MX2012012117A - Polioles adecuados para producir espumas moldeadas en caliente con elevado contenido de recursos renovables. - Google Patents
Polioles adecuados para producir espumas moldeadas en caliente con elevado contenido de recursos renovables.Info
- Publication number
- MX2012012117A MX2012012117A MX2012012117A MX2012012117A MX2012012117A MX 2012012117 A MX2012012117 A MX 2012012117A MX 2012012117 A MX2012012117 A MX 2012012117A MX 2012012117 A MX2012012117 A MX 2012012117A MX 2012012117 A MX2012012117 A MX 2012012117A
- Authority
- MX
- Mexico
- Prior art keywords
- percentage
- molded foam
- renewable resource
- foam production
- resource content
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/36—Hydroxylated esters of higher fatty acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/487—Polyethers containing cyclic groups
- C08G18/4883—Polyethers containing cyclic groups containing cyclic groups having at least one oxygen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/006—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by oxidation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyethers (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Los polioles se producen mediante un proceso de alcoxilación en el que un aceite vegetal que contiene grupos funcionales hidroxilo se combina con un catalizador de DMC para formar una mezcla, a continuación se activa el catalizador de DMC añadiendo óxido de etileno y/u óxido de propileno a la mezcla de aceite vegetal/catalizador, y se añaden óxido de etileno y óxido de propileno a la mezcla que contiene el catalizador de DMC activado en cantidades tales que el total del porcentaje de óxido de etileno en el poliol más el porcentaje de grupos hidroxilo primarios en el poliol producido es del 50 al 77% y el porcentaje de grupos hidroxilo primarios es de por lo menos el 30% pero inferior al 50%. Estos polioles son útiles para la producción de espumas de poliuretano moldeadas, en concreto, espumas de poliuretano moldeadas de curado en caliente.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US32726210P | 2010-04-23 | 2010-04-23 | |
PCT/US2011/000685 WO2011133208A2 (en) | 2010-04-23 | 2011-04-15 | Polyols suitable for hot molded foam production with high renewable resource content |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2012012117A true MX2012012117A (es) | 2012-12-17 |
Family
ID=44834715
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2012012117A MX2012012117A (es) | 2010-04-23 | 2011-04-15 | Polioles adecuados para producir espumas moldeadas en caliente con elevado contenido de recursos renovables. |
Country Status (10)
Country | Link |
---|---|
US (1) | US10323212B2 (es) |
EP (1) | EP2560944A4 (es) |
JP (1) | JP6038775B2 (es) |
KR (1) | KR20130091631A (es) |
CN (1) | CN102858732B (es) |
BR (1) | BR112012027070A2 (es) |
CA (1) | CA2796656C (es) |
MX (1) | MX2012012117A (es) |
SG (2) | SG10201503146WA (es) |
WO (1) | WO2011133208A2 (es) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8598248B2 (en) * | 2010-07-16 | 2013-12-03 | Bayer Materialscience Llc | Flexible polyurethane foams made from alkoxylated natural oil |
CN102532457B (zh) * | 2012-02-09 | 2013-10-02 | 中国农业大学 | 一种利用玉米芯和工业辣椒废渣合成可降解聚氨酯的方法 |
JP2014125516A (ja) * | 2012-12-26 | 2014-07-07 | Kao Corp | 硬質ポリウレタンフォーム製造用ポリオール混合物 |
US10000442B2 (en) | 2014-03-27 | 2018-06-19 | Trent University | Certain metathesized natural oil triacylglycerol polyols for use in polyurethane applications and their related properties |
US10000601B2 (en) | 2014-03-27 | 2018-06-19 | Trent University | Metathesized triacylglycerol polyols for use in polyurethane applications and their related properties |
CA2972281A1 (en) * | 2015-01-26 | 2016-08-04 | Trent University | Methods of making triacylglycerol polyols from fractions of metathesized natural oils and uses thereof |
US9777245B2 (en) | 2015-01-30 | 2017-10-03 | Trent University | Methods of fractionating metathesized triacylglycerol polyols and uses thereof |
CA2986015A1 (en) * | 2015-05-15 | 2016-11-24 | Stepan Company | Ethoxylated vegetable oils in low density spray foam formulations |
