NO970944L - Fremgangsmåte for fremstilling av n-butyraldehyd og/eller n-butanol - Google Patents

Fremgangsmåte for fremstilling av n-butyraldehyd og/eller n-butanol

Info

Publication number
NO970944L
NO970944L NO970944A NO970944A NO970944L NO 970944 L NO970944 L NO 970944L NO 970944 A NO970944 A NO 970944A NO 970944 A NO970944 A NO 970944A NO 970944 L NO970944 L NO 970944L
Authority
NO
Norway
Prior art keywords
heterogeneous
catalyst
nr1r2
adduct
amine
Prior art date
Application number
NO970944A
Other languages
English (en)
Other versions
NO970944D0 (no
Inventor
Juergen Kanand
Michael Roeper
Rocco Paciello
Alfred THOME
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of NO970944D0 publication Critical patent/NO970944D0/no
Publication of NO970944L publication Critical patent/NO970944L/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/023—Preparation; Separation; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/12—Monohydroxylic acyclic alcohols containing four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/516—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of nitrogen-containing compounds to >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/562—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with nitrogen as the only hetero atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Den foreslåtte fremgangsmåte for fremstilling av n-butyraldehyd og/eller n-butanol omfatter følgende trinn: a) 1,3-butadien får reagere med et amin med formelen I R'R^NH, hvor restene uavhengig av hverandre står for hydrogen, eventuelt substituerte alifa- tiske eller cykloalifatiske rester, aryl- eller aralkylrester, eller er forbundet til et broledd som kan inneholde heteroatomer, ved forhøyet temperatur og ved for- høyet trykk i nærvær av en forbindelse av et element fra gruppe Vlllb i elemen- tenes periodiske system, i nærvær av et alkalimetallamid eller et basisk metall- oksyd, til en blanding av forbindelser med formelen NR1r2 og III NRlR2 b) Jsomeriserer adduktet III til adduktet II, c) isomeriserer adduktet II i nærvær av en homogen eller heterogen overgangsmetankatalysatcr i flytende fase eller i nærvær av en heterogen overgangsmetallholdig katalysator i gassfase, til enamin med formelen IV ¿NR1r2 IV og, d) av dette enamin IV ved omsetning av dette med hydrogen og vann eller vann i nærvær av en homogen eller heterogen overgangsmetallkatalysator i flytende fase, i nærvær av en heterogen overgangselementholdig katalysator i gassfase, i nærvær av en syre eller i nærvær av én av de nevnte katalysatorer og en syre, danner n-butyraldehyd og/eller n-butanol, hvoretter aminet I frigjøres og det frisatte amin I føres tilbake i omsetningen ifølge delreaksjonen a).
NO970944A 1994-09-03 1997-02-28 Fremgangsmåte for fremstilling av n-butyraldehyd og/eller n-butanol NO970944L (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4431528A DE4431528A1 (de) 1994-09-03 1994-09-03 Verfahren zur Herstellung von n-Butyraldehyd und/oder n-Butanol
PCT/EP1995/003358 WO1996007630A1 (de) 1994-09-03 1995-08-24 Verfahren zur herstellung von n-butyraldehyd und/oder n-butanol

Publications (2)

Publication Number Publication Date
NO970944D0 NO970944D0 (no) 1997-02-28
NO970944L true NO970944L (no) 1997-04-28

Family

ID=6527419

Family Applications (1)

Application Number Title Priority Date Filing Date
NO970944A NO970944L (no) 1994-09-03 1997-02-28 Fremgangsmåte for fremstilling av n-butyraldehyd og/eller n-butanol

Country Status (14)

Country Link
US (1) US5892125A (no)
EP (1) EP0778819B1 (no)
JP (1) JP3746514B2 (no)
KR (1) KR970705530A (no)
CN (1) CN1064344C (no)
BR (1) BR9508689A (no)
CA (1) CA2198937C (no)
DE (2) DE4431528A1 (no)
ES (1) ES2127551T3 (no)
FI (1) FI970837A (no)
MX (1) MX9701476A (no)
NO (1) NO970944L (no)
TW (1) TW374760B (no)
WO (1) WO1996007630A1 (no)

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US6576796B1 (en) 2000-06-28 2003-06-10 Basf Aktiengesellschaft Process for the preparation of alkylamines
DE10110842A1 (de) 2001-03-07 2002-09-12 Basf Ag Verfahren zur Herstellung von n-Butylaminen
DE10155520A1 (de) * 2001-11-12 2003-05-22 Basf Ag Verfahren zur Herstellung von n-Butyraldehyd, n-Butanol und 2-Ethylhexanol aus 1,3-butadienhaltigen Kohlenwasserstoffströmen
DE10155474A1 (de) * 2001-11-12 2003-05-22 Basf Ag Verfahren zur Herstellung von Alkalimetall-Dialkylamiden
JP2006527746A (ja) * 2003-06-16 2006-12-07 ザ ユニバーシティ オブ サザン ミシシッピ リサーチ ファンデーション ブタジエン付加生成物の誘導体を製造するための一体となったプロセス
DE102004029732A1 (de) 2004-06-21 2006-01-19 Basf Ag Hilfsmittel enthaltend Cyclohexanpolycarbonsäurederivate
DE102005049568A1 (de) * 2005-10-17 2007-04-19 Basf Ag Verfahren zur kontinuierlichen Hydrierung oder hydrierenden Aminierung
EP2277871A4 (en) * 2008-05-01 2011-12-28 Kuraray Co METHOD FOR PRODUCING A VINYL ETHER COMPOUND
EP2496637B1 (de) 2009-11-03 2015-10-07 Styrolution Europe GmbH THERMOPLASTISCHE ZUSAMMENSETZUNGEN MIT VERBESSERTER FLIEßFÄHIGKEIT
MX2012013942A (es) 2010-06-01 2013-01-29 Basf Se Metodo para producir composiciones de polimero de estireno expandible.
EP2716623A1 (de) 2012-10-05 2014-04-09 Basf Se Verfahren zur Herstellung von Cyclohexanpolycarbonsäure-Derivaten mit geringem Nebenproduktanteil
CN107537516B (zh) * 2016-06-28 2020-05-12 中国石油化工股份有限公司 用于制备仲丁醇的催化剂及其制备方法
EP3931175B1 (de) 2019-02-25 2024-04-10 Basf Se Verfahren zur aufarbeitung von benzolpolycarbonsäureestern und deren verwendung zur herstellung von cyclohexanpolycarbonsäureestern

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Also Published As

Publication number Publication date
DE4431528A1 (de) 1996-03-07
JPH10505074A (ja) 1998-05-19
EP0778819B1 (de) 1999-01-13
FI970837A0 (fi) 1997-02-27
NO970944D0 (no) 1997-02-28
BR9508689A (pt) 1997-12-30
CN1159796A (zh) 1997-09-17
DE59504832D1 (de) 1999-02-25
KR970705530A (ko) 1997-10-09
CN1064344C (zh) 2001-04-11
FI970837A (fi) 1997-04-25
CA2198937C (en) 2005-05-03
JP3746514B2 (ja) 2006-02-15
WO1996007630A1 (de) 1996-03-14
TW374760B (en) 1999-11-21
MX9701476A (es) 1997-05-31
ES2127551T3 (es) 1999-04-16
US5892125A (en) 1999-04-06
CA2198937A1 (en) 1996-03-14
EP0778819A1 (de) 1997-06-18

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