LU86215A1 - CHLORINATED EFFERVESCENT COMPOSITIONS FOR DISINFECTION PELLETS - Google Patents
CHLORINATED EFFERVESCENT COMPOSITIONS FOR DISINFECTION PELLETS Download PDFInfo
- Publication number
- LU86215A1 LU86215A1 LU86215A LU86215A LU86215A1 LU 86215 A1 LU86215 A1 LU 86215A1 LU 86215 A LU86215 A LU 86215A LU 86215 A LU86215 A LU 86215A LU 86215 A1 LU86215 A1 LU 86215A1
- Authority
- LU
- Luxembourg
- Prior art keywords
- acid
- pellets
- chlorinated
- weight
- disinfection
- Prior art date
Links
- 239000008188 pellet Substances 0.000 title claims description 13
- 238000004659 sterilization and disinfection Methods 0.000 title claims description 6
- 239000000203 mixture Substances 0.000 title description 15
- WDZLZBIKRZDKIE-UHFFFAOYSA-N ClN1C(N(C(C=2NC(NC1=2)=O)=O)[N+]#[C-])=O Chemical class ClN1C(N(C(C=2NC(NC1=2)=O)=O)[N+]#[C-])=O WDZLZBIKRZDKIE-UHFFFAOYSA-N 0.000 claims description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- 150000007524 organic acids Chemical class 0.000 claims description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 claims description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004327 boric acid Substances 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- 239000003826 tablet Substances 0.000 claims description 4
- 239000007938 effervescent tablet Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 150000004683 dihydrates Chemical class 0.000 claims description 2
- IFIDXBCRSWOUSB-UHFFFAOYSA-N potassium;1,3-dichloro-1,3,5-triazinane-2,4,6-trione Chemical compound [K+].ClN1C(=O)NC(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-N 0.000 claims description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
- 239000004299 sodium benzoate Substances 0.000 claims description 2
- 235000010234 sodium benzoate Nutrition 0.000 claims description 2
- 239000001384 succinic acid Substances 0.000 claims description 2
- 229950009390 symclosene Drugs 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims 1
- 235000015165 citric acid Nutrition 0.000 claims 1
- 235000011044 succinic acid Nutrition 0.000 claims 1
- 239000011975 tartaric acid Substances 0.000 claims 1
- 235000002906 tartaric acid Nutrition 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 6
- 239000011734 sodium Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000007937 lozenge Substances 0.000 description 2
- 235000010603 pastilles Nutrition 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- GHXRKGHKMRZBJH-UHFFFAOYSA-N boric acid Chemical compound OB(O)O.OB(O)O GHXRKGHKMRZBJH-UHFFFAOYSA-N 0.000 description 1
- -1 citric acid tartaric acid chloroisocyanuric derivative Chemical class 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940061368 sonata Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Description
page 1page 1
La présente invention concerne des compositions effervescentes chlorées destinées à être mises sous forme de pastilles pour un usage de désinfection.The present invention relates to chlorinated effervescent compositions intended to be put into the form of tablets for disinfection use.
Plus particulièrement, l'invention concerne des compositions effervescentes contenant un dérivé chloroisocyanurique.More particularly, the invention relates to effervescent compositions containing a chloroisocyanuric derivative.
5 Les dérivés chloroisocyanuriques ont d'excellentes propriétés dans le domaine de la désinfection mais ils ne se dissolvent que lentement dans l'eau.5 The chloroisocyanuric derivatives have excellent properties in the field of disinfection but they dissolve only slowly in water.
Un objet de la présente invention est de fournir des compositions pouvant être mises sous une forme de pastilles, qui sont faciles à stocker,ces pastilles étant effervescentes et se dissolvant rapidement dans l'eau sans qu'il 10 soit,en général, besoin d'une agitation.It is an object of the present invention to provide compositions which can be formed into lozenges, which are easy to store, these lozenges being effervescent and dissolving quickly in water without there being, in general, any need for agitation.
