MX2011011643A - Procedimiento para preparar poliolesteres con grupos terminales oh secundarios. - Google Patents

Procedimiento para preparar poliolesteres con grupos terminales oh secundarios.

Info

Publication number
MX2011011643A
MX2011011643A MX2011011643A MX2011011643A MX2011011643A MX 2011011643 A MX2011011643 A MX 2011011643A MX 2011011643 A MX2011011643 A MX 2011011643A MX 2011011643 A MX2011011643 A MX 2011011643A MX 2011011643 A MX2011011643 A MX 2011011643A
Authority
MX
Mexico
Prior art keywords
terminal groups
polyester
groups
carboxyl
polyester polyols
Prior art date
Application number
MX2011011643A
Other languages
English (en)
Inventor
Joerg Hofmann
Klaus Lorenz
Bert Klesczewski
Erika Bauer
Hartmut Nefzger
Original Assignee
Bayer Materialscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Materialscience Ag filed Critical Bayer Materialscience Ag
Publication of MX2011011643A publication Critical patent/MX2011011643A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91Polymers modified by chemical after-treatment
    • C08G63/914Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/18Catalysts containing secondary or tertiary amines or salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4261Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups prepared by oxyalkylation of polyesterpolyols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66Polyesters containing oxygen in the form of ether groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/87Non-metals or inter-compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

La invención se refiere a un procedimiento para preparar poliolésteres con grupos terminales hidroxilo secundarios, que comprende la etapa de reacción de un poliéster que comprende grupos terminales carboxilo con un epóxido de fórmula general (1) en la que R1 representa un resto alquilo o un resto arilo y se realiza la reacción en presencia de un catalizador, que por molécula comprende al menos un átomo de nitrógeno. El procedimiento se caracteriza por que el poliéster que comprende grupos terminales carboxilo presenta un índice de acidez de = 25 mg de KOH/g a = 400 mg de KOH/g y un índice de hidroxilo de = 5 mg de KOH/g y por que se prepara el poliéster que comprende grupos terminales carboxilo usándose por mol de grupos hidroxilo de un alcohol de = 1,03 mola = 1,90 mol de grupos carboxilo o equivalentes de grupos carboxilo de un componente ácido. Los poliolésteres obtenidos que comprenden grupos terminales hidroxilo secundarios pueden usarse para preparar polímeros de poliuretano.
MX2011011643A 2009-05-06 2010-05-04 Procedimiento para preparar poliolesteres con grupos terminales oh secundarios. MX2011011643A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09006162 2009-05-06
PCT/EP2010/002697 WO2010127823A2 (de) 2009-05-06 2010-05-04 Verfahren zur herstellung von polyesterpolyolen mit sekundären oh-endgruppen

Publications (1)

Publication Number Publication Date
MX2011011643A true MX2011011643A (es) 2011-11-28

Family

ID=41010271

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2011011643A MX2011011643A (es) 2009-05-06 2010-05-04 Procedimiento para preparar poliolesteres con grupos terminales oh secundarios.

Country Status (13)

