MX2017011022A - Proceso para preparar dimetacrilato de isosorbida. - Google Patents

Proceso para preparar dimetacrilato de isosorbida.

Info

Publication number
MX2017011022A
MX2017011022A MX2017011022A MX2017011022A MX2017011022A MX 2017011022 A MX2017011022 A MX 2017011022A MX 2017011022 A MX2017011022 A MX 2017011022A MX 2017011022 A MX2017011022 A MX 2017011022A MX 2017011022 A MX2017011022 A MX 2017011022A
Authority
MX
Mexico
Prior art keywords
isosorbide
meth
alkyl
steps
entrainer
Prior art date
Application number
MX2017011022A
Other languages
English (en)
Inventor
Misske Andrea
Fleckenstein Christoph
Kaller Martin
Fleischhaker Friederike
Stengel Ulrik
Blanchot Mathieu
Nair Ritesh
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2017011022A publication Critical patent/MX2017011022A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/22—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system
    • C07C35/23—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system with hydroxy on a condensed ring system having two rings
    • C07C35/24—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system with hydroxy on a condensed ring system having two rings the condensed ring system containing five carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C61/16—Unsaturated compounds
    • C07C61/20—Unsaturated compounds having a carboxyl group bound to a five-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/10—Esters
    • C08F22/12—Esters of phenols or saturated alcohols
    • C08F22/20—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
    • C09K8/426—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells for plugging
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
    • C09K8/44—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing organic binders only

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La invención se refiere a un proceso para preparar dimetacrilato de isosorbida por transesterificación de (met)acrilato de alquilo con isosorbida, que comprende las siguientes etapas: (i) la reacción de (met)acrilato de alquilo con isosorbida en presencia de un catalizador que comprende titanio (IV) o zirconio (IV) y un estabilizante en presencia de un agente azeotrópico que forma un azeátropo con el alcohol ligado en el (met)acrilato de alquilo, (ii) la destilación continua del azeótropo de agente azeotrópico y alcohol, en donde las etapas (i) y (ii) se llevan a cabo simultáneamente hasta que la isosorbida se haya convertido esencialmente por completo, (iii) la adición de agua a la mezcla de producto que comprende (met)acrilato de isosorbida y se obtiene en las etapas (i) y (ii) y la remoción del hidrolizado del catalizador que comprende titanio (IV) o zirconio (IV), (iv) la destilación de (met)acrilato de alquilo sin convertir y el agente azeotrópico de la mezcla de producto, y (v) la destilación de agua de la mezcla de producto, en donde la etapa (iv) también se puede llevar a cabo antes de la etapa (iii) y las etapas (iv) y (v) también se puede llevar a cabo en una etapa de destilación.
MX2017011022A 2015-02-26 2016-02-24 Proceso para preparar dimetacrilato de isosorbida. MX2017011022A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562120922P 2015-02-26 2015-02-26
PCT/EP2016/053858 WO2016135191A1 (de) 2015-02-26 2016-02-24 Verfahren zur herstellung von isosorbiddi(meth)acrylat

Publications (1)

Publication Number Publication Date
MX2017011022A true MX2017011022A (es) 2017-10-20

Family

ID=55436096

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017011022A MX2017011022A (es) 2015-02-26 2016-02-24 Proceso para preparar dimetacrilato de isosorbida.

Country Status (14)

