MX2017015816A - Composiciones de aislamiento de cables que comprenden un antioxidante que contiene fosforo. - Google Patents

Composiciones de aislamiento de cables que comprenden un antioxidante que contiene fosforo.

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Publication number
MX2017015816A
MX2017015816A MX2017015816A MX2017015816A MX2017015816A MX 2017015816 A MX2017015816 A MX 2017015816A MX 2017015816 A MX2017015816 A MX 2017015816A MX 2017015816 A MX2017015816 A MX 2017015816A MX 2017015816 A MX2017015816 A MX 2017015816A
Authority
MX
Mexico
Prior art keywords
phosphorus
cable insulation
antioxidant
alkyl
group
Prior art date
Application number
MX2017015816A
Other languages
English (en)
Inventor
W Dunchus Neil
M Cogen Jeffrey
H Peterson Thomas
J Person Timothy
Talreja Manish
Roy Raghunath
Drazba Jessica
Groot-Enzerink Gerrit
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of MX2017015816A publication Critical patent/MX2017015816A/es

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37Thiols
    • C08K5/372Sulfides, e.g. R-(S)x-R'
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005Stabilisers against oxidation, heat, light, ozone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/14Peroxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432Six-membered rings
    • C08K5/3435Piperidines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/307Other macromolecular compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/206Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

La presente invención se relaciona con un proceso para elaborar un aislante de cable de extra alto voltaje que se mejora usando una composición que comprende, en porcentaje en peso, basado en el peso de la composición: (A) 95 a 99.9% de un polímero a base de etileno; (B) 0.2 a 2.5% de peróxido; (C) 0.01 a 0.5% de un primer antioxidante que contiene azufre que tiene por lo menos un grupo -S(CH2)2CO2R, en donde R es un alquilo de C6 a C20; (D) 0.001 a 0.009% de un segundo antioxidante que contiene fósforo que no contiene un grupo - S(CH2)2CO2R, en donde R es un alquilo de C6 a C20; (E) opcionalmente, una base nitrogenada orgánica; y (F) opcionalmente, un tercer antioxidante fenólico que no contiene un grupo -S(CH2)2CO2R, en donde R es un alquilo de C6 a C20.
MX2017015816A 2015-06-17 2016-05-25 Composiciones de aislamiento de cables que comprenden un antioxidante que contiene fosforo. MX2017015816A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562180901P 2015-06-17 2015-06-17
PCT/US2016/034004 WO2016204951A1 (en) 2015-06-17 2016-05-25 Cable insulation compositions comprising a phosphorus-containing antioxidant

Publications (1)

Publication Number Publication Date
MX2017015816A true MX2017015816A (es) 2018-04-10

Family

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Family Applications (1)

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MX2017015816A MX2017015816A (es) 2015-06-17 2016-05-25 Composiciones de aislamiento de cables que comprenden un antioxidante que contiene fosforo.

Country Status (9)

Country Link
US (1) US10093788B2 (es)
EP (1) EP3310852B1 (es)
JP (1) JP6857621B2 (es)
KR (1) KR102537800B1 (es)
CN (1) CN107771197B (es)
BR (1) BR112017026118B1 (es)
CA (1) CA2989418C (es)
MX (1) MX2017015816A (es)
WO (1) WO2016204951A1 (es)

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TW202010784A (zh) * 2018-09-13 2020-03-16 美商陶氏全球科技有限責任公司 含有氧化膦之基於乙烯之聚合物組合物
US11753566B2 (en) 2019-01-31 2023-09-12 Synthomer Adhesive Technologies Llc Low volatile tackifier compositions
CN114008127B (zh) * 2019-06-25 2024-01-19 陶氏环球技术有限责任公司 含有三有机氨基膦的基于乙烯的聚合物组合物
CN113583321B (zh) * 2020-04-30 2024-07-23 国家能源投资集团有限责任公司 可交联聚乙烯组合物及其制备方法与应用、交联聚乙烯及其应用
CN113621187B (zh) * 2020-05-07 2024-05-07 国家能源投资集团有限责任公司 可交联绝缘聚烯烃组合物及其制备方法与应用、交联绝缘聚烯烃及其应用
WO2022139885A1 (en) * 2020-12-22 2022-06-30 Dow Global Technologies Llc Modified polyethylene resins and process for making the same
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Also Published As

Publication number Publication date
EP3310852B1 (en) 2020-10-28
BR112017026118B1 (pt) 2022-01-04
KR20180018650A (ko) 2018-02-21
JP6857621B2 (ja) 2021-04-14
WO2016204951A1 (en) 2016-12-22
CN107771197B (zh) 2020-12-01
BR112017026118A2 (es) 2018-08-21
KR102537800B1 (ko) 2023-05-31
CA2989418A1 (en) 2016-12-22
EP3310852A1 (en) 2018-04-25
US20180215899A1 (en) 2018-08-02
JP2018525454A (ja) 2018-09-06
CN107771197A (zh) 2018-03-06
US10093788B2 (en) 2018-10-09
CA2989418C (en) 2023-09-12

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