MX2014010088A - Composiciones detergentes que comprenden polimeros de injerto que tienen distribuciones de polaridad amplias. - Google Patents
Composiciones detergentes que comprenden polimeros de injerto que tienen distribuciones de polaridad amplias.Info
- Publication number
- MX2014010088A MX2014010088A MX2014010088A MX2014010088A MX2014010088A MX 2014010088 A MX2014010088 A MX 2014010088A MX 2014010088 A MX2014010088 A MX 2014010088A MX 2014010088 A MX2014010088 A MX 2014010088A MX 2014010088 A MX2014010088 A MX 2014010088A
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- Mexico
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Links
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
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- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 150000003681 vanadium Chemical class 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3788—Graft polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Graft Or Block Polymers (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261608900P | 2012-03-09 | 2012-03-09 | |
| PCT/US2013/029781 WO2013134601A1 (en) | 2012-03-09 | 2013-03-08 | Detergent compositions comprising graft polymers having broad polarity distributions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2014010088A true MX2014010088A (es) | 2014-09-16 |
Family
ID=47901433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014010088A MX2014010088A (es) | 2012-03-09 | 2013-03-08 | Composiciones detergentes que comprenden polimeros de injerto que tienen distribuciones de polaridad amplias. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8859484B2 (enExample) |
| EP (1) | EP2823029A1 (enExample) |
| JP (1) | JP2015518059A (enExample) |
| CN (1) | CN104160009A (enExample) |
| AR (1) | AR091800A1 (enExample) |
| CA (1) | CA2865507A1 (enExample) |
| IN (1) | IN2014DN06969A (enExample) |
| MX (1) | MX2014010088A (enExample) |
| RU (1) | RU2014133350A (enExample) |
| WO (1) | WO2013134601A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016004615A1 (en) | 2014-07-11 | 2016-01-14 | The Procter & Gamble Company | Structured particles comprising amphiphilic graft copolymer, and granular laundry detergent comprising thereof |
| EP2980198A1 (en) * | 2014-07-31 | 2016-02-03 | The Procter and Gamble Company | Composition comprising amphiphilic graft polymer |
| EP2980197A1 (en) * | 2014-07-31 | 2016-02-03 | The Procter and Gamble Company | Liquid laundry detergent composition |
| WO2019008016A1 (en) * | 2017-07-04 | 2019-01-10 | Atotech Deutschland Gmbh | CLEANING SOLUTION COMPRISING A MIXTURE OF NONIONIC SURFACTANTS OF POLYOXYALKYLENE FOR THE CLEANING OF METALLIC SURFACES |
| US11326129B2 (en) | 2018-06-26 | 2022-05-10 | The Procter & Gamble Company | Fabric care compositions that include a graft copolymer and related methods |
| CN111103378A (zh) * | 2019-11-25 | 2020-05-05 | 上海师范大学 | 一种阴离子类表面活性剂的色谱检测方法 |
| US11186805B2 (en) | 2019-12-20 | 2021-11-30 | The Procter & Gamble Company | Particulate fabric care composition |
| EP4134421B1 (en) * | 2021-08-12 | 2025-05-21 | The Procter & Gamble Company | Detergent composition comprising detersive surfactant and graft polymer |
| ES3033638T3 (en) | 2021-08-12 | 2025-08-06 | Procter & Gamble | Detergent composition comprising detersive surfactant and biodegradable graft polymers |
| WO2023048245A1 (ja) * | 2021-09-24 | 2023-03-30 | 積水化学工業株式会社 | 塩素化塩化ビニル系樹脂、成形用樹脂組成物及び成形体 |
| JP7474350B2 (ja) * | 2021-09-24 | 2024-04-24 | 積水化学工業株式会社 | 塩素化塩化ビニル系樹脂、成形用樹脂組成物及び成形体 |
| WO2024011345A1 (en) | 2022-07-11 | 2024-01-18 | The Procter & Gamble Company | Laundry detergent composition containing graft copolymer and benefit agent |
Family Cites Families (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1222944A (fr) | 1958-04-15 | 1960-06-14 | Hoechst Ag | Polymères greffés et leur procédé de préparation |
