MX353465B - Capsulas de coacervados hibridos. - Google Patents
Capsulas de coacervados hibridos.Info
- Publication number
- MX353465B MX353465B MX2014014107A MX2014014107A MX353465B MX 353465 B MX353465 B MX 353465B MX 2014014107 A MX2014014107 A MX 2014014107A MX 2014014107 A MX2014014107 A MX 2014014107A MX 353465 B MX353465 B MX 353465B
- Authority
- MX
- Mexico
- Prior art keywords
- polymer
- hybrid
- mixture
- core material
- particle
- Prior art date
Links
- 239000002775 capsule Substances 0.000 title abstract 3
- 229920000642 polymer Polymers 0.000 abstract 4
- 239000002245 particle Substances 0.000 abstract 3
- 239000011162 core material Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000011247 coating layer Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
- A23L2/56—Flavouring or bittering agents
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/70—Fixation, conservation, or encapsulation of flavouring agents
- A23L27/72—Encapsulation
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
- A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
- A21D2/02—Treatment of flour or dough by adding materials thereto before or during baking by adding inorganic substances
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
- A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
- A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C19/00—Cheese; Cheese preparations; Making thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/12—Fermented milk preparations; Treatment using microorganisms or enzymes
- A23C9/13—Fermented milk preparations; Treatment using microorganisms or enzymes using additives
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
- A23G9/32—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
- A23L27/203—Alicyclic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/25—Exudates, e.g. gum arabic, gum acacia, gum karaya or tragacanth
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/275—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of animal origin, e.g. chitin
- A23L29/281—Proteins, e.g. gelatin or collagen
- A23L29/284—Gelatin; Collagen
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/294—Inorganic additives, e.g. silica
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P10/00—Shaping or working of foodstuffs characterised by the products
- A23P10/30—Encapsulation of particles, e.g. foodstuff additives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Nutrition Science (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Zoology (AREA)
- Microbiology (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Cosmetics (AREA)
- Medicinal Preparation (AREA)
Abstract
La presente invención se refiere a un proceso para preparar una cápsula de coacervado híbrido caracterizado porque comprende: (a) mezclar una solución de un primer polímero con una dispersión de por lo menos un tipo de partículas sólidas en una temperatura que está arriba de la temperatura de gelificación del primer polímero, en donde el primer polímero se adsorbe en por lo menos un tipo de partículas sólidas para producir una dispersión de complejos de partículas/polímero; (b) agregar una solución de un segundo polímero a la dispersión, en donde el segundo polímero interactúa con los complejos de partícula/polímero para formar coacervados complejos híbridos que contiene inclusiones particuladas; (c) agregar un material núcleo a los coacervados complejos híbridos, en donde los coacervados complejos híbridos se depositan como una capa de recubrimiento alrededor de la interfase de solución/material activo núcleo para formar las cápsulas de núcleo/capa exterior cada una que contiene el material núcleo encapsulado por una capa exterior de coacervado híbrido; y (d) reducir la temperatura de las cápsulas de núcleo/capa exterior a una temperatura que está debajo de la temperatura de gelificación del primer polímero; (e) opcionalmente, reticular las capas exteriores de coacervado híbrido de las cápsulas; en donde la composición de la materia seca de la capa exterior de coacervado híbrido es de tal forma que la proporción de la masa total de partículas sólidas a masa total de primer polímero y del segundo polímero está entre 0.01 y 1.85.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12169278 | 2012-05-24 | ||
