MX2010006785A - Lubricante sintetico universal, metodo y producto por proceso para reemplazar la perdida de lubricacion de azufre cuando se utilizan combustibles diesel bajos en azufre. - Google Patents
Lubricante sintetico universal, metodo y producto por proceso para reemplazar la perdida de lubricacion de azufre cuando se utilizan combustibles diesel bajos en azufre.Info
- Publication number
- MX2010006785A MX2010006785A MX2010006785A MX2010006785A MX2010006785A MX 2010006785 A MX2010006785 A MX 2010006785A MX 2010006785 A MX2010006785 A MX 2010006785A MX 2010006785 A MX2010006785 A MX 2010006785A MX 2010006785 A MX2010006785 A MX 2010006785A
- Authority
- MX
- Mexico
- Prior art keywords
- mixture
- low
- producing
- diesel fuel
- olefins
- Prior art date
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- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
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- C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
- C10M111/04—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
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- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/08—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic sulfur-, selenium- or tellurium-containing compound
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/1608—Well defined compounds, e.g. hexane, benzene
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- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10N2030/34—Fragrance or deodorizing properties
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- C10N2040/16—Dielectric; Insulating oil or insulators
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- C10N2070/00—Specific manufacturing methods for lubricant compositions
Abstract
LUBRICANTE SINTETICO UNIVERSAL, METODO Y PRODUCTO POR PROCESO PARA REEMPLAZAR LA PERDIDA DE LUBRICACION DE AZUFRE CUANDO SE UTILIZAN COMBUSTIBLES DIESEL BAJOS EN AZUFRE.
Description
CANTE SINTETICO UNIVERSAL, METODO Y PRODUCTO POR REEMPLAZAR LA PERDIDA DE LUBRICACION DE AZUFRE C UTILIZAN COMBUSTIBLES DIESEL BAJOS EN AZUFRE.
e la Invención.
campo de la invención se refiere a la más reciente tecnología e bricante sintético de reemplazo para adaptarlo a la dramática re o de azufre en combustibles Ultra-Bajos y Bajos en azufre.
ntes de la Invención.
través de los años, los combustibles diesel han estado sujeto les para tener el factor de lubricación (azufre) dramáticament . El azufre ha jugado un rol importante en la lubricación de piez eí sistema de lubricantes de las máquinas diesel. El Combustible está limitado a 15 ppm de azufre, fue propuesto por la Agencia l de los Estados Unidos (EPA) como un nuevo estándar para el n el combustible diesel de carretera, vendido en los Estados 15 de 2006, excepto para California y Alaska rural. California ha r ptiembre 1 de 2006 y Alaska rural hará la transición de todo el o en Azufre cerca del 2010. El nuevo reglamento aplica a todo aditivos para combustible diesel y combustibles destilados m de la Invención
describe en la presente un lubricante de combustible die o para lubricación de azufre en combustibles Diesel Ultra-Bajo l proceso para producir dicho lubricante y el método para usar dic nte comprende alfa-olefinas; solventes aromáticos de bajo olor; ásico seleccionado del grupo de aceite que consiste de A ados altamente básicos y Aceites Básicos HT Severamente Hidro 0 otros ingredientes. También se describe un método para e.
ion Detallada
invención se refiere al uso de un lubricante de combusti o para Diesel de Ultra-Bajo y Bajo Azufre, que puede ser ibies, para reemplazar la dramática pérdida de lubricación, con alto contenido de azufre en combustibles diesel. El pr n todas las formas de máquinas o turbinas diesel en donde el nte integral de lubricación interna. Esta invención ha sido enví ¡ón confidencial a la EPA y ha recibido el registro bajo el Códi ones (40CFR 79.23) en Octubre de 2007.
