KR960040155A - 방오제로서 피롤 화합물의 용도 - Google Patents

방오제로서 피롤 화합물의 용도 Download PDF

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KR960040155A
KR960040155A KR1019960017418A KR19960017418A KR960040155A KR 960040155 A KR960040155 A KR 960040155A KR 1019960017418 A KR1019960017418 A KR 1019960017418A KR 19960017418 A KR19960017418 A KR 19960017418A KR 960040155 A KR960040155 A KR 960040155A
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pyrrole
carbonitrile
trifluoromethyl
bromo
para
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아아서 조오세파 반 데르 플라스 마아크
스티븐 크로올리 랜쯔
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윌리엄 에이취 캘넌
아메리칸 사이아나밋드 캄파니
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
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    • C09D5/16—Antifouling paints; Underwater paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612—Non-macromolecular compounds
    • C09D5/1625—Non-macromolecular compounds organic

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Abstract

본원에서는 부착성 생물과 방오-효과량의 2-아릴피롤 화합물을 접촉시키는 것으로 특징지워지는 수중 표면에 대한 부착성 생물의 부착을 구제 또는 퇴치하는 방법을 제공한다. 해수 및 담수 부탁성 생물에 의한 오염으로부터 수중 구조물을 보호하는 방법 이를 위한 방오 조성물 또한 제공된다.