CN106748767B (zh) * | 2015-11-19 | 2020-03-17 | 中国石油化工股份有限公司 | 一种低羟值植物油基多元醇及其制备方法 |
CN108003323B (zh) * | 2017-11-20 | 2021-01-15 | 万华化学(北京)有限公司 | 一种减震吸能聚氨酯材料及其制备方法 |
CN109134841A (zh) * | 2018-07-18 | 2019-01-04 | 江苏理工学院 | 一种高活性植物多元醇的制备方法 |
US11920017B2 (en) * | 2018-12-14 | 2024-03-05 | Nanjing Tech University | Preparation method of polyurethane foam |
US11912814B2 (en) * | 2018-12-14 | 2024-02-27 | Nanjing Tech University | Preparation method of flexible polyurethane foam |
US11613604B2 (en) | 2021-06-28 | 2023-03-28 | Covestro Llc | Isocyanate-reactive compositions, polyurethane foams formed therefrom, multi-layer composite articles that include such foams, and methods for their preparation |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW307778B (es) * | 1992-10-28 | 1997-06-11 | Takeda Pharm Industry Co Ltd | |
JPH09124766A (ja) * | 1995-10-27 | 1997-05-13 | Asahi Glass Co Ltd | 軟質ポリウレタンフォームの製造方法 |
DE19903274A1 (de) * | 1999-01-28 | 2000-08-03 | Basf Ag | Verfahren zur Herstellung von Polyetherpolyolen |
DE19928156A1 (de) | 1999-06-19 | 2000-12-28 | Bayer Ag | Aus Polyetherpolyolen hergestellte Polyurethan-Weichschäume |
DE10240186A1 (de) * | 2002-08-28 | 2004-03-11 | Basf Ag | Verfahren zur Herstellung von emissionsarmen Polyurethan-Weichschaumstoffen |
US20060073321A1 (en) * | 2004-10-01 | 2006-04-06 | Kaushiva Bryan D | Molded flexible polyurethane foams with reduced flammability and superior durability |
US20060229375A1 (en) | 2005-04-06 | 2006-10-12 | Yu-Ling Hsiao | Polyurethane foams made with alkoxylated vegetable oil hydroxylate |
DE102005041142A1 (de) * | 2005-08-30 | 2007-03-01 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
DE102005056432A1 (de) * | 2005-11-26 | 2007-05-31 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyolen auf Basis natürlicher Öle |
US20070238798A1 (en) | 2006-04-05 | 2007-10-11 | Mcdaniel Kenneth G | Flexible polyurethane foams made from vegetable oil alkoxylated via DMC-catalysis |
KR20090102731A (ko) * | 2006-12-19 | 2009-09-30 | 아사히 가라스 가부시키가이샤 | 연질 폴리우레탄 폼의 제조 방법 |
JP5956979B2 (ja) * | 2010-04-30 | 2016-07-27 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | ポリエーテルポリオール、ポリエーテルポリオールを製造するための方法、及びポリウレタンを製造するために、このポリエーテルポリオールを使用する方法 |
US9115246B2 (en) * | 2010-04-30 | 2015-08-25 | Basf Se | Polyether polyols, process for preparing polyether polyols and their use for producing polyurethanes |
US8598248B2 (en) * | 2010-07-16 | 2013-12-03 | Bayer Materialscience Llc | Flexible polyurethane foams made from alkoxylated natural oil |
-
2011
- 2011-04-15 SG SG10201503146WA patent/SG10201503146WA/en unknown
- 2011-04-15 EP EP20110772349 patent/EP2560944A4/en not_active Withdrawn
- 2011-04-15 KR KR1020127027437A patent/KR20130091631A/ko not_active Application Discontinuation
- 2011-04-15 CA CA2796656A patent/CA2796656C/en not_active Expired - Fee Related
- 2011-04-15 JP JP2013506135A patent/JP6038775B2/ja not_active Expired - Fee Related
- 2011-04-15 US US13/641,890 patent/US10323212B2/en not_active Expired - Fee Related
- 2011-04-15 MX MX2012012117A patent/MX2012012117A/es unknown
- 2011-04-15 CN CN201180020311.9A patent/CN102858732B/zh not_active Expired - Fee Related
- 2011-04-15 WO PCT/US2011/000685 patent/WO2011133208A2/en active Application Filing
- 2011-04-15 SG SG2012071890A patent/SG184309A1/en unknown
- 2011-04-15 BR BR112012027070A patent/BR112012027070A2/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JP2013530263A (ja) | 2013-07-25 |
WO2011133208A2 (en) | 2011-10-27 |
CA2796656C (en) | 2018-07-03 |
CN102858732B (zh) | 2015-11-25 |
EP2560944A2 (en) | 2013-02-27 |
BR112012027070A2 (pt) | 2016-07-26 |
US20130210951A1 (en) | 2013-08-15 |
KR20130091631A (ko) | 2013-08-19 |
EP2560944A4 (en) | 2014-03-26 |
JP6038775B2 (ja) | 2016-12-07 |
CA2796656A1 (en) | 2011-10-27 |
WO2011133208A3 (en) | 2012-02-23 |
SG10201503146WA (en) | 2015-06-29 |
US10323212B2 (en) | 2019-06-18 |
SG184309A1 (en) | 2012-11-29 |
CN102858732A (zh) | 2013-01-02 |
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