D'autres objets et avantages de l'invention apparaîtront à la lecture de la description ci-après.Other objects and advantages of the invention will appear on reading the description below.
Les compositions de la présente invention contiennent 15 à 70 % en poids, de préférence 20 à 50 % en poids, d'un dérivé chloroisocyanurique, de 15 15 à 40 % en poids, de préférence de 20 à 35 % en poids d'un bicarbonate alcalin, de 10 à 35 % en poids, de préférence de 15 à 35 % en poids, d'un acide organique et de 5 à 10 % en poids,de préférence 8 à 10 % en poids,d'un adjuvant de pastillage. :The compositions of the present invention contain 15 to 70% by weight, preferably 20 to 50% by weight, of a chloroisocyanuric derivative, 15 to 40% by weight, preferably 20 to 35% by weight of a alkaline bicarbonate, from 10 to 35% by weight, preferably from 15 to 35% by weight, of an organic acid and from 5 to 10% by weight, preferably 8 to 10% by weight, of a tableting aid . :
Ledit dérivé chloroisocyanurique peut être, par exemple, l'acide 20 trichloisocyanurique (ATCC), le dichloroisocÿanurate de sodium (DCCNa) sous forme anhydre ou sous forme de dihydrate, bu le dichloroisocyanurate de potassium.Said chloroisocyanuric derivative can be, for example, trichloisocyanuric acid (ATCC), sodium dichloroisocÿanurate (DCCNa) in anhydrous form or in the form of dihydrate, or potassium dichloroisocyanurate.
Ledit acide organique peut être choisi parmi les acides suivants : acide adipique, tartrique, citrique, succinique.Said organic acid can be chosen from the following acids: adipic, tartaric, citric, succinic acid.
25 Ledit adjuvant de pastillage est un adjuvant de type lubrifiant destiné à faciliter le démoulage, l'adjuvant de pastillage peut être choisi parmi l'acide borique, le benzoate de sodium, les stéarates, les silices, etc ...Said tabletting aid is a lubricating type aid intended to facilitate demolding, the tableting aid can be chosen from boric acid, sodium benzoate, stearates, silicas, etc.
Le bicarbonate alcalin est, par exemple, du bicarbonate de sodium.The alkaline bicarbonate is, for example, sodium bicarbonate.
La préparation des compositions selon l'invention, peut être effectuée 30 de la façon suivante : a) mélange du bicarbonate alcalin et de l'acide organique, b) addition du dérivé chloroisocyanurique et mélange, c) addition de l'adjuvant de pastillage et mélange,.The preparation of the compositions according to the invention can be carried out as follows: a) mixing the alkaline bicarbonate and the organic acid, b) adding the chloroisocyanuric derivative and mixing, c) adding the tableting aid and mixed,.
La charge homogène obtenue à l'étape c) est ensuite alimentée à un 35 pastilleur.The homogeneous load obtained in step c) is then fed to a pelletizer.
Les pastilles sont formées a une pression comprises en générai entre 200 et 1000 kg/cm2.The pellets are formed at a pressure generally between 200 and 1000 kg / cm2.
' Elles ont avantageusement un diamètre compris entre environ 15 et 30 mm et une épaisseur comprise environ entre 15 et 30 mm.'They advantageously have a diameter of between approximately 15 and 30 mm and a thickness of approximately between 15 and 30 mm.
page 2page 2
Selon une variante du procédé de préparation des pastilles selon l'invention, on effectue une première opération de pastillage après l'étape b), c'est-à-dire avant l'addition de l'adjuvant de pastillage et on broie les pastilles „ obtenues de façon à obtenir des granulés que l'on mélange avec l'adjuvant de 5 pastillage.Le mélange est soumis ensuite à une opération de pastillage.According to a variant of the process for preparing the pellets according to the invention, a first tableting operation is carried out after step b), that is to say before the addition of the tableting adjuvant and the pellets are ground „Obtained so as to obtain granules which are mixed with the tabletting aid. The mixture is then subjected to a tableting operation.
