MX170572B - Mejoras a composicion recubridora a base de fluoropolimero para la adhesion directa al vidrio - Google Patents
Mejoras a composicion recubridora a base de fluoropolimero para la adhesion directa al vidrioInfo
- Publication number
- MX170572B MX170572B MX016960A MX1696089A MX170572B MX 170572 B MX170572 B MX 170572B MX 016960 A MX016960 A MX 016960A MX 1696089 A MX1696089 A MX 1696089A MX 170572 B MX170572 B MX 170572B
- Authority
- MX
- Mexico
- Prior art keywords
- fluoropolymer
- glass
- based coating
- carbon atoms
- formula
- Prior art date
Links
- 229920002313 fluoropolymer Polymers 0.000 title abstract 3
- 239000004811 fluoropolymer Substances 0.000 title abstract 3
- 239000011248 coating agent Substances 0.000 title 1
- 238000000576 coating method Methods 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- -1 glycidoxy, mercapto Chemical class 0.000 abstract 2
- 210000000056 organ Anatomy 0.000 abstract 2
- 150000001282 organosilanes Chemical class 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- 239000004593 Epoxy Substances 0.000 abstract 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 125000001475 halogen functional group Chemical group 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/4838—Halogenated polymers
- C04B41/4842—Fluorine-containing polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/4988—Organosilicium-organic copolymers, e.g. olefins with terminal silane groups
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
- C04B41/83—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
- C04B41/84—Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
Abstract
La presente invención se refiere a mejoras a composición recubridora, que comrpende un fluoropolímero, una resina auxiliar formadora de película, la cual es diferente del fluoropolímero y adaptada para raccionar con el grupo representado por F en el organosilano funcional de la fórmula I; y una cantidad efectiva para promover la adhesión del organosilano funcional representado por la fórmula I: en donde A representa un grupo organo conteniendo de desde 1 a 18 átomos de carbono; G representa un grupo organo conteniendo de desde 2 a 10 átomos de carbono; X representa un grupo hidrolizable; b es un entero de desde 0 a 2, y F representa amino, poliamino, epoxi, glicidoxi, mercapto, ciano, alil, vinilo, uretano, halo, isocianato, ureido, imidazolinil, acrilato o metacrilato.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/224,837 US4879345A (en) | 1988-07-27 | 1988-07-27 | Fluoropolymer based coating composition for adhesion direct to glass |
Publications (1)
Publication Number | Publication Date |
---|---|
MX170572B true MX170572B (es) | 1993-08-31 |
Family
ID=22842440
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX016960A MX170572B (es) | 1988-07-27 | 1989-07-27 | Mejoras a composicion recubridora a base de fluoropolimero para la adhesion directa al vidrio |
Country Status (10)
Country | Link |
---|---|
US (1) | US4879345A (es) |
EP (1) | EP0426735B1 (es) |
KR (1) | KR950013732B1 (es) |
AU (1) | AU631561B2 (es) |
BR (1) | BR8907584A (es) |
CA (1) | CA1335393C (es) |
DE (1) | DE68925582T2 (es) |
ES (1) | ES2020813A6 (es) |
MX (1) | MX170572B (es) |
WO (1) | WO1990001054A1 (es) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5688864A (en) * | 1990-04-03 | 1997-11-18 | Ppg Industries, Inc. | Autophobic water repellent surface treatment |