Description

방오제로서 피롤 화합물의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 부착성 생물을 방오-유효량의 일반식(Ⅰ)의 화합물과 접촉시킴을 특징으로 하여, 수중 표면의 부착성 생물의 부착을 퇴치 또는 구제하는 방법.
    상기 식에서, X는 할로겐, CN, NO2또는 S(O)nR1이고; Y는 수소, 할로겐 또는 S(O)nR1이며; Z는 할로겐, C1-C4할로알킬 또는 S(O)nR1이며; n은 0,1 또는 2의 정수이며; R1은 C1-C4할로알킬이며; L은 수소 또는 할로겐이며; M 및 Q는 각각 독립적으로 수소, 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4-알콕시, C1-C4알킬티오, C1-C4알킬설피닐, C1-C4알킬설포닐, CN, NO2, R2CO 또는 NR3R4이거나 M 및 Q가 근접한 위치에 있고 이들이 부착된 탄소원자와 함께 취해질때 MQ는 -OCH2O-, OCF2O- 또는 -CH=CH-CH=CH-의 구조를 나타내며; R은 수소, C1-C4알콕시알킬, C1-C4알킬티오 또는 R6CO이며; R2는 C1-C4알킬, C1-C4할로알킬, C1-C4알콕시 또는 NR3R4이며; R3는 수소 또는 C1-C4알킬이며; R4는 수소 C1-C4알킬 또는 R5CO이며; R5는 수소 또는 C1-C4알킬이며; R6는 C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C2-C6알케닐옥시, C1-C4할로알콕시, 1 내지 3개의 C1-C4알킬기로 임의로 치환된 페닐, 벤질, 페녹시, 벤질옥시, C1-C4알킬카보닐옥시, C3-C6시클로알킬, 나프틸, 피리딜, 티에닐 또는 푸라닐이다.
  2. 제1항에 있어서, 부착성 생물이 바나클, 지브라 머슬스, 조류, 규조류, 히드로층, 브리오조아, 아시디안스, 튜브웜 및 아시아 대합조개로 이루어진 그룹 중에서 선택되는 방법.
  3. 제1항에 있어서, 일반식(Ⅰ)의 화합물이 4,5-디클로로-2-(a,a,a-트리플루오로-파라-트릴)피롤-3-카보니트릴; 4-브로모-5-클로로-2-(파라-클로로페닐)피롤-3-카보니트릴; 4-브로모-2-(파라-클로로페닐)-5-(트리플루오로메틸)피롤-3-카보니트릴; 3,4-디클로로-2-(3,4-디클로로페닐)피롤-5-카보니트릴; 4-클로로-2-(파라-클로로페닐)-5-(트리플루오로메틸)피롤-3-카보니트릴; 4,5-디브로모-2-(파라-클로로페닐)-3-(트리플루오로메틸-설포닐)피롤; 4-브로모-2-(3,5-디클로로페닐)-5-(트리플루오로메틸)피롤-3-카보니트릴; 2-(파라-클로로페닐)-5-(트리플루오로메틸)-4-(트리플루오로메틸티오)피롤-3-카보니트릴; 4-브로모-2-(2,3,4-트리클로로페닐)-5-(트리플루오로메틸)-피롤-3-카보니트릴; 4-브로모-2-(2,3,5-트리클로로페닐)-5-(트리플루오로메틸)-피롤-3-카보니트릴; 4-브로모-2-(파라-클로로페닐)-5-(α,α,β,β-테트라플루오로에틸티오)피롤-3-카보니트릴; 4-브로모-2-(메타-플루오로페닐)-5-(트리플루오로메틸)피롤-3-카보니트릴; 2-(3,5-디클로로페닐)-5-(트리플루오로메틸)-4-(트리플루오로메틸티오)피롤-3-카보니트릴; 및 4-브로모-2-(파라-클로로페닐)-5-[(β-브로모-β,α,α-트리플루오로)-에틸티오]피롤-3-카보니트릴로 이루어진 그룹중에서 선택되는 방법.
  4. 수중 구조물에 방오-유효량의 일반식(Ⅰ)의 화합물을 도포하거나 침투시킴을 특징으로하여, 해수 및 담수 부착성 생물에 의한 오염으로부터 수중 구조물을 보호하는 방법.
    상기 식에서, X는 할로겐, CN, NO2또는 S(O)nR1이고; Y는 수소, 할로겐 또는 S(O)nR1이며; Z는 할로겐, C1-C4할로알킬 또는 S(O)nR1이며; n은 0, 1 또는 2의 정수이며; R1은 C1-C4할로알킬이며; L은 수소 또는 할로겐이며; M 및 Q는 각각 독립적으로 수소, 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4알킬티오, C1-C4알킬설피닐, C1-C4알킬설포닐, CN, NO2, R2CO 또는 NR3R4이거나 M 및 Q가 근접한 위치에 있고 이들이 부착된 탄소원자와 함께 취해질때 MQ는 -OCH2O-, -OCF2O- 또는 -CH=CH-CH=CH-의 구조를 나타내며; R은 수소, C1-C4알콕시알킬, C1-C4알킬티오 또는 R6CO이며; R2는 C1-C4알킬, C1-C4할로알킬, C1-C4알콕시 또는 NR3R4이며; R3는 수소 또는 C1-C4알킬이며; R4는 수소, C1-C4알킬 또는 R5CO이며; R5는 수소 또는 C1-C4알킬이며; R6는 C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C2-C6알케닐옥시, C1-C4할로알콕시, 1 내지 3개의 C1-C4알킬기로 임의로 치환된 페닐, 벤질, 페녹시, 벤질옥시, C1-C4 알킬카보닐옥시, C3-C6 시클로알킬, 나프틸, 피리딜, 티에닐 또는 푸라닐이다.
  5. 제4항에 있어서, 수중 구조물이 어망, 보트, 선박, 적재물, 방파제, 흡입구, 간막이, 냉각탑 파이프 라인 또는 저수탑인 방법.
