KR960701738A - 다공성 세라믹 재료의 제조 방법(Method For Forming Porous Ceramic Materials) - Google Patents

다공성 세라믹 재료의 제조 방법(Method For Forming Porous Ceramic Materials)

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Publication number
KR960701738A
KR960701738A KR1019950704476A KR19950704476A KR960701738A KR 960701738 A KR960701738 A KR 960701738A KR 1019950704476 A KR1019950704476 A KR 1019950704476A KR 19950704476 A KR19950704476 A KR 19950704476A KR 960701738 A KR960701738 A KR 960701738A
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KR
South Korea
Prior art keywords
sol
gel
substituted
porous ceramic
prepared
Prior art date
Application number
KR1019950704476A
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English (en)
Inventor
마크 에이. 앤더슨
릭신 츄
니콜라스 제이. 시이
Original Assignee
리차드 리저
위스콘신 앨럼나이 리서치 파운데이숀
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 리차드 리저, 위스콘신 앨럼나이 리서치 파운데이숀 filed Critical 리차드 리저
Publication of KR960701738A publication Critical patent/KR960701738A/ko

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0045—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by a process involving the formation of a sol or a gel, e.g. sol-gel or precipitation processes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/624—Sol-gel processing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Silicon Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Glass Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)

Abstract

넓은 표면적을 갖는 열 안정성 미세 다공성 세라믹 재료를 제조하는 방법은 실리카(실리큰 디윽사이드)를 함유하는 졸 또는 겔의 실리큰 일부를 기타 다른 금속의 양이온으로 대체하는 것을 포함한다. 금속으로 치환된 실리카 졸을 건조하고 하소시켜 다공성 세라믹 재료를 만든다. 이와 유사하게, 금속으로 치환된 겔을 하소시켜 다공성 세라믹 재료를 만든다. 치환시키지 아니한 실리카 재료와 비교하였을 때, 이렇게 제조된 재료는, 염기성 환경하에서의 안정성이 향상되고, 열 안정성이 개선되며, 고유의 음의 하천과 같은 유리한 표면 특성을 포함하는 유리한 장점들을 제공한다.

Description

다공성 세라믹 재료의 제조 방법 (Method For Forming Porous Ceramic Materials)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 Al이 2.5%, 5%, 7.5% 및 10%인 표면 Al/Si 비율을 갖는 알루미노실리케이트 겔의 질소 흡착 곡선을 나타낸다.
제2도는, 다양한 하소 온도로 하소 시킨 후의 순수한 실리카 다공성 세라믹 재료와 실리큰의 대해 2.5%의 알루미늄을 함유하는 다공성 세라믹 재료들의 비표면적을 도시한 것이다.
제3도는 강 염기로 처리한 후의 알루미노실리케이트 겔의 비표면적을 유지하는 능력을 도시한다. 순수한 실리카 겔의 강 염기내에서의 안정성도 도시하였다.
제4도는 실리카 매트릭스 표면에서의 알루미늄 양이온의 실리큰 치환을 나타내는, 다양한 pH값에서의 알루미노실리케이트와 실리카 겔의 전기 영동 이동성을 나타낸다.

Claims (29)