s aditivos de combustible diesel previos se basaban en l oradas cuya longitud de cadena de carbono es de 12 a 24 con so de cloro de 21 a 70%, un HCI de 4 a 10 ppm y peso molécul 0 y peso de cloro (2) de 20 a 70% con gravedad específica ntígrados de 1.050 a 1.50 y un porcentaje en peso JQD de HCI 60 máximo. El uso primario para el ingrediente anterior, es para lubricante, compuestos aditivos para lubricante, formulacione esión extrema y para compuestos de trabajo en metal. Adicion efinas o productos asociados reducen el desarrollo de algas en c edida que el envejecimiento o la humedad excesiva se acumula y mbustible a lo largo del tiempo mientras que se proporcion trema al sistema de combustible y a la cámara de explosión d to proporciona la carencia de lubricación en diesel ultra bajo en a lventes Aromáticos Bajos en Olor: Este es un ingrediente prima lvente altamente refinado, de baja toxicidad y bajo olor, ideal rnices, recubrimientos grado alimenticio, adhesivos, elgazadores, agroquímicos, pesticidas domésticos, aceites d pecialmente productos químicos. El porcentaje de aromáticos es C-A-G04), un punto de inflamación de 20 a 80 grados centígrad ) y una densidad a 30 grados centígrados (más/menos) de 0 STM D-4052 .
itivos de presión extrema. Estos se agregan a ia lubricación de esel ultra-bajos en azufre.
redientes
ezcla Reductora de Potencializador de cetano, Detergente, Punt de Cera: De acuerdo con esta invención, esta es una mezcla qu itrato de 2-etihexilo con porcentaje sugerido de 10 a 30 % en pe 247-96-7, que es el ingrediente primario de esta mezcla. Nafta rcentaje sugerido de 50 a 70% en peso y CAS 64742-94-5. rcentaje sugerido de 5 a 7 % y CAS No. 91-20-3. Trimetil rcentaje sugerido de 1 a 7 % en peso con un CAS de 25551-13- compuestos cuando se mezclan juntos, limpia y mantiene l cendido del motor, incrementando las Unidades Térmicas mbustible y reduce el concentrado de los cristales de cer mbustible.
lfonatos Sintéticos de Calcio: Un sulfonato sintético de calcio co 0 a 600, cuyo propósito primario es para formulaciones de aditiv trema ofreciendo protección contra la corrosión, dispersantes y d itivos solubles en aceite para metales ferrosos y no ferrosos c so de calcio de 10.00 a 20.00 %, un número básico total, mg KO
- alicíclico saturado con un máximo de 40 %. El punto de inflamaci 40 grados centígrados, punto de anilina de 50 a 80 grados nsidad de vapor de 3.5 a 6.0 (de aire de 1 ) y viscosidad (cp ntígrados) 0.70 a 1.75. Como un solvente de limpieza, limpia ntro del sistema de combustible.
lorantes activados por solvente: Estos son comúnmente ntificar usos de grados o designaciones de combustibles y lubri n producidos en forma tanto en polvo como en líquido y, cuando el producto, son estables y dejan un color identificable en el prod presores del Punto de Fluidez o Depresores del Punto de Turbid ados para reducir aglomeraciones o concentraciones de cristale mpuestos de parafina tales como lubricantes y combustible diesel formado de Isómeros: También referidos como un Solvente, Tol etilbenceno y Fenilmetano con una fórmula química de C7Hi8 (C S No. 108-88-3, un peso molecular de 90.00 a 95.00 g/mol y pecífica de 0.800 a 0.900 (de agua de 1). El producto qu rocarburo aromático que es ampliamente usado como materia pr como un solvente para limpiar los sistemas de combustible, tención y la cámara de combustión del motor,
lefinas: 5 a 30 % en peso y preferiblemente 7.0 a 25 % en mente 9.0 a 18 % en peso. El más preferible es 11.0 % en peso, ntes Aromáticos de Bajo Olor: 3.0 a 27 % en peso y preferibleme so y más preferiblemente 7.0 a 18 % en peso. El mas preferido
s Altamente Básicos Hidro-lsomerizados y Aceites HT Básicos ccionados: 0.50 a 15 porciento en peso y preferiblemente 0.75 a eferiblemente 2.0 a 8.0 % en peso. El mas preferible es 5.0 % en la reductora de Potencializador de Cetano, Detergente, Punto de 3 a 0.25 % en peso y preferiblemente 0.05 a 0.20 % en mente 0.09 a 0.17 % en peso. El mas preferible es el 0.13 % en p atos Sintéticos de Calcio: 0.05 a 0.25 % en peso, preferiblement o y más preferiblemente 0.10 a 0.18 % en peso. El mas preferibl
itus Minerales de Bajo Punto de Inflamación: 15 a 50 % mente 20 a 45 % en peso y más preferiblemente 25 - 39 % en es el 35 % en peso.
antes Activados por Solvente: 0.002 a 0.005 % en peso y pr 0.004 % en peso y más preferiblemente 0.027 a 0.035 % en es el 0.003 % en peso.
ocidad del agitador y la temperatura dictará la cantidad de tiemp la mezcla. El intervalo de tiempo de mezclado puede variar de 4 ura ideal para cada componente es entre 22 a 30 grados centígra eal. Aún cuando esta es una mezcla, una mezcla secundaria par cializador de Cetano, Detergente y Punto de Turbidez, puede ser ador pequeño adjunto de alta velocidad, y luego agregada
s sulfonatos sintéticos de calcio son empleados (haciendo notar l tados Unidos que podría restringir su uso en los Estados Unidos) que el sulfonato sintético de calcio sea mezclado con los Espíri roporción de aproximadamente 50/50 en la etapa inicial de la una mezcla terciaria. (Los Espíritus Minerales usados serán je preferido establecido anteriormente). Esta mezcla terciaría, o s solos, en ausencia de los sulfonatos sintéticos de calcio, junto c ientes, pueden ser luego agregados a la mezcla principal y el agi sta que los componentes parecen estar completamente mez nsistente,
Mezclado Preferido
cuencia del proceso involucra una serie de tanques de mezclad e el producto puede ser pesado y luego bombeado a través d ientes de Prueba
todo reciente para probar el desgaste con combustibles diesel Contenido de Azufre es el Equipo de Oscilación de Alta Frecue 975. El combustible se somete a una prueba de desgaste y debe e cicatriz de desgaste de no más de 520 micrones.
ue todos los combustibles diesel probados excedieron el desga o máximo, unos 20 a 30 micrones, la adición de la invención agre o en azufre (2.0 onzas por cada 10 galones de combustible dies riz de desgaste que fue reducida por aproximadamente un 28% e desgaste permitida de aproximadamente 375 micrones.
pruebas experimentales han demostrado la habilidad de la inven ste que está siendo actualmente experimentado por equipo die e se han desarrollado estándares ASTM de prueba adicionale o en azufre, se llevaran a cabo pruebas experimentales adicion .
uando solo se han ilustrado y descrito ciertas características pr , muchas modificaciones, cambios y sustituciones se les oc en el arte. Deberá, por lo tanto, entenderse que las reivindicad intención de cubrir todas esas modificaciones y cambios que cae o espíritu de la invención.