US5674967A (en) * | 1990-04-03 | 1997-10-07 | Ppg Industries, Inc. | Water repellent surface treatment with integrated primer |
US4983459A (en) * | 1990-04-03 | 1991-01-08 | Ppg Industries, Inc. | Chemically reacted glass surface |
US5707740A (en) * | 1990-04-03 | 1998-01-13 | Ppg Industries, Inc. | Water repellent surface treatment with acid activation |
US5328768A (en) * | 1990-04-03 | 1994-07-12 | Ppg Industries, Inc. | Durable water repellant glass surface |
US6025025A (en) * | 1990-04-03 | 2000-02-15 | Ppg Industries Ohio, Inc. | Water-repellent surface treatment |
US5932657A (en) * | 1990-06-21 | 1999-08-03 | Fina Research, S. A. | Powder primer of thermosetting binder and PVdF-compatible thermoplastic |
US5281444A (en) * | 1992-01-02 | 1994-01-25 | Ppg Industries, Inc. | Isophorone-free fluorocarbon coating composition |
JP3465191B2 (ja) * | 1992-10-15 | 2003-11-10 | ネイル マクマレン、ポール | 陶器体の処理法 |
US5439747A (en) * | 1993-03-19 | 1995-08-08 | Ppg Industries, Inc. | Anodized aluminum having protective coating |
US6037412A (en) * | 1994-07-21 | 2000-03-14 | Fina Research, S.A. | Preparing powder primer of thermoset binder and PVdF-compatible thermoplastic |
US5886125A (en) * | 1997-02-25 | 1999-03-23 | E. I. Du Pont De Nemours And Company | Crosslinkable copolymers comprising vinyl silane and vinyl esters of branched fatty acid |
US6096700A (en) * | 1998-08-24 | 2000-08-01 | Northrop Grumman Corporation | Environmental wipe solvent compositions and processes |
US6379448B1 (en) | 1999-04-16 | 2002-04-30 | Ict Coatings N.V. | Siliceous substrate with a silane layer and its manufacture |
MXPA01007110A (es) * | 1999-11-12 | 2002-03-20 | Atofina Chem Inc | Fluoropolimeros que contienen organo-silanos y metodos para hacer los mismos. |
AU2001233314A1 (en) * | 2000-02-02 | 2001-08-14 | Denovus L.L.C. | Polymeric blends and composites and laminates thereof |
US6774168B2 (en) * | 2001-11-21 | 2004-08-10 | Ppg Industries Ohio, Inc. | Adhesion promoting surface treatment or surface cleaner for metal substrates |
US6921787B2 (en) * | 2002-12-03 | 2005-07-26 | Akzo Nobel Non-Stick Coatings | Non-stick coating and method of forming same |
US20050103224A1 (en) * | 2003-11-19 | 2005-05-19 | Sanjay Patel | Polyamide-amic acid coating formulations and processes |
CN100487071C (zh) * | 2003-12-18 | 2009-05-13 | 日产化学工业株式会社 | 具有低折射率及斥水性的覆膜 |
US20070155897A1 (en) * | 2003-12-19 | 2007-07-05 | Nissan Chemical Industries Limited | Coating film having low refractive index and large water contact angle |
US7267865B2 (en) * | 2004-02-20 | 2007-09-11 | Saint-Gobain Performance Plastics Corporation | Draw resonant resistant multilayer films |
US7297391B2 (en) * | 2004-02-20 | 2007-11-20 | Saint-Gobain Performance Plastics Corporation | Draw resonance resistant multilayer films |
US7550040B2 (en) * | 2005-06-17 | 2009-06-23 | Nissan Chemical Industries, Ltd. | Coating fluid for forming film, and film thereof and film-forming process |
US7901778B2 (en) * | 2006-01-13 | 2011-03-08 | Saint-Gobain Performance Plastics Corporation | Weatherable multilayer film |
US20090087646A1 (en) * | 2007-10-01 | 2009-04-02 | Cf Supplies International Ltd. | Coated substrate, composition for treating a substrate and process of treatment |
CN104245863B (zh) | 2012-04-17 | 2018-08-14 | 阿科玛股份有限公司 | 水性氟聚合物玻璃涂料 |
