KR960705987A - 화학적 연화제 조성물 및 결합제 물질을 포함한 다겹 화장지 제품(multi-ply facial tissue paper product comprising chemical softening compositions and binder materials) - Google Patents

화학적 연화제 조성물 및 결합제 물질을 포함한 다겹 화장지 제품(multi-ply facial tissue paper product comprising chemical softening compositions and binder materials)

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Publication number
KR960705987A
KR960705987A KR1019960702050A KR19960702050A KR960705987A KR 960705987 A KR960705987 A KR 960705987A KR 1019960702050 A KR1019960702050 A KR 1019960702050A KR 19960702050 A KR19960702050 A KR 19960702050A KR 960705987 A KR960705987 A KR 960705987A
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South Korea
Prior art keywords
toilet paper
paper product
fibers
ply
strength binder
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KR1019960702050A
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English (en)
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KR100336065B1 (ko
Inventor
와드 윌리암 오스튼도르프
스티븐 로버트 켈리
폴 데니스 트로칸
딘 반 판
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제이코버스 코넬리스 레이서
더 프록터 앤드 갬블 캄파니
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07—Nitrogen-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22—Agents rendering paper porous, absorbent or bulky
    • D21H21/24—Surfactants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply

Landscapes

  • Paper (AREA)
  • Sanitary Thin Papers (AREA)

Abstract

화학적 연화제 조성물, 및 영구적 또는 일시적인 습윤 강도 결합제와 건조 강도 결합제의 혼합물을 포함한 다겹 화장지 제품을 개시한다. 다겹 화장지 제품은 4차 암모늄 화합물 및 폴리하이드록시 화합물의 혼합물을 포함하는 화학적 연화제 조성물을 함유한다. 바람직한 4차 암모늄 화합물은 디(수소화)탈로우 디메틸 암모늄 클로라이드 및/또는 디(수소화)탈로우 디메틸 암모늄 메틸 설페이트와 같은 디알킬 디메틸 암모뮴 염을 포함한다. 바람직한 폴리하이드록시 화합물은 글리세롤, 약 150 내지 약800의 중량 평균 분자량을 갖는 폴리글리세롤, 약 200 내지 약 1000의 중량 평균 분자량을 갖는 폴리옥시에틸렌 글리콜 및 폴리옥시프로필렌 글리콜로 구성된 그룹에서 선택된다. 다겹 화장지 제품은 린팅 제어 및/또는 화학적 연화제 조성물의 사용으로 인한 인장 강도의 손실(발생한다면)을 상쇄하는데 효과적인 양의 영구적 및/또는 일시적인 건조 강도 결합제 및 습윤 강도 결합제를 함유한다. 영구적 및/또는 일시적인 습윤 강도 결합제 및 건조 결합제 둘모두의 사용이 시이트에서 화학적 연화제 조성물의 잔류를 개선시킨다. 바람직하게는 화학적 연화제 조성물의 대부분은 가장 효과적인 장소인 다겹 화장지 제품의 외층에 위치된다. 다르게 말하면, 화학적 연화제 조성물 및 영구적 또는 일시적인 습윤 강도 결합제 및 건조 강도 결합제는 특정한 층 또는 겹의 부드러움, 흡수성 및/또는 린트 내성을 개선시키기 위해 다겹 화장지 제품내부에 선택적으로 분포될 수 있다.

Description

화학적 연화제 조성물 및 결합제 물질을 포함한 다겹 화장지 제품(MULTI-PLY FACIAL TISSUE PAPER PRODUCT COMPRISING CHEMICAL SOFTENING COMPOSITIONS AND BINDER MATERIALS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따른 이겹, 이층 화장지의 개략적인 단면도, 제2도는 본 발명에 따른 세겹, 단층 화장지의 개략적인 단면도, 제3도는 바람직한 공중합체 제지 벨트의 불규칙한 직조 패턴 단위의 반복되는 셀의 평면도이다.