Cette variante (pastillage en deux temps) permet, toutes choses égales par ailleurs, d'obtenir des pastilles dont le temps d'effervescence est plus faible.This variant (pelletizing in two stages) allows, all other things being equal, to obtain pellets whose effervescence time is shorter.
La présente invention permet d'obtenir des pastilles dont le temps 10 d'effervescence est faible (compris en général entre 1 mn et 15 mn).The present invention makes it possible to obtain pellets whose effervescence time is short (generally between 1 min and 15 min).
» En outre, selon la présente invention, il est possible de régler le temps d'effervescence des pastilles en agissant sur les paramètres suivants : - Rapport composé chloroisocyanurique/mélange effervescent. Plus ce rapport est faible, plus le temps d'effervescence est faible.In addition, according to the present invention, it is possible to regulate the effervescence time of the pellets by acting on the following parameters: The lower this ratio, the shorter the effervescence time.
15 - Pression de pastillage. Plus la pression de pastillage est faible, plus le temps d'effervescence est faible.15 - Pellet pressure. The lower the tableting pressure, the shorter the effervescence time.
- L'écart par rapport à la stoecheométrie du mélange acide organique -bicarbonate alcalin. Plus cet écart est grand, plus le temps d'effervescence est élevé.- The deviation from the stoecheometry of the organic acid-alkaline bicarbonate mixture. The greater this difference, the greater the effervescence time.
20 - Le mode de préparation des pastilles, le pastillage en deux temps, conduisent à un temps d'effervescence plus faible.20 - The mode of preparation of the pastilles, the pastillage in two stages, leads to a lower effervescence time.
Les pastilles effervescentes préparées à partir des compositions selon la présente intention conviennent particulièrement bien à un usage dans la désinfection cpmme, par exemple, la désinfection des sols et des sanitaires.The effervescent tablets prepared from the compositions according to the present intention are particularly well suited for use in the same disinfection, for example, the disinfection of floors and sanitary facilities.
25 Les exemples suivants illustrent l'invention de façon non limitative.The following examples illustrate the invention without limitation.
ExempJeJExempJeJ
On alimente un mélangeur industriel avec 35 kg de bicarbonate de sodium et 35 kg d'acide citrique. On laisse mélanger pendant 10 mn. On ajoute ensuite 70 kg de dichloroisocyanurate de sodium (DCCNa)et on laisse mélanger 30 pendant 10 mn .On ajoute encore 10 kg d’acide borique et on laisse mélanger encore pendant 10 mn.An industrial mixer is supplied with 35 kg of sodium bicarbonate and 35 kg of citric acid. The mixture is left to mix for 10 min. 70 kg of sodium dichloroisocyanurate (DCCNa) are then added and the mixture is left to mix for 30 minutes. Another 10 kg of boric acid is added and the mixture is left to mix for another 10 minutes.
On obtient une charge homogène de 100 kg que l'on alimente dans un pastilleur travaillant à une pression de 435 kg/cm2.A homogeneous load of 100 kg is obtained which is fed into a pelletizer working at a pressure of 435 kg / cm2.
On obtient des pastilles de 5 g.5 g pellets are obtained.
35 Ces pastilles se dissolvent complètement dans 10 1 d'eau à 20°C en 2 mn 30 s J._x_e_mp_l_e__2 _à _5 _35 These pastilles dissolve completely in 10 1 of water at 20 ° C in 2 min 30 s J._x_e_mp_l_e__2 _à _5 _
On opère comme dans l'exemple 1, mais en faisant varier la nature et la proportion des constituants ainsi que la pression de pastillage. Les résultats ^0 sont donnés dans le tableau 1, ci après : --1-<- page 3 ! « ! ^ <u ! «J Q-The procedure is as in Example 1, but by varying the nature and the proportion of the constituents as well as the tableting pressure. The results ^ 0 are given in table 1, below: --1 - <- page 3! "! ^ <u! "J Q-
1 C Îr D1 C Îr D
•Λ ! hO^jbC’ïj&Û^ciû®" r- “ ! :|2 S.• Λ! hO ^ jbC’ïj & Û ^ ciû® "r-“!: | 2 S.
