KR960001050A - 알루미늄 산화 피막의 충전 착색용 안료 분산 조성물 - Google Patents

알루미늄 산화 피막의 충전 착색용 안료 분산 조성물 Download PDF

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KR960001050A
KR960001050A KR1019950014477A KR19950014477A KR960001050A KR 960001050 A KR960001050 A KR 960001050A KR 1019950014477 A KR1019950014477 A KR 1019950014477A KR 19950014477 A KR19950014477 A KR 19950014477A KR 960001050 A KR960001050 A KR 960001050A
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pigment
dispersion composition
pigment dispersion
oxide film
particle diameter
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KR1019950014477A
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English (en)
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KR100375280B1 (ko
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히로시 이노우에
시게야스 이노우에
세이시로 이또
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니시무라 데이이찌
가부시끼가이샤 사쿠라 크레파스
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Priority claimed from JP12141494A external-priority patent/JP3410548B2/ja
Priority claimed from JP28459694A external-priority patent/JP3512871B2/ja
Priority claimed from JP28459794A external-priority patent/JP3512872B2/ja
Application filed by 니시무라 데이이찌, 가부시끼가이샤 사쿠라 크레파스 filed Critical 니시무라 데이이찌
Publication of KR960001050A publication Critical patent/KR960001050A/ko
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Publication of KR100375280B1 publication Critical patent/KR100375280B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0084—Dispersions of dyes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/006—Preparation of organic pigments
    • C09B67/0066—Aqueous dispersions of pigments containing only dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02—Anodisation
    • C25D11/04—Anodisation of aluminium or alloys based thereon
    • C25D11/18—After-treatment, e.g. pore-sealing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31692—Next to addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31692—Next to addition polymer from unsaturated monomers
    • Y10T428/31699—Ester, halide or nitrile of addition polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Paints Or Removers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

본 발명은 알루미늄 또는 알루미늄 합금의 표면을 피복하는 산화 피막에 다수 분포하는 세공의 직경을 확대처리하여 50 내지 250nm의 크기로 하고, 이 확대된 세공에 전기 영동법으로 안료를 충전하기 위한 안료 분산조성물이다. 안료 분산 조성물은 퀴나크리돈계, 페리논계, 피릴렌계, 디옥사진계, 이소인돌리논계, 이소인돌린계, 퀴노프탈론계, 안트라퀴논계, 피롤로피롤계, 티오인디고계 및 금속 착체계 등의 축합 다환 안료, 프탈로시아닌계 안료, 축합 아조계 등의 유기 안료, 카본 블랙, 산화티탄 및 산화규소 등의 무기안료로부터 선택된 안료, 수용성 수지, 고분자 물질, 산 또는 염기로 중화시킴으로써 수용성이 되는 고분자 화합물 또는 호제로부터 선택된 안료 분산제 및 물을 적어도 포함하고, 안료 분산 조성물 중의 안료 입자는 그 입자 직경 분포에 있어서 체눈의 크기가 300nm인 체를 통과하지 못하는 양이 안료 전체의 30%이하, 입자 직경이 작은 분획으로부터 누계하여 안료 전체의 50%가 되는 점에서의 입자 직경을 250nm이하로 한다. 이로 인해 알루미늄 양극 산화 피막의 충전 착색에 바람직하게 사용되고, 반복 착색성이 우수하며, 안료 분산 조성물로서 유용하다.

