MX370761B - Sistema de depuracion de dioxido de azufre y proceso para la produccion de productos de potasio. - Google Patents

Sistema de depuracion de dioxido de azufre y proceso para la produccion de productos de potasio.

Info

Publication number
MX370761B
MX370761B MX2018008055A MX2018008055A MX370761B MX 370761 B MX370761 B MX 370761B MX 2018008055 A MX2018008055 A MX 2018008055A MX 2018008055 A MX2018008055 A MX 2018008055A MX 370761 B MX370761 B MX 370761B
Authority
MX
Mexico
Prior art keywords
potassium
thiosulfate
optionally
bisulfite
sulfite
Prior art date
Application number
MX2018008055A
Other languages
English (en)
Other versions
MX2018008055A (es
Inventor
Massoud Hojjatie Michael
Dimitriadis Alexandros
Lynn Frank Lockhart Constance
P Clarkson Mark
Charles Kominski Harry
S Shult Nicholas
T Goldsmith Adam
Van Cauwenbergh Jeroen
Original Assignee
Tessenderlo Kerley Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tessenderlo Kerley Inc filed Critical Tessenderlo Kerley Inc
Publication of MX2018008055A publication Critical patent/MX2018008055A/es
Publication of MX370761B publication Critical patent/MX370761B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/64—Thiosulfates; Dithionites; Polythionates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1481—Removing sulfur dioxide or sulfur trioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/502—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/62—Methods of preparing sulfites in general
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/306—Alkali metal compounds of potassium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/604—Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/606—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/608—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/10—Inorganic absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/204—Inorganic halogen compounds
    • B01D2257/2045—Hydrochloric acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/80—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Treating Waste Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

La invención se refiere a un proceso para la preparación de tiosulfato de potasio, sulfito de potasio o bisulfito de potasio, que comprende las siguientes etapas: Etapa (1a): la provisión de una solución de carbonato de potasio o hidróxido de potasio para neutralizar componentes formadores de ácido, tal como mediante la disolución de SO2 o H2S; Etapa (1b): la provisión de una solución de contacto de SO2, que contiene por lo menos algo de sulfito de potasio o bisulfito de potasio o tiosulfato de potasio; Etapa (2): la provisión de gas SO2; Etapa (3): la reacción de estos para absorber el gas SO2 y formar una mezcla de reacción intermedia que comprende sulfito de potasio, o bisulfito de potasio o una de sus mezclas, y en forma opcional, la recuperación del sulfito de potasio, o bisulfito de potasio o una de sus mezclas, y/u opcionalmente, el uso de las etapas 4 y 5; Etapa (4): la adición de compuesto que contiene azufre o sulfuro, que contiene azufre que tiene el estado de oxidación de 0, -2 o de entre 0 y -2, a la mezcla de reacción, y en forma opcional, hidróxido de potasio o carbonato de potasio, y la reacción de la mezcla en condiciones adecuadas para formar tiosulfato de potasio; y Etapa (5): la recuperación del tiosulfato de potasio, y en forma opcional, la concentración del tiosulfato de potasio.
MX2018008055A 2015-12-30 2016-12-16 Sistema de depuracion de dioxido de azufre y proceso para la produccion de productos de potasio. MX370761B (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562273389P 2015-12-30 2015-12-30
US15/380,702 US10005667B2 (en) 2015-12-30 2016-12-15 Sulfur dioxide scrubbing system and process for producing potassium products
PCT/US2016/067313 WO2017116773A1 (en) 2015-12-30 2016-12-16 Sulfur dioxide scrubbing system and process for producing potassium products

Publications (2)

Publication Number Publication Date
MX2018008055A MX2018008055A (es) 2018-11-29
MX370761B true MX370761B (es) 2019-12-13

Family

ID=59225327

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2018008055A MX370761B (es) 2015-12-30 2016-12-16 Sistema de depuracion de dioxido de azufre y proceso para la produccion de productos de potasio.

Country Status (18)

Country Link
US (2) US10005667B2 (es)
EP (1) EP3397793B1 (es)
KR (1) KR102251321B1 (es)
CN (2) CN108495954A (es)
AU (1) AU2016382880B2 (es)
BR (2) BR112018013555B1 (es)
CA (1) CA3007484C (es)
CL (1) CL2018001718A1 (es)
CO (1) CO2018007613A2 (es)
EA (1) EA037223B1 (es)
ES (1) ES2981003T3 (es)
HU (1) HUE066700T2 (es)
MX (1) MX370761B (es)
PE (1) PE20181185A1 (es)
PL (1) PL3397793T3 (es)
UA (1) UA126145C2 (es)
WO (1) WO2017116773A1 (es)
ZA (1) ZA201803423B (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10005667B2 (en) * 2015-12-30 2018-06-26 Tessenderlo Kerley, Inc. Sulfur dioxide scrubbing system and process for producing potassium products
EP3208237A1 (en) * 2016-02-18 2017-08-23 Tessenderlo Kerley, Inc. Sulfur dioxide scrubbing system and process for producing potassium products
WO2021003479A1 (en) * 2019-07-03 2021-01-07 Tessenderlo Kerley, Inc. Products prepared from waste gas streams containing h 2s, so 2, and/or nh 3
CN110790235B (zh) * 2019-11-15 2021-05-25 浙江大洋生物科技集团股份有限公司 作为有机合成副产物的含氟氯化钾的综合利用方法
CN111003692B (zh) * 2019-12-13 2020-09-08 南京工业大学 一种二氧化硫资源化回用系统及方法
CN111039309A (zh) * 2019-12-31 2020-04-21 中船重工（邯郸）派瑞特种气体有限公司 一种分离硫酸氢钾和硫酸钾混合物的装置及方法
US11214489B1 (en) * 2020-11-28 2022-01-04 Ceres Technology, LLC Crossflow scrubbing method and apparatus to produce a product such as potassium thiosulfate or ammonium thiosulfate
WO2023057397A1 (en) 2021-10-04 2023-04-13 Tessenderlo Group Nv Methods for the production of thiosulfates via salt metathesis

