MX172040B - , "proceso para preparar alfa-olefinas lineales con el uso de productos de adicion de zirconio como catalizadores - Google Patents

, "proceso para preparar alfa-olefinas lineales con el uso de productos de adicion de zirconio como catalizadores

Info

Publication number
MX172040B
MX172040B MX011844A MX1184488A MX172040B MX 172040 B MX172040 B MX 172040B MX 011844 A MX011844 A MX 011844A MX 1184488 A MX1184488 A MX 1184488A MX 172040 B MX172040 B MX 172040B
Authority
MX
Mexico
Prior art keywords
olefins
linear alpha
zirconium
catalysts
component
Prior art date
Application number
MX011844A
Other languages
English (en)
Inventor
David Alexander Young
Larry Oliver Jones
Troy John Campione
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of MX172040B publication Critical patent/MX172040B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of titanium, zirconium or hafnium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un proceso para preparar alfa-olefinas esencialmente lineales de Mn 70 a aproximadamente 700 mediante la oligomerización de etileno en la presencia de un catalizador de dos componentes, homogeneo, en que el primer componente es un producto de adición de ZrC1aBrb, en que a+b 4 y a o b puede ser 0, 1, 2, 3 ó 4, con un compuesto orgánico seleccionado del grupo que consiste en esteres, cetonas, eteres, aminas, nitrilos, anhídridos, cloruros de ácidos, amidas o aldehidos y dicho compuesto orgánico tiene hasta 30 átomos de carbono y el segundo componente es un catalizador de metal de alquilo seleccionado del grupo que consiste en R2A1X, RA1X2, R3A12X3, R3A1 y R2Zn, en que R es alquilo de C1-C20 y X es Cl y Br.
MX011844A 1987-06-19 1988-06-10 , "proceso para preparar alfa-olefinas lineales con el uso de productos de adicion de zirconio como catalizadores MX172040B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US6366287A 1987-06-19 1987-06-19
US07/195,665 US4855525A (en) 1987-06-19 1988-05-18 Process for preparing linear alpha-olefins using zirconium adducts as catalysts

Publications (1)

Publication Number Publication Date
MX172040B true MX172040B (es) 1993-11-30

Family

ID=26743656

Family Applications (1)

Application Number Title Priority Date Filing Date
MX011844A MX172040B (es) 1987-06-19 1988-06-10 , "proceso para preparar alfa-olefinas lineales con el uso de productos de adicion de zirconio como catalizadores

Country Status (12)

Country Link
US (1) US4855525A (es)
EP (1) EP0295960B1 (es)
JP (1) JP2565546B2 (es)
CN (1) CN1015360B (es)
AR (1) AR245087A1 (es)
AT (1) ATE121063T1 (es)
AU (1) AU598676B2 (es)
CA (1) CA1307517C (es)
DE (1) DE3853556T2 (es)
ES (1) ES2070850T3 (es)
MX (1) MX172040B (es)
NZ (1) NZ224845A (es)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8918497D0 (en) * 1989-08-14 1989-09-20 Exxon Chemical Patents Inc Process for preparing linear alpha-olefins from ethylene
GB8929269D0 (en) * 1989-12-28 1990-02-28 Shell Int Research Process and catalyst composition for the preparation of linear alpha olefins
JP2538811B2 (ja) * 1990-10-19 1996-10-02 出光石油化学株式会社 線状α―オレフィンの製造方法
US5449850A (en) * 1991-03-12 1995-09-12 Exxon Chemical Patents Inc. Process for oligomerizing C3 and higher olefins using zirconium adducts as catalysts (CS-467)
FR2693455B1 (fr) * 1992-07-09 1994-09-30 Inst Francais Du Petrole Procédé de fabrication d'oléfines alpha légères par oligomérisation de l'éthylène.
US5523136A (en) * 1993-04-30 1996-06-04 Cypress Packaging Packaging film, packages and methods for using them
FR2748018B1 (fr) * 1996-04-26 1998-06-26 Inst Francais Du Petrole Procede ameliore de conversion de l'ethylene en olefines alpha legeres avec utilisation d'additifs a base de sels d'ammonium quaternaire
FR2759922B1 (fr) * 1997-02-25 1999-05-07 Inst Francais Du Petrole Composition catalytique amelioree pour la conversion de l'ethylene en olefines alpha legeres
US6930218B2 (en) * 2001-01-23 2005-08-16 Indian Petrochemicals Corporation Limited Process for the preparation of linear low molecular weight olefins by the oligomerization of ethylene
US7087686B2 (en) 2001-08-06 2006-08-08 Bp Chemicals Limited Chain growth reaction process
US8426535B2 (en) 2001-08-06 2013-04-23 Ineos Europe Limited Chain growth reaction process
DE10140859A1 (de) * 2001-08-21 2003-03-06 Bayer Ag Verfahren zur Herstellung von Isoolefincopolymeren
CN100338081C (zh) * 2004-10-29 2007-09-19 中国石油化工股份有限公司 用于烯烃齐聚的催化剂组分及其制备方法和催化剂
EP1748038A1 (en) * 2005-07-29 2007-01-31 Linde AG Method for preparing linear alpha-olefins
EP1749807A1 (en) * 2005-08-02 2007-02-07 Linde AG Method for producing linear alpha-olefins with improved product distribution
DE602005024134D1 (de) * 2005-08-31 2010-11-25 Saudi Basic Ind Corp Prozess zur Darstellung linearer Alpha-Olefine und ein Katalysator hierfür
JP5539229B2 (ja) * 2008-01-30 2014-07-02 リンデ アーゲー 直鎖状アルファオレフィンを調製する方法
FR2942796B1 (fr) * 2009-03-09 2011-05-27 Inst Francais Du Petrole Procede de conversion directe d'une charge comprenant des olefines a quatre et/ou cinq atomes de carbone pour la production de propylene
CN104926589A (zh) * 2010-03-26 2015-09-23 三菱化学株式会社 α-烯烃低聚物的制造方法
FR2995894B1 (fr) * 2012-09-21 2015-09-11 Axens Procede de production de butadiene-1,3 mettant en oeuvre l'oligomerisation de l'ethylene et la deshydrogenation des butenes obtenus
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
IN201921051272A (es) 2019-12-11 2022-01-06
CN114247476B (zh) * 2020-09-25 2023-05-26 北京化工大学 一种锆基催化体系及其用于催化乙烯齐聚制备线性α-烯烃的方法
US11667590B2 (en) 2021-05-26 2023-06-06 Chevron Phillips Chemical Company, Lp Ethylene oligomerization processes

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4442309A (en) * 1960-09-14 1984-04-10 Exxon Reserch And Engineering Co. Preparation of linear olefin products
US4486615A (en) * 1960-09-14 1984-12-04 Exxon Research & Engineering Co. Preparation of linear olefin products
US4396788A (en) * 1960-09-14 1983-08-02 Exxon Research And Engineering Co. Preparation of linear olefin products
DE1301528B (de) * 1965-04-27 1969-08-21 Mitsubishi Petrochemical Co Verfahren zur Herstellung von kristallinen Polymerisaten aus alpha-Olefinen und Styro
US4434312A (en) * 1978-03-02 1984-02-28 Exxon Research And Engineering Co. Preparation of linear olefin products
US4410750A (en) * 1981-12-14 1983-10-18 Exxon Research And Engineering Co. Preparation of linear olefin products
US4377720A (en) * 1981-12-14 1983-03-22 Exxon Research And Engineering Co. Preparation of linear olefin products
US4361714A (en) * 1981-12-14 1982-11-30 Exxon Research And Engineering Co. Preparation of linear olefin products
US4434313A (en) * 1981-12-14 1984-02-28 Exxon Research And Engineering Co. Preparation of linear olefin products
US4409409A (en) * 1982-06-10 1983-10-11 Exxon Research And Engineering Co. Two stage olefin wax process
JPS62430A (ja) * 1985-06-26 1987-01-06 Idemitsu Petrochem Co Ltd 線状α−オレフインの製造方法
DE3675385D1 (de) * 1986-04-17 1990-12-06 Idemitsu Petrochemical Co Verfahren zur herstellung von linearen alpha-olefinen.
CA1287067C (en) * 1988-02-15 1991-07-30 Yasushi Shiraki PRODUCTION OF LINEAR .alpha.-OLEFINS

Also Published As

Publication number Publication date
ATE121063T1 (de) 1995-04-15
US4855525A (en) 1989-08-08
CA1307517C (en) 1992-09-15
CN1015360B (zh) 1992-02-05
ES2070850T3 (es) 1995-06-16
AR245087A1 (es) 1993-12-30
NZ224845A (en) 1990-02-26
JP2565546B2 (ja) 1996-12-18
CN1031833A (zh) 1989-03-22
DE3853556D1 (de) 1995-05-18
DE3853556T2 (de) 1995-09-28
EP0295960A1 (en) 1988-12-21
EP0295960B1 (en) 1995-04-12
AU598676B2 (en) 1990-06-28
JPS6463532A (en) 1989-03-09
AU1697888A (en) 1988-12-22

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