DE3853556D1 - Homogener Zweikomponenten-Katalysator und Verfahren zur Herstellung linearer alpha-Olefine. - Google Patents

Homogener Zweikomponenten-Katalysator und Verfahren zur Herstellung linearer alpha-Olefine.

Info

Publication number
DE3853556D1
DE3853556D1 DE3853556T DE3853556T DE3853556D1 DE 3853556 D1 DE3853556 D1 DE 3853556D1 DE 3853556 T DE3853556 T DE 3853556T DE 3853556 T DE3853556 T DE 3853556T DE 3853556 D1 DE3853556 D1 DE 3853556D1
Authority
DE
Germany
Prior art keywords
olefins
homogeneous
production
linear alpha
component catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE3853556T
Other languages
English (en)
Other versions
DE3853556T2 (de
Inventor
David Alexander Young
Larry Oliver Jones
Troy John Campione
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of DE3853556D1 publication Critical patent/DE3853556D1/de
Application granted granted Critical
Publication of DE3853556T2 publication Critical patent/DE3853556T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/30Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122Metal aryl or alkyl compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20Olefin oligomerisation or telomerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48Zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06Halogens; Compounds thereof
    • C07C2527/125Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/38Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of titanium, zirconium or hafnium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE3853556T 1987-06-19 1988-06-17 Homogener Zweikomponenten-Katalysator und Verfahren zur Herstellung linearer alpha-Olefine. Expired - Fee Related DE3853556T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US6366287A 1987-06-19 1987-06-19
US07/195,665 US4855525A (en) 1987-06-19 1988-05-18 Process for preparing linear alpha-olefins using zirconium adducts as catalysts

Publications (2)

Publication Number Publication Date
DE3853556D1 true DE3853556D1 (de) 1995-05-18
DE3853556T2 DE3853556T2 (de) 1995-09-28

Family

ID=26743656

Family Applications (1)

Application Number Title Priority Date Filing Date
DE3853556T Expired - Fee Related DE3853556T2 (de) 1987-06-19 1988-06-17 Homogener Zweikomponenten-Katalysator und Verfahren zur Herstellung linearer alpha-Olefine.

Country Status (12)

