MX167036B - Composicion de catalizador para la prepracion de acidos carboxilicos insaturados y metodo para su preparacion - Google Patents

Composicion de catalizador para la prepracion de acidos carboxilicos insaturados y metodo para su preparacion

Info

Publication number
MX167036B
MX167036B MX197548A MX19754883A MX167036B MX 167036 B MX167036 B MX 167036B MX 197548 A MX197548 A MX 197548A MX 19754883 A MX19754883 A MX 19754883A MX 167036 B MX167036 B MX 167036B
Authority
MX
Mexico
Prior art keywords
preparation
catalyst
carboxylic acids
unsaturated carboxylic
catalyst composition
Prior art date
Application number
MX197548A
Other languages
English (en)
Inventor
William James Kennelly
Lawrence Sameul Kirch
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of MX167036B publication Critical patent/MX167036B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a composición de catalizador para preparación de ácidos carboxílicos insaturados y método para su preparación de ácidos caracterizados porque el catalizador comprende; Mo12PaX1bVcAsdCuSbfX2gOx donde X es uno o más elementos seleccionados de cesio, talio o rubidio; X es uno o más de los elementos seleccionados del tungsteno, niobio, tantalo, zirconio, estaño, hierro, zinc, cobalto, bismuto, boro aproximadamente 0.85 a acerca de 1.2; b es un número en el rango de aproximadamente 0.75 a cerca de 1.25, c es el número en el rango de aprxomadamente 0.05 a cerca de 0.7; d es un número en el rango de aproximadamente 0.5 a cerca de 2.0; e es un número en el rango de aproximadamente 0 a cerca de 0.4; f es un número en el rango de aproximadamente cerca de 0.3; q es un número en el rango de aproximadamente 0 a cercade 2.0y x es el número de oxígeno requeridos para satisfacer los requerimientos de valencia de los otros elementos presentes, y el método de preparación de la composición del catalizador se caracteriza por estar preparados al suspender el trióxido de molibdeno en aga, seguido de la adición de ácido fosfórico, calentado a temperatura en el rango de aproximadamente 60 grados a cerca de 95 grados C por al menos una hora, mezclado los elementos restantes como sus óxidos o sales compuestos convertibles por calentamiento en sus óxidos con trióxido de molibdeno acuoso ya sea antes o despues de la adición de ácido fosfórico, mezclando con hidróxido de amonio, aislando el materia. calcinando a una temperatura de aproximadamente 350 grados C a cerca de 450 grados C.
MX197548A 1982-06-07 1983-06-06 Composicion de catalizador para la prepracion de acidos carboxilicos insaturados y metodo para su preparacion MX167036B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US38536582A 1982-06-07 1982-06-07

Publications (1)

Publication Number Publication Date
MX167036B true MX167036B (es) 1993-02-24

Family

ID=23521114

Family Applications (1)

Application Number Title Priority Date Filing Date
MX197548A MX167036B (es) 1982-06-07 1983-06-06 Composicion de catalizador para la prepracion de acidos carboxilicos insaturados y metodo para su preparacion

Country Status (7)

Country Link
EP (1) EP0102688B1 (es)
JP (1) JPS594445A (es)
AT (1) ATE21243T1 (es)
BR (1) BR8302974A (es)
CA (1) CA1199905A (es)
DE (1) DE3365122D1 (es)
MX (1) MX167036B (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4022212A1 (de) * 1990-07-12 1992-01-16 Basf Ag Massen der allgemeinen formel mo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)2(pfeil abwaerts)(pfeil hoch)p(pfeil hoch)(pfeil abwaerts)a(pfeil abwaerts)(pfeil hoch)v(pfeil hoch)(pfeil abwaerts)b(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)1(pfeil hoch)(pfeil abwaerts)c(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)2(pfeil hoch)(pfeil abwaerts)d(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)3(pfeil hoch)(pfeil abwaerts)e(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil hoch)b(pfeil hoch)(pfeil abwaerts)f(pfeil abwaerts)(pfeil hoch)r(pfeil hoch)(pfeil hoch)e(pfeil hoch)(pfeil abwaerts)g(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil abwaerts)h(pfeil abwaerts)(pfeil hoch)o(pfeil hoch)(pfeil abwaerts)n(pfeil abwaerts)
US5221767A (en) * 1990-07-12 1993-06-22 Basf Aktiengesellschaft Compositions of the formula Mo12 Pa Vb X1 c X2 d X3 e Sbf Reg Sh On
DE19638249A1 (de) * 1996-09-19 1998-03-26 Basf Ag Verfahren zur Herstellung einer katalytisch aktiven Multimetalloxidmasse
JP4671320B2 (ja) * 2000-09-21 2011-04-13 日本化薬株式会社 メタクリル酸製造用被覆触媒の製法
WO2004062798A1 (ja) * 2003-01-09 2004-07-29 Mitsubishi Rayon Co., Ltd. 触媒の保存方法
CN1972751B (zh) * 2004-06-28 2010-05-12 三菱丽阳株式会社 甲基丙烯酸合成用催化剂的制造方法
JP4745766B2 (ja) * 2004-09-07 2011-08-10 三菱レイヨン株式会社 メタクリル酸製造用触媒及びその製造方法並びにメタクリル酸の製造方法
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PH12128A (en) * 1973-09-04 1978-11-07 Standard Oil Co Chromium-containing catalysts useful for oxidation reactions
DE2460541C3 (de) * 1973-12-29 1979-10-18 Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) Phosphor, Molybdän und Vanadium sowie gegebenenfalls Kupfer, Kobalt, Zirkon, Wismut, Antimon und/oder Arsen enthaltender Oxydkatalysator und dessen Verwendung zur Herstellung von Methacrylsäure
JPS57297B2 (es) * 1974-01-19 1982-01-06
JPS5827255B2 (ja) * 1974-05-31 1983-06-08 三菱レイヨン株式会社 不飽和脂肪酸の製造方法
JPS51115414A (en) * 1975-04-03 1976-10-12 Mitsubishi Rayon Co Ltd Process for preparation of unsaturated fatty acids
US4148757A (en) * 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
US4252682A (en) * 1978-12-26 1981-02-24 Halcon Research And Development Corp. Catalyst for producing methacrylic acid
YU41495B (en) * 1979-01-23 1987-08-31 Nippon Kayaku Kk Process for obtaining methacrolein and methacrylic acid
JPS55100324A (en) * 1979-01-23 1980-07-31 Nippon Kayaku Co Ltd Preparation of methacrolein and methacrylic acid
JPS55122734A (en) * 1979-03-16 1980-09-20 Nippon Kayaku Co Ltd Preparation of methacrylic acid and its catalyst
JPS55124734A (en) * 1979-03-22 1980-09-26 Nippon Kayaku Co Ltd Preparation of methacrylic acid
JPS5712830A (en) * 1980-06-26 1982-01-22 Nippon Shokubai Kagaku Kogyo Co Ltd Oxidation catalyst and its preparation
US4419270A (en) * 1980-06-26 1983-12-06 Nippon Shokubai Kagaku Kogyo Co. Ltd. Oxidation catalyst

Also Published As

Publication number Publication date
CA1199905A (en) 1986-01-28
ATE21243T1 (de) 1986-08-15
BR8302974A (pt) 1984-02-07
DE3365122D1 (en) 1986-09-11
EP0102688A1 (en) 1984-03-14
JPH0428417B2 (es) 1992-05-14
JPS594445A (ja) 1984-01-11
EP0102688B1 (en) 1986-08-06

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