KR970705189A - 리튬 바나듐 펜톡사이드 양전극을 가진 리튬이온 배터리(lithium ion battery with lithium vanadium pentoxide positive electrode) - Google Patents

리튬 바나듐 펜톡사이드 양전극을 가진 리튬이온 배터리(lithium ion battery with lithium vanadium pentoxide positive electrode) Download PDF

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KR970705189A
KR970705189A KR1019970700961A KR19970700961A KR970705189A KR 970705189 A KR970705189 A KR 970705189A KR 1019970700961 A KR1019970700961 A KR 1019970700961A KR 19970700961 A KR19970700961 A KR 19970700961A KR 970705189 A KR970705189 A KR 970705189A
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positive electrode
liv
lithium
conductive material
battery
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차알스 알. 월크
네헤미아 마가리트
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케이. 브루스 해밀톤
트라코르 어플라이드 사이언시스 인코퍼레이티드
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Publication of KR970705189A publication Critical patent/KR970705189A/ko

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G31/00—Compounds of vanadium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/0459—Electrochemical doping, intercalation, occlusion or alloying
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
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    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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Abstract

리튬 이온 배터리는 음전극, 비수성 용매 및 전도성 물질과 혼합된 LiV2O5를 가지는 양전극으로 구성된다. 전도성 물질은 양전극에 대해 2 내지 20중량%인 탄소이다. 10 중량%가 선호된다. LiV2O5는 리튬 금속 음전극과 비수성 용매에 전해질염을 가진 전기 화학 반응기에서 V2O5와 전도성 물질의 혼합물을 방전시켜 V2O51몰당 1패러데이 만큼 환원시켜서 V2O5전부를 전환시킴으로써 형성된다. 전지는 LiV2O5양전극을 형성하고 제거되어 리튬 금속이 없는 전지에서 양전극으로 사용하도록 예정된 전극 구성으로 형성되기 위해서 2.8 볼트까지 방전된다.

Description

리튬 바나듐 펜톡사이드 양전극을 가진 리튬이온 배터리(LITHIUM ION BATTERY WITH LITHIUM VANADIUM PENTOXIDE POSITIVE ELECTRODE).
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 비수성 용매에 리튬을 포함한 전해질을 가지는 전기화학 반응기에서 V2O5의 혼합물과 리튬 금속을 포함한 전극을 전기 화학 반응시킴으로서 상기 혼합물을 환원시켜 상기 V2O5의 전부를 LiV2O5로 변화시켜 형성되며, 전도성 물질과 혼합되는 LiV2O5를 포함하는 리튬 이온 배터리용으로 유용한 양전극.
  2. 제 1 항에 있어서, 상기 전도성 물질이 상기 양전극에 대해 2내지 20중량%인 탄소임을 특징으로 하는 양전극.
  3. 제 2 항에 있어서, 상기 전지가 2.8 볼트까지 방전되어서 상기 LiV2O5양전극을 형성함을 특징으로 하는 양전극.
  4. 리튬이 없는 음전극: 비수성 용매: 및 전도성 물질과 혼합된 LiV2O5를 포함한 양전극을 포함하는 리튬 이온 전지로서 상기 LiV2O5는 비수성 용매에 리튬을 포함한 전해질이 있는 전지에서 리튬 금속함유 전극을 사용하여 V2O5혼합물을 상기 혼합물의 V2O51몰당 1패러데이만큼 전기화학적으로 환원시켜서 상기 V2O5전부를 LiV2O5로 전화시키고 상기 전기 화학적으로 형성된 LiV2O5를 상기 반응기에서 제거하고 상기 양전극을 형성하는 반응기 전지에서 LiV2O5를 형성한 후에 상기 LiV2O5가 상기 전지에 포함되며: V2O51몰당 리튬 이온 1몰이 상기 양전극에 있을 때 상기 음전극은 리튬 이온이 없는 전지.
  5. 제 4 항에 있어서, 상기 전도성 물질은 상기 양전극에 대해 2내지 20중량%인 탄소임을 특징으로 하는 전지.
  6. 제 5항에 있어서, 상기 반응기 전지는 2.8 볼트까지 방전되어서 상기 LiV2O5양전극을 형성함을 특징으로 하는 전지.
  7. 비수성 용매에 리튬 함유 전해질염과 리튬 금속함유 음전극을 가지는 전기화학 반응기 전지에서 V2O5와 전도성 물질의 혼합물을 방전시켜서 V2O51몰당 1패러데이만큼 환원시켜서 상기 V2O5의 전부를 전환시켜서 LiV2O5양전극 재료를 형성하고: 상기 양전극 재료를 상기 반응기 전지로 부터 제거하고: 상기 양전극 재료를 상기 양전극으로 형성하는 단계를 포함하는 리튬 이온 배터리용으로 유용한 양전극 제조방법.
  8. 제 7 항에 있어서, 상기 반응기 전지가 2.8 볼트까지 방전되어서 상기 LiV2O5양전극을 형성함을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970700961A 1994-08-19 1995-08-18 리튬 바나듐 펜톡사이드 양전극을 가진 리튬이온 배터리(lithium ion battery with lithium vanadium pentoxide positive electrode) KR970705189A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US29242794A 1994-08-19 1994-08-19
US08/292,427 1994-08-19
US08/420,294 US5496663A (en) 1994-08-19 1995-04-11 Lithium ion battery with lithium vanadium pentoxide positive electrode
US08/420,294 1995-04-11
PCT/US1995/011020 WO1996006465A1 (en) 1994-08-19 1995-08-18 Lithium ion battery with lithium vanadium pentoxide positive electrode

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US (2) US5496663A (ko)
EP (1) EP0778985B1 (ko)
JP (1) JPH10504932A (ko)
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AT (1) ATE188808T1 (ko)
AU (1) AU691972B2 (ko)
BR (1) BR9508725A (ko)
CA (1) CA2198031C (ko)
DE (1) DE69514531T2 (ko)
HK (1) HK1014225A1 (ko)
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EP0778985B1 (en) 2000-01-12
BR9508725A (pt) 1997-11-11
WO1996006465A1 (en) 1996-02-29
DE69514531T2 (de) 2000-08-24
JPH10504932A (ja) 1998-05-12
HK1014225A1 (en) 1999-09-24
DE69514531D1 (de) 2000-02-17
AU691972B2 (en) 1998-05-28
EP0778985A4 (en) 1997-11-12
EP0778985A1 (en) 1997-06-18
AU3499795A (en) 1996-03-14
US5567548A (en) 1996-10-22
US5496663A (en) 1996-03-05
ATE188808T1 (de) 2000-01-15
NZ292732A (en) 1999-01-28
CA2198031A1 (en) 1996-02-29
CA2198031C (en) 2000-10-31

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