Claims (10)

  1. a)제지 섬유; b)0.01 내지 3.0%의 하기 일반식의 4차 암모늄 화합물;
    (상기 식에서, R2치환제 각각은 C1-C6알킬, 하이드록시알킬 그룹 또는 이들의 혼합물, 바람직하게는 C1-C3알킬이고, 가장 바람직하게는 메틸이고; R1치환제 각각은 C14-C22하이드로카빌 그룹 또는 이들의 혼합물이고, 바람직하게는 C16-C18알킬이고; 및 X-는 적합한 음이온, 바람직하게는 클로라이드 또는 메틸 설페이트이다). c)0.01 내지 3.0%의 수용성 폴리하이드록시 화합물(이때, 상기 폴리하이드록시 화합물은 바람직하게는 글리세롤, 150 내지 800의 중량 평균 분자량을 갖는 폴리글리세롤, 및 200 내지 1000, 바람직하게는 200 내지 600의 중량 평균 분자량을 갖는 폴리옥시에틸렌 글리콜 및 폴리옥시프로필렌 글리콜, 및 이들의 혼합물로 구성된 그룹에서 선택된다); d)0.01내지 3.0%의 영구적 또는 일시적인 습윤 강도 결합제(이때 상기 연구적 습윤 강도 결합제는 바람직하게는 폴리아미드-에피클로하이드린 수지, 폴리아크릴아미드 수지 및 이들의 혼합물에서 선택되고, 가장 바람직하게는 폴리아미드-에피클로로하이드린 수지이고, 상기 일시적인 습윤 강도 결합제는 바람직하게는 양이온성 디알데하이드 전분계 수지, 디알데하이드 전분 수지 및 이들의 혼합물에서 선택되고, 가장 바람직하게는 폴리아미드-에피클로하이드린 수지이고, 상기 일시적인 습윤 강도 결합제는 바람직하게는 양이온성 디알데하이드 전분계 수지, 디알데히드 전분 수지 및 이들의 혼합물에서 선택되고, 가장 바람직하게는 양이온성 디알데하이드 전분계 수지이다); 및 e)0.01 내지 3.0%의 건조 강도 결합제(바람직하게는 카복시메틸 셀룰로즈 수지, 전분계 수지 및 이들의 혼합물에서 선택되고, 가장 바람직하게는 카복시메틸 셀룰로즈 수지이다)를 포함하는 다겹 화장지 제품.
  2. 제1항에 있어서, 2개 이상의 겹을 갖고, 이때 상기 겹 각각이 2개 이상의 겹친 층, 즉 내층 및 상기 내층에 인접한 외층을 포함하고, 상기 다겹 화장지 제품은 바람직하게는 병렬인 두개의 겹을 포함하고, 상기 겹은 각 겹의 외층이 상기 다겹 화장치의 하나의 노출된 표면을 형성하고 상기 겹의 상기 내층 각각이 상기 화장지 제품의 내부를 향하도록 배치되게 상기 화장지에서 배향되는 다겹 화장지 제품.
  3. 제2항에 있어서, 4차 암모늄 화합물 및 폴리하이드록시 화합물의 대부분이 상기 겹의 상기 외층중의 하나이상, 바람직하게는 상기 외층 둘다에 함유되고; 습윤 강도 결합제 및 건조 강도 결합제의 대부분이 상기 내층 중의 하나 이상, 바람직하게는 상기 내층 둘다에 함유된 다겹 화장지 제품.
  4. 제2항 또는 제3항에 있어서, 상기 2개의 내층 각각이 약 2.0mm이상의 평균 길이를 갖는 비교적 긴 제지 섬유, 바람직하게는 연질 목재 섬유, 가장 바람직하게는 노던 연질 목재 섬유를 포함하고; 상기 2개의 외층 각각이 약 0.2mm 내지 약 1.5mm의 평균 길이를 갖는 비교적 짧은 제지 섬유, 바람직하게는 경질 목재 섬유, 가장 바람직하게는 유칼립투스 섬유를 포함하는 다겹 화장지 제품.
  5. 제2항 내지 제4항 중 어느 한 항에 있어서, 상기 내층이 연질 목재 섬유, 또는 연질 목재 섬유와 저가 섬유의 혼합물을 포함하고, 상기 외층중의 하나 이상이 저가 섬유, 또는 경질 목재와 저가 섬유의 혼합물을 포함하고, 이때 상기 저가 섬유가 설파이트 섬유, 열기계적 펄프 섬유, 화학-열기계적 펄프 섬유, 재활용 섬유, 및 이들의 혼합물에서 선택되는 다겹 화장지 제품.
  6. 제1항 내지 제5항 중 어느 한 항에 있어서, 상기 4차 암모늄 화합물이 디 (수소화)탈로우 디메틸 암모늄클로라이드 또는 디(수소화)탈로우 디메틸 암모늄 메틸 설페이트인 다겹 화장지 제품.
  7. 제1항 내지 제6항 중 어느 한 항에 있어서, 4차 암모늄 화합물 대 폴리하이드록시 화합물의 중량비가 약 1.0:0.1 내지 0.1:1.0의 범위인 다겹 화장지 제품.
