MX168263B - El empleo de catalizadores de raney modificados para la obtencion de compuestos diamino aromaticos - Google Patents
El empleo de catalizadores de raney modificados para la obtencion de compuestos diamino aromaticosInfo
- Publication number
- MX168263B MX168263B MX003876A MX387686A MX168263B MX 168263 B MX168263 B MX 168263B MX 003876 A MX003876 A MX 003876A MX 387686 A MX387686 A MX 387686A MX 168263 B MX168263 B MX 168263B
- Authority
- MX
- Mexico
- Prior art keywords
- raney catalysts
- aromatic diamine
- percent
- weight
- diamine compounds
- Prior art date
Links
- 239000007868 Raney catalyst Substances 0.000 title abstract 3
- -1 AROMATIC DIAMINE COMPOUNDS Chemical class 0.000 title abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000003513 alkali Substances 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 150000001491 aromatic compounds Chemical class 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J25/00—Catalysts of the Raney type
- B01J25/02—Raney nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J25/00—Catalysts of the Raney type
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente invención se refiere a el empleo de catalizadores de raney modificados para la obtención de compuestos diamino aromáticos por hidrogenación del correspondiente compuesto dinitro aromático, caracterizado porque como catalizadores de Raney se emplean aquellos que se han obtenido por tratamiento con alcali de una aleación de un 50 hasta un 95 por ciento en peso de aluminio, un 4 hasta un 45 por ciento en peso de níquel y/o cobalto y un 1 hasta un 46 por ciento en peso de como mínimo un metal modificador, complementándose los porcentajes mencionados a 100, y donde los metales modificadores son aquellos del 1º, 4º, 5º, 6º, 7º y/u 8º grupo secundario del sistema periódico de los elmentos.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853537247 DE3537247A1 (de) | 1985-10-19 | 1985-10-19 | Verwendung von modifizierten raney-katalysatoren zur herstellung von aromatischen diaminoverbindungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX168263B true MX168263B (es) | 1993-05-14 |
Family
ID=6283961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX003876A MX168263B (es) | 1985-10-19 | 1986-09-29 | El empleo de catalizadores de raney modificados para la obtencion de compuestos diamino aromaticos |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4792626A (es) |
| EP (1) | EP0223035B1 (es) |
| JP (1) | JPH07121894B2 (es) |
| BR (1) | BR8605084A (es) |
| CA (1) | CA1260014A (es) |
| DE (2) | DE3537247A1 (es) |
| ES (1) | ES2011768B3 (es) |
| MX (1) | MX168263B (es) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4929737A (en) * | 1988-02-03 | 1990-05-29 | Eastman Kodak Company | Hydrogenation of halonitroaromatic compounds |
| US4895994A (en) * | 1988-04-14 | 1990-01-23 | W. R. Grace & Co.-Conn. | Shaped catalysts and processes |
| CN1027191C (zh) * | 1990-01-31 | 1994-12-28 | 西屋电气公司 | 自动伪主相量发生器 |
| DE69124401T2 (de) * | 1991-04-03 | 1997-07-24 | Eastman Kodak Co | Verfahren zur herstellung von aromatischen aminen |
| DE4323687A1 (de) * | 1993-07-15 | 1995-01-19 | Bayer Ag | Kontinuierliches Verfahren zur Herstellung von aromatischen Aminen |
