KR950703039A - 에틸렌디아민-n,n′-디석신산에 의해 안정화된, 적층 실리케이트 증강제 및 퍼카보네이트를 함유하는 세제 표백제 조성물(detergent bleach compositions containing layered silicate builder and percarbonate stabilized by edds) - Google Patents

에틸렌디아민-n,n′-디석신산에 의해 안정화된, 적층 실리케이트 증강제 및 퍼카보네이트를 함유하는 세제 표백제 조성물(detergent bleach compositions containing layered silicate builder and percarbonate stabilized by edds) Download PDF

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KR950703039A
KR950703039A KR1019950700421A KR19950700421A KR950703039A KR 950703039 A KR950703039 A KR 950703039A KR 1019950700421 A KR1019950700421 A KR 1019950700421A KR 19950700421 A KR19950700421 A KR 19950700421A KR 950703039 A KR950703039 A KR 950703039A
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composition
weight
percarbonate
ethylenediamine
stabilized
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KR100290329B1 (ko
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크롬비 에디슨 마이클
앨런 제이. 모쓰 마이클
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자코버스 코넬리스 라써
더 프록터 앤드 갬블 캄파니(The Procter And Gamble Company)
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
    • C01B15/10—Peroxyhydrates; Peroxyacids or salts thereof containing carbon
    • C01B15/106—Stabilisation of the solid compounds, subsequent to the preparation or to the crystallisation, by additives or by coating
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937—Stabilising agents
    • C11D3/394—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Slide Fasteners, Snap Fasteners, And Hook Fasteners (AREA)

Abstract

에틸렌디아민-N,N′-디석신산 또는 이의 염, 알칼리 금속 퍼카보네이트 표백제 및 일반식 LmSixO2×H. yH2O의 결정성 적층 나트륨 실리케이트(여기서, L은 알칼리 금속이고, M은 나트륨 또는 수소이며, X는 1.9 내지 4의 수이고 y는 0 내지 20의 수이다)를 포함하는 세제 조성물이 제공된다. 또한, 본 조성물을 바람직하게는 추가의 비-포스페이트 세제 중강제 화합물을 포함한다.

Description

에틸렌디아민-N,N′-디석신산에 의해 안정화된, 적층 실리케이트 증강제 및 퍼카보네이트를 함유하는 세제 표백제 조성물(DETERGENT BLEACH COMPOSITIONS CONTAINING LAYERED SILICATE BUILDER AND PERCARBONATE STABILIZED BY EDDS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. (a)일반식 LMSixO2×H. yH2O의 결정성 적층 실리케이트 증강제 물질(여기서, L은 알칼리 금속이고 M은 나트륨 또는 수소이며, X는 1.9 내지 4의 수이고 y는 0 내지 20의 수이다) 1 내지 80중량%; (b) 알칼리 금속 퍼카보네이트 표백제 3 내지 40중량%; 및 (c) 에틸렌디아민-N,N′-디석신산, 이의 알칼리 금속, 알칼리 토금속, 암모늄 또는 치환된 암모늄 염, 또는 이들의 혼합물 0.05 내지 10중량%를 포함하는 세제 조성물.
  2. 제1항에 있어서, 에틸렌디아민-N,M′-디석신산 성분이 이의 [S,S] 이성체 형태로 존재하는 조성물.
  3. 제1항 또는 제2항에 있어서, 에틸렌디아민-N,N′-디석신산 성분이 마그네슘 염 형태로 존재하는 조성물.
  4. 제1항 내지 제3항 중의 어느 한 항에 있어서, 결정성 적층 실리케이트 물질이 σ-Na2Si2O5(Na SKS-6)인 조성물.
  5. 제1항 내지 제4항 중이 어느 한 항에 있어서, (a) 음이온성 계면활성제, 비이온성 제면활성제, 쯔비터이온성 계면활성제, 양쪽성 계면활성제, 양이온성 계면활성제 및 이들의 혼합물 중에서 선택된 세제 계면활성제 3 내지 30중량%; 및 (b) 추가의 비-포스페이트 세제 증강제 화합물 0 내지 70중량%를 함유하는 조성물.
  6. 제1항 내지 제5항 중의 어느 한 항에 있어서, 음이온성 계면활성제가 C13-C20알킬 설페이트 염과 1mol당 평균 1 내지 7개의 에톡시 그룹을 함유하는 수용성 C11-C19알킬 에톡시설페이트 염의 혼합물(이때, 알킬 에톡시페이트 염에 대한 알킬 설페이트 염의 중량비는 2 : 1 내지 19 : 1의 범위이다)을 포함하는 조성물.
  7. 제6항에 있어서, 알킬 설페이트 염이 C14-C15알킬 설페이트 염이고, 알킬 에톡시설페이트 염이 1mol당 평균 3개의 에톡시 그룹을 함유하는 C12-C15알킬 에톡시설페이트 염이며, 이때 중량비가 3.5 : 1 내지 10 : 1 범위인 조성물.
  8. 제1항 내지 제7항 중의 어느 한 항에 있어서, 비이온성 계면활성제가 일반식의 폴리하드록시 지방산 아미드(여기서, R1은 H, C1-C4하이드로카빌, 2-하이드록시에틸, 2-하이드록시 프로필 또는 이들의 혼합물이고, R2는 C5-C31하이드로카빌이며, Z는 선형 탄화수소 쇄에 3개 이상의 하이드록시 그룹이 직접 결합되어 있는 폴리하이드록시하이드로카빌 또는 이의 알콕실화 유도체이다)인 조성물.
  9. 제1항 내지 제8항 중의 어느 한 항에 있어서, 비이온성 계면활성제가 알콜 1mol당 평균 3 내지 8mol의 에틸렌 옥사이드를 함유하는 C9-C151급 알콜 에톡실레이트인 조성물.
  10. 제9항에 있어서, 1급 알콜 에톡실레이트가 알콜 1mol당 평균 3 내지 8mol의 에틸렌 옥사이드를 함유하는 C12-C151급 알콜인 조성물.
  11. 제1항 내지 제10항 중의 어느 한 항에 있어서 추가의 비-포스페이트 증강제 화합물이 나트륨 알루미노실리케이트 제올라이트, 알칼리 금속 카보네이트 및 바이카보네이트, 카복실레이트 및 폴리카복실레이트, 및 말레산 무수물/아크릴산 공중합체 중에서 선택되는 조성물.
  12. 제1항 내지 제11항 중의 어느 한항에 있어서, 결정성 적응 실리케이트 증강제 물질 7 내지 20중량% 및 추가의 비-포스페이트 증강제 화합물 10 내지 40중량%를 포함하는 조성물.
  13. 제1항 내지 제12항 중의 어느 한 항에 있어서, 고체 퍼옥시산 표백제 전구체 1 내지 20중량%를 함유하는 조성물.
  14. 제13항에 있어서, 알칼리 금속 퍼카보네이트 표백제가 조성물의 5 내지 30중량%의 양으로 존재하는 나트륨 퍼카보네이트이고, 고체 퍼옥시산 표백제 전구체가 조성물의 1 내지 10중량%의 양으로 존재하는 TAED인 조성물.
  15. 제1항 내지 제14항 중의 어느 한 항에 있어서, 유기 퍼옥시산 1 내지 10중량%를 함유하는 조성물.
  16. 제1항 내지 제15항 중의 어느 한 항에 있어서, 세제 효소, 오염물 현탁 및 재부착방지제, 형광증백제, 거품 억제제, 향료 및 이들의 혼합물 중에서 선택된 추가의 세제 성분을 포함하는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950700421A 1992-08-01 1993-07-21 에틸렌디아민-n,n-디석신산에의해안정화된,적층실리케이트빌더와퍼카보네이트표백제를함유하는세제조성물 KR100290329B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB929216410A GB9216410D0 (en) 1992-08-01 1992-08-01 Detergent compositions
GB9216410.2 1992-08-01
PCT/US1993/006877 WO1994003554A1 (en) 1992-08-01 1993-07-21 Detergent bleach compositions containing layered silicate builder and percarbonate stabilized by edds