Country Link
US (1) US10370383B2 (es)
EP (1) EP3262130B1 (es)
JP (1) JP6789231B6 (es)
KR (1) KR102572781B1 (es)
CN (1) CN107428771B (es)
AU (1) AU2016223466A1 (es)
BR (1) BR112017018072A2 (es)
CA (1) CA2976594A1 (es)
ES (1) ES2847651T3 (es)
MX (1) MX2017011022A (es)
MY (1) MY185533A (es)
RU (1) RU2703461C2 (es)
SG (1) SG11201706500SA (es)
WO (1) WO2016135191A1 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013066461A2 (en) 2011-08-10 2013-05-10 Palmese Giuseppe R Renewable bio-based (meth) acrylated monomers as vinyl ester cross-linkers
JP6762958B2 (ja) * 2015-04-03 2020-09-30 ヘンケル アイピー アンド ホールディング ゲゼルシャフト ミット ベシュレンクテル ハフツング 嫌気硬化性組成物
ES2917178T3 (es) 2015-07-09 2022-07-07 Basf Se Composiciones curables
WO2018098011A1 (en) * 2016-11-22 2018-05-31 Sadler Joshua Matthew Process to produce blended (meth)acrylate/vinyl ester resin cross-linkers
EP3573946B1 (de) 2017-01-27 2020-12-16 Basf Se Verfahren zur herstellung von (meth)acrylsäurenorbornylestern
EP3489241A1 (de) * 2017-11-22 2019-05-29 Basf Se Verfahren zur synthese von isosorbidmono- und di-(meth)acrylat
EP3489205A1 (de) * 2017-11-28 2019-05-29 HILTI Aktiengesellschaft Isosorbidderivate als reaktive zusätze in reaktivharzen und chemischen dübeln
WO2021164893A1 (en) * 2020-02-20 2021-08-26 The University Of The Basque Country Method for producing a removable pressure-sensitive adhesive (psa) and pressure-sensitive adhesive thus produced

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DE2317226C3 (de) 1973-04-06 1980-10-30 Deutsche Texaco Ag, 2000 Hamburg Verfahren zur Herstellung von höhermolekularen Alkylacrylaten bzw. -methacrylaten
US4602073A (en) * 1985-06-07 1986-07-22 National Starch And Chemical Corporation Adhesive compositions
US4777265A (en) * 1986-03-11 1988-10-11 Basf Aktiengesellschaft Preparation of acrylates and methacrylates
DE4131458A1 (de) * 1991-09-21 1993-03-25 Basf Ag Zweikomponentenklebmasse fuer die chemische befestigungstechnik
JP4217425B2 (ja) * 2001-07-06 2009-02-04 日本乳化剤株式会社 新規な高分子電解質及びリチウム二次電池
JP2006315960A (ja) * 2005-05-10 2006-11-24 Hitachi Chem Co Ltd トリシクロデカンジオールジ（メタ）アクリレート及びその製造方法
DE102005044250A1 (de) * 2005-09-15 2007-03-29 Röhm Gmbh Verfahren zur Herstellung von Methacrylaten mit reaktiven Doppelbindungen
EP2139878A2 (en) * 2007-02-20 2010-01-06 Basf Se High refractive index monomers, compositions and uses thereof
JP2011506517A (ja) * 2007-12-19 2011-03-03 エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツング （メタ）アクリレートの製造方法
DE102008040221A1 (de) * 2008-07-07 2010-01-14 Evonik Röhm Gmbh Verfahren zur Herstellung von (Meth)acrylsäureestern
JP5270510B2 (ja) * 2009-10-19 2013-08-21 第一工業製薬株式会社 環状（メタ）アクリレート化合物、その製造方法、及び樹脂組成物
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KR101860176B1 (ko) * 2012-01-23 2018-05-21 헨켈 아이피 앤드 홀딩 게엠베하 2-액형, 시아노아크릴레이트/자유 라디칼 경화성 접착제 시스템
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Also Published As

Publication number Publication date
JP6789231B6 (ja) 2020-12-16
US10370383B2 (en) 2019-08-06
EP3262130A1 (de) 2018-01-03
AU2016223466A1 (en) 2017-09-07
CA2976594A1 (en) 2016-09-01
KR20170124541A (ko) 2017-11-10
RU2017133283A (ru) 2019-03-27
KR102572781B1 (ko) 2023-08-31
MY185533A (en) 2021-05-19
CN107428771B (zh) 2020-06-12
WO2016135191A1 (de) 2016-09-01
SG11201706500SA (en) 2017-09-28
JP6789231B2 (ja) 2020-11-25
US20160251371A1 (en) 2016-09-01
JP2018511576A (ja) 2018-04-26
EP3262130B1 (de) 2020-10-28
RU2017133283A3 (es) 2019-03-27
CN107428771A (zh) 2017-12-01
ES2847651T3 (es) 2021-08-03
RU2703461C2 (ru) 2019-10-17
BR112017018072A2 (pt) 2018-04-10

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