KR970700545A - 개질된 mcm-22 촉매 조성물(improved mcm-22 catalyst composition) - Google Patents

개질된 mcm-22 촉매 조성물(improved mcm-22 catalyst composition)

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Publication number
KR970700545A
KR970700545A KR1019960704112A KR19960704112A KR970700545A KR 970700545 A KR970700545 A KR 970700545A KR 1019960704112 A KR1019960704112 A KR 1019960704112A KR 19960704112 A KR19960704112 A KR 19960704112A KR 970700545 A KR970700545 A KR 970700545A
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KR
South Korea
Prior art keywords
catalyst composition
ammonium
phosphorus
catalytic cracking
contacting
Prior art date
Application number
KR1019960704112A
Other languages
English (en)
Other versions
KR100326413B1 (ko
Inventor
주니어 토마스 프란시스 데그난
룬 안토니 흥 시우
해리 하치코스 조지
존 케네디 고든
앤 코월스키 조슬린
Original Assignee
맬컴 디. 킨
모빌 오일 코오포레이숀
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 맬컴 디. 킨, 모빌 오일 코오포레이숀 filed Critical 맬컴 디. 킨
Publication of KR970700545A publication Critical patent/KR970700545A/ko
Application granted granted Critical
Publication of KR100326413B1 publication Critical patent/KR100326413B1/ko

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

본 발명은 MCM-22의 구조를 가진 다공성 결정형 물질에 인, 임의로는 매트릭스 물질을 첨가함에 따라 제조된 촉매 조성물에 관한 것이다. MCM-22에 인을 첨가하면 제조된 촉매의 열수 안정성이 향상되는 것으로 밝혀졌다. 개질된 촉매는 유기 전환 공정, 예를 들면 촉매적 크래킹 공정에 유용하다.

Description

개질된 MCM-22 촉매 조성물(IMPROVED MCM-22 CATALYST COMPOSITION)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 값을 비롯한 X-선 회절 패턴을 가진 제올라이트와 혼합된 인을 포함하는 촉매 조성물:
  2. 제1항에 있어서, 매트릭스 물질을 부가로 포함하는 촉매 조성물.
  3. 제1항 또는 제2항에 있어서, 촉매적 크래킹 성분을 부가로 포함하는 촉매 조성물.
  4. 제3항에 있어서, 촉매적 크래킹 성분이 1 미만의 제한 지수를 가진 분자체 및 가공 크기가 13 내지 200Å인 중간 가공의 결정형 물질중에서 선택되는 촉매 조성물.
  5. 제1항 내지 제4항중 어느 한항에 있어서, 인 성분의 함량이 약 0.1중량% 이상인 촉매 조성물.
  6. 상기 제올라이트를 인 원료와 접촉시키는 단계; 및 인 변성된 제올라이트로부터 촉매 입자를 형성하는 단계를 포함하는 제1항 내지 제5항중 어느 한항의 촉매 조성물의 제조방법.
  7. 제6항에 있어서, 인의 원료가 암모늄 모노하이드로젠 인산염, 암모늄 디하이드로젠 인산염, 트리암모늄 인산염, 암몬늄 아인산염, 암모늄 오르토인산염, 암모늄 디하이드로젠 오르토인산염, 암모늄 모노하이드로젠 오르로인산임.
    암모늄 차아인산염, 암모늄 디하이드로젠 오르토아인산염, 인산 및 이들의 혼합물중에서 선택되는 방법.
  8. 제1항 내지 제5항중 어느 한항의 촉매 조성물과 탄화수소 공급 원료를 접촉시킴으로써 탄화수소 공급 원료를 전환시키는 방법.
  9. 중 탄화수소 공급원료와 제3항 또는 제4항의 촉매 조성물을 접촉시키는 단계를 포함하는 촉매적 크래킹 방법.
KR1019960704112A 1994-02-02 1995-01-25 개질된mcm-22촉매조성물 KR100326413B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/190,438 1994-02-02
US08/190,438 US5470810A (en) 1994-02-02 1994-02-02 Catalyst and method of manufacture
PCT/US1995/000991 WO1995021021A1 (en) 1994-02-02 1995-01-25 Improved mcm-22 catalyst composition

