=O)C1=C(C)C=C(C)C=C1C HGBBFIVJLKAPGV-UHFFFAOYSA-N 0.000 claims description 3
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 2
- 125000006755 (C2-C20) alkyl group Chemical group 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims description 2
- 230000003115 biocidal effect Effects 0.000 claims description 2
- 159000000011 group IA salts Chemical class 0.000 claims description 2
- 230000001678 irradiating effect Effects 0.000 claims description 2
- 239000013049 sediment Substances 0.000 claims 2
- 239000000178 monomer Substances 0.000 abstract description 11
- 239000013011 aqueous formulation Substances 0.000 abstract description 7
- 150000002431 hydrogen Chemical group 0.000 abstract description 4
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 description 30
- 229920001577 copolymer Polymers 0.000 description 24
- 150000003254 radicals Chemical class 0.000 description 19
- 239000003795 chemical substances by application Substances 0.000 description 18
- 239000010410 layer Substances 0.000 description 18
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 14
- 125000004432 carbon atom Chemical group C* 0.000 description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
- 239000011230 binding agent Substances 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 12
- 239000011521 glass Substances 0.000 description 12
- 229920005862 polyol Polymers 0.000 description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 10
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 9
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 9
- 239000007795 chemical reaction product Substances 0.000 description 9
- 239000000975 dye Substances 0.000 description 9
- 150000003077 polyols Chemical class 0.000 description 9
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 9
- 150000003839 salts Chemical group 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 8
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 8
- 239000011324 bead Substances 0.000 description 8
- 150000002148 esters Chemical class 0.000 description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000000600 sorbitol Substances 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 239000007859 condensation product Substances 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 7
- 239000003999 initiator Substances 0.000 description 7
- 229920002635 polyurethane Polymers 0.000 description 7
- 239000004814 polyurethane Substances 0.000 description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- 150000001735 carboxylic acids Chemical class 0.000 description 6
- 239000008199 coating composition Substances 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 6
- 239000011976 maleic acid Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 229920000647 polyepoxide Polymers 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 5
- 150000001408 amides Chemical class 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 5
- 150000002009 diols Chemical class 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 5
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 4
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 4
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 125000005907 alkyl ester group Chemical group 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 4
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 150000004671 saturated fatty acids Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 4
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 4