| CN1085560C (zh) * | 1993-12-28 | 2002-05-29 | 罗纳布朗克化学公司 | 用于将腈催化氢化为胺的催化剂及其制备方法与用途 |
| JP2851439B2 (ja) * | 1993-12-28 | 1999-01-27 | ローヌープーラン シミ | ニトリルを水素化してアミンにするための触媒の調製方法及びこの触媒の水素化における用途 |
| DE19753501A1 (de) * | 1997-12-03 | 1999-06-10 | Bayer Ag | Raney-Nickel-Katalysatoren, ein Verfahren zu deren Herstellung und deren Verwendung zur Hydrierung organischer Verbindungen |
| DE19907829C2 (de) | 1999-02-24 | 2001-05-10 | Bayer Ag | Verfahren zur Herstellung von cis-2,6-Dimethylpiperazin |
| DE19909176A1 (de) | 1999-03-03 | 2000-09-07 | Kataleuna Gmbh Catalysts | Hydrierkatalysator und Verfahren zu seiner Herstellung |
| DE19909168A1 (de) * | 1999-03-03 | 2000-09-07 | Basf Ag | Verfahren zur Herstellung von Aminen |
| DE19909177A1 (de) | 1999-03-03 | 2000-09-07 | Kataleuna Gmbh Catalysts | Katalysator zur Hydrierung funktioneller Gruppen und Verfahren zu seiner Herstellung |
| US6309758B1 (en) * | 1999-05-06 | 2001-10-30 | W. R. Grace & Co.-Conn. | Promoted porous catalyst |
| TW553772B (en) | 1999-07-31 | 2003-09-21 | Degussa | Fixed bed catalysts |
| DE19936135A1 (de) * | 1999-07-31 | 2001-02-15 | Degussa | Festbettkatalysatoren |
| FR2807036B1 (fr) | 2000-03-28 | 2002-05-10 | Rhodia Chimie Sa | Hydrogenation continue de composes nitres aromatiques utilisant un catalyseur a faible teneur en aluminium |
| DE10056840A1 (de) * | 2000-11-16 | 2002-05-23 | Basf Ag | Verfahren zur Hydrierung von Nitrilen an Raney-Katalysatoren |
| US6762324B2 (en) | 2002-05-01 | 2004-07-13 | Air Products And Chemicals, Inc. | Metal modified Pd/Ni catalysts |
| JP4500302B2 (ja) * | 2003-07-04 | 2010-07-14 | チアンス・シノケム・テクノロジー・カンパニー・リミテッド | 4−アミノジフェニルアミンの製造方法 |
| PT1645555E (pt) * | 2003-07-04 | 2011-11-28 | Jiangsu Sinorgchem Tech Co Ltd | Um método para produzir 4-aminodifenilamina |
| US8686188B2 (en) | 2003-07-04 | 2014-04-01 | Jiangsu Sinorgchem Technology Co., Ltd. | Process for preparing 4-aminodiphenylamine |
| US8486223B2 (en) * | 2003-07-04 | 2013-07-16 | Jiangsu Sinorgchem Technology Co., Ltd. | Falling film evaporator |
| DE10341269A1 (de) * | 2003-09-08 | 2005-03-31 | Bayer Materialscience Ag | Verfahren zur Herstellung von Raney-Nickel-Katalysatoren und deren Verwendung zur Hydrierung organischer Verbindungen |
| DE102006059678A1 (de) * | 2006-12-18 | 2008-06-19 | Bayer Materialscience Ag | Verfahren zur Herstellung von aromatischen Aminen |
| DE102006060572A1 (de) | 2006-12-19 | 2008-06-26 | Bayer Materialscience Ag | Verfahren zur Herstellung von Toluylendiaminen durch katalytische Hydrierung von Dinitrotoluolen |
| US9643162B2 (en) * | 2007-05-29 | 2017-05-09 | Evonik Degussa Gmbh | Activated base metal catalysts |
| KR101372177B1 (ko) * | 2007-05-29 | 2014-03-07 | 에보니크 데구사 게엠베하 | 활성화된 베이스 금속 촉매 |
| US8889911B2 (en) * | 2007-05-29 | 2014-11-18 | Evonik Degussa Gmbh | Activated base metal catalysts |
| BRPI0722161A2 (pt) * | 2007-10-15 | 2014-03-18 | Evonik Degussa Gmbh | Misturas catalíticas em pó de filtragem rápida |
| DE102008063308B4 (de) | 2008-12-29 | 2013-03-07 | Basf Se | Verfahren zur Herstellung von Toluylendiamin durch Hydrierung von Dinitrotoluol |
| DE102009025374A1 (de) * | 2009-06-18 | 2010-12-23 | Bayer Materialscience Ag | Verfahren zur Herstellung von aromatischen Aminen |
| HUE026176T2 (en) | 2010-01-14 | 2016-05-30 | Bayer Ip Gmbh | A method for producing aromatic amines in a liquid phase |
| CN102259029B (zh) | 2010-05-24 | 2014-12-10 | 江苏圣奥化学科技有限公司 | 固体碱催化剂 |
| EP2705902B1 (de) | 2012-09-06 | 2015-05-06 | Allessa Chemie GmbH | Verfahren zur Hydrierung von Nitroaromaten mit ausgewählten Platinkatalysatoren |
| HUE030188T2 (en) | 2013-01-22 | 2017-04-28 | Covestro Deutschland Ag | Process for the preparation of aromatic amines |
| KR20170005803A (ko) | 2014-05-13 | 2017-01-16 | 코베스트로 도이칠란트 아게 | 톨루엔디아민의 제조 방법 |
| CN104888794B (zh) * | 2015-05-21 | 2017-05-24 | 浙江新和成股份有限公司 | 金属复合物催化剂、其制备方法以及在制备d,l‑薄荷醇中的应用 |
| JP2020534150A (ja) * | 2017-09-20 | 2020-11-26 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 触媒成形体の製造方法 |
| CN117255715A (zh) | 2021-05-06 | 2023-12-19 | 巴斯夫欧洲公司 | 包含Ni、一种或多种附加金属M和特定的氧化载体材料的适用于氢化反应的催化材料 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1066582A (fr) * | 1952-11-14 | 1954-06-08 | Electro Chimie Soc D | Catalyseurs d'hydrogénation et leur procédé de préparation |
| DE1044099B (de) * | 1957-06-27 | 1958-11-20 | Bayer Ag | Verfahren zur Herstellung von Toluylendiamin |
| GB919273A (en) * | 1960-12-29 | 1963-02-20 | Gen Aniline & Film Corp | Modified nickel hydrogenation catalyst |
| US3544485A (en) * | 1967-10-16 | 1970-12-01 | Toray Industries | Method of activating catalytic alloys |
| FR1599004A (es) * | 1968-10-17 | 1970-07-15 | ||
| US3895065A (en) * | 1968-10-17 | 1975-07-15 | Rhone Poulenc Ind | Process for carrying out chemical reactions in heterogeneous medium |
| DE2713374C3 (de) * | 1977-03-25 | 1987-07-30 | Bayer Ag, 5090 Leverkusen | Verwendung von Raney-Nickel-Eisen-Katalysatoren zur Reduktion von m-Nitrotoluol, p-Nitrophenetol oder 2,4-/2,6-Dinitrotoluol-Gemischen |
| US4513149A (en) * | 1982-04-05 | 1985-04-23 | Olin Corporation | Raney nickel alloy expanded mesh hydrogenation catalysts |
| DE3315191A1 (de) * | 1983-04-27 | 1984-10-31 | Bayer Ag, 5090 Leverkusen | Verfahren zur kontinuierlichen herstellung von aromatischen diaminen unter gleichzeitiger erzeugung von dampf |
-
1985
- 1985-10-19 DE DE19853537247 patent/DE3537247A1/de not_active Withdrawn
-
1986
- 1986-09-29 MX MX003876A patent/MX168263B/es unknown
- 1986-10-01 CA CA000519559A patent/CA1260014A/en not_active Expired
- 1986-10-04 DE DE8686113764T patent/DE3666947D1/de not_active Expired
- 1986-10-04 ES ES86113764T patent/ES2011768B3/es not_active Expired - Lifetime
- 1986-10-04 EP EP86113764A patent/EP0223035B1/de not_active Expired
- 1986-10-10 US US06/917,449 patent/US4792626A/en not_active Expired - Lifetime
- 1986-10-17 BR BR8605084A patent/BR8605084A/pt not_active IP Right Cessation
- 1986-10-17 JP JP61245673A patent/JPH07121894B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE3537247A1 (de) | 1987-04-23 |
| US4792626A (en) | 1988-12-20 |
| JPH07121894B2 (ja) | 1995-12-25 |
| EP0223035B1 (de) | 1989-11-15 |
| BR8605084A (pt) | 1987-07-21 |
| DE3666947D1 (en) | 1989-12-21 |
| ES2011768B3 (es) | 1990-02-16 |
| EP0223035A1 (de) | 1987-05-27 |
| JPS6299350A (ja) | 1987-05-08 |
| CA1260014A (en) | 1989-09-26 |
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