MA60715B1 - Procédé de purification d'une solution de lixiviation de nickel-cobalt-manganèse - Google Patents

Procédé de purification d'une solution de lixiviation de nickel-cobalt-manganèse

Info

Publication number
MA60715B1
MA60715B1 MA60715A MA60715A MA60715B1 MA 60715 B1 MA60715 B1 MA 60715B1 MA 60715 A MA60715 A MA 60715A MA 60715 A MA60715 A MA 60715A MA 60715 B1 MA60715 B1 MA 60715B1
Authority
MA
Morocco
Prior art keywords
manganese
solution
cobalt
nickel
same
Prior art date
Application number
MA60715A
Other languages
English (en)
Inventor
Bo Liu
Changdong LI
Ran He
Honghui TANG
Minjie Ye
Dongren LYU
Original Assignee
Guangdong Brunp Recycling Technology Co., Ltd
Hunan Brunp Recycling Technology Co., Ltd.
Hunan Brunp Vehicles Recycling Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Brunp Recycling Technology Co., Ltd, Hunan Brunp Recycling Technology Co., Ltd., Hunan Brunp Vehicles Recycling Co., Ltd. filed Critical Guangdong Brunp Recycling Technology Co., Ltd
Publication of MA60715B1 publication Critical patent/MA60715B1/fr

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/04Obtaining nickel or cobalt by wet processes
    • C22B23/0453Treatment or purification of solutions, e.g. obtained by leaching
    • C22B23/0461Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/44Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/04Obtaining nickel or cobalt by wet processes
    • C22B23/0407Leaching processes
    • C22B23/0415Leaching processes with acids or salt solutions except ammonium salts solutions
    • C22B23/0423Halogenated acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/04Obtaining nickel or cobalt by wet processes
    • C22B23/0407Leaching processes
    • C22B23/0415Leaching processes with acids or salt solutions except ammonium salts solutions
    • C22B23/043Sulfurated acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10Obtaining alkali metals
    • C22B26/12Obtaining lithium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006Wet processes
    • C22B7/007Wet processes by acid leaching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

La présente invention appartient au domaine de l'hydrométallurgie. L'invention concerne un procédé de purification d'une solution de lixiviation de nickel-cobalt-manganèse. Le procédé comprend les étapes suivantes : chauffer une solution de lixiviation de nickel-cobalt-manganèse, y ajouter une poudre de manganèse, ajuster le pH, faire réagir celle-ci et la filtrer pour obtenir des scories de fer-aluminium et un liquide dont le fer et l'aluminium ont été retirés ; chauffer le liquide dont le fer et l'aluminium ont été retirés, y ajouter une poudre de manganèse, ajuster le pH, faire réagir celle-ci et la filtrer pour obtenir des scories de cuivre et une solution dont le cuivre a été retiré ; chauffer la solution dont le cuivre a été retiré, y ajouter une solution alcaline, ajuster le pH, faire réagir celle-ci et la filtrer pour obtenir une solution précipitée de nickel-cobalt et d'hydroxyde de nickel-cobalt-manganèse ; et ajouter de l'eau dans l'hydroxyde de nickel-cobalt-manganèse pour la mise en suspension, chauffer celui-ci, ajouter une solution acide pour la dissolution, ajuster le pH, le faire réagir, le chauffer, y ajouter une poudre de manganèse, ajuster le pH et le filtrer pour obtenir des scories de fer-aluminium et une solution de sulfate de nickel-cobalt-manganèse conforme à la norme.Selon la présente invention, tout d'abord, le fer ferreux dans le système de solution est oxydé à l'aide d'un minerai d'oxyde de manganèse, la valeur du pH de celui-ci est ajustée avec un minerai de carbonate de manganèse au moyen d'une neutralisation, le fer et l'aluminium sont éliminés, l'acide résiduel dans le système de solution est consommé, et le minerai de carbonate de manganèse est également lixivié pour produire du sulfate de manganèse.
MA60715A 2020-09-09 2021-08-03 Procédé de purification d'une solution de lixiviation de nickel-cobalt-manganèse MA60715B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN202010938544.8A CN112159897B (zh) 2020-09-09 2020-09-09 一种镍钴锰浸出液净化的方法
EP21865726.0A EP4199185B1 (fr) 2020-09-09 2021-08-03 Procédé de purification d'une solution de lixiviation de nickel-cobalt-manganèse
PCT/CN2021/110265 WO2022052670A1 (fr) 2020-09-09 2021-08-03 Procédé de purification d'une solution de lixiviation de nickel-cobalt-manganèse

Publications (1)