| FR2436213A1 (fr) | 1978-09-13 | 1980-04-11 | Oreal | Composition de traitement des matieres fibreuses a base de polymeres cationiques et anioniques |
| DE3536530A1 (de) | 1985-10-12 | 1987-04-23 | Basf Ag | Verwendung von pfropfcopolymerisaten aus polyalkylenoxiden und vinylacetat als vergrauungsinhibitoren beim waschen und nachbehandeln von synthesefasern enthaltendem textilgut |
| DE3711318A1 (de) | 1987-04-03 | 1988-10-20 | Basf Ag | Verwendung von pfropfpolymerisaten auf basis von polyalkylenoxiden als vergrauungsinhibitoren beim waschen und nachbehandeln von synthesefasern enthaltendem textilgut |
| DE3711298A1 (de) | 1987-04-03 | 1988-10-13 | Basf Ag | Verwendung von propfpolymerisaten auf basis von polyalkylenoxiden als vergrauungsinhibitoren beim waschen und nachbehandeln von synthesefasern enthaltendem textilgut |
| DE3711319A1 (de) | 1987-04-03 | 1988-10-20 | Basf Ag | Verwendung von pfropfpolymerisaten auf basis von polyalkylenoxiden als vergrauungsinhibitoren beim waschen und nachbehandeln von synthesefasern enthaltendem textilgut |
| GB8821034D0 (en) | 1988-09-07 | 1988-10-05 | Unilever Plc | Detergent compositions |
| GB8821035D0 (en) | 1988-09-07 | 1988-10-05 | Unilever Plc | Detergent compositions |
| GB8821032D0 (en) | 1988-09-07 | 1988-10-05 | Unilever Plc | Detergent compositions |
| US5049302A (en) | 1988-10-06 | 1991-09-17 | Basf Corporation | Stable liquid detergent compositions with enchanced clay soil detergency and anti-redeposition properties |
| US5082585A (en) | 1989-02-02 | 1992-01-21 | Lever Brothers Company, Division Of Conopco, Inc. | Enzymatic liquid detergent compositions containing nonionic copolymeric stabilizing agents for included lipolytic enzymes |
| US4908150A (en) | 1989-02-02 | 1990-03-13 | Lever Brothers Company | Stabilized lipolytic enzyme-containing liquid detergent composition |
| CA2029631A1 (en) | 1989-11-22 | 1991-05-23 | Kathleen A. Hughes | Graft polymers as biodegradable detergent additives |
| GB9300311D0 (en) | 1993-01-08 | 1993-03-03 | Unilever Plc | Detergent powders and process for preparing them |
| GB9403155D0 (en) * | 1994-02-18 | 1994-04-06 | Unilever Plc | Detergent compositions |
| US5733856A (en) | 1994-04-08 | 1998-03-31 | Basf Corporation | Detergency boosting polymer blends as additives for laundry formulations |
| DE4424818A1 (de) | 1994-07-14 | 1996-01-18 | Basf Ag | Niederviskose Mischungen aus amphiphilen nicht-ionischen Pfropfcopolymeren und viskositätserniedrigenden Zusätzen |
| DE69618507T2 (de) | 1995-02-03 | 2002-08-08 | Nippon Shokubai Co. Ltd., Osaka | Wasserlösliches polymer, verfahren zu dessen herstellung und detergentienzusammensetzung die dieses wasserlösliches polymer enthalten |
| GB2304726A (en) | 1995-09-04 | 1997-03-26 | Unilever Plc | Granular adjuncts containing soil release polymers, and particulate detergent compositions containing them |
| US5576282A (en) | 1995-09-11 | 1996-11-19 | The Procter & Gamble Company | Color-safe bleach boosters, compositions and laundry methods employing same |
| EP0786514B1 (en) | 1996-01-25 | 2004-07-14 | Unilever N.V. | Stick pretreatment compositions |
| MA24137A1 (fr) | 1996-04-16 | 1997-12-31 | Procter & Gamble | Fabrication d'agents de surface ramifies . |
| CA2269604A1 (en) | 1996-10-25 | 1998-05-07 | The Procter & Gamble Company | Cleansing products |
| US5756444A (en) | 1996-11-01 | 1998-05-26 | The Procter & Gamble Company | Granular laundry detergent compositions which are substantially free of phosphate and aluminosilicate builders |
| MA24733A1 (fr) | 1997-03-07 | 1999-10-01 | Procter & Gamble | Compositions de blanchiment contenant un catalyseur metallique de blanchiment et activateurs de blanchiment et/ou acides percarboxyliques organiques |
| DE69814641T2 (de) | 1997-07-21 | 2004-03-25 | The Procter & Gamble Company, Cincinnati | Verbessertes alkylarylsulfonattensid |
