MX365691B - Sistemas de poliuretano de dos componentes con separacion de fases. - Google Patents
Sistemas de poliuretano de dos componentes con separacion de fases.Info
- Publication number
- MX365691B MX365691B MX2014010292A MX2014010292A MX365691B MX 365691 B MX365691 B MX 365691B MX 2014010292 A MX2014010292 A MX 2014010292A MX 2014010292 A MX2014010292 A MX 2014010292A MX 365691 B MX365691 B MX 365691B
- Authority
- MX
- Mexico
- Prior art keywords
- phase separation
- polyurethane systems
- mol
- composition
- polyol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/1701—Component parts, details or accessories; Auxiliary operations using a particular environment during moulding, e.g. moisture-free or dust-free
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
- B29C70/48—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/20—Heterocyclic amines; Salts thereof
- C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
- C08G18/2027—Heterocyclic amines; Salts thereof containing one heterocyclic ring having two nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
La invención se refiere a una composición de poliuretano de dos componentes que contiene i) 10 a 80% en peso de por lo menos un poliol con un peso molecular promedio de 200 g/mol a 3000 g/mol, ii) 5 a 60% en peso de por lo menos un poliisocianato aromático, y iii) 0 a 15% en peso de un aditivo. La composición tiene una relación de NCO:OH de 2:1 a 1:2, y la composición tiene una viscosidad de 20 a 3000 mPas (EN ISO 2555, viscosímetro de Brookfield, 25°C) y muestra una incompatibilidad de fase después del proceso de mezclado. La funcionalidad de la mezcla de polioles es mayor que 2.3.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12157299 | 2012-02-28 | ||
EP12157301 | 2012-02-28 | ||
PCT/EP2013/053699 WO2013127732A1 (de) | 2012-02-28 | 2013-02-25 | 2k-polyurethansysteme mit phasentrennung |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014010292A MX2014010292A (es) | 2014-10-13 |
MX365691B true MX365691B (es) | 2019-06-11 |
Family
ID=47748639
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014010290A MX365277B (es) | 2012-02-28 | 2013-02-25 | Sistemas de poliuretano 2k con temperatura de transición vítrea elevada. |
MX2014010292A MX365691B (es) | 2012-02-28 | 2013-02-25 | Sistemas de poliuretano de dos componentes con separacion de fases. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014010290A MX365277B (es) | 2012-02-28 | 2013-02-25 | Sistemas de poliuretano 2k con temperatura de transición vítrea elevada. |
Country Status (10)
Country | Link |
---|---|
US (2) | US10131738B2 (es) |
EP (2) | EP2820061B1 (es) |
JP (3) | JP2015510011A (es) |
KR (2) | KR20140129304A (es) |
CN (2) | CN104136477B (es) |
AU (1) | AU2013225178B2 (es) |
CA (2) | CA2863145C (es) |
ES (1) | ES2885763T3 (es) |
MX (2) | MX365277B (es) |
WO (2) | WO2013127734A1 (es) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102011002809A1 (de) * | 2011-01-18 | 2012-07-19 | Henkel Ag & Co. Kgaa | 2K-PU-Zusammensetzung mit verzögerter Vernetzung |
CN104136477B (zh) * | 2012-02-28 | 2016-06-29 | 汉高股份有限及两合公司 | 具有相分离的双组分聚氨酯体系 |
DE102014208353A1 (de) | 2014-05-05 | 2015-11-05 | Henkel Ag & Co. Kgaa | Mehrphasige Polyurethan-Zusammensetzung mit reduzierter Schaumentwicklung |
ES2620980T3 (es) | 2014-09-30 | 2017-06-30 | Henkel Ag & Co. Kgaa | Composiciones que comprenden un material de fibra y un aglutinante termoplástico |
CN110114380B (zh) | 2016-12-28 | 2022-04-26 | 汉高股份有限及两合公司 | 双组分聚氨酯粘合剂 |
EP3533530A1 (en) | 2018-03-01 | 2019-09-04 | Henkel AG & Co. KGaA | Process for the production of composite materials at low temperatures |