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KR950703039A true KR950703039A (ko) 1995-08-23
KR100290329B1 KR100290329B1 (ko) 2001-10-22

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DE (1) DE69330755T2 (ko)
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DE3526405A1 (de) * 1985-07-24 1987-02-05 Henkel Kgaa Schichtsilikate mit beschraenktem quellvermoegen, verfahren zu ihrer herstellung und ihre verwendung in wasch- und reinigungsmitteln
US4704233A (en) * 1986-11-10 1987-11-03 The Procter & Gamble Company Detergent compositions containing ethylenediamine-N,N'-disuccinic acid
DE3812556A1 (de) * 1988-04-15 1989-10-26 Hoechst Ag Waschmittel mit lagerstabilisiertem bleichsystem
DE3929896A1 (de) * 1989-09-08 1991-03-14 Hoechst Ag Geschirrspuelmittel
CA2096255C (en) * 1990-11-14 1998-01-20 Jeffrey D. Painter Nonphosphated automatic dishwashing compositions with oxygen bleach systems and process for their preparation
GB9216408D0 (en) * 1992-08-01 1992-09-16 Procter & Gamble Stabilized bleaching compositions

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AU4779793A (en) 1994-03-03
DE69330755D1 (de) 2001-10-18
JP3534755B2 (ja) 2004-06-07
GB9216410D0 (en) 1992-09-16
MA22948A1 (fr) 1994-04-01
WO1994003554A1 (en) 1994-02-17
TW284784B (ko) 1996-09-01
ATE205520T1 (de) 2001-09-15
DE69330755T2 (de) 2002-07-04
CA2141609C (en) 1998-12-22
MX9304668A (es) 1994-03-31
JPH07509527A (ja) 1995-10-19
EP0652925B1 (en) 2001-09-12
CA2141609A1 (en) 1994-02-17
EP0652925A1 (en) 1995-05-17
EP0652925A4 (en) 1998-10-07
KR100290329B1 (ko) 2001-10-22
AU667398B2 (en) 1996-03-21
ES2160104T3 (es) 2001-11-01
CN1084554A (zh) 1994-03-30
CN1047624C (zh) 1999-12-22
IN187081B (ko) 2002-01-26

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