- ONTODYXHFBKCDK-UHFFFAOYSA-N 2-(2,4-dimethylphenyl)-1,3,5-triazine Chemical compound CC1=CC(C)=CC=C1C1=NC=NC=N1 ONTODYXHFBKCDK-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 229920003086 cellulose ether Polymers 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 235000013980 iron oxide Nutrition 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 3
- UJRDRFZCRQNLJM-UHFFFAOYSA-N methyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=CC=CC3=N2)=C1O UJRDRFZCRQNLJM-UHFFFAOYSA-N 0.000 description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 125000004043 oxo group Chemical group O=* 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 229920001195 polyisoprene Polymers 0.000 description 3
- 229940116351 sebacate Drugs 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- 235000014692 zinc oxide Nutrition 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
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- 150000003573 thiols Chemical class 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- WXBXVVIUZANZAU-CMDGGOBGSA-N trans-2-decenoic acid Chemical compound CCCCCCC\C=C\C(O)=O WXBXVVIUZANZAU-CMDGGOBGSA-N 0.000 description 1
- IBYFOBGPNPINBU-OUKQBFOZSA-N trans-2-tetradecenoic acid Chemical compound CCCCCCCCCCC\C=C\C(O)=O IBYFOBGPNPINBU-OUKQBFOZSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- AYNNSCRYTDRFCP-UHFFFAOYSA-N triazene Chemical compound NN=N AYNNSCRYTDRFCP-UHFFFAOYSA-N 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Colloid Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99810953 | 1999-10-20 | ||
| PCT/EP2000/010043 WO2001029093A1 (en) | 1999-10-20 | 2000-10-12 | Photoinitiator formulations |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA02002793A true MXPA02002793A (es) | 2002-07-22 |
Family
ID=8243093
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA02002793A MXPA02002793A (es) | 1999-10-20 | 2000-10-12 | Formulaciones de fotoiniciador. |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US6803392B1 (enExample) |
| EP (1) | EP1230276B1 (enExample) |
| JP (1) | JP4966462B2 (enExample) |
| KR (1) | KR100722179B1 (enExample) |
| CN (1) | CN1142944C (enExample) |
| AT (1) | ATE312850T1 (enExample) |
| AU (1) | AU774305B2 (enExample) |
| BR (1) | BR0014919B1 (enExample) |
| CA (1) | CA2383059C (enExample) |
| CZ (1) | CZ297808B6 (enExample) |
| DE (1) | DE60024867T2 (enExample) |
| DK (1) | DK1230276T3 (enExample) |
| ES (1) | ES2253267T3 (enExample) |
| MX (1) | MXPA02002793A (enExample) |
| SK (1) | SK286855B6 (enExample) |
| WO (1) | WO2001029093A1 (enExample) |
| ZA (1) | ZA200203076B (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6737216B2 (en) * | 2000-12-08 | 2004-05-18 | E.I. Du Pont De Nemours And Company | Laser engravable flexographic printing element and a method for forming a printing plate from the element |
| GB0416285D0 (en) * | 2004-07-21 | 2004-08-25 | Ciba Spec Chem Water Treat Ltd | Method of treating polymers |
| EP3473681B1 (en) | 2005-08-12 | 2020-10-07 | Cambrios Film Solutions Corporation | Nanowires-based transparent conductors |
| AT502764B1 (de) * | 2005-09-12 | 2010-11-15 | Semperit Ag Holding | Mischung und verfahren zur herstellung eines vernetzten elastomers sowie vorrichtung zur herstellung eines tauchartikels |
| US8018568B2 (en) | 2006-10-12 | 2011-09-13 | Cambrios Technologies Corporation | Nanowire-based transparent conductors and applications thereof |
| JP5409369B2 (ja) | 2006-10-12 | 2014-02-05 | カンブリオス テクノロジーズ コーポレイション | ナノワイヤベースの透明導電体およびその適用 |
| JP5101862B2 (ja) * | 2006-10-31 | 2012-12-19 | スリーエム イノベイティブ プロパティズ カンパニー | シート形成性単量体組成物、熱伝導性シート及びその製法 |
