ES2071078T3 - Mezclas de materiales, endurecibles, a base de resina epoxi, que contienen un endurecedor latente, una amina y un tiol. - Google Patents

Mezclas de materiales, endurecibles, a base de resina epoxi, que contienen un endurecedor latente, una amina y un tiol.

Info

Publication number
ES2071078T3
ES2071078T3 ES90810873T ES90810873T ES2071078T3 ES 2071078 T3 ES2071078 T3 ES 2071078T3 ES 90810873 T ES90810873 T ES 90810873T ES 90810873 T ES90810873 T ES 90810873T ES 2071078 T3 ES2071078 T3 ES 2071078T3
Authority
ES
Spain
Prior art keywords
amine
epoxy resin
thyol
hardenable
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90810873T
Other languages
English (en)
Inventor
Frans Dr Setiabudi
Urs Dr Gruber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Application granted granted Critical
Publication of ES2071078T3 publication Critical patent/ES2071078T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/66—Mercaptans
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/56—Amines together with other curing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether

Abstract

MEZCLA DE MATERIAS ENDURECIBLE CONTENIENDO (A) UNA RESINA EPOXI, (B) UN ENDURECEDOR LATENTE PARA LA RESINA EPOXI, QUE SOLO EMPIEZA A REACCIONAR A UNA TEMPERATURA DE 80 C COMO MINIMO (MEDIDO POR MEDIO DE DSC PARA UNA VELOCIDAD DE CALENTAMIENTO DE 10 C POR MIN). (C) UNA AMINA CON AL MENOS UN HIDROGENO AMINICO Y (D) UN TIOL AL MENOS CON UN GRUPO SH, TENIENDO LA AMINA (C) AL MENOS DOS ATOMOS DE HIDROGENO COMBINADOS EN UNO O VARIOS ATOMOS DE NITROGENO O PRESENTANDO EL TIOL (D) AL MENOS DOS GRUPOS SH, Y SIENDO LA DIFERENCIA DE LA MAXIMA REACCION EN EL DIAGRAMA DSC A UNA VELOCIDAD DE CALENTAMIENTO DE 10 C, DE 30 C COMO MINIMO, SIENDO APROPIADOS PARA LA FABRICACION DE PRODUCTOS RETICULADOS, EN PARTICULAR PARA LA FABRICACION DE PREPREGS FLEXIBLES CON ESCALON B NO CRITICO Y MUY BUENA CAPACIDAD DE ALAMCENADO.
ES90810873T 1989-11-21 1990-11-13 Mezclas de materiales, endurecibles, a base de resina epoxi, que contienen un endurecedor latente, una amina y un tiol. Expired - Lifetime ES2071078T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH417089 1989-11-21

Publications (1)

Publication Number Publication Date
ES2071078T3 true ES2071078T3 (es) 1995-06-16

Family

ID=4271116

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90810873T Expired - Lifetime ES2071078T3 (es) 1989-11-21 1990-11-13 Mezclas de materiales, endurecibles, a base de resina epoxi, que contienen un endurecedor latente, una amina y un tiol.

Country Status (6)