WO2020102871A1 (pt) * | 2018-11-22 | 2020-05-28 | Formtap Interni Sistemas Automotivos S/A | Aperfeiçoamento introduzido em processo de obtenção de compósitos termo estruturais |
Family Cites Families (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU532047B2 (en) | 1978-12-11 | 1983-09-15 | Ici Ltd. | Modified isocyanate |
DE3626223A1 (de) * | 1986-08-02 | 1988-02-04 | Henkel Kgaa | Polyurethan-praepolymere auf basis oleochemischer polyole, ihre herstellung und verwendung |
JPS63309510A (ja) * | 1987-06-12 | 1988-12-16 | Nippon Polyurethan Kogyo Kk | ポリイソシアヌレ−ト複合体の製造法 |
DE8711301U1 (de) * | 1987-08-20 | 1987-10-29 | Pelzer, Helmut, 58313 Herdecke | Faserverstärkter, hoch temperaturstabiler, plattenförmiger Werkstoff |
US4800058A (en) | 1987-08-24 | 1989-01-24 | Arco Chemical Company | Method for the preparation of rigid cast or transfer molded thermoset polyurethane modified polyisocyanurate compositions |
US4743626A (en) | 1987-09-14 | 1988-05-10 | Basf Corporation | Liquid carbodiimide-uretonimine modified polymethylene polyphenylene polyisocyanates and polyurethane foams made therefrom |
ES2099240T3 (es) * | 1991-05-03 | 1997-05-16 | Ciba Geigy Ag | Componente poliolico para la fabricacion de piezas moldeadas de poliuretano. |
CA2188503A1 (en) * | 1995-12-22 | 1997-06-23 | Neil H. Nodelman | Polyurethane resin transfer molding systems |
BR9812680A (pt) * | 1997-09-26 | 2000-08-22 | Dow Chemical Co | ElastÈmeros de poliuretano com alta temperatura de operação |
DE19750820B4 (de) * | 1997-11-17 | 2004-04-29 | Höpner Lacke GmbH | Beschichtungsstoff für mit Restrost behaftete Oberflächen |
KR20010103702A (ko) | 1998-11-16 | 2001-11-23 | 추후제출 | 폴리이소시아누레이트 조성물 및 복합재료 |
JP4031632B2 (ja) * | 2001-10-31 | 2008-01-09 | 三菱重工業株式会社 | 繊維強化型プラスチックの製造方法 |
JP3924258B2 (ja) * | 2003-04-01 | 2007-06-06 | 三菱重工業株式会社 | 繊維強化プラスチックの製造方法 |
DE10318740A1 (de) | 2003-04-25 | 2004-11-11 | Bayer Materialscience Ag | Polyurethan-Formulierungen und ihre Verwendung |
DE10356767A1 (de) * | 2003-12-05 | 2005-07-07 | Henkel Kgaa | Platten und Formkörper auf Basis von Polyurethanbindemittel |
DE102004033849A1 (de) | 2004-07-13 | 2006-02-16 | Bayer Materialscience Ag | Verfahren zur Herstellung flüssiger, lagerstabiler Carbodiimid- und/oder Uretonimingruppen aufweisender organischer Isocyanate mit niedriger Farbzahl |
US20060014890A1 (en) * | 2004-07-14 | 2006-01-19 | Zielinski David P | Polyisocyanates with improved compatibility with high hydroxyl content polyols |
US8048935B2 (en) * | 2004-11-08 | 2011-11-01 | Carpenter Co. | Liquid foam systems and ASTM E-84 class 1 rated rigid, high-density polyurethane foams and articles prepared therefrom |
US20060264534A1 (en) * | 2005-05-23 | 2006-11-23 | Zeying Ma | Inkjet inks having reduced bronzing |
DE102006002158A1 (de) * | 2006-01-17 | 2007-07-19 | Bayer Materialscience Ag | Verfahren zur Herstellung flüssiger, lagerstabiler Carboddimid- und/oder Uretonimingruppen aufweisender organischer Isocyanate |
ITMI20061107A1 (it) * | 2006-06-08 | 2007-12-09 | Diab Int Ab | Formulazioni per prodotti cellulari di polimero espanso basati su polivinl cloruro prodotti cellulari di polimero espanso migliorati basati su polivinil cloruro e processo per produrre detti prodotti cellulari di polimero espanso migliorati |
US20080099141A1 (en) * | 2006-10-26 | 2008-05-01 | Ashland Inc. | Method of producing flexible laminates |
JP5041794B2 (ja) * | 2006-12-07 | 2012-10-03 | 住化バイエルウレタン株式会社 | 変性ポリイソシアネートの製造方法 |
EP1970420A1 (en) * | 2007-03-15 | 2008-09-17 | Huntsman International Llc | Polyisocyanate-based adhesive composition |
US7842349B2 (en) * | 2007-10-11 | 2010-11-30 | Tse Industries, Inc. | Method for spray forming high modulus polyurethane structures |