  6. 제6항에 있어서, 해수 및 담수 부착성 생물이 바나클, 지브라 머슬스, 조류, 규조류, 히드로층, 브리오조아, 아시디안스, 튜브웜 및 아시아 대합조개로 이루어진 그룹중에서 선택되는 방법.
  7. 제4항에 있어서, 일반식(Ⅰ)의 화합물이 4,5-디클로로-2-(α,α,α-트리플루오로-파라-토릴)피롤-3-카보니트릴; 4-브로모-5-클로로-2-(파라-클로로페닐)피롤-3-카보니트릴; 4-브로모-2-(파라-클로로페닐)-5-(트리플루오로메틸)피롤-3-카보니트릴; 3,4-디클로로-2-(3,4-디클로로페닐)피롤-5-카보니트릴; 4-클로로-2-(파라-클로로페닐)-5-(트리플루오로메틸)피롤-3-카보니트릴; 4,5-디브로모-2-(파라-클로로페닐)-3-(트리플루오로메틸-설포닐)피롤; 4-브로모-2-(3,5-디클로로페닐)-5-(트리플루오로메틸)피롤-3-카보니트릴; 2-(파라-클로로페닐)-5-(트리플루오로메틸)-4-(트리플루오로메틸티오)피롤-3-카보니트릴; 4-브로모-2-(2,3,4-트리클로로페닐)-5-(트리플루오로메틸)-피롤-3-카보니트릴; 4-브로모-2-(2,3,5-트리클로로페닐)-5-(트리플루오로메틸)-피롤-3-카보니트릴; 4-브로모-2-(파라-클로로페닐)-5-(α,α,β,β-테트라플루오로에틸티오)피롤-3-카보니트릴; 4-브로모-2-(메타-플루오로페닐)-5-(트리플루오로메틸)피롤-3-카보니트릴; 2-(3,5-디클로로페닐)-5-(트리플루오로메틸)-4-(트리플루오로메틸티오)피롤-3-카보니트릴; 및 4-브로모-2-(파라-클로로페닐)-5-[(β-브로모-β,α,α-트리플루오로)-에틸티오]피롤-3-카보니트릴로 이루어진 그룹중에서 선택되는 방법.
  8. 수중에서 허용되는 불활성 담체 또는 희석제 및 방오-유효량의 일반식(Ⅰ)의 화합물로 이루어짐을 특성으로 하는 해수 및 담수 방오성 조성물.
    상기 식에서, X는 할로겐, CN, NO2또는 S(O)nR1이고; Y는 수소, 할로겐 또는 S(O)nR1이며; Z는 할로겐, C1-C4할로알킬 또는 S(O)nR1이며; n은 0, 1 또는 2의 정수이며; R1은 C1-C4할로알킬이며; L은 수소 또는 할로겐이며; M 및 Q는 각각 독립적으로 수소, 할로겐, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C1-C4알킬티오, C1-C4알킬설피닐, C1-C4알킬설포닐, CN, NO2, R2CO 또는 NR3R4이거나 M 및 Q가 근접한 위치에 있고 이들이 부착된 탄소원자와 함께 취해질 때 MQ는 -OCH2O-, -OCF2O- 또는 -CH=CH-CH=CH-의 구조를 나타내며; R은 수소, C1-C4알콕시알킬, C1-C4알킬티오 또는 R6CO이며; R2는 C1-C4알킬, C1-C4할로알킬, C1-C4알콕시 또는 NR3R4이며; R3는 수소 또는 C1-C4알킬이며; R4는 수소, C1-C4알킬 또는 R5CO이며; R5는 수소 또는 C1-C4알킬이며; R6는 C1-C4알킬, C1-C4할로알킬, C1-C4알콕시, C2-C6알케닐옥시, C1-C4할로알콕시, 1 내지 3개의 C1-C4알킬기로 임의로 치환된 페닐, 벤질, 페녹시, 벤질옥시, C1-C4알킬카보닐옥시, C3-C6시클로알킬, 나프틸, 피리딜, 티에닐 또는 푸라닐이다.
  9. 제8항에 있어서, L이 수소 또는 할로겐이고, M 및 Q가 각각 독립적으로 수소, 할로겐 또는 C1-C4 할로알킬인 조성물.
  10. 제8항에 있어서, 일반식(Ⅰ)의 화합물이 4,5-디클로로-2-(α,α,α-트리플루오로-파라-토릴)피롤-3-카보니트릴; 4-브로모-5-클로로-2-(파라-클로로페닐)피롤-3-카보니트릴; 4-브로모-2-(파라-클로로페닐)-5-(트리플루오로메틸)피롤-3-카보니트릴; 3,4-디클로로-2-(3,4-디클로로페닐)피롤-5-카보니트릴; 4-클로로-2-(파라-클로로페닐)-5-(트리플루오로메틸)피롤-3-카보니트릴; 4,5-디브로모-2-(파라-클로로페닐)-3-(트리플루오로메틸-설포닐)피롤; 4-브로모-2-(3,5-디클로로페닐)-5-(트리플루오로메틸)피롤-3-카보니트릴; 2-(파라-클로로페닐)-5-(트리플루오로메틸)-4-(트리플루오로메틸티오)피롤-3-카보니트릴; 4-브로모-2-(2,3,4-트리클로로페닐)-5-(트리플루오로메틸)-피롤-3-카보니트릴; 4-브로모-2-(2,3,5-트리클로로페닐)-5-(트리플루오로메틸)-피롤-3-카보니트릴; 4-브로모-2-(파라-클로로페닐)-5-(α,α,β,β-테트라플루오로에틸티오)피롤-3-카보니트릴; 4-브로모-2-(메타-플루오로페닐)-5-(트리플루오로메틸(피롤-3-카보니트릴; 2-(3,5-디클로로페닐)-5-(트리플루오로메틸)-4-(트리플루오로메틸티오)피롤-3-카보니트릴; 및 4-브로모-2-(파라-클로로페닐)-5-[(β-브로모-β,α,α-트리플루오로)-에틸티오]피롤-3-카보니트릴로 이루어진 그룹중에서 선택되는 조성물.
    ※ 참고사항 : 최초출원 내용에 의거하여 공개하는 것임.
KR1019960017418A 1995-05-23 1996-05-22 방오제로서피롤화합물의용도 KR100443180B1 (ko)

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