MX352948B - Produccion de acido sulfurico con reciclaje de gas desulfurado. - Google Patents
Produccion de acido sulfurico con reciclaje de gas desulfurado.Info
- Publication number
- MX352948B MX352948B MX2014003017A MX2014003017A MX352948B MX 352948 B MX352948 B MX 352948B MX 2014003017 A MX2014003017 A MX 2014003017A MX 2014003017 A MX2014003017 A MX 2014003017A MX 352948 B MX352948 B MX 352948B
- Authority
- MX
- Mexico
- Prior art keywords
- process gas
- stream
- desulphurized
- recycle
- gas
- Prior art date
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title abstract 3
- 235000011149 sulphuric acid Nutrition 0.000 title abstract 3
- 239000001117 sulphuric acid Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 abstract 8
- 239000011149 active material Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 238000011144 upstream manufacturing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/765—Multi-stage SO3-conversion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8609—Sulfur oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/765—Multi-stage SO3-conversion
- C01B17/7655—Multi-stage SO3-conversion with intermediate absorption
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/80—Apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/202—Alkali metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20723—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Gas Separation By Absorption (AREA)
- Electrostatic Separation (AREA)
- Epoxy Compounds (AREA)
- Industrial Gases (AREA)
- Drying Of Gases (AREA)
- Catalysts (AREA)
Abstract
La invención se refiere a un proceso para la oxidación de SO2 a SO3 que comprende los pasos que consisten en, (a) dirigir una corriente de gas de alimentación que comprende SO2 y O2 a un material catalíticamente activo, (b) oxidar una cantidad del SO2 en el gas de proceso a SO3 en presencia del material catalíticamente activo, lo que proporciona un primer gas de proceso oxidado, (c) hacer reaccionar el SO3 con agua, (d) condensar el H2SO4, (e) retirar un primer gas de proceso desulfurado y una primera corriente de ácido sulfúrico, (f) del gas de proceso desulfurado retirar una corriente de reciclaje de gas de proceso desulfurado, en donde la corriente de reciclaje se agrega a la corriente de gas de alimentación o el primer gas de proceso oxidado con el beneficio asociado de reducir el flujo molar de gas de proceso corriente abajo del retiro de la corriente de reciclaje y corriente arriba del punto de mezcla. La figura más representativa de la invención es la número 2.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2011/004860 WO2013044937A1 (en) | 2011-09-29 | 2011-09-29 | Sulphuric acid production with recycle of desulphurized gas |
| PCT/EP2012/069099 WO2013045558A1 (en) | 2011-09-29 | 2012-09-27 | Sulphuric acid production with recycle of desulphurized gas |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014003017A MX2014003017A (es) | 2014-05-28 |
| MX352948B true MX352948B (es) | 2017-12-15 |
Family
ID=46924468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014003017A MX352948B (es) | 2011-09-29 | 2012-09-27 | Produccion de acido sulfurico con reciclaje de gas desulfurado. |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US9045342B2 (es) |
| JP (1) | JP6081466B2 (es) |
| KR (1) | KR101998682B1 (es) |
| CN (1) | CN103826726B (es) |
| AR (1) | AR088074A1 (es) |
| AU (1) | AU2012314458B2 (es) |
| BR (1) | BR112014006769B1 (es) |
| CA (1) | CA2843208C (es) |
| CL (1) | CL2014000701A1 (es) |
| EA (1) | EA029442B9 (es) |
| ES (1) | ES2568635T3 (es) |
| IN (1) | IN2014CN02208A (es) |
| MX (1) | MX352948B (es) |
| PE (1) | PE20141047A1 (es) |
| TW (1) | TWI547435B (es) |
| UA (1) | UA112662C2 (es) |
| WO (2) | WO2013044937A1 (es) |
| ZA (1) | ZA201400603B (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014094352A (ja) * | 2012-11-09 | 2014-05-22 | Mitsubishi Heavy Ind Ltd | 排ガス処理装置及び方法 |
| CN105636902A (zh) * | 2013-07-18 | 2016-06-01 | 康世富技术公司 | 由酸性尾气田生产硫酸的方法 |
| LU92547B1 (de) | 2014-09-17 | 2016-03-18 | Cppe Carbon Process & Plant Engineering S A | Verfahren zur katalytischen entfernung von schwefeldioxid aus abgasen |
| EP3075434A1 (de) | 2015-04-02 | 2016-10-05 | Bayer Technology Services GmbH | Kontinuierliches verfahren zur reinigung von so2-haltigen gasen |
| BR112017023546B1 (pt) * | 2015-07-02 | 2022-04-12 | Haldor Tops0E A/S | Planta de processo para a produção de ácido sulfúrico e referido processo |
