MX357104B - Sistemas de catalizador de ziegler-natta y polímeros formados a partir de los mismos. - Google Patents
Sistemas de catalizador de ziegler-natta y polímeros formados a partir de los mismos.Info
- Publication number
- MX357104B MX357104B MX2014013282A MX2014013282A MX357104B MX 357104 B MX357104 B MX 357104B MX 2014013282 A MX2014013282 A MX 2014013282A MX 2014013282 A MX2014013282 A MX 2014013282A MX 357104 B MX357104 B MX 357104B
- Authority
- MX
- Mexico
- Prior art keywords
- reaction product
- catalyst systems
- contacting
- compound
- formed therefrom
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/10—Magnesium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6548—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof magnesium or compounds thereof, not provided for in C08F4/6543 or C08F4/6546
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
- C08F4/6555—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof and magnesium or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Se describen en la presente procesos para formar sistemas de catalizador, sistemas de catalizador y polímeros formados a partir de los mismos. Los procesos generalmente incluyen proporcionar un primer compuesto que incluye un dialcóxido de magnesio, poner en contacto el primer compuesto con un segundo compuesto para formar una solución del producto de reacción "A", en donde el segundo compuesto es generalmente representado por la fórmula: Ti(OR1)4 en donde se selecciona de alquilos lineales a ramificados de C1 a C10, poner en contacto la solución del producto de reacción "A" con un primer haluro de metal para formar un producto de reacción sólido "B", poner en contacto el producto de reacción sólido "B" con un segundo haluro de metal para formar el producto de reacción "C" y poner en contacto el producto de reacción "C" con un agente de reducción para formar un componente de catalizador.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/685,198 US8592535B2 (en) | 2010-01-11 | 2010-01-11 | Ziegler-natta catalyst systems and polymers formed therefrom |
PCT/US2011/020780 WO2011085350A1 (en) | 2010-01-11 | 2011-01-11 | Ziegler-natta catalyst systems and polymers formed therefrom |
Publications (1)
Publication Number | Publication Date |
---|---|
MX357104B true MX357104B (es) | 2018-06-26 |
Family
ID=44259013
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2012007812A MX2012007812A (es) | 2010-01-11 | 2011-01-11 | Sistemas de catalizador de ziegler-natta y polimeros formados a partir de los mismos. |
MX2014013282A MX357104B (es) | 2010-01-11 | 2011-01-11 | Sistemas de catalizador de ziegler-natta y polímeros formados a partir de los mismos. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2012007812A MX2012007812A (es) | 2010-01-11 | 2011-01-11 | Sistemas de catalizador de ziegler-natta y polimeros formados a partir de los mismos. |
Country Status (12)
Country | Link |
---|---|
US (2) | US8592535B2 (es) |
EP (1) | EP2523754B1 (es) |
JP (1) | JP5922039B2 (es) |
KR (1) | KR101861091B1 (es) |
CN (1) | CN102711980B (es) |
BR (1) | BR112012017021B1 (es) |
CA (1) | CA2785565C (es) |
EA (1) | EA022767B1 (es) |
ES (1) | ES2586235T3 (es) |
MX (2) | MX2012007812A (es) |
TW (1) | TWI607027B (es) |
WO (1) | WO2011085350A1 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10002325B2 (en) | 2005-03-30 | 2018-06-19 | Primal Fusion Inc. | Knowledge representation systems and methods incorporating inference rules |
US10474647B2 (en) | 2010-06-22 | 2019-11-12 | Primal Fusion Inc. | Methods and devices for customizing knowledge representation systems |
US9650448B2 (en) * | 2014-06-13 | 2017-05-16 | Fina Technology, Inc. | Formation of a Ziegler-Natta catalyst |
US9624321B2 (en) * | 2014-06-13 | 2017-04-18 | Fina Technology, Inc. | Formation of a Ziegler-Natta catalyst |
Family Cites Families (51)
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DE2021831C3 (de) | 1970-05-05 | 1974-08-01 | Farbwerke Hoechst Ag, Vormals Meister Lucius & Bruening, 6000 Frankfurt | Verfahren zur Herstellung von Polymerisationskatalysatoren |
US4271060A (en) | 1979-09-17 | 1981-06-02 | Phillips Petroleum Company | Solution polymerization process |