Country Link
US (1) US9193822B2 (es)
EP (1) EP2427510B1 (es)
JP (1) JP5536877B2 (es)
KR (1) KR20120027217A (es)
CN (1) CN102414239B (es)
BR (1) BRPI1013969A2 (es)
CA (1) CA2760855A1 (es)
ES (1) ES2439320T3 (es)
MX (1) MX2011011643A (es)
PL (1) PL2427510T3 (es)
RU (1) RU2546123C2 (es)
SG (1) SG175433A1 (es)
WO (1) WO2010127823A2 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2465890A1 (de) * 2010-12-17 2012-06-20 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen mit primären Hydroxyl-Endgruppen und daraus hergestellte Polyurethanpolymere
WO2013024107A1 (de) 2011-08-16 2013-02-21 Bayer Intellectual Property Gmbh Verfahren zur herstellung eines polyurethan-polyisocyanurat-hartschaums
WO2013024108A1 (de) 2011-08-16 2013-02-21 Bayer Intellectual Property Gmbh Verfahren zur herstellung eines polyurethan-polyisocyanurat-hartschaums
JP6179361B2 (ja) * 2012-11-29 2017-08-16 東レ株式会社 末端変性ポリマーを含む熱可塑性樹脂
DE202013004202U1 (de) * 2013-04-26 2014-08-05 Bayer Materialscience Ag Geschäumter Formkörper
CN104262596B (zh) * 2014-09-23 2016-08-31 四川东材科技集团股份有限公司 一种高官能度聚酯多元醇及其制备方法
AR102914A1 (es) * 2014-11-12 2017-04-05 Dow Global Technologies Llc Adhesivo de laminación por embutición en frío de bisfenol-a-libre
US11046866B2 (en) 2016-08-24 2021-06-29 Basf Coatings Gmbh Method for producing a coating system with an aqueous basecoat
EP3515957B1 (en) 2016-09-25 2023-01-11 PTT Global Chemical Public Company Limited Biorenewable high performance polyester polyols
CN109054002A (zh) * 2018-09-21 2018-12-21 吉林化工学院 线性聚酯多元醇的制备与应用
CN111961196A (zh) * 2019-05-20 2020-11-20 湖州欧美化学有限公司 包含仲羟基端基的聚合物多元醇的制备方法
US11932761B2 (en) * 2021-02-08 2024-03-19 Covestro Llc HFCO-containing isocyanate-reactive compositions, polyurethane foams formed therefrom, and composite articles that include such foams

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE663892A (es) * 1964-05-13
US4144395A (en) 1977-12-05 1979-03-13 Basf Wyandotte Corporation Process for the preparation of polyether-ester polyols
EP0010804A1 (en) 1978-11-03 1980-05-14 THE PROCTER & GAMBLE COMPANY Method for producing highly aromatized coffee products
JPS56116718A (en) * 1980-02-19 1981-09-12 Nippon Synthetic Chem Ind Co Ltd:The Preparation of carboxyl group-type polyester resin for powder paint
EP0086309B1 (en) * 1981-12-28 1986-07-30 Ford Motor Company Limited Coating compositions and polyhydroxy oligomer precursor therefor
US4647595A (en) * 1985-10-17 1987-03-03 Asahi Glass Company, Ltd. Process for producing a urethane-modified polyisocyanurate foam
DE3613875A1 (de) 1986-04-24 1987-10-29 Basf Ag Verfahren zur herstellung von polyester-polyolen
DE3621039A1 (de) * 1986-06-24 1988-01-07 Bayer Ag Verfahren zur herstellung von hydroxylgruppen aufweisenden oligoestern und deren verwendung
DE19623065A1 (de) * 1996-06-10 1997-12-11 Bayer Ag Verfahren zur Herstellung von Polyurethan Hartschaumstoffen mit geringer Wärmeleitfähigkeit
DE102004060800A1 (de) * 2004-12-17 2007-05-03 Bayer Materialscience Ag Kunststoffformteile aus gegebenenfalls gefüllten Polyurethanen und deren Verwendung

Also Published As

Publication number Publication date
US9193822B2 (en) 2015-11-24
EP2427510A2 (de) 2012-03-14
EP2427510B1 (de) 2013-11-06
KR20120027217A (ko) 2012-03-21
WO2010127823A2 (de) 2010-11-11
JP2012526161A (ja) 2012-10-25
CA2760855A1 (en) 2010-11-11
CN102414239A (zh) 2012-04-11
SG175433A1 (en) 2011-12-29
CN102414239B (zh) 2014-01-29
WO2010127823A3 (de) 2011-10-27
RU2011149350A (ru) 2013-06-20
RU2546123C2 (ru) 2015-04-10
US20120116114A1 (en) 2012-05-10
JP5536877B2 (ja) 2014-07-02
BRPI1013969A2 (pt) 2016-04-05
ES2439320T3 (es) 2014-01-22
PL2427510T3 (pl) 2014-04-30

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