MX352948B - Produccion de acido sulfurico con reciclaje de gas desulfurado. - Google Patents
Produccion de acido sulfurico con reciclaje de gas desulfurado.Info
- Publication number
- MX352948B MX352948B MX2014003017A MX2014003017A MX352948B MX 352948 B MX352948 B MX 352948B MX 2014003017 A MX2014003017 A MX 2014003017A MX 2014003017 A MX2014003017 A MX 2014003017A MX 352948 B MX352948 B MX 352948B
- Authority
- MX
- Mexico
- Prior art keywords
- process gas
- stream
- desulphurized
- recycle
- gas
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/765—Multi-stage SO3-conversion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8609—Sulfur oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/765—Multi-stage SO3-conversion
- C01B17/7655—Multi-stage SO3-conversion with intermediate absorption
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/80—Apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/202—Alkali metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20723—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Treating Waste Gases (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Gas Separation By Absorption (AREA)
- Epoxy Compounds (AREA)
- Electrostatic Separation (AREA)
- Drying Of Gases (AREA)
- Industrial Gases (AREA)
- Catalysts (AREA)
Abstract
La invención se refiere a un proceso para la oxidación de SO2 a SO3 que comprende los pasos que consisten en, (a) dirigir una corriente de gas de alimentación que comprende SO2 y O2 a un material catalíticamente activo, (b) oxidar una cantidad del SO2 en el gas de proceso a SO3 en presencia del material catalíticamente activo, lo que proporciona un primer gas de proceso oxidado, (c) hacer reaccionar el SO3 con agua, (d) condensar el H2SO4, (e) retirar un primer gas de proceso desulfurado y una primera corriente de ácido sulfúrico, (f) del gas de proceso desulfurado retirar una corriente de reciclaje de gas de proceso desulfurado, en donde la corriente de reciclaje se agrega a la corriente de gas de alimentación o el primer gas de proceso oxidado con el beneficio asociado de reducir el flujo molar de gas de proceso corriente abajo del retiro de la corriente de reciclaje y corriente arriba del punto de mezcla. La figura más representativa de la invención es la número 2.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2011/004860 WO2013044937A1 (en) | 2011-09-29 | 2011-09-29 | Sulphuric acid production with recycle of desulphurized gas |
| PCT/EP2012/069099 WO2013045558A1 (en) | 2011-09-29 | 2012-09-27 | Sulphuric acid production with recycle of desulphurized gas |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014003017A MX2014003017A (es) | 2014-05-28 |
| MX352948B true MX352948B (es) | 2017-12-15 |
Family
ID=46924468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014003017A MX352948B (es) | 2011-09-29 | 2012-09-27 | Produccion de acido sulfurico con reciclaje de gas desulfurado. |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US9045342B2 (es) |
| JP (1) | JP6081466B2 (es) |
| KR (1) | KR101998682B1 (es) |
| CN (1) | CN103826726B (es) |
| AR (1) | AR088074A1 (es) |
| AU (1) | AU2012314458B2 (es) |
| BR (1) | BR112014006769B1 (es) |
| CA (1) | CA2843208C (es) |
| CL (1) | CL2014000701A1 (es) |
| EA (1) | EA029442B9 (es) |
| ES (1) | ES2568635T3 (es) |
| IN (1) | IN2014CN02208A (es) |
| MX (1) | MX352948B (es) |
| PE (1) | PE20141047A1 (es) |
| TW (1) | TWI547435B (es) |
| UA (1) | UA112662C2 (es) |
| WO (2) | WO2013044937A1 (es) |
| ZA (1) | ZA201400603B (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014094352A (ja) * | 2012-11-09 | 2014-05-22 | Mitsubishi Heavy Ind Ltd | 排ガス処理装置及び方法 |
| CN105636902A (zh) * | 2013-07-18 | 2016-06-01 | 康世富技术公司 | 由酸性尾气田生产硫酸的方法 |
| LU92547B1 (de) * | 2014-09-17 | 2016-03-18 | Cppe Carbon Process & Plant Engineering S A | Verfahren zur katalytischen entfernung von schwefeldioxid aus abgasen |
| EP3075434A1 (de) | 2015-04-02 | 2016-10-05 | Bayer Technology Services GmbH | Kontinuierliches verfahren zur reinigung von so2-haltigen gasen |
| EP3317226B1 (en) * | 2015-07-02 | 2020-05-27 | Haldor Topsøe A/S | Process for production of sulfuric acid |