PCT/EP2013/060619 WO2013174921A1 (en) | 2012-05-24 | 2013-05-23 | Hybrid coacervate capsules |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014014107A MX2014014107A (es) | 2015-02-24 |
MX353465B true MX353465B (es) | 2018-01-15 |
Family
ID=48534370
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014014107A MX353465B (es) | 2012-05-24 | 2013-05-23 | Capsulas de coacervados hibridos. |
Country Status (7)
Country | Link |
---|---|
US (1) | US10092023B2 (es) |
EP (1) | EP2854560B1 (es) |
JP (1) | JP6534613B2 (es) |
CN (1) | CN104334032B (es) |
BR (1) | BR112014028735B1 (es) |
MX (1) | MX353465B (es) |
WO (1) | WO2013174921A1 (es) |
Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10993466B2 (en) * | 2015-04-24 | 2021-05-04 | International Flavors & Fragrances Inc. | Delivery systems and methods of preparing the same |
WO2017058875A1 (en) * | 2015-09-28 | 2017-04-06 | International Flavors & Fragrances Inc. | Hybrid capsules |
JP6921476B2 (ja) | 2015-12-15 | 2021-08-18 | ロレアル | ポリイオンコンプレックス粒子と2つ以上の酸解離定数を有する非ポリマー酸との組合せ |
JP6812100B2 (ja) * | 2015-12-15 | 2021-01-13 | ロレアル | ポリイオンコンプレックス粒子と親水性又は水溶性uv遮蔽剤との組合せ |
FR3046088B1 (fr) | 2015-12-28 | 2018-01-19 | Capsulae | Microcapsule comprenant une membrane issue d'une microencapsulation par coacervation complexe, et procede d'obtention |
EP3429740B1 (en) * | 2016-03-18 | 2021-05-05 | International Flavors & Fragrances Inc. | Silica microcapsules and methods of preparing same |
CA3029979A1 (en) | 2016-07-06 | 2018-01-11 | Qualicaps Co., Ltd. | Hard capsule having improved hardness, and method for manufacturing same |
FR3064189B1 (fr) * | 2017-03-21 | 2019-04-26 | Capsum | Encapsulation de reactifs pour la preparation d'un biomateriau |
JP7176836B2 (ja) | 2017-06-13 | 2022-11-22 | ロレアル | ポリイオンコンプレックス粒子と油とを含む組成物 |
CN107982095B (zh) * | 2017-10-19 | 2020-03-27 | 珀莱雅化妆品股份有限公司 | 一种具有抗皱功效的缓释固体微球的制备方法 |
CN107811262A (zh) * | 2017-12-06 | 2018-03-20 | 宁夏红山河食品股份有限公司 | 一种生物活性烧烤调味料的制备方法和应用 |
EP3668481A1 (en) | 2017-12-14 | 2020-06-24 | Firmenich SA | Process for releasing an active ingredient |
JP7275115B2 (ja) | 2017-12-14 | 2023-05-17 | フイルメニツヒ ソシエテ アノニム | 粉末状組成物を製造する方法 |
WO2020009439A1 (ko) * | 2018-07-03 | 2020-01-09 | 주식회사 엘지생활건강 | 유무기 하이브리드 마이크로캡슐의 제조방법 |
JP7472028B2 (ja) * | 2018-10-02 | 2024-04-22 | クオリカプス株式会社 | 強度が改善された硬質カプセル、及びその製造方法 |
WO2020214877A1 (en) * | 2019-04-17 | 2020-10-22 | The Procter & Gamble Company | Capsules |
CN113631695A (zh) | 2019-04-17 | 2021-11-09 | 宝洁公司 | 胶囊 |
US11628413B2 (en) | 2019-04-17 | 2023-04-18 | The Procter & Gamble Company | Methods of making capsules |
US20220132900A1 (en) * | 2019-06-27 | 2022-05-05 | Firmenich Sa | Flavored food product |
CA3145836A1 (en) * | 2019-07-19 | 2021-01-28 | Dsm Ip Assets B.V. | Encapsulation of lipophilic actives which are sensitive to acid degradation |
CN110522061B (zh) * | 2019-08-28 | 2021-09-14 | 青岛职业技术学院 | 一种微胶囊及其制备方法 |
JP2023516535A (ja) * | 2019-12-25 | 2023-04-20 | ユニリーバー・アイピー・ホールディングス・ベスローテン・ヴェンノーツハップ | マイクロカプセルおよびそれを含む化粧品組成物 |
JP2023515562A (ja) | 2020-02-26 | 2023-04-13 | フイルメニツヒ ソシエテ アノニム | フレーバリングされた組成物 |
JP2023515560A (ja) | 2020-02-26 | 2023-04-13 | フイルメニツヒ ソシエテ アノニム | フレーバー付与した組成物の製造方法 |
MX2023004226A (es) | 2020-10-16 | 2023-04-21 | Procter & Gamble | Composiciones antitranspirantes y desodorantes que comprenden capsulas. |