i u ÛJ flj ; (d x x η·« ·— ! xj (d cd I "" "' ' " 1,1 1 —«ΜΒ^^ηΜΒΗΙΜ····· I t ! 5 ' Qj ^ -j. I tiOXDDnÖoZtjß^ 1 -X Dû Π· Ύ u ^ S ^ ci u ÛJ flj; (dxx η · «· -! xj (d cd I" "" '' "1.1 1 -" ΜΒ ^^ ηΜΒΗΙΜ ····· I t! 5 'Qj ^ -j. I tiOXDDnÖoZtjß ^ 1 -X Due Π · Ύ u ^ S ^ c
• 1 <U .S f 1 π- ° C• 1 <U .S f 1 π- ° C
X : O +-J O Q.Oi<O.Xj- UJ N ItN-iAÜ-i 1-ΙΛΜ)X: O + -J O Q.Oi <O.Xj- UJ N ItN-iAÜ-i 1-ΙΛΜ)
Π X OΠ X O
i O (d JDi O (d JD
i XJi XJ
i i_ (U <Di i_ (U <D
' id x X'id x X
: .y ü u ; x td td ! ' Z w : . <u S «o ° ! bO^oc'-tic^tjCT c f'\iDü<lJDü.B'-*UDüS-„y ' X f ) .Mot J ! Otd^gu^XOL-r^: .y ü u; x td td! 'Z w:. <u S "o °! bO ^ oc'-tic ^ tjCT c f '\ iDü <lJDü.B' - * UDüS- „y 'X f) .Mot J! Otd ^ gu ^ XOL-r ^
* a- c m ” -< û —'O-3-CM* a- c m ”- <û —'O-3-CM
ω I O a; xi t XJ x 11-..-1 di ; (d u. x .y « û xi (d .ω I O a; xi t XJ x 11 -..- 1 di; (d u. x .y «û xi (d.
' | ! n! --j-1—“““““ (d i i 1)1 ! Si Z td i +J i ! qj CJ td i "d 3 / nj , Μ ω σ 60 f; bd - r i .γωχύ-Γ-χΰυχύϊΡ,^Ε'| ! not! --j-1— ““ ““ “(d i i 1) 1! If Z td i + J i! qj CJ td i "d 3 / nj, Μ ω σ 60 f; bd - r i .γωχύ-Γ-χΰυχύϊΡ, ^ Ε
rsj 1 +- h f I .¾ O Ersj 1 + - h f I .¾ O E
. ' «^(ΰ^ΐΙοχΟι-ΓΛ. '' ^ (Ϋ́ ^ ΐΙοχΟι-ΓΛ
x ; r^Cf^^CMÜ—> O -a- fMx; r ^ Cf ^^ CMÜ—> O -a- fM
UJ i Ο -H XUJ i Ο -H X
1 XJ „1 XJ „
I· !_ ÛJ (UI ·! _ ÛJ (U
' (d x x ; -H ‘G ‘u ; xi (d td'(d x x; -H ‘G‘ u; xi (d td
'! ÎN'! ÎN
! ‘ E! ‘E
: ^ ; QJ b0 1 3 Dû: ^; QJ b0 1 3 Due
i CTi CT
.y : ’ê ti . c-.y: ’ti. vs-
P ' E gF DC CP 'E gF DC C
rn ' c ra JS Jd £ ^ 1 IZI ^ γξ ξξ u X > (H U +J en ω ; S » g 8 g u . (d D- ‘ο a fc • tu c ο ° tl ^ • +- rd JJ X JJ ^rn 'c ra JS Jd £ ^ 1 IZI ^ γξ ξξ u X> (HU + J en ω; S »g 8 gu. (d D-' ο a fc • tu c ο ° tl ^ • + - rd JJ X DD ^
J - td uo SL TJ (DJ - td uo SL TJ (D
! g fe ü | g ^ XJ 'CJ P -!j ΐΛ > U (U > > CΛ Q.! g fe ü | g ^ XJ 'CJ P -! j ΐΛ> U (U>> CΛ Q.