| US10933368B2 (en) | 2017-09-14 | 2021-03-02 | Noram Engineering And Constructors Ltd. | Gas treatment processes and systems for reducing tail gas emissions |
| CN209536975U (zh) | 2017-11-28 | 2019-10-25 | 托普索公司 | 用于制备硫和硫酸的工艺装置 |
| CN108046221B (zh) * | 2017-12-12 | 2020-10-02 | 中国恩菲工程技术有限公司 | 一种冶炼烟气制酸的方法 |
| CN115535970B (zh) * | 2021-06-29 | 2023-12-22 | 杭州瑞佑科技有限公司 | 以废硫酸溶液制备高纯度电子级硫酸的方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2223131C3 (de) * | 1972-05-12 | 1979-10-11 | Davy Powergas Gmbh, 5000 Koeln | Verfahren zur Herstellung von Schwefelsäure aus Schwefel und Sauerstoff |
| US4490347A (en) * | 1983-02-07 | 1984-12-25 | E. I. Du Pont De Nemours And Company | Process for sulfuric acid regeneration |
| US4559211A (en) * | 1983-08-05 | 1985-12-17 | Research-Cottrell, Inc. | Method for reduced temperature operation of flue gas collectors |
| DE3534060A1 (de) * | 1983-08-05 | 1987-04-02 | Cottrell Res Inc | Verfahren zum betreiben von rauchgas-sammlern bei verminderter temperatur |
| FR2781216B1 (fr) * | 1998-07-17 | 2000-08-18 | Air Liquide | Procede et dispositif de production d'acide sulfurique |
| DE602006017608D1 (de) | 2006-11-29 | 2010-11-25 | Haldor Topsoe As | Verfahren zur herstellung von schwefelsäure |
| EP2163515B1 (en) * | 2008-09-12 | 2015-03-25 | Haldor Topsoe A/S | Process for the production of sulphuric acid |
| SI2330075T1 (sl) * | 2009-12-01 | 2015-12-31 | Bayer Intellectual Property Gmbh | Postopek izdelave žveplove kisline |
| BR112012020931A2 (pt) | 2010-02-22 | 2016-05-03 | Haldor Topsoe As | dispositivo misturador |
-
2011
- 2011-09-29 WO PCT/EP2011/004860 patent/WO2013044937A1/en not_active Application Discontinuation
-
2012
- 2012-09-27 EA EA201490645A patent/EA029442B9/ru not_active IP Right Cessation
- 2012-09-27 US US14/343,092 patent/US9045342B2/en active Active
- 2012-09-27 CA CA2843208A patent/CA2843208C/en active Active
- 2012-09-27 AU AU2012314458A patent/AU2012314458B2/en active Active
- 2012-09-27 PE PE2014000416A patent/PE20141047A1/es active IP Right Grant
- 2012-09-27 JP JP2014532383A patent/JP6081466B2/ja not_active Expired - Fee Related
- 2012-09-27 ES ES12762630.7T patent/ES2568635T3/es active Active
- 2012-09-27 AR ARP120103586A patent/AR088074A1/es active IP Right Grant
- 2012-09-27 BR BR112014006769-4A patent/BR112014006769B1/pt active IP Right Grant
- 2012-09-27 CN CN201280047199.2A patent/CN103826726B/zh active Active
- 2012-09-27 TW TW101135507A patent/TWI547435B/zh not_active IP Right Cessation
- 2012-09-27 UA UAA201404442A patent/UA112662C2/uk unknown
- 2012-09-27 WO PCT/EP2012/069099 patent/WO2013045558A1/en active Application Filing
- 2012-09-27 MX MX2014003017A patent/MX352948B/es active IP Right Grant
- 2012-09-27 KR KR1020147003880A patent/KR101998682B1/ko active IP Right Grant
-
2014
- 2014-01-24 ZA ZA2014/00603A patent/ZA201400603B/en unknown
- 2014-03-21 CL CL2014000701A patent/CL2014000701A1/es unknown
- 2014-03-22 IN IN2208CHN2014 patent/IN2014CN02208A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IN2014CN02208A (es) | 2015-06-12 |
| NZ623437A (en) | 2016-07-29 |
| CA2843208A1 (en) | 2013-04-04 |
| TWI547435B (zh) | 2016-09-01 |
| KR20140085416A (ko) | 2014-07-07 |
| JP2014534151A (ja) | 2014-12-18 |
| AU2012314458A1 (en) | 2014-04-17 |
| EA029442B9 (ru) | 2018-09-28 |
| BR112014006769A2 (pt) | 2017-03-28 |
| CL2014000701A1 (es) | 2014-09-05 |
| TW201332884A (zh) | 2013-08-16 |
| AU2012314458B2 (en) | 2017-01-12 |
| EA201490645A1 (ru) | 2014-09-30 |
| KR101998682B1 (ko) | 2019-07-10 |
| US9045342B2 (en) | 2015-06-02 |
| ES2568635T3 (es) | 2016-05-03 |
| CA2843208C (en) | 2019-12-03 |
| EA029442B1 (ru) | 2018-03-30 |
| WO2013045558A1 (en) | 2013-04-04 |
| BR112014006769B1 (pt) | 2021-01-19 |
| CN103826726B (zh) | 2017-08-04 |
| CN103826726A (zh) | 2014-05-28 |
| ZA201400603B (en) | 2015-10-28 |
| PE20141047A1 (es) | 2014-09-24 |
| WO2013044937A1 (en) | 2013-04-04 |
| UA112662C2 (uk) | 2016-10-10 |
| MX2014003017A (es) | 2014-05-28 |
| AR088074A1 (es) | 2014-05-07 |
| JP6081466B2 (ja) | 2017-02-15 |
| US20140219910A1 (en) | 2014-08-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |