NO970944L - Fremgangsmåte for fremstilling av n-butyraldehyd og/eller n-butanol - Google Patents
Fremgangsmåte for fremstilling av n-butyraldehyd og/eller n-butanolInfo
- Publication number
- NO970944L NO970944L NO970944A NO970944A NO970944L NO 970944 L NO970944 L NO 970944L NO 970944 A NO970944 A NO 970944A NO 970944 A NO970944 A NO 970944A NO 970944 L NO970944 L NO 970944L
- Authority
- NO
- Norway
- Prior art keywords
- heterogeneous
- catalyst
- nr1r2
- adduct
- amine
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/12—Monohydroxylic acyclic alcohols containing four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/516—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of nitrogen-containing compounds to >C = O groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
- C07C45/562—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with nitrogen as the only hetero atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Den foreslåtte fremgangsmåte for fremstilling av n-butyraldehyd og/eller n-butanol omfatter følgende trinn: a) 1,3-butadien får reagere med et amin med formelen I R'R^NH, hvor restene uavhengig av hverandre står for hydrogen, eventuelt substituerte alifa- tiske eller cykloalifatiske rester, aryl- eller aralkylrester, eller er forbundet til et broledd som kan inneholde heteroatomer, ved forhøyet temperatur og ved for- høyet trykk i nærvær av en forbindelse av et element fra gruppe Vlllb i elemen- tenes periodiske system, i nærvær av et alkalimetallamid eller et basisk metall- oksyd, til en blanding av forbindelser med formelen NR1r2 og III NRlR2 b) Jsomeriserer adduktet III til adduktet II, c) isomeriserer adduktet II i nærvær av en homogen eller heterogen overgangsmetankatalysatcr i flytende fase eller i nærvær av en heterogen overgangsmetallholdig katalysator i gassfase, til enamin med formelen IV ¿NR1r2 IV og, d) av dette enamin IV ved omsetning av dette med hydrogen og vann eller vann i nærvær av en homogen eller heterogen overgangsmetallkatalysator i flytende fase, i nærvær av en heterogen overgangselementholdig katalysator i gassfase, i nærvær av en syre eller i nærvær av én av de nevnte katalysatorer og en syre, danner n-butyraldehyd og/eller n-butanol, hvoretter aminet I frigjøres og det frisatte amin I føres tilbake i omsetningen ifølge delreaksjonen a).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4431528A DE4431528A1 (de) | 1994-09-03 | 1994-09-03 | Verfahren zur Herstellung von n-Butyraldehyd und/oder n-Butanol |
PCT/EP1995/003358 WO1996007630A1 (de) | 1994-09-03 | 1995-08-24 | Verfahren zur herstellung von n-butyraldehyd und/oder n-butanol |
Publications (2)
Publication Number | Publication Date |
---|---|
NO970944D0 NO970944D0 (no) | 1997-02-28 |
NO970944L true NO970944L (no) | 1997-04-28 |
Family
ID=6527419
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO970944A NO970944L (no) | 1994-09-03 | 1997-02-28 | Fremgangsmåte for fremstilling av n-butyraldehyd og/eller n-butanol |
Country Status (14)
Country | Link |
---|---|
US (1) | US5892125A (no) |
EP (1) | EP0778819B1 (no) |
JP (1) | JP3746514B2 (no) |
KR (1) | KR970705530A (no) |
CN (1) | CN1064344C (no) |
BR (1) | BR9508689A (no) |
CA (1) | CA2198937C (no) |
DE (2) | DE4431528A1 (no) |
ES (1) | ES2127551T3 (no) |
FI (1) | FI970837A (no) |
MX (1) | MX9701476A (no) |
NO (1) | NO970944L (no) |
TW (1) | TW374760B (no) |
WO (1) | WO1996007630A1 (no) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9828338D0 (en) | 1998-12-22 | 1999-02-17 | Bp Chem Int Ltd | A process for making butyraldehyde from butadiene |
US6576796B1 (en) | 2000-06-28 | 2003-06-10 | Basf Aktiengesellschaft | Process for the preparation of alkylamines |
DE10110842A1 (de) | 2001-03-07 | 2002-09-12 | Basf Ag | Verfahren zur Herstellung von n-Butylaminen |
DE10155520A1 (de) * | 2001-11-12 | 2003-05-22 | Basf Ag | Verfahren zur Herstellung von n-Butyraldehyd, n-Butanol und 2-Ethylhexanol aus 1,3-butadienhaltigen Kohlenwasserstoffströmen |
DE10155474A1 (de) * | 2001-11-12 | 2003-05-22 | Basf Ag | Verfahren zur Herstellung von Alkalimetall-Dialkylamiden |
JP2006527746A (ja) * | 2003-06-16 | 2006-12-07 | ザ ユニバーシティ オブ サザン ミシシッピ リサーチ ファンデーション | ブタジエン付加生成物の誘導体を製造するための一体となったプロセス |
DE102004029732A1 (de) | 2004-06-21 | 2006-01-19 | Basf Ag | Hilfsmittel enthaltend Cyclohexanpolycarbonsäurederivate |
DE102005049568A1 (de) * | 2005-10-17 | 2007-04-19 | Basf Ag | Verfahren zur kontinuierlichen Hydrierung oder hydrierenden Aminierung |
