MX2009003288A - Pieza de trabajo con revestimiento duro. - Google Patents

Pieza de trabajo con revestimiento duro.

Info

Publication number
MX2009003288A
MX2009003288A MX2009003288A MX2009003288A MX2009003288A MX 2009003288 A MX2009003288 A MX 2009003288A MX 2009003288 A MX2009003288 A MX 2009003288A MX 2009003288 A MX2009003288 A MX 2009003288A MX 2009003288 A MX2009003288 A MX 2009003288A
Authority
MX
Mexico
Prior art keywords
workpiece
hard coating
hlo
cno
cra
Prior art date
Application number
MX2009003288A
Other languages
English (en)
Spanish (es)
Inventor
Wolfgang Kalss
Frederic Fontaine
Markus Lechthaler
Original Assignee
Oerlikon Trading Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oerlikon Trading Ag filed Critical Oerlikon Trading Ag
Publication of MX2009003288A publication Critical patent/MX2009003288A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0641—Nitrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/123—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24—Vacuum evaporation
    • C23C14/32—Vacuum evaporation by explosion; by evaporation and subsequent ionisation of the vapours, e.g. ion-plating
    • C23C14/325—Electric arc evaporation
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34—Sputtering
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • C23C28/044—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material coatings specially adapted for cutting tools or wear applications
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/40—Coatings including alternating layers following a pattern, a periodic or defined repetition
    • C23C28/42—Coatings including alternating layers following a pattern, a periodic or defined repetition characterized by the composition of the alternating layers
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T83/00—Cutting
    • Y10T83/04—Processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Physical Vapour Deposition (AREA)
  • Drilling Tools (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
MX2009003288A 2006-09-26 2007-08-30 Pieza de trabajo con revestimiento duro. MX2009003288A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US82694306P 2006-09-26 2006-09-26
US90955907P 2007-04-02 2007-04-02
PCT/EP2007/059070 WO2008037556A2 (en) 2006-09-26 2007-08-30 Workpiece with hard coating

Publications (1)

Publication Number Publication Date
MX2009003288A true MX2009003288A (es) 2009-06-30

Family

ID=39230563

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009003288A MX2009003288A (es) 2006-09-26 2007-08-30 Pieza de trabajo con revestimiento duro.

Country Status (17)

Country Link
US (2) US8211554B2 (enExample)
EP (1) EP2069553B1 (enExample)
JP (1) JP5593069B2 (enExample)
KR (1) KR101432847B1 (enExample)
CN (1) CN104805436A (enExample)
AU (1) AU2007302162B2 (enExample)
BR (1) BRPI0717566B1 (enExample)
CA (1) CA2662537C (enExample)
ES (1) ES2945897T3 (enExample)
IL (1) IL197787A (enExample)
MX (1) MX2009003288A (enExample)
MY (1) MY149446A (enExample)
NZ (1) NZ575279A (enExample)
PL (1) PL2069553T3 (enExample)
RU (1) RU2469128C2 (enExample)
TW (1) TWI422710B (enExample)
WO (1) WO2008037556A2 (enExample)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010003902A1 (en) * 2008-07-09 2010-01-14 Oerlikon Trading Ag, Truebbach Coating system, coated workpiece and method for manufacturing the same
EP2443267B1 (en) * 2009-06-18 2020-01-08 Oerlikon Surface Solutions AG, Pfäffikon Protective coating, a coated member having a protective coating as well as method for producing a protective coating
US8277958B2 (en) 2009-10-02 2012-10-02 Kennametal Inc. Aluminum titanium nitride coating and method of making same
JP4753144B2 (ja) * 2009-12-21 2011-08-24 住友電工ハードメタル株式会社 表面被覆切削工具
JP4753143B2 (ja) * 2009-12-21 2011-08-24 住友電工ハードメタル株式会社 表面被覆切削工具
CN102725434B (zh) 2010-02-04 2014-10-29 欧瑞康贸易股份公司(特吕巴赫) 具有AL-Cr-B-N/Ti-Al-N多层覆层的切削工具
US8409702B2 (en) 2011-02-07 2013-04-02 Kennametal Inc. Cubic aluminum titanium nitride coating and method of making same
US9447488B2 (en) * 2011-09-30 2016-09-20 Oerlikon Surface Solutions Ag, Pfaffikon Aluminum titanium nitride coating with adapted morphology for enhanced wear resistance in machining operations and method thereof
EP2839051B1 (en) * 2012-04-16 2018-09-26 Oerlikon Surface Solutions AG, Pfäffikon High performance tools exhibiting reduced crater wear in particular by dry machining operations
US9103036B2 (en) 2013-03-15 2015-08-11 Kennametal Inc. Hard coatings comprising cubic phase forming compositions
EP2988898B1 (en) * 2013-04-22 2019-01-16 The Gleason Works Skiving of cylindrical gears
EP3006601B1 (en) * 2013-05-30 2019-12-11 Hitachi Metals, Ltd. Method for manufacturing mold for cold working use
JP5663814B2 (ja) 2013-07-03 2015-02-04 住友電工ハードメタル株式会社 表面被覆窒化硼素焼結体工具
US9168664B2 (en) 2013-08-16 2015-10-27 Kennametal Inc. Low stress hard coatings and applications thereof
US9896767B2 (en) 2013-08-16 2018-02-20 Kennametal Inc Low stress hard coatings and applications thereof
DE102013018867A1 (de) * 2013-11-12 2015-06-25 Oerlikon Trading Ag, Trübbach (Al,Cr,Ta)N-Beschichtung zur verbesserten Temperaturbeständigkeit
DE102013018007A1 (de) * 2013-11-29 2015-06-03 Oerlikon Trading Ag, Trübbach Verfahren zur Verbesserung des Gegenkörperverschleisses im tribologischen Kontakt
EP3387164B1 (en) * 2015-12-07 2024-01-17 IHI Bernex AG Coated extrusion tool
CN108368601B (zh) * 2015-12-22 2020-10-30 山特维克知识产权股份有限公司 涂覆的切削工具和方法
CN109196137B (zh) 2016-06-02 2021-11-30 田中贵金属工业株式会社 金溅射靶
RU2639425C1 (ru) * 2016-12-20 2017-12-21 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Способ получения многослойного покрытия для режущего инструмента
US10570501B2 (en) 2017-05-31 2020-02-25 Kennametal Inc. Multilayer nitride hard coatings
JP6617942B2 (ja) * 2017-11-16 2019-12-11 三菱日立ツール株式会社 被覆切削工具およびその製造方法
CN112055632B (zh) * 2018-05-30 2023-06-30 株式会社Moldino 包覆切削工具及其制造方法
WO2020075191A1 (en) * 2018-10-12 2020-04-16 Tata Consultancy Services Limited Method and system for monitoring tool wear to estimate rul of tool in machining
CN113874143B (zh) 2019-05-09 2024-09-27 株式会社Moldino 包覆切削工具
US11731202B2 (en) 2021-04-19 2023-08-22 Kennametal Inc. Coating, method for coating, and coated cutting tool
JP7760424B2 (ja) * 2022-03-22 2025-10-27 株式会社神戸製鋼所 被覆部材
WO2024213666A1 (en) 2023-04-13 2024-10-17 Oerlikon Surface Solutions Ag, Pfäffikon Surface-coated cutting tool with alternating nanothick layers

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Publication number Priority date Publication date Assignee Title
SE520802C2 (sv) * 1997-11-06 2003-08-26 Sandvik Ab Skärverktyg belagt med aluminiumoxid och process för dess tillverkning
SE516622C2 (sv) * 2000-06-15 2002-02-05 Uddeholm Tooling Ab Stållegering, plastformningsverktyg och seghärdat ämne för plastformningsverktyg
ATE343659T1 (de) * 2000-12-28 2006-11-15 Kobe Steel Ltd Hartstoffschicht für schneidwerkzeuge
JP3971337B2 (ja) * 2003-04-30 2007-09-05 株式会社神戸製鋼所 α型結晶構造主体のアルミナ皮膜の製造方法、α型結晶構造主体のアルミナ皮膜で被覆された部材およびその製造方法
KR101047630B1 (ko) * 2003-04-28 2011-07-07 오를리콘 트레이딩 아크티엔게젤샤프트, 트뤼프바흐 Ａｌｃｒ-함유 경질 재료 층을 포함하는 공작물 및 제조방법
US7226670B2 (en) * 2003-04-28 2007-06-05 Oc Oerlikon Balzers Ag Work piece with a hard film of AlCr-containing material, and process for its production
MX2007000405A (es) * 2004-07-15 2007-06-25 Oc Oerlikon Balzers Ag Recubrimiento duro altamente resistente a la oxidacion para herramientas de corte.
JP2006082207A (ja) * 2004-09-17 2006-03-30 Sumitomo Electric Hardmetal Corp 表面被覆切削工具
JP5060714B2 (ja) * 2004-09-30 2012-10-31 株式会社神戸製鋼所 耐摩耗性および耐酸化性に優れた硬質皮膜、並びに該硬質皮膜形成用ターゲット
JP2006188736A (ja) * 2005-01-07 2006-07-20 Nissin Electric Co Ltd 耐摩耗性膜被覆物品
US7879443B2 (en) * 2005-02-10 2011-02-01 Oc Oerlikon Trading Ag, Truebbach High wear resistant triplex coating for cutting tools
JP4702520B2 (ja) 2005-02-14 2011-06-15 三菱マテリアル株式会社 高硬度鋼の高速切削加工で硬質被覆層がすぐれた耐摩耗性を発揮する表面被覆超硬合金製切削工具
US7348074B2 (en) * 2005-04-01 2008-03-25 Oc Oerlikon Balzers Ag Multilayer hard coating for tools
JP4672442B2 (ja) * 2005-05-31 2011-04-20 オーエスジー株式会社 硬質積層被膜、および硬質積層被膜被覆工具

Also Published As

Publication number Publication date
EP2069553B1 (en) 2023-03-08
US8329000B2 (en) 2012-12-11
US8211554B2 (en) 2012-07-03
RU2469128C2 (ru) 2012-12-10
CN104805436A (zh) 2015-07-29
NZ575279A (en) 2012-05-25
AU2007302162A1 (en) 2008-04-03
WO2008037556A3 (en) 2008-12-11
US20120234143A1 (en) 2012-09-20
CA2662537C (en) 2015-01-20
KR101432847B1 (ko) 2014-08-26
BRPI0717566A2 (pt) 2013-12-03
JP5593069B2 (ja) 2014-09-17
BRPI0717566B1 (pt) 2019-01-22
AU2007302162B2 (en) 2012-06-28
TW200831706A (en) 2008-08-01
MY149446A (en) 2013-08-30
ES2945897T3 (es) 2023-07-10
IL197787A (en) 2013-09-30
RU2009115694A (ru) 2010-11-10
TWI422710B (zh) 2014-01-11
KR20090063250A (ko) 2009-06-17
US20100263503A1 (en) 2010-10-21
CA2662537A1 (en) 2008-04-03
EP2069553A2 (en) 2009-06-17
IL197787A0 (en) 2009-12-24
JP2010504439A (ja) 2010-02-12
PL2069553T3 (pl) 2023-07-31
WO2008037556A2 (en) 2008-04-03

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