  8. 제1항에 있어서, 상기 화장지 제품이 병렬인 세겹, 즉 두개의 외겹 및 하나의 내겹을 포함하고, 이때 상기 내겹이 상기 2개의 외겹 사이에 위치하고, 상기 두개의 외겹 각각이 바람직하게는 2개의 겹친 층을 포함하고, 상기 세겹 각각이 단층 웹을 포함하고, 이때 상기 내겹이 바람직하게는 긴 연질 목재 섬유를 포함하고 상기 외겹이 바람직하게는 짧은 경질 목재 섬유를 포함하는 다겹 화장지 제품.
  9. 제8항에 있어서, 4차 암모늄 화합물 및 폴리하이드록시 화합물의 대부분이 2개의 상기 외겹에 함유되고, 상기 영구적 습윤 강도 결합제 및 건조 강도 결합제의 대부분이 상기 내겹에 위치하는 다겹 화장지 제품.
  10. 제1항 내지 제9항 중 어느 한 항에 있어서, 상기 4차 암모늄 화합물이 디(수소화)탈로우 디메틸 클로라이드 또는 메틸설페이트이고, 상기 폴리하이드록시 화합물이 200 내지 600의 중량 평균 분자량을 갖는 폴리옥시 에틸렌 글리콜이고, 상기 영구적 습윤 강도 결합제가 폴리아미드-에피클로로하이드린 수지이고, 상기 건조 강도 결합제가 카복시메틸 셀룰로즈 수지인 다겹 화장지 제품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960702050A 1993-10-22 1994-10-17 화학적연화제조성물및결합제물질을포함한다겹화장지제품 KR100336065B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/140,571 1993-10-22
US08/140,571 US5397435A (en) 1993-10-22 1993-10-22 Multi-ply facial tissue paper product comprising chemical softening compositions and binder materials
PCT/US1994/011845 WO1995011344A1 (en) 1993-10-22 1994-10-17 Multi-ply facial tissue paper product comprising chemical softening compositions and binder materials

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Publication Number Publication Date
KR960705987A true KR960705987A (ko) 1996-11-08
KR100336065B1 KR100336065B1 (ko) 2002-11-20

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US (1) US5397435A (ko)
EP (1) EP0724665A1 (ko)
JP (1) JP3183890B2 (ko)
KR (1) KR100336065B1 (ko)
CN (1) CN1046777C (ko)
AU (1) AU698951B2 (ko)
BR (1) BR9407878A (ko)
CA (1) CA2173715A1 (ko)
CZ (1) CZ114696A3 (ko)
EG (1) EG20517A (ko)
FI (1) FI961712A (ko)
HU (1) HUT77995A (ko)
MY (1) MY111615A (ko)
NO (1) NO961556L (ko)
NZ (1) NZ275262A (ko)
SG (1) SG52689A1 (ko)
TR (1) TR27852A (ko)
TW (1) TW305003B (ko)
WO (1) WO1995011344A1 (ko)

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TR27852A (tr) 1995-09-04
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EP0724665A1 (en) 1996-08-07
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BR9407878A (pt) 1996-10-29
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US5397435A (en) 1995-03-14
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HU9601032D0 (en) 1996-06-28
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