Country Link
US (1) US5214098A (es)
EP (1) EP0429395B1 (es)
AT (1) ATE120469T1 (es)
DE (1) DE59008799D1 (es)
ES (1) ES2071078T3 (es)
MY (1) MY104771A (es)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4110219A1 (de) * 1991-03-28 1992-10-01 Huels Troisdorf Verfahren zur herstellung von prepregs mit loesungsmittelfreiem epoxidharz
KR100204325B1 (ko) * 1991-05-17 1999-06-15 월터클라웨인 한스-피터워트린 잠재적 경화제, 아민 및 디티올을 포함하는 경화성 에폭시 수지 조성물
US5444127A (en) * 1992-10-19 1995-08-22 Henkel Corporation Tertiary amine derivatives as components of polymer forming systems
EP0594133B1 (en) * 1992-10-22 1998-05-06 Ajinomoto Co., Inc. Polythiol epoxy resin composition with extended working life
EP0603131A1 (de) * 1992-12-18 1994-06-22 Ciba-Geigy Ag Aromatische Harnstoffverbindung als Härtungsbeschleuniger für eine Mischung aus Epoxiharz und Dicyandiamid
KR0163981B1 (ko) * 1993-06-29 1999-01-15 사또오 아키오 필름제 액정셀 봉지용 수지조성물
GB2280441A (en) * 1993-07-28 1995-02-01 Peter Drummond Boys White Gelled reactive resin compositions
US5541000A (en) * 1993-08-17 1996-07-30 Minnesota Mining And Manufacturing Company Latent, thermal cure accelerators for epoxy-aromatic amine resins having lowered peak exotherms
US6231959B1 (en) 1995-02-27 2001-05-15 Matsushita Electric Works, Ltd. Prepreg of epoxy resin, hardener, and organodialkyurea promotor
WO1997006198A1 (fr) * 1995-08-04 1997-02-20 Asahi Denka Kogyo Kabushiki Kaisha Composition de resine epoxy durcissable permettant d'obtenir un article flexible solidifie
US6001902A (en) * 1996-03-27 1999-12-14 Ciba Specialty Chemicals Corp. Wollastonite-containing curable epoxy resin mixture
TW457284B (en) * 1997-09-12 2001-10-01 Cytec Tech Corp Water based primer compositions and their use for treating metal surfaces
NL1009134C2 (nl) * 1998-05-12 1999-08-24 Vincent Alfred Joseph Woudsma Werkwijze voor het repareren c.q. opvullen c.q. verlijmen c.q. beschermen van organische of anorganische materialen d.m.v. menging en/of verdunning van elastische uithardbare epoxy gebaseerde producten.
US5972423A (en) * 1998-08-03 1999-10-26 Lord Corporation Primerless substrate repair with polyepoxide and polythiol
US6265519B1 (en) 1998-12-08 2001-07-24 Molex Incorporated Thiolamide curing agents
US6313257B1 (en) 1999-03-23 2001-11-06 Lord Corporation Poly (mercaptopropylaryl) curatives
JP4358505B2 (ja) * 2000-06-21 2009-11-04 三井化学株式会社 プラスチック製液晶表示セル用シール剤組成物
US6468660B2 (en) * 2000-12-29 2002-10-22 St. Jude Medical, Inc. Biocompatible adhesives
US20030082385A1 (en) * 2001-07-13 2003-05-01 Toray Composites (America), Inc. Quick cure carbon fiber reinforced epoxy resin
DE60218480T2 (de) * 2001-07-31 2007-10-31 Huntsman Advanced Materials (Switzerland) Gmbh Epoxydharz
DE60303593T2 (de) * 2002-03-08 2006-10-26 Owens-Corning, Toledo Bindemittel für endlos-vliesbahnen
DE602005025805D1 (de) 2004-12-21 2011-02-17 Nektar Therapeutics San Carlos Stabilisierte polymer-thiol-reagenzien
US7470755B2 (en) * 2005-11-29 2008-12-30 Prc-Desoto International, Inc. Polyepoxide, amine and mercaptan-terminated polyoxyalkylene
DE102010020882A1 (de) 2010-05-18 2011-11-24 Alzchem Trostberg Gmbh Semicarbazone zur Härtung von Epoxidharzen
EP2588554B1 (en) * 2010-06-29 2014-11-19 Dow Global Technologies LLC Storage-stable heat-activated tertiary amine catalysts for epoxy resins
BR112013021411B1 (pt) 2011-02-23 2020-04-14 Alzchem Ag endurecedores de alta latência para resinas epóxi, seus usos, composição de resina epóxi e de poliuretano compreendendo os mesmos e material compósito
DE102011118501A1 (de) 2011-11-15 2013-05-16 Alzchem Ag Alkyl- oder Dialkyl-Semicarbazone als Härter für Epoxidharze
DE102011118760A1 (de) 2011-11-15 2013-05-16 Alzchem Ag Verwendung von N,N'(-Dimethyl)-Uronen sowie Verfahren zur Härtung von Epoxidharz-Zusammensetzungen
JP5842736B2 (ja) * 2012-06-06 2016-01-13 デクセリアルズ株式会社 熱硬化性樹脂組成物、熱硬化性接着シート及び熱硬化性接着シートの製造方法
DE102012015315A1 (de) * 2012-08-02 2014-05-15 Alzchem Ag Flüssige Härter zur Härtung von Epoxidharzen (I)
DE102012015316A1 (de) * 2012-08-02 2014-05-15 Alzchem Ag Flüssige Härter zur Härtung von Epoxidharzen (II)
US9499659B2 (en) 2012-08-02 2016-11-22 Alzchem Ag Liquid hardeners for hardening epoxide resins (I)
US9862798B2 (en) 2013-09-30 2018-01-09 Evonik Degussa Gmbh Epoxy liquid curing agent compositions
US9290462B1 (en) 2013-12-17 2016-03-22 Tda Research, Inc. Polythiol curing agents with low odor
FR3017394B1 (fr) * 2014-02-12 2017-10-20 Astrium Sas Composition d'ensimage pour fibres de renfort et ses applications
EP2957606A1 (de) * 2014-06-18 2015-12-23 HILTI Aktiengesellschaft Brandschutz-Zusammensetzung und deren Verwendung
CN104530390A (zh) * 2014-12-11 2015-04-22 广东生益科技股份有限公司 一种可降解的树脂组合物及使用它的预浸料、层压板、覆铜板及其降解方法
CN112852370A (zh) * 2021-03-18 2021-05-28 东莞市帆朗电子科技有限公司 一种透明单组份低温固化胶粘剂及其制备方法

