MX2013004646A - Copolimeros en bloque elastomericos con una arquitectura molecular en forma de estrella, la arquitectura molecular en forma de estrella teniendo la estrella al menos dos brazos diferentes. - Google Patents
Copolimeros en bloque elastomericos con una arquitectura molecular en forma de estrella, la arquitectura molecular en forma de estrella teniendo la estrella al menos dos brazos diferentes.Info
- Publication number
- MX2013004646A MX2013004646A MX2013004646A MX2013004646A MX2013004646A MX 2013004646 A MX2013004646 A MX 2013004646A MX 2013004646 A MX2013004646 A MX 2013004646A MX 2013004646 A MX2013004646 A MX 2013004646A MX 2013004646 A MX2013004646 A MX 2013004646A
- Authority
- MX
- Mexico
- Prior art keywords
- star
- elastomeric block
- molecular architecture
- shaped molecular
- block copolymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/04—Azo-compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
- C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/30—Applications used for thermoforming
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C08L2312/08—Crosslinking by silane
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
La invención se refiere a los copolímeros en bloque elastoméricos con una arquitectura molecular en forma de estrella, la arquitectura molecular en forma de estrella teniendo la estrella al menos dos brazos diferentes. Al menos un brazo de la estrella está compuesto de al menos un bloque A el cual tiene unidades de al menos un monómero vinil aromático, siendo las unidades incorporadas por polimerización, y las cuales forman una fase dura; como una opción, al menos un bloque B que tiene uno o más monómeros dienos diferentes y que forma una primera fase elastomérica (blanda); y al menos un bloque elastomérico B/A que tiene unidades de al menos un monómero vinil aromático así como al menos un dieno, siendo las unidades incorporadas por polimerización, y las cuales forman una fase blanda. La invención también se refiere a un método para producir los copolímeros en bloque elastoméricos de acuerdo con la invención, al uso de los copolímeros en bloque elastoméricos de acuerdo con la invención para producir piezas moldeadas, como pueden ser películas, espumas, partes termoformadas y piezas moldeadas por inyección; tubos o perfiles extruidos, como puede ser una capa adhesiva en películas multicapa; como un sellado; como un promotor de la adhesión o componente termoplástico en compuestos de madera-plástico; como un componente adhesivo de fusión en caliente; y para la modificación por choque de termoplásticos o elastómeros o para la promoción de la compatibilidad, y a las películas, espumas, piezas termoformadas, piezas moldeadas por inyección, tubos o perfiles extruidos fabricados de al menos un copolímero en bloque eleastomérico de acuerdo con al invención.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10189117 | 2010-10-27 | ||
PCT/EP2011/068768 WO2012055919A1 (de) | 2010-10-27 | 2011-10-26 | Gummielastische blockcopolymerisate mit einer sternförmigen molekularen architektur, wobei die sternförmige molekulare architektur mindestens zwei unterschiedliche sternäste aufweist |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2013004646A true MX2013004646A (es) | 2013-07-03 |
MX362662B MX362662B (es) | 2019-01-31 |
Family
ID=44863050
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2013004646A MX362662B (es) | 2010-10-27 | 2011-10-26 | Copolímeros en bloque elastoméricos con una arquitectura molecular en forma de estrella, la arquitectura molecular en forma de estrella teniendo la estrella al menos dos brazos diferentes. |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP2632964B1 (es) |
JP (1) | JP6109070B2 (es) |
KR (1) | KR101934127B1 (es) |
CN (2) | CN107513142A (es) |
ES (1) | ES2544828T3 (es) |
MX (1) | MX362662B (es) |
WO (1) | WO2012055919A1 (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3105288B1 (en) | 2014-02-11 | 2020-04-08 | INEOS Styrolution Group GmbH | Blends of thermoplastic elastomers based on styrene (s-tpe) and polyolefins |
US10131779B2 (en) | 2014-09-03 | 2018-11-20 | Ineos Styrolution Group Gmbh | Blends of styrene-butadiene copolymers |
CN104960260A (zh) * | 2015-06-30 | 2015-10-07 | 怀宁县鑫源无纺布有限公司 | 一种弹性无纺布的制备方法 |
KR102273553B1 (ko) | 2016-04-21 | 2021-07-06 | 이네오스 스티롤루션 그룹 게엠베하 | 개선된 균열 및 화학적 내성을 갖는 abs 몰딩 조성물 및 그의 사용 |
US11124644B2 (en) * | 2016-09-01 | 2021-09-21 | University Of Florida Research Foundation, Inc. | Organic microgel system for 3D printing of silicone structures |