DE102007062529A1 (de) * | 2007-12-20 | 2009-06-25 | Henkel Ag & Co. Kgaa | 2K-PU-Klebstoff zum Verkleben von Faserformteilen |
MX2010007943A (es) * | 2008-01-29 | 2010-08-10 | Basf Se | Metodo para la produccion de alcoholes de polieter. |
DE102008027914A1 (de) | 2008-06-12 | 2009-12-17 | Henkel Ag & Co. Kgaa | Vernetzende 2K-Isocyanat-Zusammensetzungen |
CA2732421C (en) | 2008-08-28 | 2016-05-17 | Huntsman International Llc | Mixture obtained by reacting polyol and anhydride and its use in polyisocyanates for making polyisocyanurates |
CA2782010A1 (en) * | 2009-12-01 | 2011-06-09 | Basf Se | Polyurethane-based pultrusion resin system |
DE102011002809A1 (de) * | 2011-01-18 | 2012-07-19 | Henkel Ag & Co. Kgaa | 2K-PU-Zusammensetzung mit verzögerter Vernetzung |
CN104136477B (zh) * | 2012-02-28 | 2016-06-29 | 汉高股份有限及两合公司 | 具有相分离的双组分聚氨酯体系 |
HUP1400402A2 (hu) * | 2014-08-29 | 2016-03-29 | Borsodchem Zrt | Eljárás világos színû, stabilan tárolható uretonimin modifikált poliizocianát elõállítására |
CN105447437B (zh) | 2015-02-13 | 2017-05-03 | 比亚迪股份有限公司 | 指纹识别方法和装置 |
-
2013
- 2013-02-25 CN CN201380010986.4A patent/CN104136477B/zh active Active
- 2013-02-25 MX MX2014010290A patent/MX365277B/es active IP Right Grant
- 2013-02-25 JP JP2014559167A patent/JP2015510011A/ja active Pending
- 2013-02-25 KR KR1020147027024A patent/KR20140129304A/ko not_active Application Discontinuation
- 2013-02-25 MX MX2014010292A patent/MX365691B/es active IP Right Grant
- 2013-02-25 JP JP2014559166A patent/JP6534260B2/ja not_active Expired - Fee Related
- 2013-02-25 EP EP13706002.6A patent/EP2820061B1/de active Active
- 2013-02-25 WO PCT/EP2013/053703 patent/WO2013127734A1/de active Application Filing
- 2013-02-25 EP EP13705802.0A patent/EP2820060A1/de active Pending
- 2013-02-25 KR KR1020147023787A patent/KR102046197B1/ko active IP Right Grant
- 2013-02-25 WO PCT/EP2013/053699 patent/WO2013127732A1/de active Application Filing
- 2013-02-25 CA CA2863145A patent/CA2863145C/en not_active Expired - Fee Related
- 2013-02-25 CN CN201380010852.2A patent/CN104136476B/zh active Active
- 2013-02-25 CA CA2863141A patent/CA2863141C/en active Active
- 2013-02-25 ES ES13706002T patent/ES2885763T3/es active Active
- 2013-02-25 AU AU2013225178A patent/AU2013225178B2/en not_active Ceased
-
2014
- 2014-08-25 US US14/467,782 patent/US10131738B2/en active Active
- 2014-08-25 US US14/467,550 patent/US10093766B2/en active Active
-
2018
- 2018-10-10 JP JP2018191609A patent/JP2019035088A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
EP2820060A1 (de) | 2015-01-07 |
CN104136477A (zh) | 2014-11-05 |
AU2013225176A1 (en) | 2014-09-18 |
CA2863141C (en) | 2021-08-17 |
JP6534260B2 (ja) | 2019-06-26 |
CA2863141A1 (en) | 2013-09-06 |
US10131738B2 (en) | 2018-11-20 |
AU2013225178B2 (en) | 2016-01-07 |
MX2014010290A (es) | 2014-10-13 |
JP2019035088A (ja) | 2019-03-07 |
US20160362516A1 (en) | 2016-12-15 |
CN104136476A (zh) | 2014-11-05 |
EP2820061A1 (de) | 2015-01-07 |
CA2863145C (en) | 2021-03-16 |
KR20140129304A (ko) | 2014-11-06 |
KR102046197B1 (ko) | 2019-11-18 |
EP2820061B1 (de) | 2021-07-21 |
AU2013225178A1 (en) | 2014-09-18 |
CN104136476B (zh) | 2017-04-19 |
JP2015512979A (ja) | 2015-04-30 |
KR20140127830A (ko) | 2014-11-04 |
AU2013225176B2 (en) | 2016-01-28 |
CN104136477B (zh) | 2016-06-29 |
WO2013127734A1 (de) | 2013-09-06 |
US20140371391A1 (en) | 2014-12-18 |
WO2013127732A1 (de) | 2013-09-06 |
MX365277B (es) | 2019-05-29 |
JP2015510011A (ja) | 2015-04-02 |
CA2863145A1 (en) | 2013-09-06 |
ES2885763T3 (es) | 2021-12-15 |
MX2014010292A (es) | 2014-10-13 |
US10093766B2 (en) | 2018-10-09 |
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