MX2023004227A (es) | 2020-10-16 | 2023-04-21 | Procter & Gamble | Composiciones liquidas para el cuidado de telas que comprenden capsulas. |
SI26119A (sl) * | 2020-12-14 | 2022-06-30 | Mikrocaps D.O.O. | Biorazgradljive mikrokapsule osnovane na kompozitnem materialu in postopek sinteze |
CN113351125B (zh) * | 2021-06-22 | 2022-06-28 | 上海应用技术大学 | 一种柑橘精油微胶囊及其制备方法和应用 |
EP4358727A1 (en) | 2021-08-17 | 2024-05-01 | Firmenich SA | Sweetened composition |
CN115707475B (zh) * | 2021-08-20 | 2023-05-12 | 江苏省农业科学院 | 一种核壳型噬菌体粉剂及其制备方法和应用 |
CA3231913A1 (en) * | 2021-09-14 | 2023-03-23 | Ehsan Moaseri | Alimentary-related particles, production methods, and production apparatus |
WO2023177360A1 (en) | 2022-03-15 | 2023-09-21 | Mikrocaps D.O.O. | Biodegradable microcapsules based on crystalline materials and synthesis process |
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US3627581A (en) * | 1970-10-19 | 1971-12-14 | Ncr Co | Pressure-sensitive record material |
US4115315A (en) * | 1977-02-16 | 1978-09-19 | Ncr Corporation | Pearlescent capsules and process for their preparation |
US4394287A (en) | 1981-04-10 | 1983-07-19 | Eurand America, Inc. | Incorporation of finely divided additives at the surface of microcapsule walls |
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JPS5840551A (ja) * | 1981-09-02 | 1983-03-09 | Fuji Photo Film Co Ltd | カラ−画像形成方法 |
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EP0455598B1 (en) | 1990-05-04 | 1994-01-26 | Warner-Lambert Company | Microencapsulated flavoring agents and methods for preparing same |
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US20050156340A1 (en) | 2004-01-20 | 2005-07-21 | E Ink Corporation | Preparation of capsules |
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US7473467B2 (en) | 2002-09-03 | 2009-01-06 | Firmenich Sa | Preparation of microcapsules |
US7794836B2 (en) * | 2002-09-04 | 2010-09-14 | Southwest Research Institute | Microencapsulation of oxygen or water sensitive materials |
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WO2008142637A1 (en) | 2007-05-21 | 2008-11-27 | Firmenich Sa | Large coacervated capsules |
DE102008002145A1 (de) | 2008-06-02 | 2009-12-03 | Symrise Gmbh & Co. Kg | Kapsel mit organisch-anorganischer Hybridwand |
US8778867B2 (en) * | 2008-12-18 | 2014-07-15 | Firmenich Sa | Microcapsules and uses thereof |
DE102009019370A1 (de) | 2009-04-29 | 2011-01-27 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zum Verkapseln von flüssigen oder pastösen Substanzen in einem vernetzten Verkapselungsmaterial |
WO2011124706A1 (en) | 2010-04-09 | 2011-10-13 | Basf Se | In-situ sol-gel encapsulation of fragrances, perfumes or flavours |
JP5931859B2 (ja) | 2010-06-30 | 2016-06-08 | フイルメニツヒ ソシエテ アノニムFirmenich Sa | 固形コアコアセルベート化したカプセル |
-
2013
- 2013-05-23 EP EP13725345.6A patent/EP2854560B1/en active Active
- 2013-05-23 WO PCT/EP2013/060619 patent/WO2013174921A1/en active Application Filing
- 2013-05-23 US US14/402,469 patent/US10092023B2/en active Active
- 2013-05-23 MX MX2014014107A patent/MX353465B/es active IP Right Grant
- 2013-05-23 JP JP2015513181A patent/JP6534613B2/ja active Active
- 2013-05-23 BR BR112014028735-0A patent/BR112014028735B1/pt active IP Right Grant
- 2013-05-23 CN CN201380026627.8A patent/CN104334032B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
US10092023B2 (en) | 2018-10-09 |
BR112014028735A2 (pt) | 2017-06-27 |
EP2854560A1 (en) | 2015-04-08 |
JP2015517554A (ja) | 2015-06-22 |
MX2014014107A (es) | 2015-02-24 |
WO2013174921A1 (en) | 2013-11-28 |
CN104334032B (zh) | 2017-09-15 |
BR112014028735B1 (pt) | 2020-10-20 |
US20150104545A1 (en) | 2015-04-16 |
EP2854560B1 (en) | 2020-12-02 |
JP6534613B2 (ja) | 2019-06-26 |
CN104334032A (zh) | 2015-02-04 |
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