KR960010671A - 5h- 페닐-3,13- 디설포네이토디벤조포스폴 및 이의 제조방법 - Google Patents
5h- 페닐-3,13- 디설포네이토디벤조포스폴 및 이의 제조방법 Download PDFInfo
- Publication number
- KR960010671A KR960010671A KR1019950031281A KR19950031281A KR960010671A KR 960010671 A KR960010671 A KR 960010671A KR 1019950031281 A KR1019950031281 A KR 1019950031281A KR 19950031281 A KR19950031281 A KR 19950031281A KR 960010671 A KR960010671 A KR 960010671A
- Authority
- KR
- South Korea
- Prior art keywords
- water
- acid
- sulfuric acid
- process according
- orthoboric
- Prior art date
Links
- 238000002360 preparation method Methods 0.000 title 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract 7
- 229960002645 boric acid Drugs 0.000 claims abstract 7
- 235000010338 boric acid Nutrition 0.000 claims abstract 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 5
- 150000001875 compounds Chemical class 0.000 claims abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 11
- 238000000034 method Methods 0.000 claims 9
- 239000000203 mixture Substances 0.000 claims 4
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims 4
- DLXBFEHIUSAALQ-UHFFFAOYSA-N 1-cyclohexa-1,5-dien-1-yl-5h-benzo[b]phosphindole Chemical compound C1=CCCC=C1C1=CC=CC2=C1C1=CC=CC=C1P2 DLXBFEHIUSAALQ-UHFFFAOYSA-N 0.000 claims 3
- 239000000243 solution Substances 0.000 claims 3
- 150000001412 amines Chemical class 0.000 claims 2
- 239000011230 binding agent Substances 0.000 claims 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- 239000008346 aqueous phase Substances 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000012074 organic phase Substances 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 238000006277 sulfonation reaction Methods 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
- C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
본 발명은 5H-페닐-3, 13-디설포네이토디벤조포스폴 화합물 및 이의 제조방법에 관한 것이다
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 5H-페닐-3, 13-디설포네이토디벤조포스폴 화합물.
- 20 내지 170℃의 온도에서 5H-페닐디벤조포스폴을, 황산과 오르토붕산의 무수 환합물과 반응시큼을 포함하는, 5H-페닐-3, 13-디설포네이토디벤조포스폴의 제조방법.
- 제2항에 있어서, 방응을 60내지 150℃에서 수행하는 방법.
- 제2항 또는 제3항에 있어서, 황산과 오르토붕산의 혼합물에 존재하는 물을 수-결합제의 도움으로 제거하는 방법.
- 제2항 내지 제4항 중 어느 한 항에 있어서, 사용된 수 -결합제가 삼산화황인 방법.
- 제5항에 있어서, 삼산화황이 올레움의 형태로 사용되는 방법.
- 제2항 내지 제6항 중 어느 한 항에 있어서, 무수 황산 중의 용액으로서의 5H-페닐디벤조포스폴이 황산과 오르토붕산의 무수 혼합물내로 도입되는 방법.
- 제2항 내지 제7항 중 어느 한 항에 있어서, 오로토붕산이 5H-페닐디벤조포스폴을 기본으로 등몰량 이상 으로 사용되는 방법.
- 제2항 내지 제8항 중 어느 한 항에 있어서, 황산과 오르토붕산의 무수 혼합물을 오르토붕산으로 포화시키는 방법.
- 제2항 내지 제9항 중 어느 한 항에 있어서, 설폰화 반응 종료후, 반응 혼합물을 존재하는 황산을 0.5내지 50중량%로 희석시키는데 요구되는 양의 물과 혼합하고, 생성된 수용액을 수-불용성 유기 용매 중의 수-불용성 아민 용액(여기서, 아민은 설폰산의 화학적 당량당 0.5내지 3몰이 사용된다)으로 추출하고 유기상을 분리하여 수성 염기 용액과 즉시 접촉시킨 후, 수성상을 분리하며 이로부터 설폰화된 아릴포스핀을 분리시키는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP4435171.2 | 1994-09-30 | ||
| DE4435171A DE4435171A1 (de) | 1994-09-30 | 1994-09-30 | 5-H-Phenyl(di-3,13-sulfonato)dibenzophosphol und ein Verfahren zu seiner Herstellung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR960010671A true KR960010671A (ko) | 1996-04-20 |
| KR100353332B1 KR100353332B1 (ko) | 2002-12-16 |
Family
ID=6529746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019950031281A KR100353332B1 (ko) | 1994-09-30 | 1995-09-22 | 5h-페닐-3,13-디설포네이토디벤조포스폴및이의제조방법 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5637762A (ko) |
| EP (1) | EP0704452B1 (ko) |
| JP (1) | JP2812449B2 (ko) |
| KR (1) | KR100353332B1 (ko) |
| CN (1) | CN1050607C (ko) |
| AT (1) | ATE187457T1 (ko) |
| DE (2) | DE4435171A1 (ko) |
| ES (1) | ES2141876T3 (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19918284C1 (de) * | 1999-04-22 | 2000-12-14 | Celanese Chem Europe Gmbh | Verfahren zur Herstellung von sulfonierten Arylphosphinen |
| CN1075509C (zh) * | 1999-09-09 | 2001-11-28 | 北京化工大学 | 亚膦化合物 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3235030A1 (de) * | 1982-09-22 | 1984-03-22 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von sulfonierten arylphosphinen |
