KR950032561A - 방수 조성물 - Google Patents

방수 조성물 Download PDF

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Publication number
KR950032561A
KR950032561A KR1019950011863A KR19950011863A KR950032561A KR 950032561 A KR950032561 A KR 950032561A KR 1019950011863 A KR1019950011863 A KR 1019950011863A KR 19950011863 A KR19950011863 A KR 19950011863A KR 950032561 A KR950032561 A KR 950032561A
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South Korea
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alkyl radical
carbon atoms
parts
silane coupling
alkoxysilane
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KR1019950011863A
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KR100333152B1 (ko
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앤 스타크-캐슬리 로리
조셉 포파 폴
매튜 젠틀 토마스
얼 하우엔슈타인 데일
데니스 케넌 린다
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노먼 에드워드 루이스
다우 코닝 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
    • C04B41/4922—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane
    • C04B41/4944—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane containing atoms other than carbon, hydrogen, oxygen, silicon, alkali metals or halogens, e.g. N-silyldisilazane: Image
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61—Coating or impregnation
    • C04B41/62—Coating or impregnation with organic materials
    • C04B41/64—Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09D123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C09D123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Paints Or Removers (AREA)
  • Colloid Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

본 발명은 셀룰로즈 또는 석재 표면이 방수성을 지니도록 처리하기에 적합한 수성 유액에 관한 것이다. 본 발명의 조성물은, (i)일반식 RnSi(OR′)4-n의 알콕시실란[여기서 ,R은 알킬 라디칼, 알케닐 라디칼, 폐닐, 클로로프로필 또는 트리플루오로프로필이고, n은 1또는 2이며, R′는 탄소수 1내지 6의 알킬 라디칼이다.](ii) 일반식 R″mR pSi(OR′)4-m-p의 실란 커플링제[여기서, R″는 아미노 또는 4급 암모늄 유기 작용성 그룹으로 이루어진 그룹중에서 선택되고, R는 탄소수 1내지 4의 알킬라디칼이며, R′는 상술한 바와 같은 의미이고, m은 1또는 2이며, p는 0또는 1이고, 단 m+p는 2이하이다.]및 (ⅲ)폴리이소부틸렌 중합체를 포함하며, 이때 알콕시실란(i) 대 실란커플링체(ⅱ)의 몰비는 0.5:1 내지 3:1이다.
본 발명의 바람직한 유액은 왁스 성분을 추가로 포함한다.

Description

방수 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. (i)일반식 RnSi(OR′)4-N의 알콕시실란[여기서, R은 탄소수 1내지 10의 알킬 라디칼, 탄소수 2 내지 8의 알케닐 라디칼, 페닐 클로로프로필 및 트리플루오로프로필로 이루어진 그룹중에서 선택되고, n은 1또는 2이며, R′는 탄소수 1내지 6의 알킬 라디칼이다.] (ⅱ) 일반식 R˝mR pSi(OR′)4-M-P의 실란 커플링제 [여기서, R″는 이미노 또는 4급 암모늄 유기 작용성 그룹으로 이루어진 그룹중에서 선택되고, R는 탄소수 1내지 4의 알킬 라디칼이며, R′는 상술한 바와 같은 의미이고, m은 1또는 2이며, p는 0또는 1이고, 단 m+p는 2이하이다] 및 (ⅲ)폴리이소부틸렌 중합체를 포함하며, 이때 성분 (i)의 알콕시실란 대 성분(ⅱ)의 실란커플링체의 몰비가 0.5:1 내지 3:1이고, 성분 (ⅲ)의 폴리이소부틸렌 증합체의 함량이 성분(i)과 성분(ⅱ)의 총 100중량부당 10 내지 300중량부인 수성 유액.
  2. 제1항에 있어서 (ⅳ) 왁스를, 성분(i)과 성분 (ⅱ)의 총 100중량 부당, 5내지 1.500 중량부의 함량으로 추가로 포함하는 유액.
  3. 제1항 또는 제2항에 따른 유액을 표면에 적용함을 포함하여, 표면이 방수 특성을 지니도록 표면을 처리하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950011863A 1994-05-16 1995-05-15 방수조성물및이를사용한표면처리방법 KR100333152B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/242,982 US5421866A (en) 1994-05-16 1994-05-16 Water repellent compositions
US08/242,982 1994-05-16
US08/242982 1994-05-16

Publications (2)

Publication Number Publication Date
KR950032561A true KR950032561A (ko) 1995-12-22
KR100333152B1 KR100333152B1 (ko) 2002-11-20

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US (1) US5421866A (ko)
EP (1) EP0683022B1 (ko)
JP (1) JP3819453B2 (ko)
KR (1) KR100333152B1 (ko)
CA (1) CA2148664C (ko)
DE (1) DE69512827T2 (ko)
DK (1) DK0683022T3 (ko)
FI (1) FI952357A (ko)
NO (1) NO309152B1 (ko)

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US5051129A (en) * 1990-06-25 1991-09-24 Dow Corning Corporation Masonry water repellent composition
US5209775A (en) * 1992-01-23 1993-05-11 Dow Corning Corporation Water repellents containing organosilicon compounds
US5205860A (en) * 1992-01-23 1993-04-27 Dow Corning Corporation Water repellents containing organosilicon compounds
US5300327A (en) * 1993-03-22 1994-04-05 Dow Corning Corporation Water repellent organosilicon compositions

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EP0683022A3 (en) 1996-12-04
CA2148664A1 (en) 1995-11-17
DE69512827D1 (de) 1999-11-25
CA2148664C (en) 2005-01-25
EP0683022A2 (en) 1995-11-22
DK0683022T3 (da) 1999-12-27
EP0683022B1 (en) 1999-10-20
NO951704D0 (no) 1995-05-03
US5421866A (en) 1995-06-06
NO309152B1 (no) 2000-12-18
JPH0847633A (ja) 1996-02-20
FI952357A (fi) 1995-11-17
JP3819453B2 (ja) 2006-09-06
KR100333152B1 (ko) 2002-11-20
DE69512827T2 (de) 2000-06-15
NO951704L (no) 1995-11-17
FI952357A0 (fi) 1995-05-15

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