MX9701476A - Preparacion de n-butiraldeido y/o n-butanol. - Google Patents

Preparacion de n-butiraldeido y/o n-butanol.

Info

Publication number
MX9701476A
MX9701476A MX9701476A MX9701476A MX9701476A MX 9701476 A MX9701476 A MX 9701476A MX 9701476 A MX9701476 A MX 9701476A MX 9701476 A MX9701476 A MX 9701476A MX 9701476 A MX9701476 A MX 9701476A
Authority
MX
Mexico
Prior art keywords
transition metal
amine
formula
butyraldehyde
butanol
Prior art date
Application number
MX9701476A
Other languages
English (en)
Inventor
Jurgen Kanand
Michael Roper
Rocco Paciello
Alfred THOME
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of MX9701476A publication Critical patent/MX9701476A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/023—Preparation; Separation; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/12—Monohydroxylic acyclic alcohols containing four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/516—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of nitrogen-containing compounds to >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/562—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with nitrogen as the only hetero atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un proceso para la preparacion de n-butiraldeido y/o n-butanol, en el cual: (a) se hace reaccionar 1, 3-butadieno con una amina de la formula I en el cual R1 y R2 denotan independientemente hidrogeno, radicales alifáticos opcionalmente substituídos, o radicales arilo o aralquilo, o que están unidos para formar un miembro de enlace que contiene el hateroátomo, a una temperatura elevado y bajo presion superatmosférica, en la presencia de un compuesto con un elemento del grupo VIIb y en la presencia de una amida de metal alcalino un oxido de metal básico para formar una mezcla de los aductos de las formulas II y III b) el aducto se isomeriza al aducto III, c) el aducto II se isomeriza en la presencia de un catalizador de elemento de metal de transicion heterogéneo u homogéneo en la fase líquida, o en la presencia de un catalizador hatereogéneo que contiene un elemento de metal de transicion en la fase gaseosa para formar la enamida de la formula IV y d) se producen n-butiraldehído y/o n-butanol a partir de esta enamina IV mediante la reaccion de la misma con hidrogeno y agua, o solamente agua, en la presencia de un catalizador de elemento de metal de transicion homogéneo o heterogéneo en la fase líquida, o en la presencia de un catalizador de elemento de metal de transicion heterogéneo en la fase gaseosa, y en la presencia de un ácido o en la presencia de una de dichos catalizadores y un ácido y la amina I se libera, y la amina I liberada se recicla hacia la etapa definida anteriormente como la reaccion parcial (a).
MX9701476A 1994-09-03 1995-08-24 Preparacion de n-butiraldeido y/o n-butanol. MX9701476A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4431528A DE4431528A1 (de) 1994-09-03 1994-09-03 Verfahren zur Herstellung von n-Butyraldehyd und/oder n-Butanol
PCT/EP1995/003358 WO1996007630A1 (de) 1994-09-03 1995-08-24 Verfahren zur herstellung von n-butyraldehyd und/oder n-butanol

Publications (1)

Publication Number Publication Date
MX9701476A true MX9701476A (es) 1997-05-31

Family

ID=6527419

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9701476A MX9701476A (es) 1994-09-03 1995-08-24 Preparacion de n-butiraldeido y/o n-butanol.

Country Status (14)

Country Link
US (1) US5892125A (es)
EP (1) EP0778819B1 (es)
JP (1) JP3746514B2 (es)
KR (1) KR970705530A (es)
CN (1) CN1064344C (es)
BR (1) BR9508689A (es)
CA (1) CA2198937C (es)
DE (2) DE4431528A1 (es)
ES (1) ES2127551T3 (es)
FI (1) FI970837A (es)
MX (1) MX9701476A (es)
NO (1) NO970944L (es)
TW (1) TW374760B (es)
WO (1) WO1996007630A1 (es)

Families Citing this family (14)

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GB9828338D0 (en) * 1998-12-22 1999-02-17 Bp Chem Int Ltd A process for making butyraldehyde from butadiene
US6576796B1 (en) 2000-06-28 2003-06-10 Basf Aktiengesellschaft Process for the preparation of alkylamines
DE10110842A1 (de) 2001-03-07 2002-09-12 Basf Ag Verfahren zur Herstellung von n-Butylaminen
DE10155520A1 (de) * 2001-11-12 2003-05-22 Basf Ag Verfahren zur Herstellung von n-Butyraldehyd, n-Butanol und 2-Ethylhexanol aus 1,3-butadienhaltigen Kohlenwasserstoffströmen
DE10155474A1 (de) * 2001-11-12 2003-05-22 Basf Ag Verfahren zur Herstellung von Alkalimetall-Dialkylamiden
WO2004113262A2 (en) * 2003-06-16 2004-12-29 The University Of Southern Mississippi Research Foundation Integrated process to produce derivatives of butadiene addition products
DE102004029732A1 (de) 2004-06-21 2006-01-19 Basf Ag Hilfsmittel enthaltend Cyclohexanpolycarbonsäurederivate
DE102005049568A1 (de) * 2005-10-17 2007-04-19 Basf Ag Verfahren zur kontinuierlichen Hydrierung oder hydrierenden Aminierung
JP5416096B2 (ja) * 2008-05-01 2014-02-12 株式会社クラレ ビニルエーテル系化合物の製造方法
EP2496637B1 (de) 2009-11-03 2015-10-07 Styrolution Europe GmbH THERMOPLASTISCHE ZUSAMMENSETZUNGEN MIT VERBESSERTER FLIEßFÄHIGKEIT
MX2012013942A (es) 2010-06-01 2013-01-29 Basf Se Metodo para producir composiciones de polimero de estireno expandible.
EP2716623A1 (de) 2012-10-05 2014-04-09 Basf Se Verfahren zur Herstellung von Cyclohexanpolycarbonsäure-Derivaten mit geringem Nebenproduktanteil
CN107537516B (zh) * 2016-06-28 2020-05-12 中国石油化工股份有限公司 用于制备仲丁醇的催化剂及其制备方法
US20220177405A1 (en) 2019-02-25 2022-06-09 Basf Se Method for processing benzene polycarboxylic acid esters and use of same to produce cyclohexane polycarboxylic acid esters

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Also Published As

Publication number Publication date
JPH10505074A (ja) 1998-05-19
NO970944L (no) 1997-04-28
DE59504832D1 (de) 1999-02-25
FI970837A0 (fi) 1997-02-27
BR9508689A (pt) 1997-12-30
FI970837A (fi) 1997-04-25
KR970705530A (ko) 1997-10-09
NO970944D0 (no) 1997-02-28
CA2198937C (en) 2005-05-03
CN1159796A (zh) 1997-09-17
ES2127551T3 (es) 1999-04-16
CN1064344C (zh) 2001-04-11
EP0778819A1 (de) 1997-06-18
TW374760B (en) 1999-11-21
EP0778819B1 (de) 1999-01-13
DE4431528A1 (de) 1996-03-07
JP3746514B2 (ja) 2006-02-15
US5892125A (en) 1999-04-06
WO1996007630A1 (de) 1996-03-14
CA2198937A1 (en) 1996-03-14

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