Description

알루미늄 산화 피막의 충전 착색용 안료 분산 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 알루미늄 또는 알루미늄 합금의 표면을 피복하는 산화 피막중에 존재하는 크기 50 내지 250nm의 세공에 전기 영동으로 충전 착색하기 위한 안료 분산조성물로서, 이 안료 분산조성물은 적어도 안료, 안료 분산제 및 물을 포함하여 이루어지고, 이 안료 분산조성물 중의 상기 안료의 입자 직경 분포에 있어서 누적 분포의 50%가 되는 점의 입자 직경이 250nm이하이고, 체눈의 크기가 300nm인 체를 통과하지 못하는 양(광학적 측정치)이 30%이하인 것인 알루미늄 산화 피막의 충전 착색용 안료 분산조성물.
  2. 제1항에 있어서, 상기안료는 무기물 입자, 유기 화합물 입자, 합성 수지 입자 및(또는) 이들의 착색물인 것인 알루미늄 산화 피막의 충전 착색용 안료 분산조성물.
  3. 제1항 또는 제2항에 있어서, 상기 안료 분산조성물은 적어도 퀴나크리돈계, 안트라퀴논계, 디케토피롤로피롤계, 페릴렌계, 페리논계 화합물 또는 그의 유도체로 이루어진 군으로부터 선택되는 비표면적이 30 내지 100㎡/g인 1종 또는 2종 이상의 적색계 안료, 안료 분산제 및 물을 포함하여 이루어지고, 안료 분산조성물 중의 안료의 입자 직경 분포에 있어서 누적 분포의 50%가 되는 점의 입자 직경이 200nm이하인 것인 알루미늄 산화 피막의 충전 착색용 안료 분산조성물.
  4. 제1항 또는 제2항에 있어서, 상기 안료 분산조성물은 적어도 비표면적이 45 내지 100㎡/g인 프탈로시아닌계 화합물 또는 그의 유도체인 안료, 안료 분산제 및 물을 포함하여 이루어지고, 안료 분산조성물 중의 안료의 입자 직경 분포에 있어서 누적 분포의 50%가 되는 점의 입자 직경이 200nm이하인 것인 알루미늄 산화 피막의 충전 착색용 안료 분산조성물.
  5. 제1항, 2항, 3항 또는 4항에 있어서, 상기 안료 분산제가 수용성 고분자 화합물인 것인 알루미늄 산화 피막의 충전 착색용 안료 분산조성물.
  6. 제1항 내지 5항 중 어느 한 항에 있어서, 상기 안료 분산제가 α-에틸렌 또는 β-에틸렌 결합을 갖는 화합물 1종 또는 2종 이상의 중합체 또는 그의 변성체인 것인 알루미늄 산화 피막의 충전 착색용 안료 분산조성물.
  7. 제1항 내지 6항 중 어느 한 항에 있어서, 상기 안료 분산조성물 중의 안료의 제타(zeta)전위가-10mV이하인 것인 알루미늄 산화 피막의 충전 착색용 안료 분산조성물.
  8. 제1항 내지 7항 중 어느 한 항에 있어서, 협잡 이온의 함유량이 1000ppm 이하인 것인 알루미늄 산화 피막의 충전 착색용 안료 분산조성물.
  9. 알루미늄 또는 알루미늄 합금의 표면을 피복하는 산화 피막에 존재하는 크기, 50 내지 250nm의 세공에 전기 영동에 의해 제1항 내지 8항 중 어느 한 항에 기재된 안료 분산 조성물을 충전 착색한 알루미늄 또는 알루미늄 합금 재료.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950014477A 1994-06-02 1995-06-01 알루미늄산화피막의충전착색용안료분산조성물 KR100375280B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP94-121414 1994-06-02
JP12141494A JP3410548B2 (ja) 1994-06-02 1994-06-02 アルミニウム又はアルミニウム合金酸化皮膜の充填着色用顔料分散体
JP28459694A JP3512871B2 (ja) 1994-10-11 1994-10-11 アルミニウム又はアルミニウム合金酸化皮膜の充填着色用フタロシアニン系顔料分散体
JP94-284597 1994-10-11
JP28459794A JP3512872B2 (ja) 1994-10-11 1994-10-11 アルミニウム又はアルミニウム合金酸化皮膜の充填着色用赤色系顔料分散体
JP94-284596 1994-10-11

Publications (2)

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KR960001050A true KR960001050A (ko) 1996-01-25
KR100375280B1 KR100375280B1 (ko) 2003-04-23

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Country Status (6)

Country Link
US (1) US5585189A (ko)
EP (1) EP0685540B1 (ko)
KR (1) KR100375280B1 (ko)
CN (1) CN1045980C (ko)
DE (1) DE69522374T2 (ko)
TW (1) TW311925B (ko)

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Publication number Publication date
DE69522374D1 (de) 2001-10-04
CN1116637A (zh) 1996-02-14
KR100375280B1 (ko) 2003-04-23
EP0685540B1 (en) 2001-08-29
US5585189A (en) 1996-12-17
EP0685540A3 (en) 1997-07-02
DE69522374T2 (de) 2002-05-23
TW311925B (ko) 1997-08-01
EP0685540A2 (en) 1995-12-06
CN1045980C (zh) 1999-10-27

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