1 (ΰ X ·- D <r. c i μ i- —. a; b1 (ΰ X · - D <r. C i μ i- -. A; b
] .P O 'CI X i— CD] .P O 'CI X i— CD
! . xj (d x (d ex page 4 _Ex_emple_6! . xj (d x (ex page 4 _Ex_ample_6
On opère avec Jes mêmes constituants et les mêmes quantités que dans l'exemple 4 mais on effectue la préparation des pastilles par double pastillage. On alimente le mélange industriel de l'exemple 1 avec 20 kg de 5 bicarbonate de sodium et 20 kg d'acide adipique. On laisse mélanger pendant 10 mn. On ajoute ensuite 50 kg de DCCNa et on laisse mélanger pendant 10 mn. On alimente la charge homogène obtenue dans un pastilleur et l'on broie les pastilles obtenues de façon à obtenir des granulés ayant un diamètre moyen d'environ 1 mm. On mélange les granulés avec 10 kg d'acide borique et 10 on alimente ce mélange homogène dans un pastilleur travaillant sous une pression de 540 kg/cm2. On obtient des pastilles de 5 g dont le temps d'effervescence est de 4 mn (alors qu'il était de 6 mn dans l'exemple 4).The operation is carried out with the same constituents and the same quantities as in Example 4, but the pellets are prepared by double pelleting. The industrial mixture of Example 1 is supplied with 20 kg of sodium bicarbonate and 20 kg of adipic acid. The mixture is left to mix for 10 minutes. 50 kg of DCCNa are then added and the mixture is left to mix for 10 minutes. The homogeneous load obtained is fed into a pelletizer and the pellets obtained are ground so as to obtain granules having an average diameter of approximately 1 mm. The granules are mixed with 10 kg of boric acid and this homogeneous mixture is fed into a pelletizer working under a pressure of 540 kg / cm2. 5 g pellets are obtained, the effervescence time of which is 4 min (whereas it was 6 min in Example 4).
_E_x_e_mpJ_e_s_ _7_ _e t_ _8_E_x_e_mpJ_e_s_ _7_ _e t_ _8
On opère comme dans l'exemple 1, mais en utilisant une installation à 15 humidité contrôlée, le dérivé chloroisocyanurique étant l'acide trichloroisocyanu-rique (ATCC).The procedure is as in Example 1, but using a humidity-controlled installation, the chloroisocyanuric derivative being trichloroisocyanuric acid (ATCC).