Country Link
US (1) US4855525A (de)
EP (1) EP0295960B1 (de)
JP (1) JP2565546B2 (de)
CN (1) CN1015360B (de)
AR (1) AR245087A1 (de)
AT (1) ATE121063T1 (de)
AU (1) AU598676B2 (de)
CA (1) CA1307517C (de)
DE (1) DE3853556T2 (de)
ES (1) ES2070850T3 (de)
MX (1) MX172040B (de)
NZ (1) NZ224845A (de)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8918497D0 (en) * 1989-08-14 1989-09-20 Exxon Chemical Patents Inc Process for preparing linear alpha-olefins from ethylene
GB8929269D0 (en) * 1989-12-28 1990-02-28 Shell Int Research Process and catalyst composition for the preparation of linear alpha olefins
JP2538811B2 (ja) * 1990-10-19 1996-10-02 出光石油化学株式会社 線状α―オレフィンの製造方法
US5449850A (en) * 1991-03-12 1995-09-12 Exxon Chemical Patents Inc. Process for oligomerizing C3 and higher olefins using zirconium adducts as catalysts (CS-467)
FR2693455B1 (fr) * 1992-07-09 1994-09-30 Inst Francais Du Petrole Procédé de fabrication d'oléfines alpha légères par oligomérisation de l'éthylène.
US5523136A (en) * 1993-04-30 1996-06-04 Cypress Packaging Packaging film, packages and methods for using them
FR2748018B1 (fr) * 1996-04-26 1998-06-26 Inst Francais Du Petrole Procede ameliore de conversion de l'ethylene en olefines alpha legeres avec utilisation d'additifs a base de sels d'ammonium quaternaire
FR2759922B1 (fr) * 1997-02-25 1999-05-07 Inst Francais Du Petrole Composition catalytique amelioree pour la conversion de l'ethylene en olefines alpha legeres
US6930218B2 (en) * 2001-01-23 2005-08-16 Indian Petrochemicals Corporation Limited Process for the preparation of linear low molecular weight olefins by the oligomerization of ethylene
US7087686B2 (en) 2001-08-06 2006-08-08 Bp Chemicals Limited Chain growth reaction process
US8426535B2 (en) 2001-08-06 2013-04-23 Ineos Europe Limited Chain growth reaction process
DE10140859A1 (de) * 2001-08-21 2003-03-06 Bayer Ag Verfahren zur Herstellung von Isoolefincopolymeren
CN100338081C (zh) * 2004-10-29 2007-09-19 中国石油化工股份有限公司 用于烯烃齐聚的催化剂组分及其制备方法和催化剂
EP1748038A1 (de) * 2005-07-29 2007-01-31 Linde AG Verfahren zur Herstellung von linearen Alpha-Olefinen
EP1749807A1 (de) * 2005-08-02 2007-02-07 Linde AG Verfahren zur Herstellung linearer alpha Olefine mit verbesserter Prouktverteilung
DE602005024134D1 (de) * 2005-08-31 2010-11-25 Saudi Basic Ind Corp Prozess zur Darstellung linearer Alpha-Olefine und ein Katalysator hierfür
JP5539229B2 (ja) * 2008-01-30 2014-07-02 リンデ アーゲー 直鎖状アルファオレフィンを調製する方法
FR2942796B1 (fr) * 2009-03-09 2011-05-27 Inst Francais Du Petrole Procede de conversion directe d'une charge comprenant des olefines a quatre et/ou cinq atomes de carbone pour la production de propylene
CN104926589A (zh) * 2010-03-26 2015-09-23 三菱化学株式会社 α-烯烃低聚物的制造方法
FR2995894B1 (fr) * 2012-09-21 2015-09-11 Axens Procede de production de butadiene-1,3 mettant en oeuvre l'oligomerisation de l'ethylene et la deshydrogenation des butenes obtenus
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
IN201921051272A (de) 2019-12-11 2022-01-06
CN114247476B (zh) * 2020-09-25 2023-05-26 北京化工大学 一种锆基催化体系及其用于催化乙烯齐聚制备线性α-烯烃的方法
US11667590B2 (en) 2021-05-26 2023-06-06 Chevron Phillips Chemical Company, Lp Ethylene oligomerization processes

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4442309A (en) * 1960-09-14 1984-04-10 Exxon Reserch And Engineering Co. Preparation of linear olefin products
US4486615A (en) * 1960-09-14 1984-12-04 Exxon Research & Engineering Co. Preparation of linear olefin products
US4396788A (en) * 1960-09-14 1983-08-02 Exxon Research And Engineering Co. Preparation of linear olefin products
DE1301528B (de) * 1965-04-27 1969-08-21 Mitsubishi Petrochemical Co Verfahren zur Herstellung von kristallinen Polymerisaten aus alpha-Olefinen und Styro
US4434312A (en) * 1978-03-02 1984-02-28 Exxon Research And Engineering Co. Preparation of linear olefin products
US4410750A (en) * 1981-12-14 1983-10-18 Exxon Research And Engineering Co. Preparation of linear olefin products
US4377720A (en) * 1981-12-14 1983-03-22 Exxon Research And Engineering Co. Preparation of linear olefin products
US4361714A (en) * 1981-12-14 1982-11-30 Exxon Research And Engineering Co. Preparation of linear olefin products
US4434313A (en) * 1981-12-14 1984-02-28 Exxon Research And Engineering Co. Preparation of linear olefin products
US4409409A (en) * 1982-06-10 1983-10-11 Exxon Research And Engineering Co. Two stage olefin wax process
JPS62430A (ja) * 1985-06-26 1987-01-06 Idemitsu Petrochem Co Ltd 線状α−オレフインの製造方法
DE3675385D1 (de) * 1986-04-17 1990-12-06 Idemitsu Petrochemical Co Verfahren zur herstellung von linearen alpha-olefinen.
CA1287067C (en) * 1988-02-15 1991-07-30 Yasushi Shiraki PRODUCTION OF LINEAR .alpha.-OLEFINS

