MD3151F1 - Electrode and process for obtaining thereof for electrolysis of the alkaline aqueous solutions - Google Patents
Electrode and process for obtaining thereof for electrolysis of the alkaline aqueous solutions Download PDFInfo
- Publication number
- MD3151F1 MD3151F1 MDA20050357A MD20050357A MD3151F1 MD 3151 F1 MD3151 F1 MD 3151F1 MD A20050357 A MDA20050357 A MD A20050357A MD 20050357 A MD20050357 A MD 20050357A MD 3151 F1 MD3151 F1 MD 3151F1
- Authority
- MD
- Moldova
- Prior art keywords
- cobalt
- obtaining
- electrode
- nickel
- dimethylaminoborane
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000005868 electrolysis reaction Methods 0.000 title abstract 2
- 239000007864 aqueous solution Substances 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- 239000000243 solution Substances 0.000 abstract 3
- 229910000521 B alloy Inorganic materials 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- JJFNJZGXHWYGMQ-UHFFFAOYSA-N [Ni].B#[Co] Chemical compound [Ni].B#[Co] JJFNJZGXHWYGMQ-UHFFFAOYSA-N 0.000 abstract 2
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 2
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical class [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 abstract 2
- 238000000151 deposition Methods 0.000 abstract 2
- YPTUAQWMBNZZRN-UHFFFAOYSA-N dimethylaminoboron Chemical compound [B]N(C)C YPTUAQWMBNZZRN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- FYWSTUCDSVYLPV-UHFFFAOYSA-N nitrooxythallium Chemical compound [Tl+].[O-][N+]([O-])=O FYWSTUCDSVYLPV-UHFFFAOYSA-N 0.000 abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- OQVYMXCRDHDTTH-UHFFFAOYSA-N 4-(diethoxyphosphorylmethyl)-2-[4-(diethoxyphosphorylmethyl)pyridin-2-yl]pyridine Chemical compound CCOP(=O)(OCC)CC1=CC=NC(C=2N=CC=C(CP(=O)(OCC)OCC)C=2)=C1 OQVYMXCRDHDTTH-UHFFFAOYSA-N 0.000 abstract 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- 239000012670 alkaline solution Substances 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 230000005518 electrochemistry Effects 0.000 abstract 1
- 238000009713 electroplating Methods 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 abstract 1
- 239000012286 potassium permanganate Substances 0.000 abstract 1
- LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 235000011006 sodium potassium tartrate Nutrition 0.000 abstract 1
- 230000007928 solubilization Effects 0.000 abstract 1
- 238000005063 solubilization Methods 0.000 abstract 1
- 238000004065 wastewater treatment Methods 0.000 abstract 1
Landscapes
- Water Treatment By Electricity Or Magnetism (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Abstract
Inventia se refera la obtinerea electrozilor si poate fi utilizata in electrochimie, in electrolizaindustriala a solutiilor alcaline, in galvanotehnica, in procedeele de epurare a apelor reziduale. Esenta inventiei consta in aceea ca electrodul contine un substrat metalic din titan si aliajele acestuia si un strat activ depus pe el in forma de aliaj poros de cobalt-nichel-bor, cu includereain compozitia lui a Mo si/sau W si/sau Re. Procedeul de obtinere a electrodului consta in depunereape substratul metalic din titan si aliajele acestuia, tratat in prealabil cu hidruri, a unui stratactiv in forma de aliaj poros de cobalt-nichel-bor din solutiile, care contin sulfati de cobalt sinichel, sarea Seignette, saruri de Mo7+ si/sau W7+ si/sau Re7+, nitrat de taliu(I) si dimetilaminoboran, in urmatorul raport al componentelor, g/l:sulfat de nichel 5…10sulfat de cobalt 10…20sare Seignette 30…40saruri de Mo7+ si/sau W7+ si/sau Re7+ 15…20dimetilaminoboran 1…3nitrat de taliu(I) 0,001…0,002,depunerea se efectueaza la temperatura de 50…70°C si pH 6,5…10,0, la un raport dintre suprafata electrodului si volumul solutiei de 1 : (2…3), cu solubilizare ulterioara a borului din depunerea formata prin tratamentul anodic la o densitate a curentului de 1…2 A/dm2 timp de 10…15 min, in solutie de NaOH cu pH 10…12, in prezenta oxidantului, totodata in calitate de oxidant se utilizeaza peroxid de hidrogen si permanganat de potasiu inurmatorul raport al componentelor, g/l: hidroxidde sodiu 50…100peroxid de hidrogen de 33%, ml 30…50permanganat de potasiu 5…10.The invention relates to the obtaining of electrodes and can be used in electrochemistry, in industrial electrolysis and in alkaline solutions, in electroplating, in wastewater treatment processes. The essence of the invention is that the electrode contains a titanium metal substrate and its alloys and an active layer deposited on it in the form of a porous cobalt-nickel-boron alloy, including its composition of Mo and / or W and / or Re. The process of obtaining the electrode consists of depositing the titanium metal substrate and its alloys, previously treated with hydrides, of a layered porous cobalt-nickel-boron alloy in the solutions, containing sinichel cobalt sulphates, Seignette salt, salts. of Mo7 + and / or W7 + and / or Re7 +, thallium nitrate (I) and dimethylaminoborane, in the following component ratio, g / l: nickel sulphate 5 ... 10 cobalt sulphate 10 ... 20salignite 30 ... 40salts of Mo7 + and / or W7 + and / or Re7 + 15 ... 20 dimethylaminoborane 1 ... 3 thallium nitrate (I) 0.001 ... 0.002, deposition is carried out at 50 ... 70 ° C and pH 6.5 ... 10.0, at a ratio between the electrode surface and the volume of the solution of 1: (2 ... 3), with subsequent solubilization of boron from the deposit formed by the anodic treatment at a current density of 1 ... 2 A / dm2 for 10 ... 15 min, in NaOH solution with pH 10 ... 12, in the presence of the oxidant, at the same time as oxidant is used hydrogen peroxide and per potassium manganate inurmur component ratio, g / l: sodium hydroxide 50 ... 100% 33% hydrogen peroxide, 30 ... 50 potassium permanganate 5 ... 10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20050357A MD3151G2 (en) | 2005-12-05 | 2005-12-05 | Electrode and process for obtaining thereof for electrolysis of the alkaline aqueous solutions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20050357A MD3151G2 (en) | 2005-12-05 | 2005-12-05 | Electrode and process for obtaining thereof for electrolysis of the alkaline aqueous solutions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MD3151F1 true MD3151F1 (en) | 2006-09-29 |
| MD3151G2 MD3151G2 (en) | 2007-04-30 |
Family
ID=37075320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MDA20050357A MD3151G2 (en) | 2005-12-05 | 2005-12-05 | Electrode and process for obtaining thereof for electrolysis of the alkaline aqueous solutions |
Country Status (1)
| Country | Link |
|---|---|
| MD (1) | MD3151G2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD4207C1 (en) * | 2011-10-10 | 2013-09-30 | Государственный Университет Молд0 | Process for manufacturing a combined volume-porous flow-through electrode and process for electrolytic production of hydrogen |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD3383G2 (en) * | 2006-02-17 | 2008-03-31 | Государственный Университет Молд0 | Electrode and process for electroflotation separation of disperse systems and process for electrode obtaining |
| MD3753G2 (en) * | 2007-01-17 | 2009-06-30 | Государственный Университет Молд0 | Electrode for hydrogen electrolytic obtaining and process for manufacturing thereof |
| MD20070144A (en) * | 2007-05-21 | 2009-01-31 | Институт Энергетики Академии Наук Молдовы | Process for hydrogen ion flow obtaining |
| MD244Z (en) * | 2009-09-04 | 2011-02-28 | Государственный Университет Молд0 | Electrode for electrolytic production of hydrogen and process for manufacturing thereof |
| MD4087C1 (en) * | 2010-02-10 | 2011-08-31 | Государственный Университет Молд0 | Process for chemical-catalytic deposition of metal coatings |
| RU2534014C1 (en) * | 2013-10-17 | 2014-11-27 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Национальный исследовательский университет "МЭИ" (ФГБОУ ВПО "НИУ "МЭИ") | Production of electrodes with porous nickel coating for alkaline water electrolytic cells |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU537125A1 (en) * | 1974-04-25 | 1976-11-30 | Институт электрохимии Академии наук СССР | Electrode for electrolysis of an alkali aqueous solution and method for its manufacture |
-
2005
- 2005-12-05 MD MDA20050357A patent/MD3151G2/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD4207C1 (en) * | 2011-10-10 | 2013-09-30 | Государственный Университет Молд0 | Process for manufacturing a combined volume-porous flow-through electrode and process for electrolytic production of hydrogen |
Also Published As
| Publication number | Publication date |
|---|---|
| MD3151G2 (en) | 2007-04-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG4A | Patent for invention issued | ||
| KA4A | Patent for invention lapsed due to non-payment of fees (with right of restoration) | ||
| MM4A | Patent for invention definitely lapsed due to non-payment of fees |