| GB2448521B (en) * | 2007-04-18 | 2012-01-18 | Piotr Koneczny | Paint conservation-restoration composition and method |
| US8018563B2 (en) | 2007-04-20 | 2011-09-13 | Cambrios Technologies Corporation | Composite transparent conductors and methods of forming the same |
| US8697194B2 (en) * | 2008-04-10 | 2014-04-15 | Xerox Corporation | Curable overcoat compositions |
| DE102008041338A1 (de) * | 2008-08-19 | 2010-02-25 | Evonik Röhm Gmbh | Einfärbeprozess für Poly(meth)acrylate mit Flüssigfarben auf Wasserbasis und Flüssigfarben auf Wasserbasis |
| KR101734588B1 (ko) | 2009-01-14 | 2017-05-11 | 바스프 에스이 | 액체 광개시제 혼합물 |
| JP5441574B2 (ja) | 2009-09-08 | 2014-03-12 | 富士フイルム株式会社 | 水性インク組成物、インクセット、およびインクジェット画像形成方法 |
| US20110138753A1 (en) * | 2009-12-11 | 2011-06-16 | International Paper Company | Container with Repulpable Moisture Resistant Barrier |
| JP5664841B2 (ja) * | 2010-01-22 | 2015-02-04 | セイコーエプソン株式会社 | 光硬化型インク組成物およびインクジェット記録方法 |
| EP2539943B1 (en) | 2010-02-24 | 2021-01-06 | Cambrios Film Solutions Corporation | Nanowire-based transparent conductors and methods of patterning same |
| JP5557566B2 (ja) * | 2010-03-19 | 2014-07-23 | 富士フイルム株式会社 | 紫外線硬化型水性インク組成物、インクセット、およびインクジェット画像形成方法 |
| US9365980B2 (en) | 2010-11-05 | 2016-06-14 | International Paper Company | Packaging material having moisture barrier and methods for preparing same |
| US9358576B2 (en) | 2010-11-05 | 2016-06-07 | International Paper Company | Packaging material having moisture barrier and methods for preparing same |
| CN103608183B (zh) | 2011-06-21 | 2017-05-17 | 巴斯夫欧洲公司 | 在纸或纸板上印刷衍射光栅 |
| TWI501030B (zh) * | 2012-06-12 | 2015-09-21 | 第一毛織股份有限公司 | 光可固化型組成物、包含該組成物之保護層及包含該組成物之封裝裝置 |
| JP6163726B2 (ja) * | 2012-09-28 | 2017-07-19 | 株式会社リコー | 非水系光重合性組成物、インクジェットインク、及びインクカートリッジ |
| CN104592298B (zh) * | 2014-12-31 | 2016-07-06 | 湖北固润科技股份有限公司 | 一种酰基膦高效光引发剂及其制备方法 |
| EP3380893A2 (en) * | 2015-11-23 | 2018-10-03 | Yissum Research Development Company of the Hebrew University of Jerusalem Ltd. | Particulate photoinitiators and uses thereof |
| US10287400B2 (en) | 2016-04-14 | 2019-05-14 | Momentive Performance Materials Inc. | Curable silicone composition and applications and uses thereof |
| US20170321060A1 (en) | 2016-05-06 | 2017-11-09 | Momentive Performance Materials Inc. | Antifog coating composition |
| US10035911B2 (en) | 2016-05-19 | 2018-07-31 | Momentive Performance Materials Inc. | Curable, dual cure, one part silicone composition |
| US10385210B2 (en) | 2017-06-20 | 2019-08-20 | Momentive Performance Materials Inc. | Curable silicone composition and applications and uses thereof |
| GB201807653D0 (en) * | 2018-05-11 | 2018-06-27 | Fujifilm Speciality Ink Systems Ltd | A printing ink |
| EP4095185B1 (en) * | 2020-07-27 | 2025-08-27 | Lg Chem, Ltd. | Preparation method for super absorbent polymer film |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR8108983A (pt) | 1981-02-27 | 1983-01-25 | Staybond Pty Ltd | Composicoes aquosas polimerizaveis |
| DE3203096A1 (de) * | 1982-01-30 | 1983-08-04 | Merck Patent Gmbh, 6100 Darmstadt | Verwendung von hydroxyalkylphenonen als initiatoren fuer die strahlungshaertung waessriger prepolymerdispersionen |
| JPS6015405A (ja) * | 1983-07-07 | 1985-01-26 | Wako Pure Chem Ind Ltd | アゾ系重合開始剤捏和体 |
| DE3512179A1 (de) * | 1985-04-03 | 1986-12-04 | Merck Patent Gmbh, 6100 Darmstadt | Fotoinitiatoren fuer die fotopolymerisation in waessrigen systemen |
| DE3815622A1 (de) * | 1988-05-07 | 1989-11-16 | Merck Patent Gmbh | Fotoinitiator-dispersionen |