Les résultats sont donnés dans le tableau II ci-dessous : .The results are given in Table II below:
ii
Exemple Ex 7 Ex 8 f bicarbonate alcalin 35 kg 32 kg bicarbonate de Na bicar sonate de Na acide organique 21 kg 24 kg acide citrique acide tartrique dérivé chloroisocyanurique 36 kg 36 kgExample Ex 7 Ex 8 f alkaline bicarbonate 35 kg 32 kg Na bicarbonate Na bicar Na sonata organic acid 21 kg 24 kg citric acid tartaric acid chloroisocyanuric derivative 36 kg 36 kg
ATCC ATCCATCC ATCC
adjuvant de pastillage 3 kg 3 kg acide borique acide borique pression de pastillage 440 440 kg/cm2 temps d'effervescence 3 mn 2 mn 30 stableting aid 3 kg 3 kg boric acid boric acid tableting pressure 440 440 kg / cm2 effervescence time 3 min 2 min 30 s
Claims (4)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8500227A FR2575637B1 (en) | 1985-01-09 | 1985-01-09 | CHLORINE EFFERVESCENT COMPOSITIONS FOR DISINFECTION PELLETS |
| FR8500227 | 1985-01-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| LU86215A1 true LU86215A1 (en) | 1986-04-14 |
Family
ID=9315103
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LU86215A LU86215A1 (en) | 1985-01-09 | 1985-12-18 | CHLORINATED EFFERVESCENT COMPOSITIONS FOR DISINFECTION PELLETS |
Country Status (8)
| Country | Link |
|---|---|
| BE (1) | BE904011A (en) |
| CH (1) | CH668190A5 (en) |
| DE (1) | DE3545807A1 (en) |
| ES (1) | ES8800821A1 (en) |
| FR (1) | FR2575637B1 (en) |
| IT (1) | IT1182110B (en) |
| LU (1) | LU86215A1 (en) |
| NL (1) | NL8503450A (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE9314981U1 (en) * | 1993-10-02 | 1995-02-09 | Hüskens, Peter, 47839 Krefeld | Sanitary cleaner |
| ES2109871B1 (en) * | 1995-04-12 | 1998-08-16 | Salvador Nicolas Pedro | CHLORINATED DISINFECTANT PRODUCT FOR GENERAL CLEANING. |
| US5817337A (en) * | 1995-10-06 | 1998-10-06 | Desenna; Richard A. | Disinfectant effervescent tablet formulation |
| IL132780A0 (en) * | 1997-05-22 | 2001-03-19 | Zuccotto Ltd | A microbiocidal formulation |
| AU2002215169A1 (en) | 2000-11-16 | 2002-05-27 | Infowise Limited | Sanitizing composition containing chlorinated isocyanurate for in-ovo injection equipment |
| DE102005002553B3 (en) * | 2005-01-19 | 2006-03-30 | Bayrol Deutschland Gmbh | Chlorine-releasing tablets useful for chlorinating water comprise trichloroisocyanuric acid in granular form and anhydrous sodium dichloroisocyanurate in powder form |
| ES2321049B1 (en) * | 2007-10-10 | 2010-03-11 | Inquide, S.A.U. | ATCC (SYNCLOSENE) GRANULATED NON-COMBURENT FOR YOUR IMPROVED STORAGE AND TRANSPORTATION AND ITS MANUFACTURING PROCESS. |
| EP2414293A2 (en) * | 2009-03-31 | 2012-02-08 | Medentech Limited | A tablet composition |
| CN102396465A (en) * | 2011-11-15 | 2012-04-04 | 山东大明消毒科技有限公司 | Trichloroiminocyanuric acid effervescent tablet and preparation method thereof |
| RU2515829C1 (en) * | 2013-02-20 | 2014-05-20 | Закрачаева Татьяна Анатольевна | Scale removal composition |
| FR3099371A1 (en) * | 2019-07-29 | 2021-02-05 | Eurotab Operations | Small solid chlorinated disinfectant tablet |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3120378A (en) * | 1960-02-29 | 1964-02-04 | Procter & Gamble | Bleaching, sterilizing and disinfecting tablet and method of preparation |
| GB1165098A (en) * | 1968-03-25 | 1969-09-24 | H & T Kirby & Company Ltd | Improvements in the Preparation of Chlorine-Producing Bactericidal Compositions |
| GB1427710A (en) * | 1972-10-30 | 1976-03-10 | Maws Ltd | Disinfectant compositions |
| GB1505738A (en) * | 1975-02-26 | 1978-03-30 | Kirby Pharmaceuticals Ltd | Tabletting processes |