WO2013158361A1 (en) | 2012-04-17 | 2013-10-24 | Arkema Inc. | Process for coating a glass substrate with an aqueous fluroropolymer coating |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2217375A1 (de) * | 1972-04-11 | 1973-11-08 | Sueddeutsche Kalkstickstoff | Polyvinylidenfluorid-loesungen und deren verwendung zur herstellung von ueberzuegen |
US4297447A (en) * | 1978-08-03 | 1981-10-27 | Elastoflon Inc. | Compound for coating containing fluorocarbonpolymer and method for its manufacture |
DE3030556A1 (de) * | 1979-08-14 | 1981-03-26 | Daikin Kogyo Co., Ltd., Osaka | Fluorelastomer-anstrich- und -ueberzugsmittel auf wasserbasis |
US4314004A (en) * | 1980-06-26 | 1982-02-02 | Ppg Industries, Inc. | Fluorocarbon resin coated substrates and methods of making |
GB2088385A (en) * | 1980-11-21 | 1982-06-09 | Bostik Ltd | Curable fluorocarbon polymer compositions |
US4379885A (en) * | 1980-12-29 | 1983-04-12 | Ppg Industries, Inc. | Fluorocarbon coating compositions |
JPS57135871A (en) * | 1981-02-13 | 1982-08-21 | Daikin Ind Ltd | Fluororubber-containing water paint and product coated therewith |
DE3135421A1 (de) * | 1981-09-07 | 1983-03-24 | Siemens AG, 1000 Berlin und 8000 München | Roentgenuntersuchungsgeraet |
US4450197A (en) * | 1982-04-14 | 1984-05-22 | Owens-Corning Fiberglas Corporation | Polytetrafluoroethylene-impregnated bundles of sized glass fibers |
US4495247A (en) * | 1983-06-30 | 1985-01-22 | E. I. Du Pont De Nemours And Company | Primer coating composition of a fluorocarbon polymer and an amino alkyl alkoxy silane |
US4465547A (en) * | 1983-09-29 | 1984-08-14 | General Electric Company | Method of bonding a poly (vinylidene fluoride) solid to a solid substrate |
US4701508A (en) * | 1984-12-14 | 1987-10-20 | Mitsui Sekiyu Kagaku Kogyo Kabushiki Kaisha | Solvent soluble fluorine-containing polymer, coating composition containing the same and coating process thereof |
JPS62260868A (ja) * | 1986-05-07 | 1987-11-13 | Matsumoto Seiyaku Kogyo Kk | 被覆組成物 |
CA1336929C (en) * | 1988-06-28 | 1995-09-05 | Kansai Paint Co., Ltd. | Water-repellent film-forming composition |
-
1988
- 1988-07-27 US US07/224,837 patent/US4879345A/en not_active Expired - Fee Related
-
1989
- 1989-07-26 KR KR1019900700643A patent/KR950013732B1/ko not_active IP Right Cessation
- 1989-07-26 BR BR898907584A patent/BR8907584A/pt not_active Application Discontinuation
- 1989-07-26 AU AU39863/89A patent/AU631561B2/en not_active Ceased
- 1989-07-26 EP EP89908740A patent/EP0426735B1/en not_active Expired - Lifetime
- 1989-07-26 WO PCT/US1989/003229 patent/WO1990001054A1/en active IP Right Grant
- 1989-07-26 DE DE68925582T patent/DE68925582T2/de not_active Expired - Fee Related
- 1989-07-27 MX MX016960A patent/MX170572B/es unknown
- 1989-07-27 CA CA000606835A patent/CA1335393C/en not_active Expired - Fee Related
- 1989-07-27 ES ES8902669A patent/ES2020813A6/es not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
AU631561B2 (en) | 1992-12-03 |
EP0426735B1 (en) | 1996-01-31 |
AU3986389A (en) | 1990-02-19 |
BR8907584A (pt) | 1991-07-30 |
DE68925582D1 (de) | 1996-03-14 |
ES2020813A6 (es) | 1991-10-01 |
CA1335393C (en) | 1995-04-25 |
DE68925582T2 (de) | 1996-08-29 |
KR900701949A (ko) | 1990-12-05 |
EP0426735A1 (en) | 1991-05-15 |
KR950013732B1 (ko) | 1995-11-15 |
WO1990001054A1 (en) | 1990-02-08 |
US4879345A (en) | 1989-11-07 |
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