Also Published As

Publication number Publication date
ATE121063T1 (de) 1995-04-15
US4855525A (en) 1989-08-08
CA1307517C (en) 1992-09-15
CN1015360B (zh) 1992-02-05
ES2070850T3 (es) 1995-06-16
AR245087A1 (es) 1993-12-30
NZ224845A (en) 1990-02-26
JP2565546B2 (ja) 1996-12-18
CN1031833A (zh) 1989-03-22
DE3853556T2 (de) 1995-09-28
EP0295960A1 (de) 1988-12-21
EP0295960B1 (de) 1995-04-12
AU598676B2 (en) 1990-06-28
JPS6463532A (en) 1989-03-09
MX172040B (es) 1993-11-30
AU1697888A (en) 1988-12-22

Similar Documents

Publication Publication Date Title
DE3853556D1 (de) Homogener Zweikomponenten-Katalysator und Verfahren zur Herstellung linearer alpha-Olefine.
DE3765211D1 (de) Stabilisierter zirconocen/aluminoxan-katalysator und verfahren zur herstellung desselben.
DE68924623D1 (de) Polytetrafluorethylenfilament und Verfahren zur Herstellung derselben.
DE3784841D1 (de) Konfektprodukt und verfahren zur herstellung.
DE69101685D1 (de) Katalytische Eisen-Antimon-Molybdän-Zusammensetzung und Verfahren zur Herstellung derselben.
DE3884973D1 (de) Verfahren zur Herstellung von Avermectine-B und die verwendeten Kulturen.
DE3863170D1 (de) Mesophasenpech zur herstellung von kohlenstoffkoerpern und verfahren zur herstellung derselben.
DE3887625D1 (de) Verfahren zur Herstellung von 1,1,1-Trifluorodichlorethan und von 1,1,1,2-Tetrafluorchlorethan.
DE3778221D1 (de) Faserverschlingungen und verfahren zur herstellung derselben.
DE3883408D1 (de) Verfahren zur Herstellung von Avermectinen und die verwendeten Kulturen.
DE3680632D1 (de) Verfahren zur herstellung von kohlenstoffasern und diese kohlenstoffasern.
DE68921655D1 (de) Verfahren zur Herstellung von Mustern.
DE68917457D1 (de) Deodorant und verfahren zur herstellung.
DE3650008D1 (de) Katalytische Zusammensetzung und Verfahren zur Herstellung von Silanen.
DE3777189D1 (de) Modifizierte fasererzeugnisse und deren verfahren zur herstellung.
DE3851364D1 (de) Verfahren zur Herstellung von supraleitendem Material.
DE68923356D1 (de) Verfahren zur Herstellung von Graphitwhiskern.
DE68928048D1 (de) Verfahren zur Herstellung gebogener Graphitgegenstände
DE58906418D1 (de) Verfahren zur Herstellung von Festkörpern.
DE3887811D1 (de) Faseriger Schichtstoff und Verfahren zur Herstellung desselben.
DE69109347D1 (de) Verfahren zur Herstellung linearer alpha-Olefine.
DE58906122D1 (de) Verfahren zur Herstellung von Phenylethanolen.
DE69116286D1 (de) Katalytisches Verfahren zur Herstellung von Olefinen
DE3873635D1 (de) Reiskuchen und verfahren zur herstellung davon.
ATE89695T1 (de) Verfahren zur kontinuierlichen herstellung von quark und frischkaese.

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee