KR960004371A - 개선된(메트)아크롤레인 함유 중합체 제조방법 - Google Patents

개선된(메트)아크롤레인 함유 중합체 제조방법 Download PDF

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Publication number
KR960004371A
KR960004371A KR1019950000130A KR19950000130A KR960004371A KR 960004371 A KR960004371 A KR 960004371A KR 1019950000130 A KR1019950000130 A KR 1019950000130A KR 19950000130 A KR19950000130 A KR 19950000130A KR 960004371 A KR960004371 A KR 960004371A
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KR
South Korea
Prior art keywords
meth
copolymer
acrolein
weight
dioxolane
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KR1019950000130A
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English (en)
Inventor
마리 레스코 페트리시아
페어허스트 로랜드
Original Assignee
스탠리 제이. 하머
롬 앤드 하스 캄파니
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Application filed by 스탠리 제이. 하머, 롬 앤드 하스 캄파니 filed Critical 스탠리 제이. 하머
Publication of KR960004371A publication Critical patent/KR960004371A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/12—Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42—Nitriles
    • C08F220/44—Acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Polymerisation Methods In General (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

(1)공중합체의 총중량을 기준으로(메트)아크릴레인의 아세탈 유도체 약 0.1∼25중량%와 공중합체의 총중량을 기준으로 최소 하나의 α,β-에틸렌계 불포화 공단량체 약 75∼99.9중량%를 에멀젼 중합하는 단계; 및 (2) 상기 (메트)아크릴레인의 아세탈 유도체가 (메트)아크롤레인으로 가수분해 되도록 상기 공중합체의 pH를 약 5미만으로 조절하는 단계; 에 의한 에멀젼 공중합체 제조방법이 개시된다.
본 발명에 의한 방법으로 형성된(메트)아크롤레인의 에멀젼 공중합체는 단량체의 취급 및 운반도중 안정성 및 건강상의 문제가 없으며, 특성은 통상적인 중합법으로 제조한 공중합체와 동일함을 나타낸다.

Description

개선된(메트)아크롤레인 함유 중합체 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. (a)공중합체의 총중량을 기준으로(메트)아크릴레인의 아세탈 유도체 약 0.1∼25중량%와 공중합체의 총중량을 기준으로 최소 하나의 α,β-에틸렌계 불포화 공단량체 약 75∼99.9중량%로부터 공중합체를 에멀젼 중합하는 단계; 및 (b) 상기 (메트)아크릴레인의 아세탈 유도체가 (메트)아크롤레인으로 가수분해되도록 상기 공중합체의 pH를 약 5미만으로 조절하는 단계; 를 포함하는 (메트)아크롤레인의 에멀젼 공중합체 제조방법.
  2. 제1항에 있어서, 상기 (메트)아크롤레인의 아세탈 유도체는 2-비닐-1,3-디옥솔란, 2-비닐-4-메틸-1,3-디옥솔란, 3,3-디메톡시-1-프로펜, 3,3-디에톡시-1-프로펜, 3,3-디에톡시-2-메틸-1-프로펜, 2-이소프로페닐-1,3-디옥솔란 및 2-이소프로페닐-4-메틸-1,3-디옥솔란으로 구성되는 그룹으로부터 선택됨을 특징으로 하는 방법.
  3. 제1항에 있어서, 상기 (메트)아크롤레인의 아세탈은 2-비닐-1,3-디옥솔란임을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950000130A 1994-07-11 1995-01-06 개선된(메트)아크롤레인 함유 중합체 제조방법 KR960004371A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8/273,259 1994-07-11
US08/273,259 US5412041A (en) 1994-07-11 1994-07-11 Method for forming (meth)acrolein-containing polymers

Publications (1)

Publication Number Publication Date
KR960004371A true KR960004371A (ko) 1996-02-23

Family

ID=23043204

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950000130A KR960004371A (ko) 1994-07-11 1995-01-06 개선된(메트)아크롤레인 함유 중합체 제조방법

Country Status (9)

Country Link
US (1) US5412041A (ko)
EP (1) EP0692497B1 (ko)
KR (1) KR960004371A (ko)
CN (1) CN1181112C (ko)
AU (1) AU681466B2 (ko)
BR (1) BR9405328A (ko)
DE (1) DE69412081T2 (ko)
ES (1) ES2120580T3 (ko)
RU (1) RU95100776A (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AUPN327695A0 (en) * 1995-05-30 1995-06-22 Chemeq Pty. Limited Chemotherapeutic compositions
JP3798112B2 (ja) 1996-04-30 2006-07-19 ヒューレット・パッカード・カンパニー 低温硬化結合剤
TWI234567B (en) * 1998-11-27 2005-06-21 Hyundai Electronics Ind Cross-linker for photoresist, and photoresist composition comprising the same
KR100533379B1 (ko) * 1999-09-07 2005-12-06 주식회사 하이닉스반도체 유기 난반사 방지막용 조성물과 이의 제조방법
KR100359862B1 (ko) * 1999-12-23 2002-11-09 주식회사 하이닉스반도체 난반사 방지막용 중합체와 그 제조방법
KR100549574B1 (ko) * 1999-12-30 2006-02-08 주식회사 하이닉스반도체 유기 반사 방지막용 중합체 및 그의 제조방법

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3260710A (en) * 1962-06-28 1966-07-12 Standard Oil Co Lubricant additives comprising copolymers of alkenes with acetals or ketals
DE1297864B (de) * 1963-03-23 1969-06-19 Albert Ag Chem Werke Verfahren zur Herstellung von Mischpolymerisaten
CH469749A (de) * 1965-03-24 1969-03-15 Ciba Geigy Verfahren zur Herstellung von stabilen wässerigen Dispersionen von ternären Mischpolymerisaten und ihre Verwendung
US3449277A (en) * 1966-02-03 1969-06-10 Gulf Oil Corp Coating compositions comprising drying oil acid esters of styrene-acrolein copolymer-polymer reaction products
US3896085A (en) * 1971-07-06 1975-07-22 Rohm & Haas Emulsion copolymers of acrolein and their use in treating leather
DE2332562A1 (de) * 1973-06-27 1975-01-23 Agfa Gevaert Ag Photographisches material mit ver besserten eigenschaften
JPS57177003A (en) * 1981-04-24 1982-10-30 Sanyo Chem Ind Ltd Preparation of water-soluble copolymer
US4851583A (en) * 1988-01-04 1989-07-25 Betz Laboratories, Inc. Method of generating acrolein
US5079266A (en) * 1988-01-04 1992-01-07 Betz Laboratories, Inc. Method of generating acrolein
DE3834435A1 (de) * 1988-10-10 1990-06-13 Basf Ag Verbrueckte, wasserloesliche copolymerisate, verfahren zu ihrer herstellung und ihre verwendung
US5019635A (en) * 1990-03-23 1991-05-28 Eastman Kodak Company Copolymers of dioxolanes and maleic anhydride
JPH0467151A (ja) * 1990-07-09 1992-03-03 Fuji Photo Film Co Ltd 電子写真式平版印刷用原版

Also Published As

Publication number Publication date
CN1118356A (zh) 1996-03-13
CN1181112C (zh) 2004-12-22
BR9405328A (pt) 1996-05-28
US5412041A (en) 1995-05-02
EP0692497A1 (en) 1996-01-17
DE69412081T2 (de) 1999-04-15
EP0692497B1 (en) 1998-07-29
AU8177994A (en) 1996-01-25
DE69412081D1 (de) 1998-09-03
AU681466B2 (en) 1997-08-28
RU95100776A (ru) 1996-10-27
ES2120580T3 (es) 1998-11-01

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