Publications (2)

Publication Number Publication Date
KR970700545A true KR970700545A (ko) 1997-02-12
KR100326413B1 KR100326413B1 (ko) 2002-08-08

Family

ID=22701362

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960704112A KR100326413B1 (ko) 1994-02-02 1995-01-25 개질된mcm-22촉매조성물

Country Status (9)

Country Link
US (1) US5470810A (ko)
EP (1) EP0741608B1 (ko)
JP (1) JP3801627B2 (ko)
KR (1) KR100326413B1 (ko)
AU (1) AU688464B2 (ko)
DE (1) DE69526069T2 (ko)
ES (1) ES2173178T3 (ko)
TW (1) TW274060B (ko)
WO (1) WO1995021021A1 (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100446441B1 (ko) * 1996-11-08 2004-11-03 에스케이 주식회사 비결정성중형다공성분자체물질의제조방법
KR100443562B1 (ko) * 1997-02-26 2004-09-18 에스케이 주식회사 중형다공성 분자체 물질의 제조 방법 및 그 분자체 물질
US5888378A (en) * 1997-03-18 1999-03-30 Mobile Oil Corporation Catalytic cracking process
US6080303A (en) * 1998-03-11 2000-06-27 Exxon Chemical Patents, Inc. Zeolite catalyst activity enhancement by aluminum phosphate and phosphorus
US7038100B2 (en) * 2001-04-30 2006-05-02 Exxonmobil Chemical Patents, Inc. Aromatics alkylation
WO2006107462A1 (en) * 2005-03-31 2006-10-12 Exxonmobil Chemical Patents Inc. Process and catalyst for the transalkylation of aromatics
JP5383184B2 (ja) * 2005-04-27 2014-01-08 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット 流動接触分解時にＮＯｘ排出物を低減する組成物および方法
US7517824B2 (en) * 2005-12-06 2009-04-14 Exxonmobil Chemical Company Process for steam stripping hydrocarbons from a bromine index reduction catalyst

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US3972832A (en) * 1974-09-23 1976-08-03 Mobil Oil Corporation Phosphorus-containing zeolite catalyst
US4584091A (en) * 1984-12-13 1986-04-22 Exxon Research And Engineering Co. Cracking with co-matrixed zeolite and p/alumina
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US5231064A (en) * 1991-03-12 1993-07-27 Mobil Oil Corp. Cracking catalysts comprising phosphorus and method of preparing and using the same
US5110776A (en) * 1991-03-12 1992-05-05 Mobil Oil Corp. Cracking catalysts containing phosphate treated zeolites, and method of preparing the same
US5232579A (en) * 1991-06-14 1993-08-03 Mobil Oil Corporation Catalytic cracking process utilizing a zeolite beta catalyst synthesized with a chelating agent
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ES2076068B1 (es) * 1993-03-17 1996-06-16 Consejo Superior Investigacion Procedimiento de preparacion de catalizadores a base de zeolitas tratadas con acido fosforico, utiles para su aplicacion en unidades de craqueo catalitico.

Also Published As

Publication number Publication date
EP0741608B1 (en) 2002-03-27
US5470810A (en) 1995-11-28
KR100326413B1 (ko) 2002-08-08
JPH09508571A (ja) 1997-09-02
AU688464B2 (en) 1998-03-12
AU1690495A (en) 1995-08-21
DE69526069D1 (de) 2002-05-02
EP0741608A1 (en) 1996-11-13
JP3801627B2 (ja) 2006-07-26
WO1995021021A1 (en) 1995-08-10
ES2173178T3 (es) 2002-10-16
DE69526069T2 (de) 2002-12-19
EP0741608A4 (en) 1998-01-07
TW274060B (ko) 1996-04-11

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