MX2019004282A - 1-haloalcadieno y un proceso para preparar el mismo y un proceso para preparar acetato de (9e,11z)-9,11-hexadecadienilo. - Google Patents

1-haloalcadieno y un proceso para preparar el mismo y un proceso para preparar acetato de (9e,11z)-9,11-hexadecadienilo.

Info

Publication number
MX2019004282A
MX2019004282A MX2019004282A MX2019004282A MX2019004282A MX 2019004282 A MX2019004282 A MX 2019004282A MX 2019004282 A MX2019004282 A MX 2019004282A MX 2019004282 A MX2019004282 A MX 2019004282A MX 2019004282 A MX2019004282 A MX 2019004282A
Authority
MX
Mexico
Prior art keywords
preparing
haloalkadiene
hexadecadienyl acetate
same
general formula
Prior art date
Application number
MX2019004282A
Other languages
English (en)
Inventor
Watanabe Tomohiro
Miyake Yuki
Kinsho Takeshi
Original Assignee
Shinetsu Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shinetsu Chemical Co filed Critical Shinetsu Chemical Co
Publication of MX2019004282A publication Critical patent/MX2019004282A/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2632—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions involving an organo-magnesium compound, e.g. Grignard synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2635—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions involving a phosphorus compound, e.g. Wittig synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/04—Chloro-alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/12—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of mineral acids
    • C07C29/124—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of mineral acids of halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/10—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with ester groups or with a carbon-halogen bond
    • C07C67/11—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with ester groups or with a carbon-halogen bond being mineral ester groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/02—Magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/587—Monocarboxylic acid esters having at least two carbon-to-carbon double bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

El objetivo de la invención es preparar acetato de (9E,11Z)-9,11-hexadecadienilo con un buen rendimiento y alta pureza. La presente invención proporciona un proceso para preparar 1-haloalcadieno de la fórmula general (1): CH3-(CH2)3-CH=CH-CH=CH-(CH2)a-X, que comprende una etapa para conducir la reacción de Wittig entre un haloalquenal de la fórmula general (2): OHC-CH=CH-(CH2)a-X, y un pentiluro de triarilfosfonio de la fórmula general (3): CH3-(CH2)3-CH--P+Ar3, para obtener el 1-haloalcadieno, y el uso de un (7E,9Z)-1-halo-7,9-tetradecadieno obtenido mediante el proceso para un proceso de preparación de acetato de (9E,11Z)-9,11-hexadec adienilo.
MX2019004282A 2018-04-18 2019-04-12 1-haloalcadieno y un proceso para preparar el mismo y un proceso para preparar acetato de (9e,11z)-9,11-hexadecadienilo. MX2019004282A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2018079776A JP7019500B2 (ja) 2018-04-18 2018-04-18 （９ｅ，１１ｚ）－９，１１－ヘキサデカジエニル＝アセテートの製造方法

Publications (1)

Publication Number Publication Date
MX2019004282A true MX2019004282A (es) 2019-10-21

Family

ID=66102500

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019004282A MX2019004282A (es) 2018-04-18 2019-04-12 1-haloalcadieno y un proceso para preparar el mismo y un proceso para preparar acetato de (9e,11z)-9,11-hexadecadienilo.

Country Status (6)

Country Link
US (1) US10737999B2 (es)
EP (1) EP3556742B1 (es)
JP (1) JP7019500B2 (es)
CN (1) CN110386855B (es)
ES (1) ES2890957T3 (es)
MX (1) MX2019004282A (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7291105B2 (ja) * 2020-06-24 2023-06-14 信越化学工業株式会社 （９ｚ，１１ｅ）－９，１１－ヘキサデカジエナールの製造方法
JP2023178017A (ja) * 2022-06-03 2023-12-14 信越化学工業株式会社 （４ｚ，６ｅ）－４，６－ウンデカジエニル＝トリメチルアセテート、及びそれからの（５ｚ，７ｅ）－５，７－ドデカジエン化合物の製造方法
CN115466232B (zh) * 2022-10-18 2023-06-20 山西农业大学 (6z,9z)-3,4-环氧十九碳二烯的制备方法
JP2024063756A (ja) * 2022-10-26 2024-05-13 信越化学工業株式会社 共役二重結合を有する有機ハロゲン化合物、そのアセテート化合物及びアルコール化合物の製造方法、並びに該有機ハロゲン化合物を合成する為に使用される化合物

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62223136A (ja) * 1986-03-19 1987-10-01 Shin Etsu Chem Co Ltd １―ハロ―（ｅ，ｚ）―７，９―アルカジエン化合物
JP2693615B2 (ja) * 1990-02-16 1997-12-24 信越化学工業株式会社 １‐ハロ‐４，６，１０‐ヘキサデカトリエン化合物およびその製造方法
JP2007070276A (ja) 2005-09-06 2007-03-22 Shin Etsu Chem Co Ltd １−ハロ−ｅ，ｚ−４，６−ヘキサデカジエン及びその製造方法並びにこれを用いた性フェロモン化合物の製造方法
CN103102266B (zh) * 2013-01-27 2016-08-03 昆明博鸿生物科技有限公司 一种9z, 11e-十四碳二烯醇乙酸酯的合成方法

Also Published As

Publication number Publication date
JP7019500B2 (ja) 2022-02-15
US10737999B2 (en) 2020-08-11
CN110386855A (zh) 2019-10-29
EP3556742B1 (en) 2021-07-14
US20190322614A1 (en) 2019-10-24
EP3556742A1 (en) 2019-10-23
ES2890957T3 (es) 2022-01-25
CN110386855B (zh) 2023-03-28
JP2019189529A (ja) 2019-10-31

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