| JPS56142210A (en) * | 1980-04-09 | 1981-11-06 | Shikoku Chem Corp | Quickly soluble tablet having bactericidal, anti-infective and cleaning performance |
| JPS59219205A (en) * | 1983-05-27 | 1984-12-10 | Nissan Chem Ind Ltd | Production of expandable tablet |
-
1985
- 1985-01-09 FR FR8500227A patent/FR2575637B1/en not_active Expired - Fee Related
- 1985-12-14 NL NL8503450A patent/NL8503450A/en not_active Application Discontinuation
- 1985-12-18 LU LU86215A patent/LU86215A1/en unknown
- 1985-12-19 CH CH5419/85A patent/CH668190A5/en not_active IP Right Cessation
- 1985-12-23 DE DE19853545807 patent/DE3545807A1/en not_active Withdrawn
- 1985-12-23 IT IT48977/85A patent/IT1182110B/en active
- 1985-12-30 ES ES550574A patent/ES8800821A1/en not_active Expired
-
1986
- 1986-01-09 BE BE0/216114A patent/BE904011A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE3545807A1 (en) | 1986-07-10 |
| FR2575637A1 (en) | 1986-07-11 |
| ES8800821A1 (en) | 1987-12-01 |
| CH668190A5 (en) | 1988-12-15 |
| FR2575637B1 (en) | 1990-05-18 |
| IT8548977A0 (en) | 1985-12-23 |
| BE904011A (en) | 1986-07-09 |
| IT1182110B (en) | 1987-09-30 |
| ES550574A0 (en) | 1987-12-01 |
| NL8503450A (en) | 1986-08-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| LU86215A1 (en) | CHLORINATED EFFERVESCENT COMPOSITIONS FOR DISINFECTION PELLETS | |
| DE60203595T2 (en) | STABILIZED O-IODOXYBENZOIC ACID COMPOSITIONS AND METHOD FOR THE PRODUCTION THEREOF | |
| FR2723582A1 (en) | NEW AIR TRAINING AGENT. | |
| EP0181010B1 (en) | Process for sludge solidification | |
| US5908580A (en) | Chloroisocyanuric acid composition having reduced gas evolution | |
| EP0547923B1 (en) | Process for stabilising and solidifying incineration products of municipal waste, products resulting from this process and products for its implementation | |
| FR2735120A1 (en) | METHOD FOR IMMOBILIZATION OF RESIDUAL SLUDES CONTAINING METALS | |
| DE69423144T2 (en) | Pre-formulation for detergent composition based on polyimide and a silicate | |
| DE4428624A1 (en) | Cleaning and disinfecting compsn. contg. lactic acid bacteria | |
| DE2328778C2 (en) | Process for rendering waste materials harmless | |
| Worley et al. | The stability in water of a new chloramine disinfectant as a function of pH, temperature, and water quality 1 | |
| Masuyama et al. | Unique betaine types of surfactants bearing a 1, 3-dioxolane ring | |
| EP0555598B1 (en) | Composition for disinfecting water by means of electrochlorination and use of this composition | |
| Cabrera et al. | Comparative sorption and leaching study of the herbicides fluometuron and MCPA in a soil amended with biochars and other sorbents | |
| KR100812359B1 (en) | Composition for improving water quality and the method for improving water quality using the same | |
| BE842206R (en) | PROCESS FOR TREATMENT OF WASTE AND PRODUCTS OBTAINED | |
| US431528A (en) | Insecticide | |
| BE1000005A6 (en) | COMPOSITIONS sterilizing. | |
| OA21148A (en) | Process for manufacturing an ecological acrylic mosquito repellent paint based on chemical calcium carbonate purified by nano formulation of citronella essential oil. | |
| ES2113723T3 (en) | COMPOSITION FOR THE ELIMINATION OF LIMESTONE INCRUSTATIONS. | |
| EP2550103B1 (en) | Composition for regenerating resins | |
| FR2824551A1 (en) | PROCESS FOR THE CONDITIONING OR DEHYDRATION OF SLUDGE FROM THE PAPER OR AGRI-FOOD INDUSTRY | |
| FR2732249A1 (en) | Stabilising ash from incineration of mud from water purificn. plant for use as filler | |
| BE551502A (en) | ||
| WO2005042551B1 (en) | Humic acid metallic compound, preparation thereof, compositions containing same and use of said compound |