KR960014165A - 아세토아세테이트의 엔아민을 통한 작용성 중합체 제조방법 및 이에 의하여 생성된 중합체 - Google Patents

아세토아세테이트의 엔아민을 통한 작용성 중합체 제조방법 및 이에 의하여 생성된 중합체 Download PDF

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KR960014165A
KR960014165A KR1019940016888A KR19940016888A KR960014165A KR 960014165 A KR960014165 A KR 960014165A KR 1019940016888 A KR1019940016888 A KR 1019940016888A KR 19940016888 A KR19940016888 A KR 19940016888A KR 960014165 A KR960014165 A KR 960014165A
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functional group
functional
acetoacetate
enamine
polymer
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KR1019940016888A
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KR100365104B1 (ko
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찰스 라브와 알빈
토마스 브라운 워드
아서 보르 다니엘
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윌리엄 이. 램버트3세
롬 앤드 하스 캄파니
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Publication of KR960014165A publication Critical patent/KR960014165A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/04—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C251/10—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of an unsaturated carbon skeleton
    • C07C251/12—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of an unsaturated carbon skeleton being acyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/30—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and unsaturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Sealing Material Composition (AREA)

Abstract

본 발명은 반응성 작용기를 갖는 중합체 제조에 관한 것이다.
보다 상세하게는, 본 발명은 작용성 아세토아세테이트기를 함유하는 중합체를 제조한후, 그 아세토아세테이트기와 작용성 아민을 반응하여 엔아민을 형성하는 것에 관한 것이다.
본 발명의 중합체는 코팅제, 밀폐제, 접착제 및 포화제를 포함한 여러가지 용도에 사용되며 물 혹은 물－공용매 혼합물내에서 용액이나 분산물로써 가장 유용한 것이다.

Description

아세토아세테이트의 엔아민을 통한 작용성 중합체 제조방법 및 이에 의하여 생성된 중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 아세토아세테이트 작용성 중합체를 1차 아민 및 최소한 하나의 다른 형태의 작용기를 갖는 화합물과 엔아민 생성에 효과적인 조건에서 반응시킴을 포함하는 작용성 중합체 제조방법.
  2. 아세토아세테이트－작용성 단량체를 1차 아민 및 최소한 하나의 다른 형태의 작용기를 갖는 화합물과 엔아민 생성에 효과적인 조건에서 반응시키는 단계를 포함하는 작용성 단량체 제조방법.
  3. 아세토아세테이트 단량체를 함유하는 단량체 혼합물을 작용기와 혼화되지 조건에서 중합하는 단계; 중합 후 그 아세토아세테이트－작용성 중합체 산물을 1차 아민과 상기 혼화되지 않은 작용기를 갖는 화합물과 엔아민 생성에 효과적인 조건에서 반응시키는 단계;를 포함하는 작용기를 갖는 중합체 제조방법.
  4. 1항 내지 3항 중 어느 한 항에 있어서, 상기 작용기는, 분자량이 약 72∼400,000인, C2∼C18알킬, 알콕시, 및 폴리알콕실 사슬과 같은 2가의 기로 구성되는 그룹에서 선택된 결합기임을 특징으로 하는 공정.
  5. 1항 내지 3항 중 어느 한 항에 있어서, 상기 작용기는 메르캅토에틸아민, 타우린, 3－아미노프로필트리메톡시실란, 3－아미노프로필트리에톡시실란, 폴리옥시프로필렌아민, 폴리옥시에틸렌아민, 2－아미노에틸에틸렌우레아, 2－디메틸아미노에틸아민, 아미노산, 알릴아민 및 4－아미노－2,2,6,6－테트라메틸피페리딘으로 구성되는 그룹에서 선택됨을 특징으로 하는 방법.
  6. 1항 내지 3항 중 어느 한 항에 있어서, 상기 작용성 아민의 양은 아세토아세테이트 작용기의 양을 기준으로 1몰 과량이상에서 1몰 과량이하 범위에 걸쳐 변화될 수 있음을 특징으로 하는 방법.
  7. 아세토아세테이트 작용기의 엔아민을 통해 부착된 메르캅탄 작용기를 갖는 에멀션 중합체.
  8. 아세토아세테이트 작용기의 엔아민을 통해 부착된 알콕시 실란작용기를 갖는 에멀션 중합체.
  9. 아세토아세테이트 작용기의 엔아민을 통해 비닐 중합체에 부착된 올레핀 작용기를 갖는 에멀션 중합체.
  10. 아세토아세테이트 작용기의 엔아민을 통해 부착된 2차 아민 작용기를 갖는 에멀션 중합체.
  11. 내인쇄성 및 내용매성을 갖는, 청구범위 제10항의 에멀션 중합체를 사용한 코팅조성물.
  12. 아세토아세테이트 작용기의 엔아민을 통해 부착된 접착－촉진기를 갖는 에멀션 중합체.
  13. 제7, 8, 9, 10 또는 12항의 중합체를 함유하는 코팅조성물.
  14. 1항 내지 3항 중 어느 한 항에 있어서, 상기 수용성 에멀션 중합체는 아민 작용성 폴리에틸렌 옥사이드를 첨가함으로써 불용성 에멀션 중합체로 부터 제조됨을 특징으로 하는 공정.
  15. 1항 내지 3항 중 어느 한 항에 있어서, 상기 중합체의 Tg는 작용성 아민을 첨가함으로써 조절됨을 특징으로 하는 방법.
  16. 입체적으로 안정화된 라텍스를 제조하기 위하여 아세토아세테이트 작용기의 엔아민을 통해 부착된 폴리에틸렌 옥사이드기를 갖는 에멀션 중합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940016888A 1993-07-14 1994-07-13 아세토아세테이크의엔아민을통한작용성중합체제조방법및이에의하여생성된중합체 KR100365104B1 (ko)

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US08/091,489 US5525662A (en) 1993-07-14 1993-07-14 Functionalization of polymers via enamine of acetoacetate
US091,489 1993-07-14

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KR1020020031571A KR100393405B1 (ko) 1993-07-14 2002-06-05 아세토아세테이트의 엔아민을 통한 작용성 단량체 제조방법

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US (5) US5525662A (ko)
EP (1) EP0634425B1 (ko)
JP (1) JP3787168B2 (ko)
KR (2) KR100365104B1 (ko)
CN (2) CN1051319C (ko)
AU (1) AU687398B2 (ko)
BR (1) BR9402671A (ko)
CA (1) CA2127570A1 (ko)
DE (1) DE69426659T2 (ko)
IL (1) IL110136A (ko)
RU (1) RU94026093A (ko)
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JPH07138317A (ja) 1995-05-30
ZA944717B (en) 1995-01-18
DE69426659T2 (de) 2001-06-21
US5548024A (en) 1996-08-20
CN1238342A (zh) 1999-12-15
CA2127570A1 (en) 1995-01-15
AU6731894A (en) 1995-01-27
BR9402671A (pt) 1995-05-02
KR100393405B1 (ko) 2003-07-31
IL110136A (en) 1999-09-22
US5494975A (en) 1996-02-27
AU687398B2 (en) 1998-02-26
US5494961A (en) 1996-02-27
IL110136A0 (en) 1994-10-07
US5525662A (en) 1996-06-11
CN1102414A (zh) 1995-05-10
US5616764A (en) 1997-04-01
RU94026093A (ru) 1996-05-27
DE69426659D1 (de) 2001-03-15
CN1051319C (zh) 2000-04-12
KR100365104B1 (ko) 2003-03-03
EP0634425A1 (en) 1995-01-18
JP3787168B2 (ja) 2006-06-21

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