Claims (1)
- REIVINDICACIONES, n aditivo sintético universal para combustible diesel, para mejorar prende: fa-olefinas; lventes aromáticos bajos en olor; y menos un aceite básico seleccionado del grupo de aceites nsiste de aceites altamente básicos hidro-isomerizados y aceite veramente hidro-fraccionados, en donde: chas alfa-olefinas comprenden de 5 a 30 % en peso de las misma chos solventes aromáticos de bajo olor comprenden de 3 a 27 so de los mismos; cho por lo menos un aceite básico comprende de 0.5 a 15 por c l mismo; y chos porcentajes en peso están especificados en proporción relati aditivo sintético universal para combustible diesel, de la reivindi de además: a mezcla reducto ra de potencializador de cetano, detergen aditivo sintético universal para combustible diesel, de la reivindic reductora de potencializador de cetano, detergente, punto aditivo sintético universal para combustible diesel, de la reivindi de además: lfonatos de calcio. aditivo sintético universal para combustible diesel, de la reivindi de además: lorantes activados por solvente; menos un depresor seleccionado del grupo que consiste de d nto de fluidez y depresores de punto de turbidez; ormado de isómero; y metil-cetonas. aditivo sintético universal para combustible diesel, de ta reivindi de además: lorantes activados por solvente; menos un depresor seleccionado del grupo que consiste de d nto de fluidez y depresores de punto de turbidez; formado de isómero; y metil-cetonas. aditivo sintético universal para combustible diesel, de la reivin chas alfa-olefinas comprenden de 5 a 30 % en peso de las misma chos solventes aromáticos de bajo olor comprenden de 3 a 27 so de los mismos; cho por lo menos un aceite básico comprende de 0.5 a 15 por c l mismo; cha mezcla reductora de potencializador de cetano, detergen rbidez, comprende de 0.03 a 0.25 por ciento en peso del mismo; chos espíritus minerales de bajo punto de encendido, comprend r ciento en peso de los mismos; y hos porcentajes en peso están especificados en proporción relati ? aditivo sintético universal para combustible diesel, de la reivin chas alfa-olefinas comprenden de 5 a 30 % en peso de las misma chos solventes aromáticos de bajo olor comprenden de 3 a 27 so de los mismos; cho por lo menos un aceite básico comprende de 0.5 a 15 por c l mismo; y cha mezcla reductora de potencializador de cetano, detergen rbidez; comprende de 0.03 a 0.25 por ciento en peso del mismo; hos espíritus minerales de bajo punto de encendido, comprend r ciento en peso de los mismos; y cha mezcla reductora de potencializador de cetano, detergen rbidez; comprende de 0.03 a 0.25 por ciento en peso de los mism chos espíritus minerales de bajo punto de encendido, comprend r ciento en peso de los mismos; hos colorantes activados por solvente comprenden 0.002 a O.O peso de los mismos; cho al menos un depresor comprende de 0.50 a 2 por ciento ismo; cho reformado de isómero comprende de 0.50 a 5.0 por ciento del chas dimetil cetonas comprenden de 10 a 50 por ciento en peso d hos porcentajes en peso están especificados en proporción relati aditivo sintético universal para combustible diesel, de la reivin chas alfa-olefinas comprenden de 5 a 30 por ciento en peso de las chos solventes aromáticos de bajo olor comprenden de 3.0 a 27 so de los mismos; cho por lo menos un aceite básico comprende de 0.5 a 15 por ci l mismo; cha mezcla reductora de potencializador de cetano, detergen has dimetil-cetonas comprenden de 10 a 50 por ciento en peso d aditivo sintético universal para combustible diesel, de la rei o por un método que comprende: ezclar dichas alfa-olefinas, dichos solventes aromáticos de bajo o ños un aceite básico hasta que la mezcla sea una amalgamacio apariencia alguna de separación, produciendo de esta maner imaría; y regar dicho nitrato de 2-etilhexilo a dicha mezcla primaria. aditivo sintético universal para combustible diesel, de la rei o por un método que comprende: ezclar dichas alfa-olefinas, dichos solventes aromáticos de bajo o enos un aceite básico, hasta que la mezcla sea una amalgamacio apariencia alguna de separación, produciendo de esta maner imaría; ezclar separadamente dicho nitrato de 2-etilhexilo; dicha nafta ho trimetoxibenceno, produciendo