US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
DE3780260T2 (de) * | 1986-11-20 | 1993-02-11 | Mitsubishi Chem Ind | Verfahren zur herstellung von olefinpolymeren. |
FR2623812B1 (fr) * | 1987-11-30 | 1992-02-21 | Bp Chimie Sa | Catalyseur de polymerisation d'olefines de type ziegler natta et procede de preparation a partir de dialcoxyde de magnesium |
US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
JPH02269104A (ja) * | 1989-12-15 | 1990-11-02 | Idemitsu Kosan Co Ltd | ポリオレフィンの製造方法 |
US5236998A (en) | 1991-03-07 | 1993-08-17 | Occidental Chemical Corporation | Process for the manufacture of linear polyethylene containing α-alkene commonomers |
US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
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US5456471A (en) | 1992-08-18 | 1995-10-10 | Macdonald; Donald K. | Golf practice apparatus and fabricating process |
US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
JP3077940B2 (ja) | 1993-04-26 | 2000-08-21 | エクソン・ケミカル・パテンツ・インク | 流動層重合法のための安定な操作条件を決定する方法 |
ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
JPH07138322A (ja) * | 1993-09-21 | 1995-05-30 | Mitsubishi Chem Corp | エチレン系重合体及びそれを用いた燃料タンク |
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US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
KR100190434B1 (ko) * | 1995-05-18 | 1999-06-01 | 고다 시게노리 | 고체티타늄촉매성분 그 제조방법, 그를 함유한 올레핀중합촉매및올레핀중합방법 |
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EP0787747B1 (en) | 1995-08-21 | 2001-11-21 | Toho Titanium Co., Ltd. | Proces for the preparation of solid catalytic components and of a catalyst for polymerizing olefins |
ES2133881T3 (es) * | 1995-12-01 | 1999-09-16 | Borealis Ag | Catalizador soportado para la polimerizacion de olefinas. |
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CN100450620C (zh) * | 2003-09-22 | 2009-01-14 | 弗纳技术股份有限公司 | 用于聚烯烃的齐格勒-纳塔催化剂 |
US7473664B2 (en) | 2006-06-23 | 2009-01-06 | Fina Technology, Inc. | Formation of Ziegler-Natta catalyst |
US8003741B2 (en) * | 2008-02-07 | 2011-08-23 | Fina Technology, Inc. | Ziegler-Natta catalyst |
US10351640B2 (en) * | 2010-04-22 | 2019-07-16 | Fina Technology, Inc. | Formation of Ziegler-Natta catalyst using non-blended components |
-
2010
- 2010-01-11 US US12/685,198 patent/US8592535B2/en active Active
-
2011
- 2011-01-03 TW TW100100069A patent/TWI607027B/zh not_active IP Right Cessation
- 2011-01-11 MX MX2012007812A patent/MX2012007812A/es active IP Right Grant
- 2011-01-11 CN CN201180005731.XA patent/CN102711980B/zh active Active
- 2011-01-11 MX MX2014013282A patent/MX357104B/es unknown
- 2011-01-11 WO PCT/US2011/020780 patent/WO2011085350A1/en active Application Filing
- 2011-01-11 KR KR1020127018134A patent/KR101861091B1/ko active IP Right Grant
- 2011-01-11 BR BR112012017021-0A patent/BR112012017021B1/pt not_active IP Right Cessation
- 2011-01-11 CA CA2785565A patent/CA2785565C/en not_active Expired - Fee Related
- 2011-01-11 EP EP11732300.6A patent/EP2523754B1/en active Active
- 2011-01-11 ES ES11732300.6T patent/ES2586235T3/es active Active
- 2011-01-11 EA EA201270682A patent/EA022767B1/ru not_active IP Right Cessation
- 2011-01-11 JP JP2012548223A patent/JP5922039B2/ja not_active Expired - Fee Related
- 2011-12-12 US US13/316,662 patent/US9416202B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
BR112012017021A2 (pt) | 2016-04-05 |
EA201270682A1 (ru) | 2012-12-28 |
EA022767B1 (ru) | 2016-02-29 |
EP2523754B1 (en) | 2016-05-11 |
TWI607027B (zh) | 2017-12-01 |
CN102711980B (zh) | 2015-08-19 |
KR101861091B1 (ko) | 2018-05-28 |
WO2011085350A8 (en) | 2012-08-09 |
CN102711980A (zh) | 2012-10-03 |
WO2011085350A1 (en) | 2011-07-14 |
EP2523754A4 (en) | 2013-10-09 |
MX2012007812A (es) | 2012-08-31 |
EP2523754A1 (en) | 2012-11-21 |
US8592535B2 (en) | 2013-11-26 |
JP5922039B2 (ja) | 2016-05-24 |
CA2785565C (en) | 2016-08-16 |
US9416202B2 (en) | 2016-08-16 |
TW201144339A (en) | 2011-12-16 |
KR20120112542A (ko) | 2012-10-11 |
JP2013516542A (ja) | 2013-05-13 |
US20110172379A1 (en) | 2011-07-14 |
US20120083405A1 (en) | 2012-04-05 |
BR112012017021B1 (pt) | 2019-04-09 |
ES2586235T3 (es) | 2016-10-13 |
CA2785565A1 (en) | 2011-07-14 |
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