MX364905B - Procedimiento de preparación de bis(3-aminofenil) disulfuros y 3-aminotioles. - Google Patents

Procedimiento de preparación de bis(3-aminofenil) disulfuros y 3-aminotioles.

Info

Publication number
MX364905B
MX364905B MX2015007277A MX2015007277A MX364905B MX 364905 B MX364905 B MX 364905B MX 2015007277 A MX2015007277 A MX 2015007277A MX 2015007277 A MX2015007277 A MX 2015007277A MX 364905 B MX364905 B MX 364905B
Authority
MX
Mexico
Prior art keywords
aminothiols
disulfides
aminophenyl
producing bis
general formula
Prior art date
Application number
MX2015007277A
Other languages
English (en)
Other versions
MX2015007277A (es
Inventor
Thomas Himmler
Hahn Julia Johanna
Original Assignee
Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Publication of MX2015007277A publication Critical patent/MX2015007277A/es
Publication of MX364905B publication Critical patent/MX364905B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C07C319/06—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols from sulfides, hydropolysulfides or polysulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/22—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/22—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides
    • C07C319/24—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides by reactions involving the formation of sulfur-to-sulfur bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/01—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and halogen atoms, or nitro or nitroso groups bound to the same carbon skeleton
    • C07C323/09—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and halogen atoms, or nitro or nitroso groups bound to the same carbon skeleton having sulfur atoms of thio groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/31—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C07C323/33—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring
    • C07C323/34—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a mercapto group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/31—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C07C323/33—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring
    • C07C323/35—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/31—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C07C323/33—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring
    • C07C323/35—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group
    • C07C323/37—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group the sulfur atom of the sulfide group being further bound to a carbon atom of a six-membered aromatic ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un procedimiento novedoso de preparación de bis(3-aminofenil) disulfuros de fórmula general (I) y 3-aminotioles de fórmula general (II) (ver Fórmulas) donde X,Y tienen los significados citados en la descripción, que sirven como productos intermedios para la preparación de sulfóxidos de fenilo que tienen actividad insecticida, acaricida y nematicida.
MX2015007277A 2012-12-12 2013-12-12 Procedimiento de preparación de bis(3-aminofenil) disulfuros y 3-aminotioles. MX364905B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12196615 2012-12-12
PCT/EP2013/076301 WO2014090913A1 (de) 2012-12-12 2013-12-12 Verfahren zur herstellung von bis(3-aminophenyl)-disulfiden und 3-aminothiolen

Publications (2)

Publication Number Publication Date
MX2015007277A MX2015007277A (es) 2015-08-12
MX364905B true MX364905B (es) 2019-05-13

Family

ID=47325943

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015007277A MX364905B (es) 2012-12-12 2013-12-12 Procedimiento de preparación de bis(3-aminofenil) disulfuros y 3-aminotioles.

Country Status (12)

Country Link
US (2) US10053421B2 (es)
EP (1) EP2931703B1 (es)
JP (1) JP6309966B2 (es)
KR (1) KR102155759B1 (es)
CN (2) CN104854085B (es)
BR (1) BR112015013603B1 (es)
DK (1) DK2931703T3 (es)
ES (1) ES2706755T3 (es)
IL (1) IL239137B (es)
MX (1) MX364905B (es)
TW (1) TWI623520B (es)
WO (1) WO2014090913A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220348538A1 (en) * 2019-10-16 2022-11-03 Bayer Aktiengesellschaft Process of preparing 1,1'-disulfandiylbis(4-fluoro-2-methyl-5-nitrobenzol)
CN117715888A (zh) 2021-07-27 2024-03-15 拜耳公司 用于制备(2,2,2-三氟乙基)硫基苯胺衍生物的方法
CN115521234B (zh) * 2022-11-28 2023-03-24 苏州开元民生科技股份有限公司 一种邻氨基苯硫酚的合成方法
WO2024153573A1 (de) 2023-01-19 2024-07-25 Bayer Aktiengesellschaft Verfahren zur herstellung von (2,2,2-trifluorethyl)sulfanylanilin-derivaten