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3030247A (en) * 1955-07-28 1962-04-17 Minnesota Mining & Mfg Stable heat-curing epoxy resin compositions
US3278496A (en) * 1961-03-01 1966-10-11 Diamond Alkali Co Thiol terminated liquid polymers
US3310527A (en) * 1963-05-31 1967-03-21 Shell Oil Co Process for curing polyepoxides and resulting products
GB1044715A (en) * 1964-10-02 1966-10-05 Ciba Ltd New epoxy resin compositions
US3386955A (en) * 1966-01-14 1968-06-04 American Cyanamid Co Substituted ureas as low temperature epoxy curing agents
US3363026A (en) * 1966-02-07 1968-01-09 Celanese Coatings Co Epoxy resin containing a curing catalyst mixture of a polymercaptan and a fused ringamine
GB1280661A (en) * 1969-01-02 1972-07-05 Ciba Geigy U K Ltd Adducts, and their use for curing epoxide resins
FR2029420A1 (es) * 1969-01-31 1970-10-23 Aquitaine Petrole
FR2029916A5 (es) * 1969-01-31 1970-10-23 Aquitaine Petrole
CH539628A (de) * 1970-07-07 1973-07-31 Reichhold Albert Chemie Ag Verfahren zur Umsetzung von Hydroxylgruppen und Sulfhydrylgruppen enthaltenden Verbindungen mit überschüssigen Mengen Polyepoxiden allein oder im Gemisch mit Monoepoxiden
US3734968A (en) * 1970-11-16 1973-05-22 Dow Chemical Co Cyclohexyl thiol-dienes
US3678007A (en) * 1971-08-23 1972-07-18 Ppg Industries Inc Metal salt complexes of imidazolium salts as curing agents for one part epoxy resins
US3677978A (en) * 1971-08-23 1972-07-18 Ppg Industries Inc Metal salt complexes of imidazoles as curing agents for one-part epoxy resins
US4126505A (en) * 1974-11-05 1978-11-21 Ciba-Geigy Corporation Adhesive compositions
US4092293A (en) * 1976-06-24 1978-05-30 Diamond Shamrock Corporation Polymercaptans for curing epoxy resins and method of preparation thereof
CH637411A5 (de) * 1979-04-20 1983-07-29 Ciba Geigy Ag Epoxidharz, haerter und haertungsbeschleuniger enthaltende, lagerfaehige homogene mischung und deren verwendung zur herstellung gehaerteter erzeugnisse.
CH646956A5 (de) * 1981-12-15 1984-12-28 Ciba Geigy Ag Imidazolide.
US4618712A (en) * 1982-02-23 1986-10-21 Ciba-Geigy Corporation N-cyanocarboxylic acid amides, processes for their preparation and their use
US4550203A (en) * 1982-02-23 1985-10-29 Ciba Geigy Corporation Process for the preparation of N-substituted N-cyancarboxylic acid amides
US4529821A (en) * 1982-02-23 1985-07-16 Ciba-Geigy Corporation Cyanoacylamide compounds
JPH0231732B2 (ja) * 1983-01-17 1990-07-16 Dainippon Shikizai Kogyo Kk Ehokishijushisoseibutsu
DE3480392D1 (en) * 1983-04-29 1989-12-14 Ciba Geigy Ag Imidazolides and their use as curing agents for polyepoxides
DE3660221D1 (de) * 1985-02-01 1988-06-30 Ciba Geigy Ag (acylthiopropyl)-polyphenols
EP0310545A3 (de) * 1987-09-02 1989-07-26 Ciba-Geigy Ag Cyanoguanidine als Härter für Epoxidharze
US4879414A (en) * 1988-02-17 1989-11-07 Henkel Corporation Polythiols and use as epoxy resin curing agents
US4927902A (en) * 1988-02-17 1990-05-22 Henkel Corporation Polythiols and use as epoxy resin curing agents
ES2087069T3 (es) * 1988-11-23 1996-07-16 Ciba Geigy Ag Mezclas de resinas epoxi reticulables que contienen polioxialquilenditioles y poliaminas.

Also Published As

Publication number Publication date
EP0429395A2 (de) 1991-05-29
MY104771A (en) 1994-05-31
US5214098A (en) 1993-05-25
DE59008799D1 (de) 1995-05-04
EP0429395A3 (en) 1991-07-31
EP0429395B1 (de) 1995-03-29
ATE120469T1 (de) 1995-04-15

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