EP2277871A4 (en) * | 2008-05-01 | 2011-12-28 | Kuraray Co | METHOD FOR PRODUCING A VINYL ETHER COMPOUND |
EP2496637B1 (de) | 2009-11-03 | 2015-10-07 | Styrolution Europe GmbH | THERMOPLASTISCHE ZUSAMMENSETZUNGEN MIT VERBESSERTER FLIEßFÄHIGKEIT |
MX2012013942A (es) | 2010-06-01 | 2013-01-29 | Basf Se | Metodo para producir composiciones de polimero de estireno expandible. |
EP2716623A1 (de) | 2012-10-05 | 2014-04-09 | Basf Se | Verfahren zur Herstellung von Cyclohexanpolycarbonsäure-Derivaten mit geringem Nebenproduktanteil |
CN107537516B (zh) * | 2016-06-28 | 2020-05-12 | 中国石油化工股份有限公司 | 用于制备仲丁醇的催化剂及其制备方法 |
EP3931175B1 (de) | 2019-02-25 | 2024-04-10 | Basf Se | Verfahren zur aufarbeitung von benzolpolycarbonsäureestern und deren verwendung zur herstellung von cyclohexanpolycarbonsäureestern |
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US3391192A (en) * | 1965-01-29 | 1968-07-02 | Phillips Petroleum Co | Production of aldehydes |
US3361192A (en) * | 1966-02-07 | 1968-01-02 | Varo Inc Electrokinetics Div | Temperature chamber |
US3449445A (en) * | 1967-03-17 | 1969-06-10 | Gaf Corp | Process of preparing 1,4-butanediol |
US3714270A (en) * | 1970-06-24 | 1973-01-30 | Union Oil Co | Hydration of amines to alcohols |
US3725493A (en) * | 1970-08-24 | 1973-04-03 | Phillips Petroleum Co | Oxidative dehydrogenation |
DE2321101C2 (de) * | 1973-04-26 | 1982-07-22 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung im wesentlichen trägerfreier Kobaltkatalysatoren |
DE2733796A1 (de) * | 1976-07-30 | 1978-02-02 | Ciba Geigy Ag | Neue gehinderte phosphite |
US4120901A (en) * | 1977-08-31 | 1978-10-17 | Monsanto Company | Production of primary and secondary amines by reaction of ammonia with conjugated diene in the presence of Pd/phosphine catalyst and primary or secondary aliphatic alcohol solvent medium |
US4143028A (en) * | 1977-12-05 | 1979-03-06 | Ciba-Geigy Corporation | Alkylated 1,1'-biphenyl-2,2'-diyl phosphonites and stabilized compositions |
US4196117A (en) * | 1978-01-03 | 1980-04-01 | Ciba-Geigy Corporation | Alkylated 1,1'-biphenyl-2,2'-diyl phosphites and stabilized compositions |
DE2837027A1 (de) * | 1978-08-24 | 1980-03-06 | Bayer Ag | Neue phosphorigsaeureester und ihre verwendung zur stabilisierung von polyamiden |
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US4204997A (en) * | 1979-03-19 | 1980-05-27 | Monsanto Company | Asymmetric amination of 1,3-dienes |
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-
1994
- 1994-09-03 DE DE4431528A patent/DE4431528A1/de not_active Withdrawn
-
1995
- 1995-08-24 KR KR1019970701385A patent/KR970705530A/ko not_active Application Discontinuation
- 1995-08-24 CN CN95195352A patent/CN1064344C/zh not_active Expired - Fee Related
- 1995-08-24 WO PCT/EP1995/003358 patent/WO1996007630A1/de not_active Application Discontinuation
- 1995-08-24 DE DE59504832T patent/DE59504832D1/de not_active Expired - Lifetime
- 1995-08-24 CA CA002198937A patent/CA2198937C/en not_active Expired - Fee Related
- 1995-08-24 ES ES95930520T patent/ES2127551T3/es not_active Expired - Lifetime
- 1995-08-24 JP JP50916596A patent/JP3746514B2/ja not_active Expired - Fee Related
- 1995-08-24 US US08/793,480 patent/US5892125A/en not_active Expired - Fee Related
- 1995-08-24 BR BR9508689A patent/BR9508689A/pt not_active IP Right Cessation
- 1995-08-24 EP EP95930520A patent/EP0778819B1/de not_active Expired - Lifetime
- 1995-08-24 MX MX9701476A patent/MX9701476A/es unknown
- 1995-08-29 TW TW084108993A patent/TW374760B/zh active
-
1997
- 1997-02-27 FI FI970837A patent/FI970837A/fi not_active Application Discontinuation
- 1997-02-28 NO NO970944A patent/NO970944L/no unknown
Also Published As
Publication number | Publication date |
---|---|
DE4431528A1 (de) | 1996-03-07 |
JPH10505074A (ja) | 1998-05-19 |
EP0778819B1 (de) | 1999-01-13 |
FI970837A0 (fi) | 1997-02-27 |
NO970944D0 (no) | 1997-02-28 |
BR9508689A (pt) | 1997-12-30 |
CN1159796A (zh) | 1997-09-17 |
DE59504832D1 (de) | 1999-02-25 |
KR970705530A (ko) | 1997-10-09 |
CN1064344C (zh) | 2001-04-11 |
FI970837A (fi) | 1997-04-25 |
CA2198937C (en) | 2005-05-03 |
JP3746514B2 (ja) | 2006-02-15 |
WO1996007630A1 (de) | 1996-03-14 |
TW374760B (en) | 1999-11-21 |
MX9701476A (es) | 1997-05-31 |
ES2127551T3 (es) | 1999-04-16 |
US5892125A (en) | 1999-04-06 |
CA2198937A1 (en) | 1996-03-14 |
EP0778819A1 (de) | 1997-06-18 |
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