  1. 매트릭스에 배열된 이산화규소 입자로 이루어진 산성화된 실리카 졸을 제공하고; 산성화된 졸과 금속 양이온을 함유하는 충분한 양의 용액을 혼합하여 입자 표면에서의 매트릭스의 실리큰의 일부분이 금속 양이온으로 대체된 치환된 졸을 제조하고; 치환된 졸을 건조하여 겔을 만들고; 그리고 다공성 세라믹 재료가 만들어질 때까지 겔을 하소시키는 단계들로 이루어진 다공성 세라믹 재료의 제조 방법.
  2. 제1항에 있어서, 산성화된 졸이 암모니아 촉매 가수 분해와 앝킬 실리케이트 축합에 의해 제조되는 방법.
  3. 제2항에 있어서, 알킬 실리케이트가 TMOS와 TEOS로 이루어진 군에서 선택되는 방법.
  4. 제1항에 있어서, 산성화된 졸이 질산 촉매 가수 분해와 알킬 실리케이트 축합에 의해 제조되는 방법.
  5. 제4항에 있어서, 알킬 실리케이트가 TMOS와 TEOS로 이루어진 군에서 선택되는 방법.
  6. 제1항에 있어서, 산성화된 졸의 pH가 3인 방법.
  7. 제1항에 있어서, 금속이 알루미늄인 방법.
  8. 제7항에 있어서, 용액이 수성 알루미늄 니트레이트인 방법.
  9. 제1항에 있어서, 금속 양이온으로 치환된 실리큰의 일부분이 1% 내지 5%인 방법.
  10. 제1항에 있어서, 건조 단계가 건조제를 담고 있는 건조기내에 치환된 졸을 넣어두는 것으로 달성되는 방법.
  11. 제10항에 있어서, 건조제가 MgC12·6H2O인 방법.
  12. 매트릭스에 배열된 실리큰 디옥사이드의 입자로 이루어진 졸로부터 제조된 소결된 다공성 실리카 겔을 제공하고; 이 실리카 겔을 금속 양이온을 함유하는 충분한 양의 용액에 담가서 겔 표면의 실리큰의 일부분이 금속 양이온으로 대체된 치환된 겔을 제조하고; 치환된 겔을 건조하고; 그리고 다공성 세라믹 재료가 만들어질 때까지 이 겔을 하소시키는 단계들로 이루어지는, 다공성 세라믹 재료 제조 방법.
  13. 제12항에 있어서, 소결된 다공성 실리카 겔이 암모니아 촉매 가수분해와 알킬 실리케이트의 축합으로 제조된 분체 실리카 졸로부터 제조되는 방법.
  14. 제12항에 있어서, 졸이 질산 촉매 가수분해와 알킬 실리케이트의 축합으로 제조되는 방법.
  15. 제12항에 있어서, 금속이 알루미늄인 방법.
  16. 제15항에 있어서, 용액이 알루미늄 니트레이트인 방법.
  17. 제12항에 있어서, 건조 단계가 실온 내지 40℃ 범위의 온도에서 밤새워 진행되는 방법.
  18. 제12항에 있어서, 하소 단계가 약 200℃에서 약 1시간 동안 진행되는 방법.
  19. 제1항의 방법에 따라 제조된 다공성 세라믹 재료.
  20. 제19항에 있어서, 금속이 알루미늄인 다공성 세라믹 재료.
  21. 제12항의 방법에 따라 제조된 다공성 세라믹 재료.
  22. 제21항에 있어서, 금속이 알루미늄인 다공성 세라믹 재료.
  23. 재료 표면에서 1% 내지 5% Al/Si비율을 가지며 20Å이하의 평균 구멍 직경을 갖는 알루미노실리케이트 다공성 세라믹 재료.
  24. 입자 표면에서 매트릭스의 실리큰 일부분이 금속 양이온으로 대체된, 매트릭스에 배열된 실리큰 디옥사이드 입자로 이루어진 치환된 실리카졸.
  25. 제24항에 있어서, 금속 양이온으로 대체된 실리큰 일부분이 1% 내지 5%범위인 치환된 실리카 졸.
  26. 제24항에 있어서, 금속이 알루미늄인 치환된 실리카 졸.
  27. 제24항의 졸로부터 제조된 겔.
  28. 제25항의 졸로부터 제조된 겔.
  29. 제26항의 졸로부터 제조된 겔.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950704476A 1994-02-14 1995-01-19 다공성 세라믹 재료의 제조 방법(Method For Forming Porous Ceramic Materials) KR960701738A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/196,341 1994-02-14
US08/196,341 US5439624A (en) 1994-02-14 1994-02-14 Method for forming porous ceramic materials
PCT/US1995/000893 WO1995021736A1 (en) 1994-02-14 1995-01-19 Method for forming porous ceramic materials

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KR960701738A true KR960701738A (ko) 1996-03-28

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Country Status (6)

Country Link
US (4) US5439624A (ko)
EP (1) EP0701506A4 (ko)
JP (1) JPH08509199A (ko)
KR (1) KR960701738A (ko)
AU (1) AU1606295A (ko)
WO (1) WO1995021736A1 (ko)

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US5610109A (en) 1997-03-11
US5712037A (en) 1998-01-27
EP0701506A4 (en) 1997-05-07
US5639412A (en) 1997-06-17
AU1606295A (en) 1995-08-29
JPH08509199A (ja) 1996-10-01
US5439624A (en) 1995-08-08
EP0701506A1 (en) 1996-03-20
WO1995021736A1 (en) 1995-08-17

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