Publication Number Publication Date
MA60715B1 true MA60715B1 (fr) 2024-12-31

Family

ID=73858360

Family Applications (1)

Application Number Title Priority Date Filing Date
MA60715A MA60715B1 (fr) 2020-09-09 2021-08-03 Procédé de purification d'une solution de lixiviation de nickel-cobalt-manganèse

Country Status (8)

Country Link
US (1) US11981976B2 (fr)
EP (1) EP4199185B1 (fr)
CN (1) CN112159897B (fr)
CL (1) CL2023000672A1 (fr)
ES (1) ES3008561T3 (fr)
HU (1) HU231497B1 (fr)
MA (1) MA60715B1 (fr)
WO (1) WO2022052670A1 (fr)

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CN112159897B (zh) * 2020-09-09 2022-07-15 广东邦普循环科技有限公司 一种镍钴锰浸出液净化的方法
CN117337339A (zh) * 2021-03-02 2024-01-02 纯电池科技股份有限公司 金属的沉淀
WO2022183243A1 (fr) * 2021-03-02 2022-09-09 The University Of Queensland Précipitation de métaux
CN113388742A (zh) * 2021-05-31 2021-09-14 浙江中金格派锂电产业股份有限公司 一种钴中间品浸出后液连续除铁的方法
CN113802002B (zh) * 2021-08-17 2022-11-15 广东邦普循环科技有限公司 湿法回收锂电池中有价金属的方法
CN114737068A (zh) * 2022-03-17 2022-07-12 贵州金瑞新材料有限责任公司 一种高品位软锰矿的高效浸出方法
CN114824211B (zh) * 2022-04-24 2024-10-15 广东邦普循环科技有限公司 一种锡基包覆正极材料前驱体的方法及正极材料前驱体
CN115232967A (zh) * 2022-06-01 2022-10-25 金川集团镍盐有限公司 一种氢氧化镍废渣硫酸再浸出的方法
CN115353160B (zh) * 2022-09-22 2024-06-14 福建常青新能源科技有限公司 一种电池级镍钴锰三元硫酸盐溶液的制备方法
CN116179872B (zh) * 2023-01-31 2024-11-19 南通金通储能动力新材料有限公司 一种从废旧镍钴铝三元前驱体中回收镍钴溶液的方法
WO2025010528A1 (fr) * 2023-07-07 2025-01-16 广东邦普循环科技有限公司 Procédé d'élimination d'élément manganèse dans une solution contenant du nickel-cobalt-manganèse et son utilisation
CN117418117B (zh) * 2023-10-17 2026-03-27 浙江海创锂电科技有限公司 一种ncma前驱体固废料回收镍钴锰盐溶液的方法
CN117867280A (zh) * 2023-12-29 2024-04-12 湖南中邦再生资源科技有限公司 一种铁铝废料中镍钴锂的回收方法和应用
WO2025205073A1 (fr) * 2024-03-28 2025-10-02 パナソニックIpマネジメント株式会社 Procédé de récupération d'élément métallique permettant de récupérer un élément métallique présent dans une batterie au lithium-ion
EP4674993A1 (fr) * 2024-07-05 2026-01-07 Mecaware Procédé d'extraction et de récupération sélectives d'éléments chimiques à partir d'un échantillon polymétallique
CN119706968B (zh) * 2024-12-02 2025-10-10 中南大学 粗制镍钴锰硫酸盐溶液的净化除杂方法
CN119662983A (zh) * 2024-12-05 2025-03-21 长沙有色冶金设计研究院有限公司 一种从废旧三元锂离子电池材料提锂渣中回收分离镍、钴、锰的方法
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CN111455174A (zh) * 2020-06-09 2020-07-28 矿冶科技集团有限公司 一种从混合氢氧化镍钴制备电池级硫酸镍、硫酸钴的方法
CN112159897B (zh) 2020-09-09 2022-07-15 广东邦普循环科技有限公司 一种镍钴锰浸出液净化的方法

Also Published As

Publication number Publication date
CL2023000672A1 (es) 2023-09-08
HUP2200165A2 (hu) 2022-07-28
EP4199185B1 (fr) 2024-10-30
US20230243017A1 (en) 2023-08-03
US11981976B2 (en) 2024-05-14
WO2022052670A1 (fr) 2022-03-17
CN112159897B (zh) 2022-07-15
EP4199185A4 (fr) 2024-01-24
EP4199185A1 (fr) 2023-06-21
CN112159897A (zh) 2021-01-01
ES3008561T3 (en) 2025-03-24
HU231497B1 (hu) 2024-04-28

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