MX2016007946A - Regioselectividad potenciada en acilacion de glicol. - Google Patents

Regioselectividad potenciada en acilacion de glicol.

Info

Publication number
MX2016007946A
MX2016007946A MX2016007946A MX2016007946A MX2016007946A MX 2016007946 A MX2016007946 A MX 2016007946A MX 2016007946 A MX2016007946 A MX 2016007946A MX 2016007946 A MX2016007946 A MX 2016007946A MX 2016007946 A MX2016007946 A MX 2016007946A
Authority
MX
Mexico
Prior art keywords
acid
regio
selectivity
isohexide
acylation
Prior art date
Application number
MX2016007946A
Other languages
English (en)
Inventor
Stensrud Kenneth
Hagberg Erik
M Rockafellow Erin
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2016007946A publication Critical patent/MX2016007946A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Se describe un método para acilación catalizada con ácido de una isohexida. El método implica una reacción de una isohexida y un exceso de ácido carboxílico, en presencia de un catalizador de ácido de Lewis o ácido de Brønsted. Uno o más de ácido de Lewis y/o ácido de Brønsted pueden efectuar alta conversión de isohexidas en los mono y diésteres de ácido 2-ethilhexanoico correspondientes con una regioselectividad superior pronunciada de exo-OH con respecto a endo-OH de la isohexida en el producto. Las especies de ácido catalíticas particulares incluyen cloruro de circonio (ZrC14) y ácido fosfónico (H3PO3), que manifiestan una razón de reactividad exo:endo de aproximadamente 5:1 y 4:1, respectivamente.
MX2016007946A 2013-12-19 2014-12-11 Regioselectividad potenciada en acilacion de glicol. MX2016007946A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361918144P 2013-12-19 2013-12-19
PCT/US2014/069698 WO2015094894A1 (en) 2013-12-19 2014-12-11 Enhanced regio-selectivity in glycol acylation

Publications (1)

Publication Number Publication Date
MX2016007946A true MX2016007946A (es) 2016-09-09

Family

ID=53403539

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016007946A MX2016007946A (es) 2013-12-19 2014-12-11 Regioselectividad potenciada en acilacion de glicol.

Country Status (9)

Country Link
US (1) US10023586B2 (es)
EP (1) EP3083636B1 (es)
JP (1) JP6457522B2 (es)
KR (1) KR102107272B1 (es)
CN (1) CN106061979B (es)
AU (1) AU2014366353B2 (es)
CA (1) CA2932296C (es)
MX (1) MX2016007946A (es)
WO (1) WO2015094894A1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015156846A1 (en) * 2014-04-10 2015-10-15 Archer Daniels Midland Company Dehydration of a sugar alcohol with mixed combination of acid catalysts

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3028873C2 (de) * 1980-07-30 1983-10-27 Boehringer Mannheim Gmbh, 6800 Mannheim Verfahren zur Herstellung von 1,4 zu 3,6-Dianhydro-D-glucit-5-nitrat (Isosorbid-5-nitrat)
DE3102947A1 (de) * 1981-01-29 1982-09-02 Heinrich Mack Nachf., 7918 Illertissen Verfahren zur herstellung von isosorbid-5-nitrat
US4690783A (en) * 1986-08-29 1987-09-01 Union Camp Corporation Method of preparing rosin ester from polyol with phosphorous acid catalyst
US6608167B1 (en) * 2002-03-26 2003-08-19 E. I. Du Pont De Nemours And Company Bis(2-hydroxyethyl isosorbide); preparation, polymers derived therefrom, and enduses thereby
DE10353934A1 (de) * 2003-11-18 2005-06-23 Sasol Germany Gmbh Verfahren zur Herstellung von Metallsalzen der Trifluormethansulfonsäure und deren Verwendung als Veresterungskatalysatoren
CN101535372A (zh) * 2006-09-15 2009-09-16 斯蒂茨丁荷兰聚合物学会 基于二失水己糖醇的聚酯的制备方法
EP2595148A3 (en) * 2006-12-27 2013-11-13 Electronics and Telecommunications Research Institute Apparatus for coding multi-object audio signals
US8367171B2 (en) * 2008-11-26 2013-02-05 Valspar Sourcing, Inc. Polymer having polycyclic groups and coating compositions thereof
CN102612557A (zh) * 2009-09-16 2012-07-25 巴斯夫欧洲公司 制备单酰基化多元醇的酶促催化方法
US8496917B2 (en) * 2009-11-13 2013-07-30 Sytheon Ltd Compositions and methods for improving skin appearance
EP2558543B1 (en) * 2010-04-16 2017-08-30 Valspar Sourcing, Inc. Coating compositions for packaging articles and methods of coating
EP2388262A1 (en) * 2010-05-20 2011-11-23 Stichting Dutch Polymer Institute New biobased chiral compounds
CN104447779A (zh) * 2010-07-30 2015-03-25 阿彻丹尼尔斯米德兰德公司 微波辅助的脱水糖衍生物羟甲基糠醛、乙酰丙酸、无水糖醇、及其醚的合成
US8507699B2 (en) * 2010-12-10 2013-08-13 Sabic Innovative Plastics Ip B.V. Bisphenol polymer structural units and method of making the same
AU2012228490B2 (en) * 2011-03-15 2015-05-14 Oce-Technologies B.V. Bio-based polyester latex
CN103747680B (zh) * 2011-08-04 2016-01-06 克拉里安特国际有限公司 包含异山梨醇单酯和异山梨醇二酯的组合物
KR101432636B1 (ko) * 2012-04-18 2014-08-22 한국화학연구원 숙신산 또는 말레인산 그룹을 함유하는 이소솔바이드 지방산 에스테르 화합물, 이의 제조방법 및 이를 포함하는 오일

Also Published As

Publication number Publication date
JP6457522B2 (ja) 2019-01-23
JP2017501988A (ja) 2017-01-19
CN106061979B (zh) 2018-09-28
CA2932296A1 (en) 2015-06-25
KR20160098488A (ko) 2016-08-18
EP3083636B1 (en) 2018-09-05
US10023586B2 (en) 2018-07-17
US20170002018A1 (en) 2017-01-05
KR102107272B1 (ko) 2020-05-06
BR112016014032A2 (pt) 2018-01-16
CN106061979A (zh) 2016-10-26
EP3083636A4 (en) 2017-05-10
AU2014366353B2 (en) 2018-09-20
CA2932296C (en) 2019-12-17
EP3083636A1 (en) 2016-10-26
WO2015094894A1 (en) 2015-06-25
AU2014366353A1 (en) 2016-06-16

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