| US10933368B2 (en) | 2017-09-14 | 2021-03-02 | Noram Engineering And Constructors Ltd. | Gas treatment processes and systems for reducing tail gas emissions |
| BR112020010784B1 (pt) | 2017-11-28 | 2022-04-12 | Haldor Tops0E A/S | Processo para produção de enxofre a partir de um gás de carga de alimentação compreendendo h2s e uma corrente reciclada de ácido sulfúrico e instalação de processo |
| CN108046221B (zh) * | 2017-12-12 | 2020-10-02 | 中国恩菲工程技术有限公司 | 一种冶炼烟气制酸的方法 |
| CN115535970B (zh) * | 2021-06-29 | 2023-12-22 | 杭州瑞佑科技有限公司 | 以废硫酸溶液制备高纯度电子级硫酸的方法 |
| US20260042058A1 (en) * | 2024-08-08 | 2026-02-12 | Saudi Arabian Oil Company | Method and system for treating sulfur dioxide containing stream by catalytic oxidation and acid aqueous absorption |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2223131C3 (de) * | 1972-05-12 | 1979-10-11 | Davy Powergas Gmbh, 5000 Koeln | Verfahren zur Herstellung von Schwefelsäure aus Schwefel und Sauerstoff |
| US4490347A (en) * | 1983-02-07 | 1984-12-25 | E. I. Du Pont De Nemours And Company | Process for sulfuric acid regeneration |
| US4559211A (en) * | 1983-08-05 | 1985-12-17 | Research-Cottrell, Inc. | Method for reduced temperature operation of flue gas collectors |
| DE3534060A1 (de) * | 1983-08-05 | 1987-04-02 | Cottrell Res Inc | Verfahren zum betreiben von rauchgas-sammlern bei verminderter temperatur |
| FR2781216B1 (fr) * | 1998-07-17 | 2000-08-18 | Air Liquide | Procede et dispositif de production d'acide sulfurique |
| CA2670295C (en) | 2006-11-29 | 2012-10-16 | Kurt Agerbaek Christensen | Process for the production of sulfuric acid |
| EP2163515B1 (en) * | 2008-09-12 | 2015-03-25 | Haldor Topsoe A/S | Process for the production of sulphuric acid |
| HUE028069T2 (en) * | 2009-12-01 | 2016-11-28 | Bayer Ag | Process for producing sulfuric acid |
| KR101498633B1 (ko) | 2010-02-22 | 2015-03-04 | 할도르 토프쉐 에이/에스 | 부식성 및 비부식성 가스의 혼합을 위한 장치 및 방법 |
-
2011
- 2011-09-29 WO PCT/EP2011/004860 patent/WO2013044937A1/en not_active Ceased
-
2012
- 2012-09-27 AR ARP120103586A patent/AR088074A1/es active IP Right Grant
- 2012-09-27 KR KR1020147003880A patent/KR101998682B1/ko not_active Expired - Fee Related
- 2012-09-27 UA UAA201404442A patent/UA112662C2/uk unknown
- 2012-09-27 TW TW101135507A patent/TWI547435B/zh not_active IP Right Cessation
- 2012-09-27 EA EA201490645A patent/EA029442B9/ru not_active IP Right Cessation
- 2012-09-27 CN CN201280047199.2A patent/CN103826726B/zh active Active
- 2012-09-27 JP JP2014532383A patent/JP6081466B2/ja not_active Expired - Fee Related
- 2012-09-27 US US14/343,092 patent/US9045342B2/en active Active
- 2012-09-27 AU AU2012314458A patent/AU2012314458B2/en active Active
- 2012-09-27 ES ES12762630.7T patent/ES2568635T3/es active Active
- 2012-09-27 CA CA2843208A patent/CA2843208C/en active Active
- 2012-09-27 BR BR112014006769-4A patent/BR112014006769B1/pt active IP Right Grant
- 2012-09-27 MX MX2014003017A patent/MX352948B/es active IP Right Grant
- 2012-09-27 WO PCT/EP2012/069099 patent/WO2013045558A1/en not_active Ceased
- 2012-09-27 PE PE2014000416A patent/PE20141047A1/es active IP Right Grant
-
2014
- 2014-01-24 ZA ZA2014/00603A patent/ZA201400603B/en unknown
- 2014-03-21 CL CL2014000701A patent/CL2014000701A1/es unknown
- 2014-03-22 IN IN2208CHN2014 patent/IN2014CN02208A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2014534151A (ja) | 2014-12-18 |
| ES2568635T3 (es) | 2016-05-03 |
| BR112014006769A2 (pt) | 2017-03-28 |
| CN103826726A (zh) | 2014-05-28 |
| CA2843208C (en) | 2019-12-03 |
| US9045342B2 (en) | 2015-06-02 |
| UA112662C2 (uk) | 2016-10-10 |
| TWI547435B (zh) | 2016-09-01 |
| CL2014000701A1 (es) | 2014-09-05 |
| EA029442B1 (ru) | 2018-03-30 |
| KR101998682B1 (ko) | 2019-07-10 |
| AU2012314458A1 (en) | 2014-04-17 |
| BR112014006769B1 (pt) | 2021-01-19 |
| KR20140085416A (ko) | 2014-07-07 |
| AR088074A1 (es) | 2014-05-07 |
| MX2014003017A (es) | 2014-05-28 |
| EA029442B9 (ru) | 2018-09-28 |
| ZA201400603B (en) | 2015-10-28 |
| US20140219910A1 (en) | 2014-08-07 |
| CN103826726B (zh) | 2017-08-04 |
| NZ623437A (en) | 2016-07-29 |
| EA201490645A1 (ru) | 2014-09-30 |
| CA2843208A1 (en) | 2013-04-04 |
| WO2013044937A1 (en) | 2013-04-04 |
| PE20141047A1 (es) | 2014-09-24 |
| AU2012314458B2 (en) | 2017-01-12 |
| IN2014CN02208A (es) | 2015-06-12 |
| JP6081466B2 (ja) | 2017-02-15 |
| WO2013045558A1 (en) | 2013-04-04 |
| TW201332884A (zh) | 2013-08-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |