MD3151G2 - Electrode and process for obtaining thereof for electrolysis of the alkaline aqueous solutions - Google Patents
Electrode and process for obtaining thereof for electrolysis of the alkaline aqueous solutions Download PDFInfo
- Publication number
- MD3151G2 MD3151G2 MDA20050357A MD20050357A MD3151G2 MD 3151 G2 MD3151 G2 MD 3151G2 MD A20050357 A MDA20050357 A MD A20050357A MD 20050357 A MD20050357 A MD 20050357A MD 3151 G2 MD3151 G2 MD 3151G2
- Authority
- MD
- Moldova
- Prior art keywords
- electrode
- nickel
- obtaining
- oxidant
- alloys
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000005868 electrolysis reaction Methods 0.000 title abstract 2
- 239000007864 aqueous solution Substances 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 239000000243 solution Substances 0.000 abstract 3
- 229910000521 B alloy Inorganic materials 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- JJFNJZGXHWYGMQ-UHFFFAOYSA-N [Ni].B#[Co] Chemical compound [Ni].B#[Co] JJFNJZGXHWYGMQ-UHFFFAOYSA-N 0.000 abstract 2
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 2
- 230000008021 deposition Effects 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- 239000012670 alkaline solution Substances 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- YPTUAQWMBNZZRN-UHFFFAOYSA-N dimethylaminoboron Chemical compound [B]N(C)C YPTUAQWMBNZZRN-UHFFFAOYSA-N 0.000 abstract 1
- 230000005518 electrochemistry Effects 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical class [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 abstract 1
- FYWSTUCDSVYLPV-UHFFFAOYSA-N nitrooxythallium Chemical compound [Tl+].[O-][N+]([O-])=O FYWSTUCDSVYLPV-UHFFFAOYSA-N 0.000 abstract 1
- 239000012286 potassium permanganate Substances 0.000 abstract 1
- 229910052702 rhenium Inorganic materials 0.000 abstract 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 abstract 1
- 239000010865 sewage Substances 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Water Treatment By Electricity Or Magnetism (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Abstract
The invention relates to the electrode obtaining and may be used in the electrochemistry, in the industrial electrolysis of the alkaline solutions, in galvanotechnics and processes for sewage treatment.Summary of the invention consists in that the electrode contains metal substrate of titanium or alloys thereof and an active layer deposited thereon in the form of porous cobalt-nickel-boron alloy, with inclusion into its composition of molybdenum and/or wolfram and/or rhenium.The process for electrode obtaining consists in the deposition onto the metal substrate of titanium or alloys thereof, preliminarily treated with hydrids, of an active layer in the form of porous cobalt-nickel-boron alloy from the solutions containing cobalt and nickel sulphates, salt of Seignette, Mo7+ and/or Re7+ salts, thallous nitrate and dimethylaminoborane, in the following component ratio g/l:the deposition is carried out at the temperature of 50…70°C and pH 6,6…10,0, at a ratio between the electrode surface and the solution volume of 1:(2…3), with boron subsequent leaching from the formed coat by anodic treatment, at a current density of 1…2 A/dm2 during 10…15 min, in NaOH solution with pH 10…12, in the presence of oxidant, at the same time as oxidant is used hydrogen peroxide and potassium permanganate, in the following component ratio, g/l:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20050357A MD3151G2 (en) | 2005-12-05 | 2005-12-05 | Electrode and process for obtaining thereof for electrolysis of the alkaline aqueous solutions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20050357A MD3151G2 (en) | 2005-12-05 | 2005-12-05 | Electrode and process for obtaining thereof for electrolysis of the alkaline aqueous solutions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MD3151F1 MD3151F1 (en) | 2006-09-29 |
| MD3151G2 true MD3151G2 (en) | 2007-04-30 |
Family
ID=37075320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MDA20050357A MD3151G2 (en) | 2005-12-05 | 2005-12-05 | Electrode and process for obtaining thereof for electrolysis of the alkaline aqueous solutions |
Country Status (1)
| Country | Link |
|---|---|
| MD (1) | MD3151G2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD3383G2 (en) * | 2006-02-17 | 2008-03-31 | Государственный Университет Молд0 | Electrode and process for electroflotation separation of disperse systems and process for electrode obtaining |
| MD20070144A (en) * | 2007-05-21 | 2009-01-31 | Институт Энергетики Академии Наук Молдовы | Process for hydrogen ion flow obtaining |
| MD3753G2 (en) * | 2007-01-17 | 2009-06-30 | Государственный Университет Молд0 | Electrode for hydrogen electrolytic obtaining and process for manufacturing thereof |
| MD244Z (en) * | 2009-09-04 | 2011-02-28 | Государственный Университет Молд0 | Electrode for electrolytic production of hydrogen and process for manufacturing thereof |
| MD4087C1 (en) * | 2010-02-10 | 2011-08-31 | Государственный Университет Молд0 | Process for chemical-catalytic deposition of metal coatings |
| RU2534014C1 (en) * | 2013-10-17 | 2014-11-27 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Национальный исследовательский университет "МЭИ" (ФГБОУ ВПО "НИУ "МЭИ") | Production of electrodes with porous nickel coating for alkaline water electrolytic cells |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD4207C1 (en) * | 2011-10-10 | 2013-09-30 | Государственный Университет Молд0 | Process for manufacturing a combined volume-porous flow-through electrode and process for electrolytic production of hydrogen |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU537125A1 (en) * | 1974-04-25 | 1976-11-30 | Институт электрохимии Академии наук СССР | Electrode for electrolysis of an alkali aqueous solution and method for its manufacture |
-
2005
- 2005-12-05 MD MDA20050357A patent/MD3151G2/en not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU537125A1 (en) * | 1974-04-25 | 1976-11-30 | Институт электрохимии Академии наук СССР | Electrode for electrolysis of an alkali aqueous solution and method for its manufacture |
Non-Patent Citations (1)
| Title |
|---|
| Слипченко А.В., Максименко В.В., Кульский Л.А. Современные малоизнашиваемые аноды и перспективы развития электрохимических технологий водообработки. Химия и технология воды. Т.15, № 3, 1993, с. 180-231 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD3383G2 (en) * | 2006-02-17 | 2008-03-31 | Государственный Университет Молд0 | Electrode and process for electroflotation separation of disperse systems and process for electrode obtaining |
| MD3753G2 (en) * | 2007-01-17 | 2009-06-30 | Государственный Университет Молд0 | Electrode for hydrogen electrolytic obtaining and process for manufacturing thereof |
| MD20070144A (en) * | 2007-05-21 | 2009-01-31 | Институт Энергетики Академии Наук Молдовы | Process for hydrogen ion flow obtaining |
| MD244Z (en) * | 2009-09-04 | 2011-02-28 | Государственный Университет Молд0 | Electrode for electrolytic production of hydrogen and process for manufacturing thereof |
| MD4087C1 (en) * | 2010-02-10 | 2011-08-31 | Государственный Университет Молд0 | Process for chemical-catalytic deposition of metal coatings |
| RU2534014C1 (en) * | 2013-10-17 | 2014-11-27 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Национальный исследовательский университет "МЭИ" (ФГБОУ ВПО "НИУ "МЭИ") | Production of electrodes with porous nickel coating for alkaline water electrolytic cells |
Also Published As
| Publication number | Publication date |
|---|---|
| MD3151F1 (en) | 2006-09-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG4A | Patent for invention issued | ||
| KA4A | Patent for invention lapsed due to non-payment of fees (with right of restoration) | ||
| MM4A | Patent for invention definitely lapsed due to non-payment of fees |