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* Cited by examiner, † Cited by third party
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US1570253A (en) * 1925-01-13 1926-01-19 Grasselli Chemical Co Process for the manufacture of sodium thiosulphate
US1760137A (en) * 1925-12-05 1930-05-27 Grasselli Chemical Co Process for the production of sodium thiosulphate
US2219258A (en) * 1939-12-05 1940-10-22 American Cyanamid Co Solid ammonium thiosulphate
DE1186451B (de) 1963-08-14 1965-02-04 Basf Ag Verfahren zur Herstellung von festem Kaliumdisulfit
CA988679A (en) * 1972-02-02 1976-05-11 Consolidation Coal Company Treatment of gases containing sulfur dioxide
US4122148A (en) * 1976-04-20 1978-10-24 Davy Powergas Inc. Sulfur dioxide removal process
US4208395A (en) * 1978-12-05 1980-06-17 Continental Oil Company Removal of sulfur dioxide from flue gas
JPS58174223A (ja) * 1982-04-08 1983-10-13 Mitsubishi Heavy Ind Ltd 排ガス処理方法
FR2534571A1 (fr) 1982-10-19 1984-04-20 Magyar Tudomanyos Akademia Procede et equipement pour la production de sulfites de sodium et de potassium
UST103501I4 (en) * 1982-11-24 1983-10-04 Dewatering of flue gas desulfurization sulfite solids
US4976937A (en) * 1990-01-08 1990-12-11 Dravo Lime Company Sulfur dioxide removal from flue gases with sulfite oxidation inhibition
US5266285A (en) * 1992-04-13 1993-11-30 Southern Indiana Gas And Electric Company Sodium-enhanced lime scrubbing method for removing sulfur dioxide from gaseous streams
US5567406A (en) 1995-05-11 1996-10-22 Zeller, Iii; Robert L. Manufacturing clear potassium sulfite
TW358038B (en) * 1997-06-13 1999-05-11 Von Roll Umwelttechnik Ag Process for removing sulfur dioxide from flue gasses
US5944868A (en) * 1998-01-28 1999-08-31 Tessenderlo Kerley, Inc. Production of liquid fertilizers by ion exchange
US8034318B1 (en) * 2010-04-21 2011-10-11 Tessenderlo Kerley, Inc. Process for preparation of calcium thiosulfate liquid solution from lime, sulfur, and sulfur dioxide
MX357555B (es) 2011-04-05 2018-07-13 Tessenderlo Kerley Inc Fertilizantes de sulfito de potasio/bisulfito de potasio (ks/kbs)liquido, como indicador, de contacto, al voleo, foliar y ferti-irrigacion.
CN102423612B (zh) 2011-08-07 2014-05-07 宁波金远东工业科技有限公司 一种利用工业烟气生产硫代硫酸盐及回收二氧化碳的方法
CN202482062U (zh) * 2012-01-20 2012-10-10 鞍钢集团工程技术有限公司 一种由脱硫废液提取硫代硫酸铵、硫氰酸铵的装置
US10005667B2 (en) * 2015-12-30 2018-06-26 Tessenderlo Kerley, Inc. Sulfur dioxide scrubbing system and process for producing potassium products
EP3208237A1 (en) * 2016-02-18 2017-08-23 Tessenderlo Kerley, Inc. Sulfur dioxide scrubbing system and process for producing potassium products
JP2019174223A (ja) * 2018-03-28 2019-10-10 三菱重工業株式会社 温度モニタ装置、温度モニタ方法、及び複合材の製造方法

Also Published As

Publication number Publication date
US20180251375A1 (en) 2018-09-06
CA3007484C (en) 2022-04-19
AU2016382880B2 (en) 2020-04-16
BR112018013555A2 (pt) 2018-12-04
CL2018001718A1 (es) 2018-09-21
EP3397793A4 (en) 2019-05-22
AU2016382880A1 (en) 2018-06-14
EP3397793B1 (en) 2024-03-13
US10472238B2 (en) 2019-11-12
BR122022000451B1 (pt) 2022-12-20
EA037223B1 (ru) 2021-02-20
CA3007484A1 (en) 2017-07-06
UA126145C2 (uk) 2022-08-25
KR20180100056A (ko) 2018-09-06
ZA201803423B (en) 2022-12-21
CN117228639A (zh) 2023-12-15
CN108495954A (zh) 2018-09-04
EP3397793A1 (en) 2018-11-07
PE20181185A1 (es) 2018-07-20
HUE066700T2 (hu) 2024-08-28
KR102251321B1 (ko) 2021-05-12
ES2981003T3 (es) 2024-10-04
EA201891398A1 (ru) 2018-12-28
WO2017116773A1 (en) 2017-07-06
PL3397793T3 (pl) 2024-07-22
US10005667B2 (en) 2018-06-26
CO2018007613A2 (es) 2018-07-31
MX2018008055A (es) 2018-11-29
US20170190575A1 (en) 2017-07-06
BR112018013555B1 (pt) 2022-10-04

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