| AU8124598A (en) | 1997-07-31 | 1999-02-22 | Procter & Gamble Company, The | Wet-like cleaning articles |
| DE19814739A1 (de) | 1998-04-02 | 1999-10-07 | Basf Ag | Verwendung von Polyalkylenoxid-haltigen Pfropfpolymerisaten als Solubilisatoren |
| US6315835B1 (en) | 2000-04-27 | 2001-11-13 | Basf Corporation | Anti-spotting and anti-filming hard surface cleaning formulations and methods |
| DE10041220A1 (de) | 2000-08-22 | 2002-03-07 | Basf Ag | Hautkosmetische Formulierungen |
| GB0030669D0 (en) | 2000-12-15 | 2001-01-31 | Unilever Plc | Detergent compositions |
| GB0030671D0 (en) | 2000-12-15 | 2001-01-31 | Unilever Plc | Detergent compositions |
| EP1537198B2 (en) | 2002-09-12 | 2011-11-16 | The Procter & Gamble Company | Polymer systems and cleaning compositions comprising same |
| DE10245858A1 (de) | 2002-09-30 | 2004-04-08 | Basf Ag | Verwendung von Polyetherblöcken enthaltenden Pfropfpolymerisaten zur Oberflächenveredelung von Papier |
| AU2003277486B2 (en) | 2002-11-04 | 2007-11-15 | Unilever Plc | Laundry detergent composition |
| DE10347043A1 (de) | 2003-10-07 | 2005-05-25 | Henkel Kgaa | Erhöhung der Wasseraufnahmefähigkeit von Textilien |
| CA2605446C (en) | 2005-05-31 | 2011-09-13 | The Procter & Gamble Company | Detergent composition |
| MX2007015066A (es) | 2005-05-31 | 2008-01-24 | Procter & Gamble | Composiciones detergentes que contienen polimeros y uso de estas. |
| DE102006055473B4 (de) | 2005-12-21 | 2019-05-16 | Basf Se | Verfahren zur Herstellung von Pfropfcopolymeren auf Basis von Polyethern |
| US20080015135A1 (en) | 2006-05-05 | 2008-01-17 | De Buzzaccarini Francesco | Compact fluid laundry detergent composition |
| DE602007007940D1 (de) * | 2006-05-31 | 2010-09-02 | Procter & Gamble | Reinigungsmittel mit amphiphilen pfropfpolymeren auf basis von polyalkylenoxiden und vinylestern |
| US7465701B2 (en) * | 2006-05-31 | 2008-12-16 | The Procter & Gamble Company | Detergent composition |
| EP2014755B1 (en) * | 2007-05-29 | 2012-03-21 | The Procter & Gamble Company | Method of cleaning dishware |
| BRPI0813289A2 (pt) * | 2007-06-29 | 2014-12-30 | Procter & Gamble | Composições detergentes para lavagem de roupas que compreendem polímeros de enxerto antifílicos à base de óxidos de poliaquileno e ésteres vinílicos. |
| JP5366980B2 (ja) | 2008-02-13 | 2013-12-11 | ビーエーエスエフ ソシエタス・ヨーロピア | 被覆されたポリオキシメチレン |
| CN101515640B (zh) | 2008-02-22 | 2011-04-20 | 比亚迪股份有限公司 | 一种负极和包括该负极的锂离子二次电池 |
| KR101614173B1 (ko) | 2008-05-02 | 2016-04-20 | 바스프 에스이 | 라디칼 중합에 의한 중합체의 연속 제조를 위한 방법 및 장치 |
| EP2496611B1 (de) | 2009-11-04 | 2016-03-23 | Basf Se | Verfahren zur herstellung von wässrigen polyacrylsäurelösungen |
-
2013
- 2013-03-08 IN IN6969DEN2014 patent/IN2014DN06969A/en unknown
- 2013-03-08 US US13/789,700 patent/US8859484B2/en not_active Expired - Fee Related
- 2013-03-08 WO PCT/US2013/029781 patent/WO2013134601A1/en not_active Ceased
- 2013-03-08 EP EP13710756.1A patent/EP2823029A1/en not_active Ceased
- 2013-03-08 CN CN201380012765.0A patent/CN104160009A/zh active Pending
- 2013-03-08 CA CA2865507A patent/CA2865507A1/en not_active Abandoned
- 2013-03-08 MX MX2014010088A patent/MX2014010088A/es unknown
- 2013-03-08 JP JP2014560141A patent/JP2015518059A/ja not_active Withdrawn
- 2013-03-08 RU RU2014133350A patent/RU2014133350A/ru unknown
- 2013-03-11 AR ARP130100767A patent/AR091800A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN104160009A (zh) | 2014-11-19 |
| AR091800A1 (es) | 2015-03-04 |
| JP2015518059A (ja) | 2015-06-25 |
| EP2823029A1 (en) | 2015-01-14 |
| RU2014133350A (ru) | 2016-03-10 |
| US20130252874A1 (en) | 2013-09-26 |
| US8859484B2 (en) | 2014-10-14 |
| IN2014DN06969A (enExample) | 2015-04-10 |
| WO2013134601A1 (en) | 2013-09-12 |
| CA2865507A1 (en) | 2013-09-12 |
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