| IT1228982B (it) | 1989-03-07 | 1991-07-11 | Lamberti Flli Spa | Dispersioni acquose di fotoiniziatori e loro impiego. |
| US5196142A (en) | 1989-03-17 | 1993-03-23 | Ciba-Geigy Corporation | Aqueous antioxidant emulsions |
| JPH02305804A (ja) * | 1989-05-22 | 1990-12-19 | Shin Etsu Chem Co Ltd | 塩化ビニル系重合体の製造方法 |
| US5080994A (en) * | 1989-10-23 | 1992-01-14 | Xerox Corporation | Processes for the preparation of particles |
| EP0439427B1 (de) | 1990-01-24 | 1995-08-30 | Ciba-Geigy Ag | Wässrige Emulsionen, enthaltend Antioxidantien |
| EP0511163B1 (de) | 1991-04-24 | 1995-07-26 | Ciba-Geigy Ag | Fliessfähige wässrige Dispersionen von Polycarbonsäure-Korrosionsinhibitoren |
| US6361925B1 (en) | 1996-03-04 | 2002-03-26 | Ciba Specialty Chemicals Corporation | Photoinitiator mixtures and compositions with alkylphenylbisacylphosphine oxides |
| SG53043A1 (en) | 1996-08-28 | 1998-09-28 | Ciba Geigy Ag | Molecular complex compounds as photoinitiators |
| JP4014803B2 (ja) * | 1997-08-05 | 2007-11-28 | セリコル、リミテッド | インクジェットインク |
| GB2360283B (en) | 2000-02-08 | 2002-08-21 | Ciba Sc Holding Ag | Monoacylarylphosphines and acylphosphine oxides and sulphides |
-
2000
- 2000-10-12 SK SK524-2002A patent/SK286855B6/sk not_active IP Right Cessation
- 2000-10-12 KR KR1020027005081A patent/KR100722179B1/ko not_active Expired - Lifetime
- 2000-10-12 BR BRPI0014919-5A patent/BR0014919B1/pt not_active IP Right Cessation
- 2000-10-12 AU AU11370/01A patent/AU774305B2/en not_active Ceased
- 2000-10-12 CZ CZ20021360A patent/CZ297808B6/cs not_active IP Right Cessation
- 2000-10-12 ES ES00972744T patent/ES2253267T3/es not_active Expired - Lifetime
- 2000-10-12 MX MXPA02002793A patent/MXPA02002793A/es active IP Right Grant
- 2000-10-12 AT AT00972744T patent/ATE312850T1/de active
- 2000-10-12 DK DK00972744T patent/DK1230276T3/da active
- 2000-10-12 EP EP00972744A patent/EP1230276B1/en not_active Expired - Lifetime
- 2000-10-12 CN CNB008146926A patent/CN1142944C/zh not_active Expired - Lifetime
- 2000-10-12 WO PCT/EP2000/010043 patent/WO2001029093A1/en not_active Ceased
- 2000-10-12 DE DE60024867T patent/DE60024867T2/de not_active Expired - Lifetime
- 2000-10-12 JP JP2001531890A patent/JP4966462B2/ja not_active Expired - Lifetime
- 2000-10-12 CA CA002383059A patent/CA2383059C/en not_active Expired - Lifetime
- 2000-10-12 US US10/088,222 patent/US6803392B1/en not_active Expired - Lifetime
-
2002
- 2002-04-18 ZA ZA200203076A patent/ZA200203076B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003512484A (ja) | 2003-04-02 |
| ES2253267T3 (es) | 2006-06-01 |
| CZ297808B6 (cs) | 2007-04-04 |
| EP1230276B1 (en) | 2005-12-14 |
| EP1230276A1 (en) | 2002-08-14 |
| AU774305B2 (en) | 2004-06-24 |
| CZ20021360A3 (cs) | 2002-07-17 |
| US6803392B1 (en) | 2004-10-12 |
| KR20020040902A (ko) | 2002-05-30 |
| ATE312850T1 (de) | 2005-12-15 |
| JP4966462B2 (ja) | 2012-07-04 |
| CA2383059C (en) | 2009-04-28 |
| CN1382161A (zh) | 2002-11-27 |
| AU1137001A (en) | 2001-04-30 |
| WO2001029093A1 (en) | 2001-04-26 |
| DE60024867T2 (de) | 2006-06-29 |
| DE60024867D1 (de) | 2006-01-19 |
| BR0014919B1 (pt) | 2010-08-24 |
| KR100722179B1 (ko) | 2007-05-29 |
| ZA200203076B (en) | 2003-01-29 |
| CA2383059A1 (en) | 2001-04-26 |
| DK1230276T3 (da) | 2006-03-20 |
| SK5242002A3 (en) | 2002-10-08 |
| SK286855B6 (sk) | 2009-06-05 |
| CN1142944C (zh) | 2004-03-24 |
| BR0014919A (pt) | 2002-06-18 |
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Legal Events
| Date | Code | Title | Description |
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| FG | Grant or registration |