de esta manera una mezcla se regar dicha mezcla secundaria a dicha mezcla primaria. aditivo sintético universal para combustible diesel, de la rei o por un método que comprende: ezclar dichas alfa-olefinas, dichos solventes aromáticos de bajo o zclar dichas alfa-olefinas, dichos solventes aromáticos de bajo o enos un aceite básico hasta que la mezcla sea una amalgamació apariencia alguna de separación, produciendo de esta maner imaria; zclar separadamente dicha mezcla reductora de potencializad tergente, punto de turbidez, produciendo de esta manera cundaria; regar dicha mezcla secundaria a la mezcla primaria; ezclar separadamente dichos su If o natos de calcio y dichos espíri bajo punto de encendido, produciendo de esta manera una mezc regar dicha mezcla terciaria a dicha mezcla primaria y secundaria aditivo sintético universal para combustible diesel, de la rei o por un método que comprende: ezclar dichas alfa-olefinas, dichos solventes aromáticos de bajo o enos un aceite básico hasta que la mezcla sea una amalgamació apariencia alguna de separación, produciendo de esta maner imaria; ezclar separadamente dicha mezcla reductora de potencializad tergente, punto de turbidez, produciendo de esta manera cundaria; n apariencia alguna de separación, produciendo de esta maner imaría; ezclar separadamente dicha mezcla reductora de potencializad tergente, punto de turbidez, produciendo de esta manera cundaria; regar dicha mezcla secundaria a dicha mezcla primaria; ezclar separadamente dichos sulfonatos de calcio y dichos espíri bajo punto de encendido, produciendo de esta manera una mez regar dicha mezcla terciaria a dicha mezcla primaria y secundaria regar dichos colorantes activados por solvente; dicho al menos cho reformado de isómero; y dichas dimetil-cetonas, a dichas me cundaria y terciaria. n método para producir un aditivo sintético universal para comb prende: mezclar alfa-olefinas, solventes aromáticos de bajo olor, y aceite básico hasta que la mezcla sea una amalgamación c apariencia alguna de separación, produciendo de esta mane primaria; y agregar nitrato de 2-etilhexilo a dicha mezcla primaria, método de la reivindicación 20, que comprende además: l método de la reivindicación 21 , que comprende además: mezclar separadamente sulfonatos de calcio y espíritus miner punto de encendido, produciendo de esta manera una mezcla agregar dicha mezcla terciaria a dicha mezcla primaria y secun l método de la reivindicación 22, que comprende además: agregar colorantes activados por solvente; al menos u seleccionado del grupo que consiste de depresores de punto depresores de punto de turbidez; reformado de isómeros cetonas, a dicha mezcla de mezclas primaria y secundaria, espíritus minerales de bajo punto de encendido. l método de la reivindicación 23, que comprende además: agregar colorantes activados por solvente; al menos u seleccionado del grupo que consiste de depresores de punto depresores de punto de turbidez; reformado de isómeros cetonas, a dichas mezclas primaria, secundaria y terciaria.
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PCT/US2007/088252 WO2009078882A1 (en) | 2007-12-19 | 2007-12-19 | Universal synthetic lubricant, method and product-by-process to replace the lost sulfur lubrication when using low-sulfur diesel fuels |
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US7931704B2 (en) * | 2005-01-18 | 2011-04-26 | Bestline International Research | Universal synthetic gasoline fuel conditioner additive, method and product-by-process |
US8268022B2 (en) * | 2005-01-18 | 2012-09-18 | Bestline International Research, Inc. | Universal synthetic gasoline fuel conditioner additive, method and product-by-process |
US8022020B2 (en) * | 2005-01-18 | 2011-09-20 | Bestline International Research, Inc. | Universal synthetic penetrating lubricant, method and product-by-process |
US7745382B2 (en) | 2005-01-18 | 2010-06-29 | Bestline International Research Inc. | Synthetic lubricant additive with micro lubrication technology to be used with a broad range of synthetic or miner host lubricants from automotive, trucking, marine, heavy industry to turbines including, gas, jet and steam |
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