| FR2550202B1 (fr) * | 1983-08-03 | 1986-03-21 | Rhone Poulenc Rech | Procede de preparation de tri(m-sulfophenyl) phosphine |
| DE4220267A1 (de) * | 1992-06-20 | 1993-12-23 | Hoechst Ag | 3,4-Dimethyl-2,5,6-tris(p-sulfonatophenyl)-1-phosphanor-bornadien, Verfahren zu seiner Herstellung und Verfahren zur Hydroformylierung von olefinisch ungesättigten Verbindungen |
-
1994
- 1994-09-30 DE DE4435171A patent/DE4435171A1/de not_active Withdrawn
-
1995
- 1995-09-22 DE DE59507378T patent/DE59507378D1/de not_active Expired - Fee Related
- 1995-09-22 ES ES95114937T patent/ES2141876T3/es not_active Expired - Lifetime
- 1995-09-22 KR KR1019950031281A patent/KR100353332B1/ko not_active IP Right Cessation
- 1995-09-22 EP EP95114937A patent/EP0704452B1/de not_active Expired - Lifetime
- 1995-09-22 AT AT95114937T patent/ATE187457T1/de not_active IP Right Cessation
- 1995-09-27 JP JP7249844A patent/JP2812449B2/ja not_active Expired - Lifetime
- 1995-09-28 CN CN95117296A patent/CN1050607C/zh not_active Expired - Fee Related
- 1995-10-02 US US08/538,012 patent/US5637762A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2141876T3 (es) | 2000-04-01 |
| DE59507378D1 (de) | 2000-01-13 |
| DE4435171A1 (de) | 1996-04-04 |
| EP0704452B1 (de) | 1999-12-08 |
| US5637762A (en) | 1997-06-10 |
| JP2812449B2 (ja) | 1998-10-22 |
| EP0704452A1 (de) | 1996-04-03 |
| JPH08198887A (ja) | 1996-08-06 |
| KR100353332B1 (ko) | 2002-12-16 |
| CN1050607C (zh) | 2000-03-22 |
| ATE187457T1 (de) | 1999-12-15 |
| CN1129221A (zh) | 1996-08-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR8304994A (pt) | Processo de preparacao de arilsfosfinas mono-,di-ou tri-sulfonadas | |
| KR960010667A (ko) | 설폰화 포스핀, 이의 제조방법 및 촉매계 성분으로서의 이의 용도 | |
| KR960010671A (ko) | 5h- 페닐-3,13- 디설포네이토디벤조포스폴 및 이의 제조방법 | |
| KR950000718A (ko) | 설폰화 아릴포스핀의 제조방법 | |
| JPS54151956A (en) | Production of 2-carboxyanthraquinonemonosulfonic acid and its salt and oxidation and reduction reagent therefrom for wet desulfurization | |
| US2854476A (en) | Method of sulfonation with a sulfur trioxide addition product | |
| DK0430352T3 (da) | Fremgangsmåde til renfremstilling af paraffinsulfonsyrer | |
| GB903976A (en) | Production of dinonylnaphthalene sulfonates | |
| US2098114A (en) | Process for sulphonating alcohols | |
| GB1089136A (en) | Improvements relating to the production of sulphonic acids | |
| KR920012101A (ko) | 수용성 디포스핀의 제조방법 | |
| FR2398722A1 (fr) | Perfectionnements a la preparation de solutions aqueuses de sels alcalins de l'acide 2-hydroxy-1-naphtalenesulfonique | |
| ES532506A0 (es) | Procedimiento para desensibilizar acidos peroxicarboxilicos alifaticos o aromaticos, insolubles en agua | |
| Kelly | Sulfur trioxide-amine adducts | |
| Burkhardt | CCCXII.—The action of fuming sulphuric acid on hexane, cyclo hexane, and some of their derivatives | |
| JPS5498738A (en) | Method of sulfonation | |
| KR910011875A (ko) | 술폰화 프로필페닐포스핀, 이의 제조방법 및 용도 | |
| Truce et al. | Sulfonation of β-Bromostyrene | |
| ATE257T1 (de) | Verfahren zur herstellung von naphthalin-1,3,5-trisulfonsaeure. | |
| KR890012950A (ko) | 불포화 지방산 저급 알킬 에스테르 술포네이트의 제조방법 | |
| DK229088D0 (da) | Fremgangsmaade til fremstilling af propanon-1,3-disulfonsyre | |
| Cerfontain et al. | Sulfonation and sulfation in the reaction of 4-methylphenol with concentrated sulfuric acid | |
| GB1043043A (en) | Process for making substituted diphenyl ether sulfonates | |
| GB485649A (en) | Washing preparations | |
| GB679185A (en) | Process for the manufacture of alkyl benzene sulphochlorides |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| N231 | Notification of change of applicant | ||
| A201 | Request for examination | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| LAPS | Lapse due to unpaid annual fee |