US11041070B2 (en) | 2016-12-23 | 2021-06-22 | Ineos Styroluction Group Gmbh | Polymer compositions for shrink-wrap films |
US11879059B2 (en) * | 2017-02-21 | 2024-01-23 | Ineos Styrolution Group Gmbh | Intrinsically non-blocking shrink sleeve material |
KR102462291B1 (ko) | 2017-03-16 | 2022-11-03 | 이네오스 스티롤루션 그룹 게엠베하 | 매우 연질의 비점착성 및 투명 스티렌계 열가소성 엘라스토머 조성물 |
MX2019010368A (es) * | 2017-03-16 | 2020-01-30 | Ineos Styrolution Group Gmbh | Elastomeros termoplasticos estirenicos no pegajosos, suaves y transparentes. |
WO2018234222A1 (en) | 2017-06-19 | 2018-12-27 | Ineos Styrolution Group Gmbh | AROMATIC / DIENE-BLOCKING VINYL COPOLYMERS HAVING GOOD ORGANOLEPTIC PROPERTIES |
CN111989366B (zh) | 2018-02-16 | 2023-08-29 | 英力士苯领集团股份公司 | 高耐热性abs模塑组合物 |
KR20220051210A (ko) | 2019-08-21 | 2022-04-26 | 이네오스 스티롤루션 그룹 게엠베하 | 높은 escr, 높은 색상 및 열 안정성 및 낮은 박리 경향을 갖는 시트 압출 및 열성형을 위한 abs 성형 조성물 |
CN114685929B (zh) * | 2020-12-29 | 2023-08-15 | 广东生益科技股份有限公司 | 一种热固性树脂组合物及其应用 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
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BE638995A (es) | 1962-07-16 | |||
US3507934A (en) | 1965-12-20 | 1970-04-21 | Shell Oil Co | Block copolymer compositions having improved processability |
NL133447C (es) | 1966-11-07 | |||
US3639517A (en) | 1969-09-22 | 1972-02-01 | Phillips Petroleum Co | Resinous branched block copolymers |
US4122134A (en) | 1974-02-13 | 1978-10-24 | Sumitomo Chemical Company, Limited | Method for producing transparent block copolymer resin |
US3985830B1 (en) | 1974-07-15 | 1998-03-03 | Univ Akron | Star polymers and process for the preparation thereof |
DE2550226C2 (de) | 1975-11-08 | 1984-12-13 | Basf Ag, 6700 Ludwigshafen | Verzweigte Blockcopolymerisate und Verfahren zu ihrer Herstellung |
US4167545A (en) | 1975-11-08 | 1979-09-11 | Basf Aktiengesellschaft | Branched block copolymers and their manufacture |
US4091053A (en) | 1976-06-24 | 1978-05-23 | Phillips Petroleum Company | Coupled resinous diene copolymer with good integral hinge flex life and high hardness |
DE3738748A1 (de) * | 1987-11-14 | 1989-05-24 | Basf Ag | Verfahren zur diskontinuierlichen herstellung von unsymmetrisch aufgebauten, sternfoermig verzweigten blockcopolymerisaten und ihre verwendung |
CA2028410C (en) * | 1990-01-02 | 1996-09-17 | William J. Trepka | Tapered block styrene/butadiene copolymers |
CA2134026C (en) * | 1993-11-15 | 1998-06-09 | William J. Trepka | Tapered block copolymers of monovinylarenes and conjugated dienes |
DE4420952A1 (de) * | 1994-06-17 | 1995-12-21 | Basf Ag | Thermoplastisches Elastomer |
MX9505304A (es) * | 1994-12-23 | 1997-01-31 | Shell Int Research | Proceso para la fabricacion de copolimeros de bloque, radiales, asimetricos, de varios brazos. |
DE19615533A1 (de) * | 1996-04-19 | 1997-10-23 | Basf Ag | Thermoplastische Formmasse |
DE19638254A1 (de) | 1996-09-19 | 1998-03-26 | Basf Ag | Thermoplastische Elastomere |
DE19914075A1 (de) * | 1999-03-27 | 2000-09-28 | Basf Ag | Glasklares, schlagzähes Polystyrol auf Basis von Styrol-Butadien-Blockcopolymeren |
US20030181584A1 (en) | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
EP2382092B1 (de) | 2008-12-23 | 2019-04-17 | INEOS Styrolution Europe GmbH | Phasenseparierende blockcopolymere aus unverträglichen hartblöcken und formmassen mit hoher steifigkeit |
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2011
- 2011-10-26 ES ES11775799.7T patent/ES2544828T3/es active Active
- 2011-10-26 WO PCT/EP2011/068768 patent/WO2012055919A1/de active Application Filing
- 2011-10-26 CN CN201710735567.7A patent/CN107513142A/zh active Pending
- 2011-10-26 MX MX2013004646A patent/MX362662B/es active IP Right Grant
- 2011-10-26 KR KR1020137013296A patent/KR101934127B1/ko active IP Right Grant
- 2011-10-26 EP EP20110775799 patent/EP2632964B1/de not_active Not-in-force
- 2011-10-26 CN CN201180052186XA patent/CN103221441A/zh active Pending
- 2011-10-26 JP JP2013535418A patent/JP6109070B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN107513142A (zh) | 2017-12-26 |
KR101934127B1 (ko) | 2018-12-31 |
CN103221441A (zh) | 2013-07-24 |
EP2632964B1 (de) | 2015-05-06 |
EP2632964A1 (de) | 2013-09-04 |
KR20140001916A (ko) | 2014-01-07 |
JP2013540873A (ja) | 2013-11-07 |
ES2544828T3 (es) | 2015-09-04 |
JP6109070B2 (ja) | 2017-04-05 |
MX362662B (es) | 2019-01-31 |
WO2012055919A1 (de) | 2012-05-03 |
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