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2986581A (en) * 1959-11-05 1961-05-30 Trubek Lab Production of aromatic disulfides
DD149363A1 (de) * 1980-02-27 1981-07-08 Guenter Domschke Verfahren zur herstellung von diazidodiphenyldisulfiden
DE3216126A1 (de) * 1982-04-30 1983-11-03 Cassella Ag, 6000 Frankfurt Verfahren zur herstellung von disulfiden
DE3820948A1 (de) 1988-06-16 1989-12-21 Schering Ag 10ss, 11ss-ueberbrueckte steroide
JP2684749B2 (ja) * 1989-02-23 1997-12-03 日産化学工業株式会社 ビス―（４―フルオロ―２―クロルフェニル）ジスルフィド誘導体
DE3929170A1 (de) * 1989-09-02 1991-03-07 Bayer Ag N- (5-alkylthiophenyl)-stickstoffheterocyclen
JP2920557B2 (ja) * 1990-08-27 1999-07-19 イハラケミカル工業株式会社 ２−（５−アミノ−２−クロロ−４−フルオロフエニルチオ）酢酸メチルエステルの製造法およびその中間体
JP3172878B2 (ja) * 1990-12-27 2001-06-04 イハラケミカル工業株式会社 新規なジスルフィド化合物
JPH08506464A (ja) 1993-11-26 1996-07-09 シナール アクチエンゲゼルシヤフト シヤツフハウゼン スチル写真機及び像生成方法
JPH09506101A (ja) * 1993-12-07 1997-06-17 スミスクライン・ビーチャム・パブリック・リミテッド・カンパニー ５ｈｔ１ｄ拮抗薬として有用な複素環式ビフェニリルアミド類
JP3332561B2 (ja) * 1994-03-17 2002-10-07 イハラケミカル工業株式会社 チオアリール化合物の製造方法
DE4420777A1 (de) * 1994-06-15 1995-12-21 Bayer Ag Verfahren zur Herstellung von 4-Fluorthiophenol
JPH08198842A (ja) * 1995-01-25 1996-08-06 Nissan Chem Ind Ltd ジフェニルジスルフィド誘導体
US7101676B2 (en) * 2002-01-11 2006-09-05 Douglas Buechter Methods for identifying compounds which inhibit binding of nucleocapsid 7 protein to HIV-1 RNA
RU2394819C2 (ru) * 2004-10-20 2010-07-20 Кумиай Кемикал Индастри Ко., Лтд. Инсектицид, акарицид и нематоцид, содержащие в качестве активного компонента производное 3-триазолилфенилсульфида
KR100654208B1 (ko) * 2005-12-05 2006-12-06 주식회사 제이엠씨 방향족 디설파이드의 제조방법
CN101663302B (zh) * 2007-04-18 2013-07-24 橘生药品工业株式会社 含氮稠环衍生物、包含所述含氮稠环衍生物的药物组合物及其医药用途
JP2008308493A (ja) * 2007-05-17 2008-12-25 Kissei Pharmaceut Co Ltd 新規なカテコール誘導体、それを含有する医薬組成物およびそれらの用途
EP2226312A4 (en) * 2007-11-30 2014-04-02 Ihara Chemical Ind Co PROCESS FOR PREPARING A 3-MERCAPOTANILINE COMPOUND
WO2010031813A1 (en) * 2008-09-19 2010-03-25 Novartis Ag Glycoside derivatives and uses thereof
EP2274982A1 (de) 2009-07-16 2011-01-19 Bayer CropScience AG Verwendung von Phenyltriazolen zur Bekämpfung von Insekten und Spinnmilben durch Angiessen, Tröpfchen- oder Tauchapplikation oder durch Behandlung von Saatgut
KR101463190B1 (ko) * 2010-01-05 2014-11-18 수벤 라이프 사이언시스 리미티드 ５­ｈｔ６ 수용체 리간드인 술폰 화합물
JP2011219419A (ja) * 2010-04-09 2011-11-04 Kumiai Chemical Industry Co Ltd 光学活性（＋）−１−［２，４−ジメチル−５−（２，２，２−トリフルオロエチルスルフィニル）フェニル］−３−（トリフルオロメチル）−１ｈ−１，２，４−トリアゾール及び有害生物防除剤
GB201008047D0 (en) * 2010-05-14 2010-06-30 Ge Healthcare Ltd Method of synthesis

Also Published As

Publication number Publication date
IL239137A0 (en) 2015-07-30
TWI623520B (zh) 2018-05-11
EP2931703B1 (de) 2018-11-28
JP6309966B2 (ja) 2018-04-11
WO2014090913A1 (de) 2014-06-19
US10053421B2 (en) 2018-08-21
KR102155759B1 (ko) 2020-09-14
CN104854085A (zh) 2015-08-19
IL239137B (en) 2019-03-31
US10239831B2 (en) 2019-03-26
ES2706755T3 (es) 2019-04-01
TW201439045A (zh) 2014-10-16
US20150329485A1 (en) 2015-11-19
EP2931703A1 (de) 2015-10-21
BR112015013603B1 (pt) 2020-12-15
US20180258036A1 (en) 2018-09-13
CN104854085B (zh) 2018-06-01
KR20150092197A (ko) 2015-08-12
MX2015007277A (es) 2015-08-12
CN108640863A (zh) 2018-10-12
DK2931703T3 (en) 2019-01-07
JP2015537053A (ja) 2015-12-24

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